Organocatalytic cascade reaction of aliphatic enals and benzoylnitromethane: synthesis of enantioenriched tetrasubstituted cyclohexene carbaldehyde

A new example of the reactivity of enals with benzoylnitromethane was studied in a Michael-Michael-Aldol-Dehydration quadruple organocascade reaction. The reaction unexpectedly yielded a tetrasubstituted cyclohexene carbaldehyde with excellent enantiomeric excess when crotonaldehyde was used as the...

Full description

Autores:

David Rodriguez, Fredy A.
Maldonado Villamil, Mauricio
Guevara Pulido, James

Tipo de recurso:

Article of journal

Fecha de publicación:

2020

Institución:

Universidad El Bosque

Repositorio:

Repositorio U. El Bosque

Idioma:

eng

OAI Identifier:

oai:repositorio.unbosque.edu.co:20.500.12495/3665

Acceso en línea:

http://hdl.handle.net/20.500.12495/3665
https://doi.org/10.1155/2020/9248793
https://repositorio.unbosque.edu.co

Palabra clave:

Reacciones químicas
Catálisis
Enzimas

Rights

openAccess

License

Attribution 4.0 International