Organocatalytic cascade reaction of aliphatic enals and benzoylnitromethane: synthesis of enantioenriched tetrasubstituted cyclohexene carbaldehyde

A new example of the reactivity of enals with benzoylnitromethane was studied in a Michael-Michael-Aldol-Dehydration quadruple organocascade reaction. The reaction unexpectedly yielded a tetrasubstituted cyclohexene carbaldehyde with excellent enantiomeric excess when crotonaldehyde was used as the...

Full description

Autores:
David Rodriguez, Fredy A.
Maldonado Villamil, Mauricio
Guevara Pulido, James
Tipo de recurso:
Article of journal
Fecha de publicación:
2020
Institución:
Universidad El Bosque
Repositorio:
Repositorio U. El Bosque
Idioma:
eng
OAI Identifier:
oai:repositorio.unbosque.edu.co:20.500.12495/3665
Acceso en línea:
http://hdl.handle.net/20.500.12495/3665
https://doi.org/10.1155/2020/9248793
https://repositorio.unbosque.edu.co
Palabra clave:
Reacciones químicas
Catálisis
Enzimas
Rights
openAccess
License
Attribution 4.0 International