Evaluación de la modificación de almidón de yuca (Manihot esculenta) vía desramificación enzimática y entrecruzamiento y la utilización del almidón modificado para la obtención de películas biodegradables
ilustraciones, fotografías, gráficas, tablas
- Autores:
-
Algecira Enciso, Néstor Ariel
- Tipo de recurso:
- Doctoral thesis
- Fecha de publicación:
- 2023
- Institución:
- Universidad Nacional de Colombia
- Repositorio:
- Universidad Nacional de Colombia
- Idioma:
- spa
- OAI Identifier:
- oai:repositorio.unal.edu.co:unal/84270
- Palabra clave:
- 660 - Ingeniería química::668 - Tecnología de otros productos orgánicos
Almidones modificados
Modified starches
Almidón de yuca
Esterificación
Poliácidos orgánicos
Cassava starch
esterification
Organic polyacids
Biodegradación
Biodegradation
- Rights
- openAccess
- License
- Atribución-NoComercial 4.0 Internacional
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Evaluación de la modificación de almidón de yuca (Manihot esculenta) vía desramificación enzimática y entrecruzamiento y la utilización del almidón modificado para la obtención de películas biodegradables |
| dc.title.translated.eng.fl_str_mv |
Evaluation of the modification of cassava starch (Manihot esculenta) via enzymatic debranching and crosslinking and the use of modified starch to obtain biodegradable films |
| title |
Evaluación de la modificación de almidón de yuca (Manihot esculenta) vía desramificación enzimática y entrecruzamiento y la utilización del almidón modificado para la obtención de películas biodegradables |
| spellingShingle |
Evaluación de la modificación de almidón de yuca (Manihot esculenta) vía desramificación enzimática y entrecruzamiento y la utilización del almidón modificado para la obtención de películas biodegradables 660 - Ingeniería química::668 - Tecnología de otros productos orgánicos Almidones modificados Modified starches Almidón de yuca Esterificación Poliácidos orgánicos Cassava starch esterification Organic polyacids Biodegradación Biodegradation |
| title_short |
Evaluación de la modificación de almidón de yuca (Manihot esculenta) vía desramificación enzimática y entrecruzamiento y la utilización del almidón modificado para la obtención de películas biodegradables |
| title_full |
Evaluación de la modificación de almidón de yuca (Manihot esculenta) vía desramificación enzimática y entrecruzamiento y la utilización del almidón modificado para la obtención de películas biodegradables |
| title_fullStr |
Evaluación de la modificación de almidón de yuca (Manihot esculenta) vía desramificación enzimática y entrecruzamiento y la utilización del almidón modificado para la obtención de películas biodegradables |
| title_full_unstemmed |
Evaluación de la modificación de almidón de yuca (Manihot esculenta) vía desramificación enzimática y entrecruzamiento y la utilización del almidón modificado para la obtención de películas biodegradables |
| title_sort |
Evaluación de la modificación de almidón de yuca (Manihot esculenta) vía desramificación enzimática y entrecruzamiento y la utilización del almidón modificado para la obtención de películas biodegradables |
| dc.creator.fl_str_mv |
Algecira Enciso, Néstor Ariel |
| dc.contributor.advisor.none.fl_str_mv |
Perilla Perilla, Jairo Ernesto |
| dc.contributor.author.none.fl_str_mv |
Algecira Enciso, Néstor Ariel |
| dc.contributor.researchgroup.spa.fl_str_mv |
Grupo de Investigación en Procesos Químicos y Bioquímicos |
| dc.subject.ddc.spa.fl_str_mv |
660 - Ingeniería química::668 - Tecnología de otros productos orgánicos |
| topic |
660 - Ingeniería química::668 - Tecnología de otros productos orgánicos Almidones modificados Modified starches Almidón de yuca Esterificación Poliácidos orgánicos Cassava starch esterification Organic polyacids Biodegradación Biodegradation |
| dc.subject.agrovoc.spa.fl_str_mv |
Almidones modificados |
| dc.subject.agrovoc.eng.fl_str_mv |
Modified starches |
| dc.subject.proposal.spa.fl_str_mv |
Almidón de yuca Esterificación Poliácidos orgánicos |
| dc.subject.proposal.eng.fl_str_mv |
Cassava starch esterification Organic polyacids |
| dc.subject.wikidata.spa.fl_str_mv |
Biodegradación |
| dc.subject.wikidata.eng.fl_str_mv |
Biodegradation |
| description |
ilustraciones, fotografías, gráficas, tablas |
| publishDate |
2023 |
| dc.date.accessioned.none.fl_str_mv |
2023-07-25T21:01:19Z |
| dc.date.available.none.fl_str_mv |
2023-07-25T21:01:19Z |
| dc.date.issued.none.fl_str_mv |
2023 |
| dc.type.spa.fl_str_mv |
Trabajo de grado - Doctorado |
| dc.type.driver.spa.fl_str_mv |
info:eu-repo/semantics/doctoralThesis |
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info:eu-repo/semantics/acceptedVersion |
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http://purl.org/coar/resource_type/c_db06 |
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Text |
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http://purl.org/redcol/resource_type/TD |
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http://purl.org/coar/resource_type/c_db06 |
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acceptedVersion |
| dc.identifier.uri.none.fl_str_mv |
https://repositorio.unal.edu.co/handle/unal/84270 |
| dc.identifier.instname.spa.fl_str_mv |
Universidad Nacional de Colombia |
| dc.identifier.reponame.spa.fl_str_mv |
Repositorio Institucional Universidad Nacional de Colombia |
| dc.identifier.repourl.spa.fl_str_mv |
https://repositorio.unal.edu.co/ |
| url |
https://repositorio.unal.edu.co/handle/unal/84270 https://repositorio.unal.edu.co/ |
| identifier_str_mv |
Universidad Nacional de Colombia Repositorio Institucional Universidad Nacional de Colombia |
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spa |
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spa |
| dc.relation.references.spa.fl_str_mv |
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Laser light scattering of high amylose and high amylopectin materials in aqueous solution, effect of storage time. Carbohydrate Polymers, 37(4), 383-394. https://doi.org/10.1016/S0144-8617(97)00139-2 BeMiller, J. N. (2018). Chapter 5—Physical Modification of Starch. En M. Sjöö & L. Nilsson (Eds.), Starch in Food (Second Edition) (pp. 223-253). Woodhead Publishing. https://doi.org/10.1016/B978-0-08-100868-3.00005-6 BeMiller, J. N. (2019). Chapter 19—Corn Starch Modification. En S. O. Serna-Saldivar (Ed.), Corn (Third Edition) (pp. 537-549). AACC International Press. https://doi.org/10.1016/B978-0-12-811971-6.00019-X BeMiller, J. N., & Huber, K. C. (2015). Physical Modification of Food Starch Functionalities. Annual Review of Food Science and Technology, 6(1), 19-69. https://doi.org/10.1146/annurev-food-022814-015552 Berovic, M., & Legisa, M. (2007). Citric acid production. En M. R. El-Gewely (Ed.), Biotechnology Annual Review (Vol. 13, pp. 303-343). 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Butterworth-Heinemann. https://doi.org/10.1016/B978-0-408-10618-4.50014-7 Blennow, A., Wischmann, B., Houborg, K., Ahmt, T., Jørgensen, K., Engelsen, S. B., Bandsholm, O., & Poulsen, P. (2005). Structure function relationships of transgenic starches with engineered phosphate substitution and starch branching. International Journal of Biological Macromolecules, 36(3), 159-168. https://doi.org/10.1016/j.ijbiomac.2005.05.006 Builders, P. F., & Arhewoh, M. I. (2016). Pharmaceutical applications of native starch in conventional drug delivery. Starch - Stärke, 68(9-10), 864-873. https://doi.org/10.1002/star.201500337 Buleon, A., Gallant, D. J., Bouchet, B., Mouille, G., D’Hulst, C., Kossmann, J., & Ball, S. (1997). Starches from A to C (Chlamydomonas reinhardtii as a Model Microbial System to Investigate the Biosynthesis of the Plant Amylopectin Crystal). Plant Physiology, 115(3), 949-957. https://doi.org/10.1104/pp.115.3.949 Cael, J. J., Koenig, J. L., & Blackwell, J. (1975). Infrared and Raman spectroscopy of carbohydrates. Part VI: Normal coordinate analysis of V-amylose. Biopolymers, 14(9), 1885-1903. https://doi.org/10.1002/bip.1975.360140909 Canales, N., & Trujillo, M. (2021). La red de valor de la yuca y su potencial en la bioeconomía de Colombia. https://www.sei.org/publications/la-red-de-valor-de-la-yuca-y-su-potencial-en-la-bioeconomia-de-colombia/ Ceballos, H., Hershey, C., Iglesias, C., & Zhang, X. (2021). Fifty years of a public cassava breeding program: Evolution of breeding objectives, methods, and decision-making processes. Theoretical and Applied Genetics, 134(8), 2335-2353. https://doi.org/10.1007/s00122-021-03852-9 Chakraborty, S., Sahoo, B., Teraoka, I., Miller, L. M., & Gross, R. A. (2005). Enzyme-Catalyzed Regioselective Modification of Starch Nanoparticles. Macromolecules, 38(1), 61-68. https://doi.org/10.1021/ma048842w Chanzy, H., Vuong, R., & Jésior, J. C. (1990). 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FAOSTAT. https://www.fao.org/faostat/en/#search/cassava Fornal, J., Sadowska, J., Błaszczak, W., Jeliński, T., Stasiak, M., Molenda, M., & Hajnos, M. (2012). Influence of some chemical modifications on the characteristics of potato starch powders. Journal of Food Engineering, 108(4), 515-522. https://doi.org/10.1016/j.jfoodeng.2011.09.016 French, D. (1984). CHAPTER VII - ORGANIZATION OF STARCH GRANULES. En R. L. Whistler, J. N. Bemiller, & E. F. Paschall (Eds.), Starch: Chemistry and Technology (Second Edition) (pp. 183-247). Academic Press. https://doi.org/10.1016/B978-0-12-746270-7.50013-6 Fringant, C., Rinaudo, M., Gontard, N., Guilbert, S., & Derradji, H. (1998). A Biogradable Starch Based Coating to Waterproof Hydrophilic Materials. Starch - Stärke, 50(7), 292-296. https://doi.org/10.1002/(SICI)1521-379X(199807)50:7<292::AID-STAR292>3.0.CO;2-# Gao, Q., Li, S., Jian, H., & Liang, S. (2011). Preparation and properties of resistant starch from corn starch with enzymes. 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Carbohydrate Polymers, 83(4), 1623-1630. https://doi.org/10.1016/j.carbpol.2010.10.015 Gernat, Ch., Radosta, S., Damaschun, G., & Schierbaum, F. (1990). Supramolecular Structure of Legume Starches Revealed by X-Ray Scattering. Starch - Stärke, 42(5), 175-178. https://doi.org/10.1002/star.19900420504 Ghiena, C., Schulz, M., & Schnabl, H. (1993). Starch Degradation and Distribution of the Starch-Degrading Enzymes in Vicia faba Leaves (Diurnal Oscillation of Amylolytic Activity and Starch Content in Chloroplasts). Plant Physiology, 101(1), 73-79. https://doi.org/10.1104/pp.101.1.73 Golachowski, A., Drożdż, W., Golachowska, M., Kapelko-Żeberska, M., & Raszewski, B. (2020). Production and Properties of Starch Citrates—Current Research. Foods, 9(9), Article 9. https://doi.org/10.3390/foods9091311 Gong, B., Cheng, L., Gilbert, R. G., & Li, C. (2019). Distribution of short to medium amylose chains are major controllers of in vitro digestion of retrograded rice starch. 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Atribución-NoComercial 4.0 InternacionalDerechos reservados al autor, 2023http://creativecommons.org/licenses/by-nc/4.0/info:eu-repo/semantics/openAccesshttp://purl.org/coar/access_right/c_abf2Perilla Perilla, Jairo Ernesto6da974f5d7b47336a5ddf3bb9482b009Algecira Enciso, Néstor Ariel7e5c64906bba9ec89eddc4ec2f5f2e95Grupo de Investigación en Procesos Químicos y Bioquímicos2023-07-25T21:01:19Z2023-07-25T21:01:19Z2023https://repositorio.unal.edu.co/handle/unal/84270Universidad Nacional de ColombiaRepositorio Institucional Universidad Nacional de Colombiahttps://repositorio.unal.edu.co/ilustraciones, fotografías, gráficas, tablasEn esta investigación se estudió la morfología, cristalinidad y el proceso de gelatinización mediante seguimiento de la viscosidad y calorimetría diferencial de barrido para el almidón de yuca. Se evaluó el proceso de hidrólisis enzimática con pululanasa para obtener almidón desramificado enzimáticamente (ADRE), y se estableció que las mejores condiciones para el proceso son la temperatura de reacción 60 °C y pH 4, y mediante seguimiento cromatográfico se determinó que se producen una mezcla de alto, medio y bajo peso molecular con capacidad filmogénica. Posteriormente se trabajó con esterificación de almidón nativo y almidón desramificado (ADRE) con ácido cítrico, málico y adípico, inicialmente se realizó en medio orgánico con DMSO para la obtención de adipato de ADRE a 90 °C con un grado de sustitución de 0,009, en la segunda parte la evaluación se realizó mediante el método de calor seco en horno, y se logró sintetizar citrato, malato y adipato de almidón y de ADRE con una temperatura de reacción de 100°C, tiempo de reacción 2,5 h y relación ácido/almidón de 15 g/100g, esto se verificó con espectroscopia infrarroja y se complementó con determinaciones de calorimetría diferencial de barrido (DSC) y termogravimetría (TGA), los grados de sustitución obtenidos fueron bajos y estuvieron entre 0,04 y 1,03. Se caracterizaron estos productos y se encontró aumento de la hidrofobicidad, pocos cambios en la cristalinidad, cambios en la morfología y se prepararon películas con estos derivados de almidón por el método de casting con polioles como plastificantes y estas tienen menor permeabilidad a vapor de agua, mejores propiedades mecánicas y son biodegradables. (Texto tomado de la fuente)In this research, the morphology, crystallinity and the gelatinization process were studied by monitoring the viscosity and differential scanning calorimetry for cassava starch. The enzymatic hydrolysis process with pullulanase to obtain enzymatically debranched starch (ADRE) was evaluated, and it was established that the best conditions for the process are the reaction temperature of 60 °C and pH 4, and through chromatographic monitoring it was determined that a mixture of high, medium and low molecular weight with filmogenic capacity. Subsequently, work was carried out with esterification of native starch and debranched starch (ADRE) with citric, malic and adipic acid, initially it was carried out in an organic medium with DMSO to obtain ADRE adipate at 90 °C with a degree of substitution of 0.009, in In the second part, the evaluation was carried out using the oven-dry heat method, and it was possible to synthesize starch and ADRE citrate, malate and adipate with a reaction temperature of 100°C, reaction time of 2.5 h and acid/acid ratio. starch of 15 g/100g, this was verified with infrared spectroscopy and complemented with determinations of differential scanning calorimetry (DSC) and thermogravimetry (TGA), the degrees of substitution obtained were low and were between 0.04 and 1.03. These products were characterized and an increase in hydrophobicity was found, few changes in crystallinity, changes in morphology and films were prepared with these starch derivatives by the casting method with polyols as plasticizers and these have lower permeability to water vapor. better mechanical properties and are biodegradable.DoctoradoDoctor en IngenieríaExperimentalBiopolímerosxvi, 129 páginasapplication/pdfspaUniversidad Nacional de ColombiaBogotá - Ingeniería - Doctorado en Ingeniería - Ingeniería QuímicaFacultad de IngenieríaBogotá, ColombiaUniversidad Nacional de Colombia - Sede Bogotá660 - Ingeniería química::668 - Tecnología de otros productos orgánicosAlmidones modificadosModified starchesAlmidón de yucaEsterificaciónPoliácidos orgánicosCassava starchesterificationOrganic polyacidsBiodegradaciónBiodegradationEvaluación de la modificación de almidón de yuca (Manihot esculenta) vía desramificación enzimática y entrecruzamiento y la utilización del almidón modificado para la obtención de películas biodegradablesEvaluation of the modification of cassava starch (Manihot esculenta) via enzymatic debranching and crosslinking and the use of modified starch to obtain biodegradable filmsTrabajo de grado - Doctoradoinfo:eu-repo/semantics/doctoralThesisinfo:eu-repo/semantics/acceptedVersionhttp://purl.org/coar/resource_type/c_db06Texthttp://purl.org/redcol/resource_type/TDAburto, J., Alric, I., & Borredon, E. 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Materials, 14(5), Article 5. https://doi.org/10.3390/ma14051146EstudiantesInvestigadoresLICENSElicense.txtlicense.txttext/plain; charset=utf-85879https://repositorio.unal.edu.co/bitstream/unal/84270/1/license.txteb34b1cf90b7e1103fc9dfd26be24b4aMD51ORIGINAL79491089.2023.pdf79491089.2023.pdfTesis de Doctorado en Ingeniería Químicaapplication/pdf7935719https://repositorio.unal.edu.co/bitstream/unal/84270/3/79491089.2023.pdf35c63a8967f15274b4d7cbafd64cd3b3MD53THUMBNAIL79491089.2023.pdf.jpg79491089.2023.pdf.jpgGenerated Thumbnailimage/jpeg6432https://repositorio.unal.edu.co/bitstream/unal/84270/4/79491089.2023.pdf.jpgf0942b216013be99deb6e936d098ef44MD54unal/84270oai:repositorio.unal.edu.co:unal/842702024-08-15 23:14:38.083Repositorio Institucional Universidad Nacional de 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