p-Phenylenevinylene oligomers with application as photoredox catalysts in organic synthesis

Sixteen p-phenylenevinylene oligomers (OPVs) substituted with different electron-donating (ED) and electron-withdrawing (EW) groups were synthesized by the Mizoroki-Heck cross coupling reaction in moderate to good yields (40-95%), and with a totally trans-trans configuration in the vinyl bonds, whic...

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Autores:
Estrada Flórez, Sandra Elizabeth
Tipo de recurso:
Doctoral thesis
Fecha de publicación:
2017
Institución:
Universidad Nacional de Colombia
Repositorio:
Universidad Nacional de Colombia
Idioma:
spa
OAI Identifier:
oai:repositorio.unal.edu.co:unal/62838
Acceso en línea:
https://repositorio.unal.edu.co/handle/unal/62838
http://bdigital.unal.edu.co/62078/
Palabra clave:
54 Química y ciencias afines / Chemistry
62 Ingeniería y operaciones afines / Engineering
Phenylenevinylene systems
Mizoroki-Heck reaction
Optoelectronic properties
Photoredox catalysis
Dehalogenation
Hydroxylation
Aza-Henry reaction
Rights
openAccess
License
Atribución-NoComercial 4.0 Internacional