p-Phenylenevinylene oligomers with application as photoredox catalysts in organic synthesis
Sixteen p-phenylenevinylene oligomers (OPVs) substituted with different electron-donating (ED) and electron-withdrawing (EW) groups were synthesized by the Mizoroki-Heck cross coupling reaction in moderate to good yields (40-95%), and with a totally trans-trans configuration in the vinyl bonds, whic...
- Autores:
-
Estrada Flórez, Sandra Elizabeth
- Tipo de recurso:
- Doctoral thesis
- Fecha de publicación:
- 2017
- Institución:
- Universidad Nacional de Colombia
- Repositorio:
- Universidad Nacional de Colombia
- Idioma:
- spa
- OAI Identifier:
- oai:repositorio.unal.edu.co:unal/62838
- Acceso en línea:
- https://repositorio.unal.edu.co/handle/unal/62838
http://bdigital.unal.edu.co/62078/
- Palabra clave:
- 54 Química y ciencias afines / Chemistry
62 Ingeniería y operaciones afines / Engineering
Phenylenevinylene systems
Mizoroki-Heck reaction
Optoelectronic properties
Photoredox catalysis
Dehalogenation
Hydroxylation
Aza-Henry reaction
- Rights
- openAccess
- License
- Atribución-NoComercial 4.0 Internacional