Structural, spectroscopic, and theoretical analysis of a molecular system based on 2-((2-(4-chlorophenylhydrazone)methyl)quinolone

A novel molecular system based on 2-((2-(4-chlorophenylhydrazone)methyl)quinoline (1-E) was synthesized. Interconversion of 1-E to its configurational isomer 1-Z was achieved using UV radiation (250 W Hg lamp). Such isomerization was monitored by 1H-NMR. The results suggest that the hydrazone deriva...

Full description

Autores:
Chaur Valencia, Manuel Noé
Romero, Elkin Libardo
Gutierrez, Gustavo
Soto Monsalve, Mónica
D´Vries, Richard
Zuluaga, Héctor Fabio
Tipo de recurso:
Article of journal
Fecha de publicación:
2018
Institución:
Universidad Nacional de Colombia
Repositorio:
Universidad Nacional de Colombia
Idioma:
spa
OAI Identifier:
oai:repositorio.unal.edu.co:unal/66242
Acceso en línea:
https://repositorio.unal.edu.co/handle/unal/66242
http://bdigital.unal.edu.co/67266/
Palabra clave:
54 Química y ciencias afines / Chemistry
Hydrazone derivatives
configurational dynamic
single XRD
DFT calculations
electrochemistry
derivados hidrazónicos
dinámica configuracional
cristalografía de rayos X
cálculos DFT
electroquímica
derivados de hidrazonas
Dinâmica configuracional
Cristalografia de Raios-X
Cálculos DFT
Eletroquímica
Rights
openAccess
License
Atribución-NoComercial 4.0 Internacional