Stability criteria and critical runway conditions of propylene glycol manufacture in a continuous stirred tank reactor
Here, a new method for the analysis of the steady state and the safety operational conditions of the hydrolysis of propylene oxide with excess of water, in a Continuous Stirred Tank Reactor (CSTR), was developed. For industrial operational typical values, at first, the generated and removed heat bal...
- Autores:
-
Gómez, Miguel Ángel
López Zamora, Sandra Milena
Gómez, Isabel Dobrosz
- Tipo de recurso:
- Article of journal
- Fecha de publicación:
- 2015
- Institución:
- Universidad Nacional de Colombia
- Repositorio:
- Universidad Nacional de Colombia
- Idioma:
- spa
- OAI Identifier:
- oai:repositorio.unal.edu.co:unal/67668
- Acceso en línea:
- https://repositorio.unal.edu.co/handle/unal/67668
http://bdigital.unal.edu.co/68697/
- Palabra clave:
- 62 Ingeniería y operaciones afines / Engineering
stability criteria
propylene oxide
propylene glycol
runaway conditions.
Criterios de estabilidad
óxido de propileno
propilen glicol
condiciones de runaway.
- Rights
- openAccess
- License
- Atribución-NoComercial 4.0 Internacional
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Universidad Nacional de Colombia |
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Atribución-NoComercial 4.0 InternacionalDerechos reservados - Universidad Nacional de Colombiahttp://creativecommons.org/licenses/by-nc/4.0/info:eu-repo/semantics/openAccesshttp://purl.org/coar/access_right/c_abf2Gómez, Miguel Ángel25cff689-dde8-42b0-b2aa-368d344c021c300López Zamora, Sandra Milena4baa0a55-eaa1-4cb3-ba7d-5b59b1f74ba8300Gómez, Isabel Dobrosz286d7783-1346-4444-b7fe-7e0cf321c5903002019-07-03T04:48:51Z2019-07-03T04:48:51Z2015-05-01ISSN: 2248-8723https://repositorio.unal.edu.co/handle/unal/67668http://bdigital.unal.edu.co/68697/Here, a new method for the analysis of the steady state and the safety operational conditions of the hydrolysis of propylene oxide with excess of water, in a Continuous Stirred Tank Reactor (CSTR), was developed. For industrial operational typical values, at first, the generated and removed heat balances were examined. Next, the effect of coolant fluid temperature in the critical ignition and extinction temperatures (TCI and TCE, respectively) was analyzed. The influence of the heat exchange parameter (hS) on coolant and critical temperatures was also studied. Finally, the steady state operation areas were defined. The existence of multiple stable states was recognized when the heat exchange parameter was in the range 6.636 hS kJ/(min.K) 11.125. Unstable operation area was located between the TCI and TCE values, restricting the reactor operation area to the low stable temperatures.En este trabajo se presenta un nuevo método para el análisis del estado estable y de las condiciones operativas seguras para la hidrólisis del óxido de propileno con exceso de agua en un reactor continuo de tanque agitado (CSTR). Inicialmente, para valores típicos de operación industrial, se examinaron los balances de calor generado y removido. Luego, se analizó el efecto de la temperatura del fluido de enfriamiento en las temperaturas de ignición y extinción (TCI y TCE, respectivamente). También se estudió el efecto del parámetro de transferencia de calor (hS) sobre las temperaturas críticas y del fluido de enfriamiento. Finalmente, se definieron las áreas de operación estables. Se reconoció la existencia de múltiples estados estables cuando el parámetro de transferencia de calor está en el intervalo de 6.636 hS kJ/(min.K) 11.125. El área de operación inestable está localizada entre los valores de TCI y TCE, restringiendo la operación del reactor al área de bajas temperaturas estables.application/pdfspaUniversidad Nacional de Colombia - Sede Bogotá - Facultad de Ingenieríahttps://revistas.unal.edu.co/index.php/ingeinv/article/view/46258Universidad Nacional de Colombia Revistas electrónicas UN Ingeniería e InvestigaciónIngeniería e InvestigaciónGómez, Miguel Ángel and López Zamora, Sandra Milena and Gómez, Isabel Dobrosz (2015) Stability criteria and critical runway conditions of propylene glycol manufacture in a continuous stirred tank reactor. Ingeniería e Investigación, 35 (2). pp. 56-60. ISSN 2248-872362 Ingeniería y operaciones afines / Engineeringstability criteriapropylene oxidepropylene glycolrunaway conditions.Criterios de estabilidadóxido de propilenopropilen glicolcondiciones de runaway.Stability criteria and critical runway conditions of propylene glycol manufacture in a continuous stirred tank reactorArtículo de revistainfo:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501http://purl.org/coar/resource_type/c_2df8fbb1http://purl.org/coar/version/c_970fb48d4fbd8a85Texthttp://purl.org/redcol/resource_type/ARTORIGINAL46258-255978-2-PB.pdfapplication/pdf332291https://repositorio.unal.edu.co/bitstream/unal/67668/1/46258-255978-2-PB.pdf528e81433e250ced6d7a80287c4f19a2MD51THUMBNAIL46258-255978-2-PB.pdf.jpg46258-255978-2-PB.pdf.jpgGenerated Thumbnailimage/jpeg8788https://repositorio.unal.edu.co/bitstream/unal/67668/2/46258-255978-2-PB.pdf.jpg86f3697d775523d4a3694e491d7c1d19MD52unal/67668oai:repositorio.unal.edu.co:unal/676682024-05-22 23:34:12.907Repositorio Institucional Universidad Nacional de Colombiarepositorio_nal@unal.edu.co |
dc.title.spa.fl_str_mv |
Stability criteria and critical runway conditions of propylene glycol manufacture in a continuous stirred tank reactor |
title |
Stability criteria and critical runway conditions of propylene glycol manufacture in a continuous stirred tank reactor |
spellingShingle |
Stability criteria and critical runway conditions of propylene glycol manufacture in a continuous stirred tank reactor 62 Ingeniería y operaciones afines / Engineering stability criteria propylene oxide propylene glycol runaway conditions. Criterios de estabilidad óxido de propileno propilen glicol condiciones de runaway. |
title_short |
Stability criteria and critical runway conditions of propylene glycol manufacture in a continuous stirred tank reactor |
title_full |
Stability criteria and critical runway conditions of propylene glycol manufacture in a continuous stirred tank reactor |
title_fullStr |
Stability criteria and critical runway conditions of propylene glycol manufacture in a continuous stirred tank reactor |
title_full_unstemmed |
Stability criteria and critical runway conditions of propylene glycol manufacture in a continuous stirred tank reactor |
title_sort |
Stability criteria and critical runway conditions of propylene glycol manufacture in a continuous stirred tank reactor |
dc.creator.fl_str_mv |
Gómez, Miguel Ángel López Zamora, Sandra Milena Gómez, Isabel Dobrosz |
dc.contributor.author.spa.fl_str_mv |
Gómez, Miguel Ángel López Zamora, Sandra Milena Gómez, Isabel Dobrosz |
dc.subject.ddc.spa.fl_str_mv |
62 Ingeniería y operaciones afines / Engineering |
topic |
62 Ingeniería y operaciones afines / Engineering stability criteria propylene oxide propylene glycol runaway conditions. Criterios de estabilidad óxido de propileno propilen glicol condiciones de runaway. |
dc.subject.proposal.spa.fl_str_mv |
stability criteria propylene oxide propylene glycol runaway conditions. Criterios de estabilidad óxido de propileno propilen glicol condiciones de runaway. |
description |
Here, a new method for the analysis of the steady state and the safety operational conditions of the hydrolysis of propylene oxide with excess of water, in a Continuous Stirred Tank Reactor (CSTR), was developed. For industrial operational typical values, at first, the generated and removed heat balances were examined. Next, the effect of coolant fluid temperature in the critical ignition and extinction temperatures (TCI and TCE, respectively) was analyzed. The influence of the heat exchange parameter (hS) on coolant and critical temperatures was also studied. Finally, the steady state operation areas were defined. The existence of multiple stable states was recognized when the heat exchange parameter was in the range 6.636 hS kJ/(min.K) 11.125. Unstable operation area was located between the TCI and TCE values, restricting the reactor operation area to the low stable temperatures. |
publishDate |
2015 |
dc.date.issued.spa.fl_str_mv |
2015-05-01 |
dc.date.accessioned.spa.fl_str_mv |
2019-07-03T04:48:51Z |
dc.date.available.spa.fl_str_mv |
2019-07-03T04:48:51Z |
dc.type.spa.fl_str_mv |
Artículo de revista |
dc.type.coar.fl_str_mv |
http://purl.org/coar/resource_type/c_2df8fbb1 |
dc.type.driver.spa.fl_str_mv |
info:eu-repo/semantics/article |
dc.type.version.spa.fl_str_mv |
info:eu-repo/semantics/publishedVersion |
dc.type.coar.spa.fl_str_mv |
http://purl.org/coar/resource_type/c_6501 |
dc.type.coarversion.spa.fl_str_mv |
http://purl.org/coar/version/c_970fb48d4fbd8a85 |
dc.type.content.spa.fl_str_mv |
Text |
dc.type.redcol.spa.fl_str_mv |
http://purl.org/redcol/resource_type/ART |
format |
http://purl.org/coar/resource_type/c_6501 |
status_str |
publishedVersion |
dc.identifier.issn.spa.fl_str_mv |
ISSN: 2248-8723 |
dc.identifier.uri.none.fl_str_mv |
https://repositorio.unal.edu.co/handle/unal/67668 |
dc.identifier.eprints.spa.fl_str_mv |
http://bdigital.unal.edu.co/68697/ |
identifier_str_mv |
ISSN: 2248-8723 |
url |
https://repositorio.unal.edu.co/handle/unal/67668 http://bdigital.unal.edu.co/68697/ |
dc.language.iso.spa.fl_str_mv |
spa |
language |
spa |
dc.relation.spa.fl_str_mv |
https://revistas.unal.edu.co/index.php/ingeinv/article/view/46258 |
dc.relation.ispartof.spa.fl_str_mv |
Universidad Nacional de Colombia Revistas electrónicas UN Ingeniería e Investigación Ingeniería e Investigación |
dc.relation.references.spa.fl_str_mv |
Gómez, Miguel Ángel and López Zamora, Sandra Milena and Gómez, Isabel Dobrosz (2015) Stability criteria and critical runway conditions of propylene glycol manufacture in a continuous stirred tank reactor. Ingeniería e Investigación, 35 (2). pp. 56-60. ISSN 2248-8723 |
dc.rights.spa.fl_str_mv |
Derechos reservados - Universidad Nacional de Colombia |
dc.rights.coar.fl_str_mv |
http://purl.org/coar/access_right/c_abf2 |
dc.rights.license.spa.fl_str_mv |
Atribución-NoComercial 4.0 Internacional |
dc.rights.uri.spa.fl_str_mv |
http://creativecommons.org/licenses/by-nc/4.0/ |
dc.rights.accessrights.spa.fl_str_mv |
info:eu-repo/semantics/openAccess |
rights_invalid_str_mv |
Atribución-NoComercial 4.0 Internacional Derechos reservados - Universidad Nacional de Colombia http://creativecommons.org/licenses/by-nc/4.0/ http://purl.org/coar/access_right/c_abf2 |
eu_rights_str_mv |
openAccess |
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application/pdf |
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Universidad Nacional de Colombia - Sede Bogotá - Facultad de Ingeniería |
institution |
Universidad Nacional de Colombia |
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