Alternativas de base nanotecnológica en el control de etileno y/o actividad antimicrobiana para mejorar la vida poscosecha del aguacate Hass

Avocado ripening and many of its quality parameters are influenced by ethylene production and pathologies such as anthracnose, whose management represents a challenge for the industry since they affect the commercialization of this fruit. An alternative to control ethylene production is the use of n...

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Autores:
Nevado Velásquez, Paula Andrea
Tipo de recurso:
Fecha de publicación:
2022
Institución:
Universidad Nacional de Colombia
Repositorio:
Universidad Nacional de Colombia
Idioma:
spa
OAI Identifier:
oai:repositorio.unal.edu.co:unal/85740
Acceso en línea:
https://repositorio.unal.edu.co/handle/unal/85740
https://repositorio.unal.edu.co/
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540 - Química y ciencias afines::541 - Química física
540 - Química y ciencias afines::542 - Técnicas, procedimientos, aparatos, equipos, materiales
Aguacate - calidad
Agricultura - Investigaciones
Cultivos alimenticios
Producción agropecuaria
Nanotecnología
Nanopartículas de TiO2-Ag
poscosecha
fotocatálisis
aguacate Hass
actividad antimicrobiana
control de etileno
autocombustión en solución
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openAccess
License
Reconocimiento 4.0 Internacional
id UNACIONAL2_25e5e977c2218bb3e45d2b67be88f471
oai_identifier_str oai:repositorio.unal.edu.co:unal/85740
network_acronym_str UNACIONAL2
network_name_str Universidad Nacional de Colombia
repository_id_str
dc.title.spa.fl_str_mv Alternativas de base nanotecnológica en el control de etileno y/o actividad antimicrobiana para mejorar la vida poscosecha del aguacate Hass
dc.title.translated.eng.fl_str_mv Nanotechnology-based alternatives in the control of ethylene and/or antimicrobial activity to improve the postharvest life of Hass avocado.
title Alternativas de base nanotecnológica en el control de etileno y/o actividad antimicrobiana para mejorar la vida poscosecha del aguacate Hass
spellingShingle Alternativas de base nanotecnológica en el control de etileno y/o actividad antimicrobiana para mejorar la vida poscosecha del aguacate Hass
540 - Química y ciencias afines::541 - Química física
540 - Química y ciencias afines::542 - Técnicas, procedimientos, aparatos, equipos, materiales
Aguacate - calidad
Agricultura - Investigaciones
Cultivos alimenticios
Producción agropecuaria
Nanotecnología
Nanopartículas de TiO2-Ag
poscosecha
fotocatálisis
aguacate Hass
actividad antimicrobiana
control de etileno
autocombustión en solución
title_short Alternativas de base nanotecnológica en el control de etileno y/o actividad antimicrobiana para mejorar la vida poscosecha del aguacate Hass
title_full Alternativas de base nanotecnológica en el control de etileno y/o actividad antimicrobiana para mejorar la vida poscosecha del aguacate Hass
title_fullStr Alternativas de base nanotecnológica en el control de etileno y/o actividad antimicrobiana para mejorar la vida poscosecha del aguacate Hass
title_full_unstemmed Alternativas de base nanotecnológica en el control de etileno y/o actividad antimicrobiana para mejorar la vida poscosecha del aguacate Hass
title_sort Alternativas de base nanotecnológica en el control de etileno y/o actividad antimicrobiana para mejorar la vida poscosecha del aguacate Hass
dc.creator.fl_str_mv Nevado Velásquez, Paula Andrea
dc.contributor.advisor.none.fl_str_mv Paucar Álvarez, Carlos Guillermo
García García, Claudia Patricia
dc.contributor.author.none.fl_str_mv Nevado Velásquez, Paula Andrea
dc.contributor.researchgroup.spa.fl_str_mv Materiales Cerámicos y Vítreos
dc.contributor.orcid.spa.fl_str_mv Nevado Velásquez, Paula Andrea [0009-0009-2211-589X]
dc.contributor.googlescholar.spa.fl_str_mv Paula Andrea Nevado Velasquez
dc.subject.ddc.spa.fl_str_mv 540 - Química y ciencias afines::541 - Química física
540 - Química y ciencias afines::542 - Técnicas, procedimientos, aparatos, equipos, materiales
topic 540 - Química y ciencias afines::541 - Química física
540 - Química y ciencias afines::542 - Técnicas, procedimientos, aparatos, equipos, materiales
Aguacate - calidad
Agricultura - Investigaciones
Cultivos alimenticios
Producción agropecuaria
Nanotecnología
Nanopartículas de TiO2-Ag
poscosecha
fotocatálisis
aguacate Hass
actividad antimicrobiana
control de etileno
autocombustión en solución
dc.subject.lemb.none.fl_str_mv Aguacate - calidad
Agricultura - Investigaciones
Cultivos alimenticios
Producción agropecuaria
Nanotecnología
dc.subject.proposal.spa.fl_str_mv Nanopartículas de TiO2-Ag
poscosecha
fotocatálisis
aguacate Hass
actividad antimicrobiana
control de etileno
autocombustión en solución
description Avocado ripening and many of its quality parameters are influenced by ethylene production and pathologies such as anthracnose, whose management represents a challenge for the industry since they affect the commercialization of this fruit. An alternative to control ethylene production is the use of nanoparticles with photocatalytic behavior that inhibit ethylene production through reactions. Thus, in this work, TiO2 particles doped with different concentrations of Ag were synthesized by the self-combustion technique in solution. The obtained particles were subjected to their respective morphological characterization using techniques such as XRD and SEM. Agglomerates of TiO2 particles were obtained in anatase phase, with 0.75%, 1.5% and 3.5% mol Ag of approximately 109.5 nm and in mixed anatase-ruthyl phase with 0% and 4.5% mol Ag with average sizes of 184.03 and 205.06 nm. The presence of Ag was confirmed by EDS, and through FTIR assays the bonds associated with the obtained material were identified (O-H and Ag interactions, Ti-O vibrations, O-H narrowing). The particle size distribution analysis and BET analysis, allow concluding that as the average agglomerate size decreases, there is an increase in the surface area, which is an important element for the photocatalytic activity. It was found that TiO2 particles with 0.75% mol Ag were the ones that presented the best response and therefore, they were taken as a reference to perform ethylene removal tests, antifungal activity and simulated transport tests. The presence of TiO2 particles doped with Ag enabled ethylene removal, antifungal activity and a delay in the ripening process of Hass avocado when in contact with the material.
publishDate 2022
dc.date.issued.none.fl_str_mv 2022-08
dc.date.accessioned.none.fl_str_mv 2024-02-28T21:30:39Z
dc.date.available.none.fl_str_mv 2024-02-28T21:30:39Z
dc.type.spa.fl_str_mv Trabajo de grado - Maestría
dc.type.driver.spa.fl_str_mv info:eu-repo/semantics/masterThesis
dc.type.version.spa.fl_str_mv info:eu-repo/semantics/acceptedVersion
dc.type.content.spa.fl_str_mv Text
dc.type.redcol.spa.fl_str_mv http://purl.org/redcol/resource_type/TM
status_str acceptedVersion
dc.identifier.uri.none.fl_str_mv https://repositorio.unal.edu.co/handle/unal/85740
dc.identifier.instname.spa.fl_str_mv Universidad Nacional de Colombia
dc.identifier.reponame.spa.fl_str_mv Repositorio Institucional Universidad Nacional de Colombia
dc.identifier.repourl.spa.fl_str_mv https://repositorio.unal.edu.co/
url https://repositorio.unal.edu.co/handle/unal/85740
https://repositorio.unal.edu.co/
identifier_str_mv Universidad Nacional de Colombia
Repositorio Institucional Universidad Nacional de Colombia
dc.language.iso.spa.fl_str_mv spa
language spa
dc.relation.indexed.spa.fl_str_mv LaReferencia
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spelling Reconocimiento 4.0 Internacionalhttp://creativecommons.org/licenses/by/4.0/info:eu-repo/semantics/openAccesshttp://purl.org/coar/access_right/c_abf2Paucar Álvarez, Carlos Guillermo94d13d6f2365951b28bffaf23ff9b290García García, Claudia Patricia6448197d2cc32832cb2f81989b4a9a99Nevado Velásquez, Paula Andrea6b994dc7dc79a45ef1dbf8c8a5a5afd3Materiales Cerámicos y VítreosNevado Velásquez, Paula Andrea [0009-0009-2211-589X]Paula Andrea Nevado Velasquez2024-02-28T21:30:39Z2024-02-28T21:30:39Z2022-08https://repositorio.unal.edu.co/handle/unal/85740Universidad Nacional de ColombiaRepositorio Institucional Universidad Nacional de Colombiahttps://repositorio.unal.edu.co/Avocado ripening and many of its quality parameters are influenced by ethylene production and pathologies such as anthracnose, whose management represents a challenge for the industry since they affect the commercialization of this fruit. An alternative to control ethylene production is the use of nanoparticles with photocatalytic behavior that inhibit ethylene production through reactions. Thus, in this work, TiO2 particles doped with different concentrations of Ag were synthesized by the self-combustion technique in solution. The obtained particles were subjected to their respective morphological characterization using techniques such as XRD and SEM. Agglomerates of TiO2 particles were obtained in anatase phase, with 0.75%, 1.5% and 3.5% mol Ag of approximately 109.5 nm and in mixed anatase-ruthyl phase with 0% and 4.5% mol Ag with average sizes of 184.03 and 205.06 nm. The presence of Ag was confirmed by EDS, and through FTIR assays the bonds associated with the obtained material were identified (O-H and Ag interactions, Ti-O vibrations, O-H narrowing). The particle size distribution analysis and BET analysis, allow concluding that as the average agglomerate size decreases, there is an increase in the surface area, which is an important element for the photocatalytic activity. It was found that TiO2 particles with 0.75% mol Ag were the ones that presented the best response and therefore, they were taken as a reference to perform ethylene removal tests, antifungal activity and simulated transport tests. The presence of TiO2 particles doped with Ag enabled ethylene removal, antifungal activity and a delay in the ripening process of Hass avocado when in contact with the material.La maduración del aguacate y muchos de sus parámetros de calidad son influenciados por la producción de etileno y patologías como la antracnosis, cuyo manejo representa un reto para la industria ya que afectan la calidad del fruto y con ello su comercialización. Una alternativa en el control de la producción de etileno es el uso de nanopartículas con comportamiento fotocatalítico que mediante reacciones inhiban la producción del gas. Es así como en este trabajo se sintetizaron partículas de TiO2 dopado con diferentes concentraciones de Ag por la técnica de autocombustión en solución. Las partículas obtenidas se caracterizaron morfológicamente utilizando técnicas como DRX y SEM. Se obtuvieron aglomerados de partículas de TiO2 en fase anatasa , con 0,75%, 1,5% y 3,5% mol Ag de aproximadamente 109,5 nm y en fase mixta de anatasa-rutilo con 0% y 4,5% mol Ag con tamaños promedios de 184,03 y 205,06 nm. La presencia de Ag se confirmó mediante EDS, y a través de ensayos de FTIR se identificaron los enlaces asociados al material obtenido (interacciones O-H y Ag, vibraciones Ti-O, estrechamiento O-H). Los análisis de distribución de tamaño de partícula y análisis BET, permiten concluir que a medida que el tamaño promedio de aglomerado disminuye, hay un aumento en el área de superficie, lo cual constituye un elemento importante para la actividad fotocatalítica. Se encontró que las partículas de TiO2 con 0,75% mol Ag fueron las que mejor respuesta presentaron y por lo tanto, se tomaron como referencia para realizar pruebas de remoción de etileno, actividad antifúngica y pruebas de transporte simulado. La presencia de partículas de TiO2 dopadas con Ag posibilitaron la remoción de etileno, presentan actividad antifúngica y un retraso en el proceso de maduración del aguacate Hass al tener contacto con el material. (Tomado de la fuente)MaestríaMagíster en Ciencias - QuímicaCiencias Naturales.Sede Medellín130 páginasapplication/pdfspaUniversidad Nacional de ColombiaMedellín - Ciencias - Maestría en Ciencias - QuímicaFacultad de CienciasMedellín, ColombiaUniversidad Nacional de Colombia - Sede Medellín540 - Química y ciencias afines::541 - Química física540 - Química y ciencias afines::542 - Técnicas, procedimientos, aparatos, equipos, materialesAguacate - calidadAgricultura - InvestigacionesCultivos alimenticiosProducción agropecuariaNanotecnologíaNanopartículas de TiO2-Agposcosechafotocatálisisaguacate Hassactividad antimicrobianacontrol de etilenoautocombustión en soluciónAlternativas de base nanotecnológica en el control de etileno y/o actividad antimicrobiana para mejorar la vida poscosecha del aguacate HassNanotechnology-based alternatives in the control of ethylene and/or antimicrobial activity to improve the postharvest life of Hass avocado.Trabajo de grado - Maestríainfo:eu-repo/semantics/masterThesisinfo:eu-repo/semantics/acceptedVersionTexthttp://purl.org/redcol/resource_type/TMLaReferenciaRivera, S. 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Síntesis y Modificación de Materiales Con Actividad Fotocatalítica Para La Oxofuncionalización Selectiva de Hidrocarburos Tesis Para Optar Al Grado de Doctor En Ciencias Con Mención En Química, Universidad de Concepcion, 2017.EstudiantesInvestigadoresMaestrosORIGINALTesisMaestriaPaulaAndreaNevadoVelasquezFinal.pdfTesisMaestriaPaulaAndreaNevadoVelasquezFinal.pdfapplication/pdf3283555https://repositorio.unal.edu.co/bitstream/unal/85740/4/TesisMaestriaPaulaAndreaNevadoVelasquezFinal.pdf1da0ef085566f33f4102777e77a3a288MD54LICENSElicense.txtlicense.txttext/plain; charset=utf-85879https://repositorio.unal.edu.co/bitstream/unal/85740/3/license.txteb34b1cf90b7e1103fc9dfd26be24b4aMD53THUMBNAILTesisMaestriaPaulaAndreaNevadoVelasquezFinal.pdf.jpgTesisMaestriaPaulaAndreaNevadoVelasquezFinal.pdf.jpgGenerated 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