Two-phase kinetic model for epoxidation of soybean oil
A two-phase kinetic model was implemented for analyzing conventional epoxidation, using a percarboxylic acid gene- rated in situ through adding hydrogen peroxide in a two-phase system having a homogeneous catalyst. Data was adjusted using the least square method (0.88 correlation coefficient). The s...
- Autores:
-
Beltrán Osuna, Ángela Aurora
Boyacá Mendivelso, Luis Alejandro
- Tipo de recurso:
- Article of journal
- Fecha de publicación:
- 2010
- Institución:
- Universidad Nacional de Colombia
- Repositorio:
- Universidad Nacional de Colombia
- Idioma:
- spa
- OAI Identifier:
- oai:repositorio.unal.edu.co:unal/29665
- Acceso en línea:
- https://repositorio.unal.edu.co/handle/unal/29665
http://bdigital.unal.edu.co/19713/
http://bdigital.unal.edu.co/19713/2/
http://bdigital.unal.edu.co/19713/3/
- Palabra clave:
- Ingeniería Química
Ingeniería de Alimentos
epoxidación in situ
apertura del anillo oxirano
modelo cinético de dos fases
Chemical Engineering
Food Engineering
in situ epoxidation
oxirane ring-opening reaction
two-phase kinetic model
- Rights
- openAccess
- License
- Atribución-NoComercial 4.0 Internacional
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Atribución-NoComercial 4.0 InternacionalDerechos reservados - Universidad Nacional de Colombiahttp://creativecommons.org/licenses/by-nc/4.0/info:eu-repo/semantics/openAccesshttp://purl.org/coar/access_right/c_abf2Beltrán Osuna, Ángela Aurora1595877b-4dc1-4124-b5d3-37d38c817a97300Boyacá Mendivelso, Luis Alejandrobe66e33d-bc94-4b45-867b-72dd9540d96d3002019-06-26T13:43:57Z2019-06-26T13:43:57Z2010https://repositorio.unal.edu.co/handle/unal/29665http://bdigital.unal.edu.co/19713/http://bdigital.unal.edu.co/19713/2/http://bdigital.unal.edu.co/19713/3/A two-phase kinetic model was implemented for analyzing conventional epoxidation, using a percarboxylic acid gene- rated in situ through adding hydrogen peroxide in a two-phase system having a homogeneous catalyst. Data was adjusted using the least square method (0.88 correlation coefficient). The simulation closely predicted oxirane oxygen content values, especially during the first stage of reaction and deviation at the end of epoxidation due, possibly, to different degradation reactions.Se implementa un modelo cinético de dos fases para el análisis de un proceso convencional de epoxidación, utilizando un ácido percarboxílico generado in situ mediante la adición de peróxido de hidrógeno, en un sistema de dos fases usando un catalizador homogéneo. Los datos obtenidos se ajustan mediante el método de mínimos cuadrados (obteniendo un coeficiente de correlación de 0,88). En general, la simulación predice cercanamente los valores de contenido de oxígeno oxirano, en especial durante la primera etapa de reacción, y una desviación hacia el final de la epoxidación debida posiblemente a las múltiples reacciones de degradación.application/pdfspaUniversidad Nacional de Colombia - Facultad de Ingenieríahttp://revistas.unal.edu.co/index.php/ingeinv/article/view/15749Universidad Nacional de Colombia Revistas electrónicas UN Ingeniería e InvestigaciónIngeniería e InvestigaciónIngeniería e Investigación; Vol. 30, núm. 2 (2010); 188-196 Ingeniería e Investigación; Vol. 30, núm. 2 (2010); 188-196 2248-8723 0120-5609Beltrán Osuna, Ángela Aurora and Boyacá Mendivelso, Luis Alejandro (2010) Two-phase kinetic model for epoxidation of soybean oil. Ingeniería e Investigación; Vol. 30, núm. 2 (2010); 188-196 Ingeniería e Investigación; Vol. 30, núm. 2 (2010); 188-196 2248-8723 0120-5609 .Two-phase kinetic model for epoxidation of soybean oilArtículo de revistainfo:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501http://purl.org/coar/resource_type/c_2df8fbb1http://purl.org/coar/version/c_970fb48d4fbd8a85Texthttp://purl.org/redcol/resource_type/ARTIngeniería QuímicaIngeniería de Alimentosepoxidación in situapertura del anillo oxiranomodelo cinético de dos fasesChemical EngineeringFood Engineeringin situ epoxidationoxirane ring-opening reactiontwo-phase kinetic modelORIGINAL15749-48398-1-PB.pdfapplication/pdf1982530https://repositorio.unal.edu.co/bitstream/unal/29665/1/15749-48398-1-PB.pdf976728dadf416662ae68d2fbdd15cf69MD51THUMBNAIL15749-48398-1-PB.pdf.jpg15749-48398-1-PB.pdf.jpgGenerated Thumbnailimage/jpeg8889https://repositorio.unal.edu.co/bitstream/unal/29665/2/15749-48398-1-PB.pdf.jpg92b6e2bcae50f1c7c471f7d2a98016d8MD52unal/29665oai:repositorio.unal.edu.co:unal/296652022-11-22 23:04:38.729Repositorio Institucional Universidad Nacional de Colombiarepositorio_nal@unal.edu.co |
dc.title.spa.fl_str_mv |
Two-phase kinetic model for epoxidation of soybean oil |
title |
Two-phase kinetic model for epoxidation of soybean oil |
spellingShingle |
Two-phase kinetic model for epoxidation of soybean oil Ingeniería Química Ingeniería de Alimentos epoxidación in situ apertura del anillo oxirano modelo cinético de dos fases Chemical Engineering Food Engineering in situ epoxidation oxirane ring-opening reaction two-phase kinetic model |
title_short |
Two-phase kinetic model for epoxidation of soybean oil |
title_full |
Two-phase kinetic model for epoxidation of soybean oil |
title_fullStr |
Two-phase kinetic model for epoxidation of soybean oil |
title_full_unstemmed |
Two-phase kinetic model for epoxidation of soybean oil |
title_sort |
Two-phase kinetic model for epoxidation of soybean oil |
dc.creator.fl_str_mv |
Beltrán Osuna, Ángela Aurora Boyacá Mendivelso, Luis Alejandro |
dc.contributor.author.spa.fl_str_mv |
Beltrán Osuna, Ángela Aurora Boyacá Mendivelso, Luis Alejandro |
dc.subject.proposal.spa.fl_str_mv |
Ingeniería Química Ingeniería de Alimentos epoxidación in situ apertura del anillo oxirano modelo cinético de dos fases Chemical Engineering Food Engineering in situ epoxidation oxirane ring-opening reaction two-phase kinetic model |
topic |
Ingeniería Química Ingeniería de Alimentos epoxidación in situ apertura del anillo oxirano modelo cinético de dos fases Chemical Engineering Food Engineering in situ epoxidation oxirane ring-opening reaction two-phase kinetic model |
description |
A two-phase kinetic model was implemented for analyzing conventional epoxidation, using a percarboxylic acid gene- rated in situ through adding hydrogen peroxide in a two-phase system having a homogeneous catalyst. Data was adjusted using the least square method (0.88 correlation coefficient). The simulation closely predicted oxirane oxygen content values, especially during the first stage of reaction and deviation at the end of epoxidation due, possibly, to different degradation reactions. |
publishDate |
2010 |
dc.date.issued.spa.fl_str_mv |
2010 |
dc.date.accessioned.spa.fl_str_mv |
2019-06-26T13:43:57Z |
dc.date.available.spa.fl_str_mv |
2019-06-26T13:43:57Z |
dc.type.spa.fl_str_mv |
Artículo de revista |
dc.type.coar.fl_str_mv |
http://purl.org/coar/resource_type/c_2df8fbb1 |
dc.type.driver.spa.fl_str_mv |
info:eu-repo/semantics/article |
dc.type.version.spa.fl_str_mv |
info:eu-repo/semantics/publishedVersion |
dc.type.coar.spa.fl_str_mv |
http://purl.org/coar/resource_type/c_6501 |
dc.type.coarversion.spa.fl_str_mv |
http://purl.org/coar/version/c_970fb48d4fbd8a85 |
dc.type.content.spa.fl_str_mv |
Text |
dc.type.redcol.spa.fl_str_mv |
http://purl.org/redcol/resource_type/ART |
format |
http://purl.org/coar/resource_type/c_6501 |
status_str |
publishedVersion |
dc.identifier.uri.none.fl_str_mv |
https://repositorio.unal.edu.co/handle/unal/29665 |
dc.identifier.eprints.spa.fl_str_mv |
http://bdigital.unal.edu.co/19713/ http://bdigital.unal.edu.co/19713/2/ http://bdigital.unal.edu.co/19713/3/ |
url |
https://repositorio.unal.edu.co/handle/unal/29665 http://bdigital.unal.edu.co/19713/ http://bdigital.unal.edu.co/19713/2/ http://bdigital.unal.edu.co/19713/3/ |
dc.language.iso.spa.fl_str_mv |
spa |
language |
spa |
dc.relation.spa.fl_str_mv |
http://revistas.unal.edu.co/index.php/ingeinv/article/view/15749 |
dc.relation.ispartof.spa.fl_str_mv |
Universidad Nacional de Colombia Revistas electrónicas UN Ingeniería e Investigación Ingeniería e Investigación |
dc.relation.ispartofseries.none.fl_str_mv |
Ingeniería e Investigación; Vol. 30, núm. 2 (2010); 188-196 Ingeniería e Investigación; Vol. 30, núm. 2 (2010); 188-196 2248-8723 0120-5609 |
dc.relation.references.spa.fl_str_mv |
Beltrán Osuna, Ángela Aurora and Boyacá Mendivelso, Luis Alejandro (2010) Two-phase kinetic model for epoxidation of soybean oil. Ingeniería e Investigación; Vol. 30, núm. 2 (2010); 188-196 Ingeniería e Investigación; Vol. 30, núm. 2 (2010); 188-196 2248-8723 0120-5609 . |
dc.rights.spa.fl_str_mv |
Derechos reservados - Universidad Nacional de Colombia |
dc.rights.coar.fl_str_mv |
http://purl.org/coar/access_right/c_abf2 |
dc.rights.license.spa.fl_str_mv |
Atribución-NoComercial 4.0 Internacional |
dc.rights.uri.spa.fl_str_mv |
http://creativecommons.org/licenses/by-nc/4.0/ |
dc.rights.accessrights.spa.fl_str_mv |
info:eu-repo/semantics/openAccess |
rights_invalid_str_mv |
Atribución-NoComercial 4.0 Internacional Derechos reservados - Universidad Nacional de Colombia http://creativecommons.org/licenses/by-nc/4.0/ http://purl.org/coar/access_right/c_abf2 |
eu_rights_str_mv |
openAccess |
dc.format.mimetype.spa.fl_str_mv |
application/pdf |
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Universidad Nacional de Colombia - Facultad de Ingeniería |
institution |
Universidad Nacional de Colombia |
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