Cadmium voltametric quantification in table chocolate produced in Chiquinquira-Boyaca, Colombia

Bioaccumulation of heavy metals such as cadmium has been a major concern in scientific communities and international food organizations, given the great toxicological risk to the consumer, and in many places there is no detailed record of its actual content. In this way, the need arises to carry out...

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Autores:
Vargas Moreno, Paola Andrea
Silva Gómez, Leonardo Andrés
Chaparro Acuña, Sandra Patricia
Cárdenas, Oswaldo Eliécer
Tipo de recurso:
Article of journal
Fecha de publicación:
2017
Institución:
Universidad Nacional de Colombia
Repositorio:
Universidad Nacional de Colombia
Idioma:
spa
OAI Identifier:
oai:repositorio.unal.edu.co:unal/61104
Acceso en línea:
https://repositorio.unal.edu.co/handle/unal/61104
http://bdigital.unal.edu.co/59912/
Palabra clave:
55 Ciencias de la tierra / Earth sciences and geology
63 Agricultura y tecnologías relacionadas / Agriculture
Food
cocoa
electrochemistry
heavy metals
validation
alimentos
cacao
electroquímica
metales pesados
validación.
Rights
openAccess
License
Atribución-NoComercial 4.0 Internacional
Description
Summary:Bioaccumulation of heavy metals such as cadmium has been a major concern in scientific communities and international food organizations, given the great toxicological risk to the consumer, and in many places there is no detailed record of its actual content. In this way, the need arises to carry out a study and registration of the concentration of this metal in products such as table chocolate, of great consumption at regional and national level. Likewise, we seek to have effective quantification tools and a reliable and affordable method to achieve the aim of this research. In this research, Cadmium content in powdered and granulated table chocolate was determined, elaborated and commercialized in the municipality of Chiquinquira, Boyacá-Colombia, using the differential pulse voltammetric method of anodic redisolution (DPVMAR). Previously, the parameters of this method were evaluated, selecting selectivity, linearity, sensitivity, precision and accuracy with satisfactory results as follows: selective at a potential range of 0.54 to 0.64 V, sensitivity in ppb, R2 0.95, % CV 10% % R 80%). Analysis of variance showed no significant statistical differences (P 0.05) between the results. Cadmium quantification in samples of granulated and powder chocolate showed values of concentration between 214 and 260 ppb, with the highest concentrations of powder chocolate. Cadmium level did not exceed the tolerable weekly intake limit for this type of food.