Síntesis de zeolitas na-p empleando Clinker natural y aluminio post-consumo. evaluación en la liberación controlada de pesticidas y fungicidas en legumbres

El clinker natural es una roca sedimentaria alterada térmicamente mediante la combustión espontánea de los mantos de carbón del subsuelo, este proceso oxidativo se debe a la exposición del carbón a diferentes condiciones atmosféricas como lo son la erosión, la minería a cielo abierto y/o al contacto...

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Autores:
Triana Merlo, Andres Dario
Tipo de recurso:
http://purl.org/coar/version/c_b1a7d7d4d402bcce
Fecha de publicación:
2016
Institución:
Universidad Industrial de Santander
Repositorio:
Repositorio UIS
Idioma:
spa
OAI Identifier:
oai:noesis.uis.edu.co:20.500.14071/34955
Acceso en línea:
https://noesis.uis.edu.co/handle/20.500.14071/34955
https://noesis.uis.edu.co
Palabra clave:
Zeolitas
Zeolita Na-P
Pesticidas
Clinker Natural
Lactuca Sativa.
Natural clinker is a sedimentary rock thermally altered during the spontaneous combustion of the coal beds from the subsoil
this oxidative process is due to the coal exposition to different atmospheric conditions such as erosion
open pit mining
or contact with oxygen in the depths of the soil. Thanks to its high concentration of Si
it is possible to use this rock as a precursor for zeolites synthesis so we use a sample of natural clinker from the mining cwhich was treated in an alkaline fusion process with 3 M NaOH until its amorphization. Starting with the generated vitreous material
hydrothermal synthesis was employed to synthesize the structure of the Na-P type zeolite which was found at a concentration of 37.8% within the solid and was chosen to study its effect on Lactuca sativa crops and the elimination of a fungicide such as DithaneTM M-45 in this kind of vegetables. The combination of a 5% zeolitized clinker and 3% chicken manure mixture regarding the rice husk was the most effective because it was able to remove approximately half the concentration of the fungicide found in the plants and nurture them with a higher quantity of minerals. Natural clinker
vitreous material
and the zeolyzed clinker were analyzed by X-Ray powder Diffraction (XRD)
X-Ray Fluorescence (XRF) and Atomic Absorption spectroscopy (AA). The content of some minerals in L. sativa plants was determined by AA and the DithaneTM M-45 was characterized and quantified by Infrared spectroscopy (IR)
XRF and Ultraviolet-Visible spectroscopy (UV-Visible)
respectively.
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network_acronym_str UISANTADR2
network_name_str Repositorio UIS
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dc.title.none.fl_str_mv Síntesis de zeolitas na-p empleando Clinker natural y aluminio post-consumo. evaluación en la liberación controlada de pesticidas y fungicidas en legumbres
dc.title.english.none.fl_str_mv Zeolites, Na-P Type Zeolite, Pesticides, Natural Clinker, Lactuca Sativa.
title Síntesis de zeolitas na-p empleando Clinker natural y aluminio post-consumo. evaluación en la liberación controlada de pesticidas y fungicidas en legumbres
spellingShingle Síntesis de zeolitas na-p empleando Clinker natural y aluminio post-consumo. evaluación en la liberación controlada de pesticidas y fungicidas en legumbres
Zeolitas
Zeolita Na-P
Pesticidas
Clinker Natural
Lactuca Sativa.
Natural clinker is a sedimentary rock thermally altered during the spontaneous combustion of the coal beds from the subsoil
this oxidative process is due to the coal exposition to different atmospheric conditions such as erosion
open pit mining
or contact with oxygen in the depths of the soil. Thanks to its high concentration of Si
it is possible to use this rock as a precursor for zeolites synthesis so we use a sample of natural clinker from the mining cwhich was treated in an alkaline fusion process with 3 M NaOH until its amorphization. Starting with the generated vitreous material
hydrothermal synthesis was employed to synthesize the structure of the Na-P type zeolite which was found at a concentration of 37.8% within the solid and was chosen to study its effect on Lactuca sativa crops and the elimination of a fungicide such as DithaneTM M-45 in this kind of vegetables. The combination of a 5% zeolitized clinker and 3% chicken manure mixture regarding the rice husk was the most effective because it was able to remove approximately half the concentration of the fungicide found in the plants and nurture them with a higher quantity of minerals. Natural clinker
vitreous material
and the zeolyzed clinker were analyzed by X-Ray powder Diffraction (XRD)
X-Ray Fluorescence (XRF) and Atomic Absorption spectroscopy (AA). The content of some minerals in L. sativa plants was determined by AA and the DithaneTM M-45 was characterized and quantified by Infrared spectroscopy (IR)
XRF and Ultraviolet-Visible spectroscopy (UV-Visible)
respectively.
title_short Síntesis de zeolitas na-p empleando Clinker natural y aluminio post-consumo. evaluación en la liberación controlada de pesticidas y fungicidas en legumbres
title_full Síntesis de zeolitas na-p empleando Clinker natural y aluminio post-consumo. evaluación en la liberación controlada de pesticidas y fungicidas en legumbres
title_fullStr Síntesis de zeolitas na-p empleando Clinker natural y aluminio post-consumo. evaluación en la liberación controlada de pesticidas y fungicidas en legumbres
title_full_unstemmed Síntesis de zeolitas na-p empleando Clinker natural y aluminio post-consumo. evaluación en la liberación controlada de pesticidas y fungicidas en legumbres
title_sort Síntesis de zeolitas na-p empleando Clinker natural y aluminio post-consumo. evaluación en la liberación controlada de pesticidas y fungicidas en legumbres
dc.creator.fl_str_mv Triana Merlo, Andres Dario
dc.contributor.advisor.none.fl_str_mv Henao Martinez, Jose Antonio
Quintana Mendoza, Jose Hernando
Garnica Ruiz, Cristian Camilo
dc.contributor.author.none.fl_str_mv Triana Merlo, Andres Dario
dc.subject.none.fl_str_mv Zeolitas
Zeolita Na-P
Pesticidas
Clinker Natural
Lactuca Sativa.
topic Zeolitas
Zeolita Na-P
Pesticidas
Clinker Natural
Lactuca Sativa.
Natural clinker is a sedimentary rock thermally altered during the spontaneous combustion of the coal beds from the subsoil
this oxidative process is due to the coal exposition to different atmospheric conditions such as erosion
open pit mining
or contact with oxygen in the depths of the soil. Thanks to its high concentration of Si
it is possible to use this rock as a precursor for zeolites synthesis so we use a sample of natural clinker from the mining cwhich was treated in an alkaline fusion process with 3 M NaOH until its amorphization. Starting with the generated vitreous material
hydrothermal synthesis was employed to synthesize the structure of the Na-P type zeolite which was found at a concentration of 37.8% within the solid and was chosen to study its effect on Lactuca sativa crops and the elimination of a fungicide such as DithaneTM M-45 in this kind of vegetables. The combination of a 5% zeolitized clinker and 3% chicken manure mixture regarding the rice husk was the most effective because it was able to remove approximately half the concentration of the fungicide found in the plants and nurture them with a higher quantity of minerals. Natural clinker
vitreous material
and the zeolyzed clinker were analyzed by X-Ray powder Diffraction (XRD)
X-Ray Fluorescence (XRF) and Atomic Absorption spectroscopy (AA). The content of some minerals in L. sativa plants was determined by AA and the DithaneTM M-45 was characterized and quantified by Infrared spectroscopy (IR)
XRF and Ultraviolet-Visible spectroscopy (UV-Visible)
respectively.
dc.subject.keyword.none.fl_str_mv Natural clinker is a sedimentary rock thermally altered during the spontaneous combustion of the coal beds from the subsoil
this oxidative process is due to the coal exposition to different atmospheric conditions such as erosion
open pit mining
or contact with oxygen in the depths of the soil. Thanks to its high concentration of Si
it is possible to use this rock as a precursor for zeolites synthesis so we use a sample of natural clinker from the mining cwhich was treated in an alkaline fusion process with 3 M NaOH until its amorphization. Starting with the generated vitreous material
hydrothermal synthesis was employed to synthesize the structure of the Na-P type zeolite which was found at a concentration of 37.8% within the solid and was chosen to study its effect on Lactuca sativa crops and the elimination of a fungicide such as DithaneTM M-45 in this kind of vegetables. The combination of a 5% zeolitized clinker and 3% chicken manure mixture regarding the rice husk was the most effective because it was able to remove approximately half the concentration of the fungicide found in the plants and nurture them with a higher quantity of minerals. Natural clinker
vitreous material
and the zeolyzed clinker were analyzed by X-Ray powder Diffraction (XRD)
X-Ray Fluorescence (XRF) and Atomic Absorption spectroscopy (AA). The content of some minerals in L. sativa plants was determined by AA and the DithaneTM M-45 was characterized and quantified by Infrared spectroscopy (IR)
XRF and Ultraviolet-Visible spectroscopy (UV-Visible)
respectively.
description El clinker natural es una roca sedimentaria alterada térmicamente mediante la combustión espontánea de los mantos de carbón del subsuelo, este proceso oxidativo se debe a la exposición del carbón a diferentes condiciones atmosféricas como lo son la erosión, la minería a cielo abierto y/o al contacto con el oxígeno de las profundidades del suelo. Debido a su alto contenido de Si, es posible pensar en esta roca como un buen precursor para la síntesis de zeolitas por lo que se tomó una muestra de clinker natury fue tratada en un proceso de fusión alcalina con NaOH 3 M hasta amorfizarla. Partiendo del material vítreo generado se aplicó métodos hidrotermales para sintetizar la zeolita Na-P que se encontró en un 37,8% dentro del sólido como la fase más abundante y con la cual se estudió su influencia en cultivos experimentales de Lactuca sativa de la clase longifolia y la eliminación del fungicida DithaneTM M-45 en esta clase de legumbres. La combinación del 5% del clinker zeolitizado y 3% de gallinaza con respecto al tamo de arroz fue la más efectiva ya que logró remover aproximadamente la mitad del fungicida presente en las plantas y también las nutrió de una mayor cantidad de minerales. El clinker natural, el crudo de reacción y el clinker zeolitizado fueron caracterizados empleando las técnicas de Difracción de Rayos-X de muestras policristalinas (DRX), Fluorescencia de Rayos-X (FRX) y espectroscopia de Absorción Atómica (AA). El contenido de algunos minerales en L. sativa fue determinado por AA y el DithaneTM M-45 fue caracterizado y cuantificado por espectroscopia de Infrarrojo (IR), FRX y UV-Vis, respectivamente.
publishDate 2016
dc.date.available.none.fl_str_mv 2016
2024-03-03T22:43:29Z
dc.date.created.none.fl_str_mv 2016
dc.date.issued.none.fl_str_mv 2016
dc.date.accessioned.none.fl_str_mv 2024-03-03T22:43:29Z
dc.type.local.none.fl_str_mv Tesis/Trabajo de grado - Monografía - Pregrado
dc.type.hasversion.none.fl_str_mv http://purl.org/coar/resource_type/c_7a1f
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format http://purl.org/coar/version/c_b1a7d7d4d402bcce
dc.identifier.uri.none.fl_str_mv https://noesis.uis.edu.co/handle/20.500.14071/34955
dc.identifier.instname.none.fl_str_mv Universidad Industrial de Santander
dc.identifier.reponame.none.fl_str_mv Universidad Industrial de Santander
dc.identifier.repourl.none.fl_str_mv https://noesis.uis.edu.co
url https://noesis.uis.edu.co/handle/20.500.14071/34955
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identifier_str_mv Universidad Industrial de Santander
dc.language.iso.none.fl_str_mv spa
language spa
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dc.rights.license.none.fl_str_mv Attribution-NonCommercial 4.0 International (CC BY-NC 4.0)
dc.rights.uri.none.fl_str_mv http://creativecommons.org/licenses/by-nc/4.0
dc.rights.creativecommons.none.fl_str_mv Atribución-NoComercial-SinDerivadas 4.0 Internacional (CC BY-NC-ND 4.0)
rights_invalid_str_mv Attribution-NonCommercial 4.0 International (CC BY-NC 4.0)
http://creativecommons.org/licenses/by/4.0/
http://creativecommons.org/licenses/by-nc/4.0
Atribución-NoComercial-SinDerivadas 4.0 Internacional (CC BY-NC-ND 4.0)
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dc.publisher.none.fl_str_mv Universidad Industrial de Santander
dc.publisher.faculty.none.fl_str_mv Facultad de Ciencias
dc.publisher.program.none.fl_str_mv Química
dc.publisher.school.none.fl_str_mv Escuela de Química
publisher.none.fl_str_mv Universidad Industrial de Santander
institution Universidad Industrial de Santander
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spelling Attribution-NonCommercial 4.0 International (CC BY-NC 4.0)http://creativecommons.org/licenses/by/4.0/http://creativecommons.org/licenses/by-nc/4.0Atribución-NoComercial-SinDerivadas 4.0 Internacional (CC BY-NC-ND 4.0)http://purl.org/coar/access_right/c_abf2Henao Martinez, Jose AntonioQuintana Mendoza, Jose HernandoGarnica Ruiz, Cristian CamiloTriana Merlo, Andres Dario2024-03-03T22:43:29Z20162024-03-03T22:43:29Z20162016https://noesis.uis.edu.co/handle/20.500.14071/34955Universidad Industrial de SantanderUniversidad Industrial de Santanderhttps://noesis.uis.edu.coEl clinker natural es una roca sedimentaria alterada térmicamente mediante la combustión espontánea de los mantos de carbón del subsuelo, este proceso oxidativo se debe a la exposición del carbón a diferentes condiciones atmosféricas como lo son la erosión, la minería a cielo abierto y/o al contacto con el oxígeno de las profundidades del suelo. Debido a su alto contenido de Si, es posible pensar en esta roca como un buen precursor para la síntesis de zeolitas por lo que se tomó una muestra de clinker natury fue tratada en un proceso de fusión alcalina con NaOH 3 M hasta amorfizarla. Partiendo del material vítreo generado se aplicó métodos hidrotermales para sintetizar la zeolita Na-P que se encontró en un 37,8% dentro del sólido como la fase más abundante y con la cual se estudió su influencia en cultivos experimentales de Lactuca sativa de la clase longifolia y la eliminación del fungicida DithaneTM M-45 en esta clase de legumbres. La combinación del 5% del clinker zeolitizado y 3% de gallinaza con respecto al tamo de arroz fue la más efectiva ya que logró remover aproximadamente la mitad del fungicida presente en las plantas y también las nutrió de una mayor cantidad de minerales. El clinker natural, el crudo de reacción y el clinker zeolitizado fueron caracterizados empleando las técnicas de Difracción de Rayos-X de muestras policristalinas (DRX), Fluorescencia de Rayos-X (FRX) y espectroscopia de Absorción Atómica (AA). El contenido de algunos minerales en L. sativa fue determinado por AA y el DithaneTM M-45 fue caracterizado y cuantificado por espectroscopia de Infrarrojo (IR), FRX y UV-Vis, respectivamente.PregradoQuímicoSynthesis of na-p type zeolite using natural clinker and post consume aluminum, study of the controlled liberation of pesticides and fungicides in vegetables.application/pdfspaUniversidad Industrial de SantanderFacultad de CienciasQuímicaEscuela de QuímicaZeolitasZeolita Na-PPesticidasClinker NaturalLactuca Sativa.Natural clinker is a sedimentary rock thermally altered during the spontaneous combustion of the coal beds from the subsoilthis oxidative process is due to the coal exposition to different atmospheric conditions such as erosionopen pit miningor contact with oxygen in the depths of the soil. Thanks to its high concentration of Siit is possible to use this rock as a precursor for zeolites synthesis so we use a sample of natural clinker from the mining cwhich was treated in an alkaline fusion process with 3 M NaOH until its amorphization. Starting with the generated vitreous materialhydrothermal synthesis was employed to synthesize the structure of the Na-P type zeolite which was found at a concentration of 37.8% within the solid and was chosen to study its effect on Lactuca sativa crops and the elimination of a fungicide such as DithaneTM M-45 in this kind of vegetables. The combination of a 5% zeolitized clinker and 3% chicken manure mixture regarding the rice husk was the most effective because it was able to remove approximately half the concentration of the fungicide found in the plants and nurture them with a higher quantity of minerals. Natural clinkervitreous materialand the zeolyzed clinker were analyzed by X-Ray powder Diffraction (XRD)X-Ray Fluorescence (XRF) and Atomic Absorption spectroscopy (AA). The content of some minerals in L. sativa plants was determined by AA and the DithaneTM M-45 was characterized and quantified by Infrared spectroscopy (IR)XRF and Ultraviolet-Visible spectroscopy (UV-Visible)respectively.Síntesis de zeolitas na-p empleando Clinker natural y aluminio post-consumo. evaluación en la liberación controlada de pesticidas y fungicidas en legumbresZeolites, Na-P Type Zeolite, Pesticides, Natural Clinker, Lactuca Sativa.Tesis/Trabajo de grado - Monografía - Pregradohttp://purl.org/coar/resource_type/c_7a1fhttp://purl.org/coar/version/c_b1a7d7d4d402bcceORIGINALCarta de autorización.pdfapplication/pdf258393https://noesis.uis.edu.co/bitstreams/fc9fc0b5-1205-4f46-903d-9dc900affdf4/download92f516846869cdedbc7585e612673e21MD51Documento.pdfapplication/pdf3816437https://noesis.uis.edu.co/bitstreams/28962e29-c61e-4164-a548-892ef37f4a59/download5ebbc54b146d803196b6c48586545bc2MD52Nota de proyecto.pdfapplication/pdf174090https://noesis.uis.edu.co/bitstreams/bf4a03ef-07ba-4e70-86a1-57c4ae9193ff/downloadac4d74734e4f222bc52cbf8d2c523162MD5320.500.14071/34955oai:noesis.uis.edu.co:20.500.14071/349552024-03-03 17:43:29.812http://creativecommons.org/licenses/by-nc/4.0http://creativecommons.org/licenses/by/4.0/open.accesshttps://noesis.uis.edu.coDSpace at UISnoesis@uis.edu.co