Optimization of a cape gooseberry colloidal system for the micro-encapsulation process

Cape gooseberry is a fruit that contains various active compounds such as vitamins A, B, and C, proteins, minerals, tocopherols, and carotenoids, among others, which provide health benefits. The objective of this research was to experimentally optimize a colloidal system formulation based on cape go...

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Autores:
Eraso Grisales, Soany
Cortés Rodríguez, Misael
Hurtado-Benavides, Andrés Mauricio
Tipo de recurso:
Article of investigation
Fecha de publicación:
2024
Institución:
Universidad de Ciencias Aplicadas y Ambientales U.D.C.A
Repositorio:
Repositorio Institucional UDCA
Idioma:
eng
OAI Identifier:
oai:repository.udca.edu.co:11158/6054
Acceso en línea:
https://repository.udca.edu.co/handle/11158/6054
https://doi.org/10.31910/rudca.v27.n2.2024.2060
https://repository.udca.edu.co/
Palabra clave:
630 - Agricultura y tecnologías relacionadas::634 - Huertos, frutas, silvicultura
Fuerzas electrostáticas
Fuerzas de Van der Waals
Uchuva
Estabilidad coloidal
Homogeneización
Physalis peruviana
Rights
openAccess
License
https://creativecommons.org/licenses/by-nc-sa/4.0/legalcode.es
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dc.title.eng.fl_str_mv Optimization of a cape gooseberry colloidal system for the micro-encapsulation process
dc.title.spa.fl_str_mv Optimización de un sistema coloidal de uchuva para el proceso de microencapsulación
title Optimization of a cape gooseberry colloidal system for the micro-encapsulation process
spellingShingle Optimization of a cape gooseberry colloidal system for the micro-encapsulation process
630 - Agricultura y tecnologías relacionadas::634 - Huertos, frutas, silvicultura
Fuerzas electrostáticas
Fuerzas de Van der Waals
Uchuva
Estabilidad coloidal
Homogeneización
Physalis peruviana
title_short Optimization of a cape gooseberry colloidal system for the micro-encapsulation process
title_full Optimization of a cape gooseberry colloidal system for the micro-encapsulation process
title_fullStr Optimization of a cape gooseberry colloidal system for the micro-encapsulation process
title_full_unstemmed Optimization of a cape gooseberry colloidal system for the micro-encapsulation process
title_sort Optimization of a cape gooseberry colloidal system for the micro-encapsulation process
dc.creator.fl_str_mv Eraso Grisales, Soany
Cortés Rodríguez, Misael
Hurtado-Benavides, Andrés Mauricio
dc.contributor.author.none.fl_str_mv Eraso Grisales, Soany
Cortés Rodríguez, Misael
dc.contributor.author.spa.fl_str_mv Hurtado-Benavides, Andrés Mauricio
dc.subject.ddc.none.fl_str_mv 630 - Agricultura y tecnologías relacionadas::634 - Huertos, frutas, silvicultura
topic 630 - Agricultura y tecnologías relacionadas::634 - Huertos, frutas, silvicultura
Fuerzas electrostáticas
Fuerzas de Van der Waals
Uchuva
Estabilidad coloidal
Homogeneización
Physalis peruviana
dc.subject.proposal.none.fl_str_mv Fuerzas electrostáticas
Fuerzas de Van der Waals
dc.subject.agrovoc.none.fl_str_mv Uchuva
Estabilidad coloidal
Homogeneización
Physalis peruviana
description Cape gooseberry is a fruit that contains various active compounds such as vitamins A, B, and C, proteins, minerals, tocopherols, and carotenoids, among others, which provide health benefits. The objective of this research was to experimentally optimize a colloidal system formulation based on cape gooseberry, gum arabic (GA), and maltodextrin (MD) (SCU+GA+MD) with the purpose of being subsequently used in a spray-drying micro-encapsulation process to protect and preserve its active components. A shear homogenizer colloid mill type was employed for the colloidal system preparation. The formulation design was conducted using a face-centered central composite design (α = 1), considering the independent variables: GA (1.0- 3.0%) and MD (9.5-13.5%), and the dependent variables: total solids (TS), viscosity (μ), zeta potential (ζ), particle size (D[4,3]), total phenols (TF), and antioxidant capacity (DPPH and ABTS assays). The optimal formulation was achieved with MD: 12.3% and GA: 3.0%, where the dependent variables were: TS: 32.2±0.1%, μ: 581.0±7.8 cP, ζ: -22.6±0.6 mV, D[4,3]: 77.9±2.0 µm, TF: 97.2±1.1 mg GAE 100 g-1, DPPH: 12.6±1.4 mg TE 100 g-1, ABTS: 13.5±0.6 mg TE 100 g-1. Experimental validation of the shear homogenization process for an integral colloidal system of cape gooseberry confirmed its physicochemical stability with significant solid content, rendering it suitable for spray-drying micro-encapsulation processes.
publishDate 2024
dc.date.accessioned.none.fl_str_mv 2024-09-16T17:15:20Z
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dc.date.issued.none.fl_str_mv 2024
dc.type.none.fl_str_mv Artículo de revista
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dc.identifier.citation.none.fl_str_mv Eraso-Grisales, S., Cortés-Rodríguez, M., & Hurtado-Benavides, A. (2024). Optimización de un sistema coloidal de uchuva para el proceso de microencapsulación . Revista U.D.C.A Actualidad & Divulgación Científica, 27(2). https://doi.org/10.31910/rudca.v27.n2.2024.2060
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identifier_str_mv Eraso-Grisales, S., Cortés-Rodríguez, M., & Hurtado-Benavides, A. (2024). Optimización de un sistema coloidal de uchuva para el proceso de microencapsulación . Revista U.D.C.A Actualidad & Divulgación Científica, 27(2). https://doi.org/10.31910/rudca.v27.n2.2024.2060
0123-4226
2619-2551
Universidad de Ciencias Aplicadas y Ambientales
UDCA
url https://repository.udca.edu.co/handle/11158/6054
https://doi.org/10.31910/rudca.v27.n2.2024.2060
https://repository.udca.edu.co/
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dc.relation.ispartofjournal.none.fl_str_mv Revista U.D.C.A Actualidad & Divulgación Científica
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spelling Eraso Grisales, Soanyvirtual::329-1Cortés Rodríguez, Misaelvirtual::330-1Hurtado-Benavides, Andrés Mauricio2024-09-16T17:15:20Z2024-09-16T17:15:20Z2024Eraso-Grisales, S., Cortés-Rodríguez, M., & Hurtado-Benavides, A. (2024). Optimización de un sistema coloidal de uchuva para el proceso de microencapsulación . Revista U.D.C.A Actualidad & Divulgación Científica, 27(2). https://doi.org/10.31910/rudca.v27.n2.2024.20600123-4226https://repository.udca.edu.co/handle/11158/6054https://doi.org/10.31910/rudca.v27.n2.2024.20602619-2551Universidad de Ciencias Aplicadas y AmbientalesUDCAhttps://repository.udca.edu.co/Cape gooseberry is a fruit that contains various active compounds such as vitamins A, B, and C, proteins, minerals, tocopherols, and carotenoids, among others, which provide health benefits. The objective of this research was to experimentally optimize a colloidal system formulation based on cape gooseberry, gum arabic (GA), and maltodextrin (MD) (SCU+GA+MD) with the purpose of being subsequently used in a spray-drying micro-encapsulation process to protect and preserve its active components. A shear homogenizer colloid mill type was employed for the colloidal system preparation. The formulation design was conducted using a face-centered central composite design (α = 1), considering the independent variables: GA (1.0- 3.0%) and MD (9.5-13.5%), and the dependent variables: total solids (TS), viscosity (μ), zeta potential (ζ), particle size (D[4,3]), total phenols (TF), and antioxidant capacity (DPPH and ABTS assays). The optimal formulation was achieved with MD: 12.3% and GA: 3.0%, where the dependent variables were: TS: 32.2±0.1%, μ: 581.0±7.8 cP, ζ: -22.6±0.6 mV, D[4,3]: 77.9±2.0 µm, TF: 97.2±1.1 mg GAE 100 g-1, DPPH: 12.6±1.4 mg TE 100 g-1, ABTS: 13.5±0.6 mg TE 100 g-1. Experimental validation of the shear homogenization process for an integral colloidal system of cape gooseberry confirmed its physicochemical stability with significant solid content, rendering it suitable for spray-drying micro-encapsulation processes.La uchuva es una fruta que contiene una variedad de compuestos activos como vitaminas A, B y C, proteínas, minerales, tocoferoles, carotenoides, entre otros que otorgan beneficios a la salud. El objetivo de esta investigación fue optimizar experimentalmente la formulación de un sistema coloidal a base de uchuva, goma arábiga (GA) y maltodextrina (MD) (SCU+GA+MD), con fines de ser utilizado posteriormente en un proceso de microencapsulación por secado por aspersión, y así, proteger y conservar sus componentes activos. Se utilizó un homogenizador por cizalla tipo molino coloidal para la preparación del sistema coloidal y el diseño de la formulación se realizó utilizando un diseño experimental central compuesto cara centrada (a = 1), considerando las variables independientes: GA (1,0-3,0 %) y MD (9,5-13,5 %) y las variables dependientes: sólidos totales (TS), viscosidad (µ), potencial zeta (ζ), tamaño de partícula (D [4,3]), fenoles totales (TF), capacidad antioxidante (métodos DPPH y ABTS). La formulación óptima se obtuvo con una formulación que contenía MD: 12,3 % y GA: 3,0 %, donde las variables dependientes fueron: TS: 32.2±0.1%, μ: 581,0±7,8 cP, ζ: -22.6±0.6 mV, D[4,3]: 77.9±2.0 µm, TF: 97,2±1,1 mg GAE 100 g-1, DPPH: 12,6±1,4 mg TE 100 g-1, ABTS: 13,5±0,6 mg TE 100 g-1. La validación experimental del proceso de homogenización por cizalla de un sistema coloidal integral de uchuva permitió garantizar su estabilidad fisicoquímica con un importante contenido de sólidos, y adecuado para ser utilizado en procesos de microencapsulación por secado por aspersión.Incluye referencias bibliográficasapplication/pdfengUniversidad de Ciencias Aplicadas y AmbientalesBogotáhttps://creativecommons.org/licenses/by-nc-sa/4.0/legalcode.eshttps://creativecommons.org/licenses/by-nc-sa/4.0/info:eu-repo/semantics/openAccessAtribución-NoComercial-CompartirIgual 4.0 Internacional (CC BY-NC-SA 4.0)http://purl.org/coar/access_right/c_abf2https://revistas.udca.edu.co/index.php/ruadc/article/view/2060630 - Agricultura y tecnologías relacionadas::634 - Huertos, frutas, silviculturaFuerzas electrostáticasFuerzas de Van der WaalsUchuvaEstabilidad coloidalHomogeneizaciónPhysalis peruvianaOptimization of a cape gooseberry colloidal system for the micro-encapsulation processOptimización 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jecuta públicamente en forma digital la Obra o cualquier Obra Derivada u Obra Colectiva, Usted debe mantener intacta toda la información de derecho de autor de la Obra y proporcionar, de forma razonable según el medio o manera que Usted esté utilizando: (i) el nombre del Autor Original si está provisto (o seudónimo, si fuere aplicable), y/o (ii) el nombre de la parte o las partes que el Autor Original y/o el Licenciante hubieren designado para la atribución (v.g., un instituto patrocinador, editorial, publicación) en la información de los derechos de autor del Licenciante, términos de servicios o de otras formas razonables; el título de la Obra si está provisto; en la medida de lo razonablemente factible y, si está provisto, el Identificador Uniforme de Recursos (Uniform Resource Identifier) que el Licenciante especifica para ser asociado con la Obra, salvo que tal URI no se refiera a la nota sobre los derechos de autor o a la información sobre el licenciamiento de la Obra; y en el caso de una Obra Derivada, atribuir el crédito identificando el uso de la Obra en la Obra Derivada (v.g., "Traducción Francesa de la Obra del Autor Original," o "Guión Cinematográfico basado en la Obra original del Autor Original"). Tal crédito puede ser implementado de cualquier forma razonable; en el caso, sin embargo, de Obras Derivadas u Obras Colectivas, tal crédito aparecerá, como mínimo, donde aparece el crédito de cualquier otro autor comparable y de una manera, al menos, tan destacada como el crédito de otro autor comparable.</li>
      <li>
        Para evitar toda confusión, el Licenciante aclara que, cuando la obra es una composición musical:
        <ol type="i">
          <li>Regalías por interpretación y ejecución bajo licencias generales. El Licenciante se reserva el derecho exclusivo de autorizar la ejecución pública o la ejecución pública digital de la obra y de recolectar, sea individualmente o a través de una sociedad de gestión colectiva de derechos de autor y derechos conexos (por ejemplo, SAYCO), las regalías por la ejecución pública o por la ejecución pública digital de la obra (por ejemplo Webcast) licenciada bajo licencias generales, si la interpretación o ejecución de la obra está primordialmente orientada por o dirigida a la obtención de una ventaja comercial o una compensación monetaria privada.</li>
          <li>Regalías por Fonogramas. El Licenciante se reserva el derecho exclusivo de recolectar, individualmente o a través de una sociedad de gestión colectiva de derechos de autor y derechos conexos (por ejemplo, los consagrados por la SAYCO), una agencia de derechos musicales o algún agente designado, las regalías por cualquier fonograma que Usted cree a partir de la obra (“versión cover”) y distribuya, en los términos del régimen de derechos de autor, si la creación o distribución de esa versión cover está primordialmente destinada o dirigida a obtener una ventaja comercial o una compensación monetaria privada.</li>
        </ol>
      </li>
      <li>Gestión de Derechos de Autor sobre Interpretaciones y Ejecuciones Digitales (WebCasting). Para evitar toda confusión, el Licenciante aclara que, cuando la obra sea un fonograma, el Licenciante se reserva el derecho exclusivo de autorizar la ejecución pública digital de la obra (por ejemplo, webcast) y de recolectar, individualmente o a través de una sociedad de gestión colectiva de derechos de autor y derechos conexos (por ejemplo, ACINPRO), las regalías por la ejecución pública digital de la obra (por ejemplo, webcast), sujeta a las disposiciones aplicables del régimen de Derecho de Autor, si esta ejecución pública digital está primordialmente dirigida a obtener una ventaja comercial o una compensación monetaria privada.</li>
    </ol>
  </li>
  <br/>
  <li>
    Representaciones, Garantías y Limitaciones de Responsabilidad.
    <p>A MENOS QUE LAS PARTES LO ACORDARAN DE OTRA FORMA POR ESCRITO, EL LICENCIANTE OFRECE LA OBRA (EN EL ESTADO EN EL QUE SE ENCUENTRA) “TAL CUAL”, SIN BRINDAR GARANTÍAS DE CLASE ALGUNA RESPECTO DE LA OBRA, YA SEA EXPRESA, IMPLÍCITA, LEGAL O CUALQUIERA OTRA, INCLUYENDO, SIN LIMITARSE A ELLAS, GARANTÍAS DE TITULARIDAD, COMERCIABILIDAD, ADAPTABILIDAD O ADECUACIÓN A PROPÓSITO DETERMINADO, AUSENCIA DE INFRACCIÓN, DE AUSENCIA DE DEFECTOS LATENTES O DE OTRO TIPO, O LA PRESENCIA O AUSENCIA DE ERRORES, SEAN O NO DESCUBRIBLES (PUEDAN O NO SER ESTOS DESCUBIERTOS). ALGUNAS JURISDICCIONES NO PERMITEN LA EXCLUSIÓN DE GARANTÍAS IMPLÍCITAS, EN CUYO CASO ESTA EXCLUSIÓN PUEDE NO APLICARSE A USTED.</p>
  </li>
  <br/>
  <li>
    Limitación de responsabilidad.
    <p>A MENOS QUE LO EXIJA EXPRESAMENTE LA LEY APLICABLE, EL LICENCIANTE NO SERÁ RESPONSABLE ANTE USTED POR DAÑO ALGUNO, SEA POR RESPONSABILIDAD EXTRACONTRACTUAL, PRECONTRACTUAL O CONTRACTUAL, OBJETIVA O SUBJETIVA, SE TRATE DE DAÑOS MORALES O PATRIMONIALES, DIRECTOS O INDIRECTOS, PREVISTOS O IMPREVISTOS PRODUCIDOS POR EL USO DE ESTA LICENCIA O DE LA OBRA, AUN CUANDO EL LICENCIANTE HAYA SIDO ADVERTIDO DE LA POSIBILIDAD DE DICHOS DAÑOS. ALGUNAS LEYES NO PERMITEN LA EXCLUSIÓN DE CIERTA RESPONSABILIDAD, EN CUYO CASO ESTA EXCLUSIÓN PUEDE NO APLICARSE A USTED.</p>
  </li>
  <br/>
  <li>
    Término.
    <ol type="a">
      <li>Esta Licencia y los derechos otorgados en virtud de ella terminarán automáticamente si Usted infringe alguna condición establecida en ella. Sin embargo, los individuos o entidades que han recibido Obras Derivadas o Colectivas de Usted de conformidad con esta Licencia, no verán terminadas sus licencias, siempre que estos individuos o entidades sigan cumpliendo íntegramente las condiciones de estas licencias. Las Secciones 1, 2, 5, 6, 7, y 8 subsistirán a cualquier terminación de esta Licencia.</li>
      <li>Sujeta a las condiciones y términos anteriores, la licencia otorgada aquí es perpetua (durante el período de vigencia de los derechos de autor de la obra). No obstante lo anterior, el Licenciante se reserva el derecho a publicar y/o estrenar la Obra bajo condiciones de licencia diferentes o a dejar de distribuirla en los términos de esta Licencia en cualquier momento; en el entendido, sin embargo, que esa elección no servirá para revocar esta licencia o que deba ser otorgada , bajo los términos de esta licencia), y esta licencia continuará en pleno vigor y efecto a menos que sea terminada como se expresa atrás. La Licencia revocada continuará siendo plenamente vigente y efectiva si no se le da término en las condiciones indicadas anteriormente.</li>
    </ol>
  </li>
  <br/>
  <li>
    Varios.
    <ol type="a">
      <li>Cada vez que Usted distribuya o ponga a disposición pública la Obra o una Obra Colectiva, el Licenciante ofrecerá al destinatario una licencia en los mismos términos y condiciones que la licencia otorgada a Usted bajo esta Licencia.</li>
      <li>Si alguna disposición de esta Licencia resulta invalidada o no exigible, según la legislación vigente, esto no afectará ni la validez ni la aplicabilidad del resto de condiciones de esta Licencia y, sin acción adicional por parte de los sujetos de este acuerdo, aquélla se entenderá reformada lo mínimo necesario para hacer que dicha disposición sea válida y exigible.</li>
      <li>Ningún término o disposición de esta Licencia se estimará renunciada y ninguna violación de ella será consentida a menos que esa renuncia o consentimiento sea otorgado por escrito y firmado por la parte que renuncie o consienta.</li>
      <li>Esta Licencia refleja el acuerdo pleno entre las partes respecto a la Obra aquí licenciada. No hay arreglos, acuerdos o declaraciones respecto a la Obra que no estén especificados en este documento. El Licenciante no se verá limitado por ninguna disposición adicional que pueda surgir en alguna comunicación emanada de Usted. Esta Licencia no puede ser modificada sin el consentimiento mutuo por escrito del Licenciante y Usted.</li>
    </ol>
  </li>
  <br/>
</ol>


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