Understanding the reaction mechanism of the oxidative addition of ammonia by (PXP)Ir(i) complexes: The role of the X group
An analysis of the electronic rearrangements for the oxidative addition of ammonia to a set of five representative (PXP)Ir pincer complexes (X = B, CH, O, N, SiH) is performed. We aim to understand the factors controlling the activation and reaction energies of this process by combining different th...
- Autores:
- Tipo de recurso:
- Fecha de publicación:
- 2018
- Institución:
- Universidad de Medellín
- Repositorio:
- Repositorio UDEM
- Idioma:
- eng
- OAI Identifier:
- oai:repository.udem.edu.co:11407/4571
- Acceso en línea:
- http://hdl.handle.net/11407/4571
- Palabra clave:
- Rights
- License
- http://purl.org/coar/access_right/c_16ec