An easy method to prepare d3 and c2-tatp crystals
D3 and C2 TATP structures interconvert at room temperature. Herein, an easy method to isolate both conformers is shown that consists of multiple recrystallization steps using different solvent and heating to boiling. Spectroscopic and physical measurements, such as Raman spectroscopy, X-ray diffract...
- Autores:
-
Espinosa Fuentes, Eduardo Antonio
Colpas Castillo, Fredy
Meza Fuentes, Edgardo
Ropero, Jorge
- Tipo de recurso:
- Article of journal
- Fecha de publicación:
- 2016
- Institución:
- Corporación Universidad de la Costa
- Repositorio:
- REDICUC - Repositorio CUC
- Idioma:
- eng
- OAI Identifier:
- oai:repositorio.cuc.edu.co:11323/4211
- Acceso en línea:
- https://hdl.handle.net/11323/4211
https://repositorio.cuc.edu.co/
- Palabra clave:
- D3 and C2 TATP conformers
Raman
X-ray diffractogram
D3 y C2 conformadores TATP.
Raman
Difractograma de rayos x
- Rights
- openAccess
- License
- Attribution-NonCommercial-ShareAlike 4.0 International
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| dc.title.spa.fl_str_mv |
An easy method to prepare d3 and c2-tatp crystals |
| dc.title.translated.spa.fl_str_mv |
Un método fácil de preparar cristales d3 y c2-tatp. |
| title |
An easy method to prepare d3 and c2-tatp crystals |
| spellingShingle |
An easy method to prepare d3 and c2-tatp crystals D3 and C2 TATP conformers Raman X-ray diffractogram D3 y C2 conformadores TATP. Raman Difractograma de rayos x |
| title_short |
An easy method to prepare d3 and c2-tatp crystals |
| title_full |
An easy method to prepare d3 and c2-tatp crystals |
| title_fullStr |
An easy method to prepare d3 and c2-tatp crystals |
| title_full_unstemmed |
An easy method to prepare d3 and c2-tatp crystals |
| title_sort |
An easy method to prepare d3 and c2-tatp crystals |
| dc.creator.fl_str_mv |
Espinosa Fuentes, Eduardo Antonio Colpas Castillo, Fredy Meza Fuentes, Edgardo Ropero, Jorge |
| dc.contributor.author.spa.fl_str_mv |
Espinosa Fuentes, Eduardo Antonio Colpas Castillo, Fredy Meza Fuentes, Edgardo Ropero, Jorge |
| dc.subject.spa.fl_str_mv |
D3 and C2 TATP conformers Raman X-ray diffractogram D3 y C2 conformadores TATP. Raman Difractograma de rayos x |
| topic |
D3 and C2 TATP conformers Raman X-ray diffractogram D3 y C2 conformadores TATP. Raman Difractograma de rayos x |
| description |
D3 and C2 TATP structures interconvert at room temperature. Herein, an easy method to isolate both conformers is shown that consists of multiple recrystallization steps using different solvent and heating to boiling. Spectroscopic and physical measurements, such as Raman spectroscopy, X-ray diffraction, and melting point analysis, showed that clear and opaque crystals, respectively, represent different conformations of TATP. Additionally, the transition energy between both conformers was estimated using the Raman shifts |
| publishDate |
2016 |
| dc.date.issued.none.fl_str_mv |
2016 |
| dc.date.accessioned.none.fl_str_mv |
2019-05-17T15:16:38Z |
| dc.date.available.none.fl_str_mv |
2019-05-17T15:16:38Z |
| dc.type.spa.fl_str_mv |
Artículo de revista |
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http://purl.org/coar/resource_type/c_2df8fbb1 |
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http://purl.org/coar/resource_type/c_6501 |
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Text |
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info:eu-repo/semantics/article |
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http://purl.org/redcol/resource_type/ART |
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info:eu-repo/semantics/acceptedVersion |
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http://purl.org/coar/resource_type/c_6501 |
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acceptedVersion |
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07213115 |
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https://hdl.handle.net/11323/4211 |
| dc.identifier.instname.spa.fl_str_mv |
Corporación Universidad de la Costa |
| dc.identifier.reponame.spa.fl_str_mv |
REDICUC - Repositorio CUC |
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https://repositorio.cuc.edu.co/ |
| identifier_str_mv |
07213115 Corporación Universidad de la Costa REDICUC - Repositorio CUC |
| url |
https://hdl.handle.net/11323/4211 https://repositorio.cuc.edu.co/ |
| dc.language.iso.none.fl_str_mv |
eng |
| language |
eng |
| dc.rights.spa.fl_str_mv |
Attribution-NonCommercial-ShareAlike 4.0 International |
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http://creativecommons.org/licenses/by-nc-sa/4.0/ |
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info:eu-repo/semantics/openAccess |
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http://purl.org/coar/access_right/c_abf2 |
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Attribution-NonCommercial-ShareAlike 4.0 International http://creativecommons.org/licenses/by-nc-sa/4.0/ http://purl.org/coar/access_right/c_abf2 |
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openAccess |
| dc.publisher.spa.fl_str_mv |
Universidad de la Costa |
| institution |
Corporación Universidad de la Costa |
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Espinosa Fuentes, Eduardo AntonioColpas Castillo, FredyMeza Fuentes, EdgardoRopero, Jorge2019-05-17T15:16:38Z2019-05-17T15:16:38Z201607213115https://hdl.handle.net/11323/4211Corporación Universidad de la CostaREDICUC - Repositorio CUChttps://repositorio.cuc.edu.co/D3 and C2 TATP structures interconvert at room temperature. Herein, an easy method to isolate both conformers is shown that consists of multiple recrystallization steps using different solvent and heating to boiling. Spectroscopic and physical measurements, such as Raman spectroscopy, X-ray diffraction, and melting point analysis, showed that clear and opaque crystals, respectively, represent different conformations of TATP. Additionally, the transition energy between both conformers was estimated using the Raman shiftsLas estructuras D3 y C2 TATP se interconvierten a temperatura ambiente. En este documento, se muestra un método fácil para aislar a los dos conformadores que consiste en múltiples etapas de recristalización que utilizan diferentes disolventes y calentamiento a ebullición. Las medidas espectroscópicas y físicas, como la espectroscopia Raman, la difracción de rayos X y el análisis del punto de fusión, mostraron que los cristales claros y opacos, respectivamente, representan diferentes conformaciones de TATP. Además, la energía de transición entre ambos conformadores se estimó utilizando los turnos RamanEspinosa Fuentes, Eduardo Antonio-4a2aee36-a6fd-4d38-92d3-66e15483bf70-0Colpas Castillo, Fredy-a58dfeef-b7d3-4dd6-b70d-f3ac2c117bf8-0Meza Fuentes, Edgardo-48e4de07-6e97-4229-9267-6ccec7edc159-0Ropero, Jorge-6f3ff826-2f63-4c62-a4a3-f49661251c1e-0engUniversidad de la CostaAttribution-NonCommercial-ShareAlike 4.0 Internationalhttp://creativecommons.org/licenses/by-nc-sa/4.0/info:eu-repo/semantics/openAccesshttp://purl.org/coar/access_right/c_abf2D3 and C2 TATP conformersRamanX-ray diffractogramD3 y C2 conformadores TATP.RamanDifractograma de rayos xAn easy method to prepare d3 and c2-tatp crystalsUn método fácil de preparar cristales d3 y c2-tatp.Artículo de revistahttp://purl.org/coar/resource_type/c_6501http://purl.org/coar/resource_type/c_2df8fbb1Textinfo:eu-repo/semantics/articlehttp://purl.org/redcol/resource_type/ARTinfo:eu-repo/semantics/acceptedVersionPublicationORIGINALAn Easy Method to Prepare D3.pdfAn Easy Method to Prepare D3.pdfapplication/pdf179060https://repositorio.cuc.edu.co/bitstreams/135914be-7339-43ed-920b-4a7db6989647/download3063bd3aa4b8d83e5416f14161631448MD51CC-LICENSElicense_rdflicense_rdfapplication/rdf+xml; charset=utf-81031https://repositorio.cuc.edu.co/bitstreams/5ad24eed-1e67-489a-9da3-6ca749b1b80a/download934f4ca17e109e0a05eaeaba504d7ce4MD52LICENSElicense.txtlicense.txttext/plain; charset=utf-81748https://repositorio.cuc.edu.co/bitstreams/b07d4319-23f8-42ae-9cf8-c60f3436c602/download8a4605be74aa9ea9d79846c1fba20a33MD53THUMBNAILAn Easy Method to Prepare D3.pdf.jpgAn Easy Method to Prepare D3.pdf.jpgimage/jpeg30559https://repositorio.cuc.edu.co/bitstreams/788b7f98-3ceb-4d24-82ad-d74a27906637/download665165b319b6bf6db8474864622fbb2dMD55TEXTAn Easy Method to Prepare D3.pdf.txtAn Easy Method to Prepare D3.pdf.txttext/plain763https://repositorio.cuc.edu.co/bitstreams/c4735cd4-6289-42d1-89c3-2eab4df36e1a/downloadc6a0d0bc59afab41eb60aa2408add469MD5611323/4211oai:repositorio.cuc.edu.co:11323/42112024-09-17 10:50:26.56http://creativecommons.org/licenses/by-nc-sa/4.0/Attribution-NonCommercial-ShareAlike 4.0 Internationalopen.accesshttps://repositorio.cuc.edu.coRepositorio de la Universidad de la Costa CUCrepdigital@cuc.edu.coTk9URTogUExBQ0UgWU9VUiBPV04gTElDRU5TRSBIRVJFClRoaXMgc2FtcGxlIGxpY2Vuc2UgaXMgcHJvdmlkZWQgZm9yIGluZm9ybWF0aW9uYWwgcHVycG9zZXMgb25seS4KCk5PTi1FWENMVVNJVkUgRElTVFJJQlVUSU9OIExJQ0VOU0UKCkJ5IHNpZ25pbmcgYW5kIHN1Ym1pdHRpbmcgdGhpcyBsaWNlbnNlLCB5b3UgKHRoZSBhdXRob3Iocykgb3IgY29weXJpZ2h0Cm93bmVyKSBncmFudHMgdG8gRFNwYWNlIFVuaXZlcnNpdHkgKERTVSkgdGhlIG5vbi1leGNsdXNpdmUgcmlnaHQgdG8gcmVwcm9kdWNlLAp0cmFuc2xhdGUgKGFzIGRlZmluZWQgYmVsb3cpLCBhbmQvb3IgZGlzdHJpYnV0ZSB5b3VyIHN1Ym1pc3Npb24gKGluY2x1ZGluZwp0aGUgYWJzdHJhY3QpIHdvcmxkd2lkZSBpbiBwcmludCBhbmQgZWxlY3Ryb25pYyBmb3JtYXQgYW5kIGluIGFueSBtZWRpdW0sCmluY2x1ZGluZyBidXQgbm90IGxpbWl0ZWQgdG8gYXVkaW8gb3IgdmlkZW8uCgpZb3UgYWdyZWUgdGhhdCBEU1UgbWF5LCB3aXRob3V0IGNoYW5naW5nIHRoZSBjb250ZW50LCB0cmFuc2xhdGUgdGhlCnN1Ym1pc3Npb24gdG8gYW55IG1lZGl1bSBvciBmb3JtYXQgZm9yIHRoZSBwdXJwb3NlIG9mIHByZXNlcnZhdGlvbi4KCllvdSBhbHNvIGFncmVlIHRoYXQgRFNVIG1heSBrZWVwIG1vcmUgdGhhbiBvbmUgY29weSBvZiB0aGlzIHN1Ym1pc3Npb24gZm9yCnB1cnBvc2VzIG9mIHNlY3VyaXR5LCBiYWNrLXVwIGFuZCBwcmVzZXJ2YXRpb24uCgpZb3UgcmVwcmVzZW50IHRoYXQgdGhlIHN1Ym1pc3Npb24gaXMgeW91ciBvcmlnaW5hbCB3b3JrLCBhbmQgdGhhdCB5b3UgaGF2ZQp0aGUgcmlnaHQgdG8gZ3JhbnQgdGhlIHJpZ2h0cyBjb250YWluZWQgaW4gdGhpcyBsaWNlbnNlLiBZb3UgYWxzbyByZXByZXNlbnQKdGhhdCB5b3VyIHN1Ym1pc3Npb24gZG9lcyBub3QsIHRvIHRoZSBiZXN0IG9mIHlvdXIga25vd2xlZGdlLCBpbmZyaW5nZSB1cG9uCmFueW9uZSdzIGNvcHlyaWdodC4KCklmIHRoZSBzdWJtaXNzaW9uIGNvbnRhaW5zIG1hdGVyaWFsIGZvciB3aGljaCB5b3UgZG8gbm90IGhvbGQgY29weXJpZ2h0LAp5b3UgcmVwcmVzZW50IHRoYXQgeW91IGhhdmUgb2J0YWluZWQgdGhlIHVucmVzdHJpY3RlZCBwZXJtaXNzaW9uIG9mIHRoZQpjb3B5cmlnaHQgb3duZXIgdG8gZ3JhbnQgRFNVIHRoZSByaWdodHMgcmVxdWlyZWQgYnkgdGhpcyBsaWNlbnNlLCBhbmQgdGhhdApzdWNoIHRoaXJkLXBhcnR5IG93bmVkIG1hdGVyaWFsIGlzIGNsZWFybHkgaWRlbnRpZmllZCBhbmQgYWNrbm93bGVkZ2VkCndpdGhpbiB0aGUgdGV4dCBvciBjb250ZW50IG9mIHRoZSBzdWJtaXNzaW9uLgoKSUYgVEhFIFNVQk1JU1NJT04gSVMgQkFTRUQgVVBPTiBXT1JLIFRIQVQgSEFTIEJFRU4gU1BPTlNPUkVEIE9SIFNVUFBPUlRFRApCWSBBTiBBR0VOQ1kgT1IgT1JHQU5JWkFUSU9OIE9USEVSIFRIQU4gRFNVLCBZT1UgUkVQUkVTRU5UIFRIQVQgWU9VIEhBVkUKRlVMRklMTEVEIEFOWSBSSUdIVCBPRiBSRVZJRVcgT1IgT1RIRVIgT0JMSUdBVElPTlMgUkVRVUlSRUQgQlkgU1VDSApDT05UUkFDVCBPUiBBR1JFRU1FTlQuCgpEU1Ugd2lsbCBjbGVhcmx5IGlkZW50aWZ5IHlvdXIgbmFtZShzKSBhcyB0aGUgYXV0aG9yKHMpIG9yIG93bmVyKHMpIG9mIHRoZQpzdWJtaXNzaW9uLCBhbmQgd2lsbCBub3QgbWFrZSBhbnkgYWx0ZXJhdGlvbiwgb3RoZXIgdGhhbiBhcyBhbGxvd2VkIGJ5IHRoaXMKbGljZW5zZSwgdG8geW91ciBzdWJtaXNzaW9uLgo= |