Optoelectrical, structural and morphological characterization of Cu 2 ZnSnSe 4 compound used in photovoltaic applications

In this work, results are reported concerning the effect of the deposition parameters on the structural properties of Cu 2 ZnSnSe 4 (CZTSe) thin films, grown through a chemical reaction of the metallic precursors by co-evaporation in a two-stage process. XRD measurements revealed that the samples de...

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Tipo de recurso:
Fecha de publicación:
2016
Institución:
Universidad del Rosario
Repositorio:
Repositorio EdocUR - U. Rosario
Idioma:
eng
OAI Identifier:
oai:repository.urosario.edu.co:10336/22655
Acceso en línea:
https://doi.org/10.1016/j.apsusc.2016.04.073
https://repository.urosario.edu.co/handle/10336/22655
Palabra clave:
Copper compounds
Deposition
Thin films
Tin compounds
Zinc compounds
Cztse
Deposition temperatures
Electrical conductivity
Electrical transport
Morphological characterization
Photovoltaic applications
Raman
Variable range hopping
Selenium compounds
Cztse
Electrical transport
Raman
Thin films
XRD
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id EDOCUR2_48e43fcb9fa24c2e145381c2ae8a0bb5
oai_identifier_str oai:repository.urosario.edu.co:10336/22655
network_acronym_str EDOCUR2
network_name_str Repositorio EdocUR - U. Rosario
repository_id_str
spelling 13169185-4401-4ef0-836e-55ddc5b782cb-1e96cab77-54c2-45c5-93e5-62e946e941c8-12066645c-bed7-4285-859b-d4865a297372-1f566d894-9660-41ea-bc89-95c30802e5bc-12020-05-25T23:57:23Z2020-05-25T23:57:23Z2016In this work, results are reported concerning the effect of the deposition parameters on the structural properties of Cu 2 ZnSnSe 4 (CZTSe) thin films, grown through a chemical reaction of the metallic precursors by co-evaporation in a two-stage process. XRD measurements revealed that the samples deposited by selenization of Cu and Sn grow in the kesterite phase (CZTSe), respectively. Effect of the deposition temperature and mass ratio Cu/ZnSe on the transport properties of CZTSe films were analyzed. It was also found that the electrical conductivity of the thin films is affected by the transport of free carriers in extended states of the conduction band as well as for variable range hopping transport mechanisms, each one predominating in a different temperature range. The molecular and morphological effect on the compound through Raman and AFM measurements was studied. © 2016 Elsevier B.V.application/pdfhttps://doi.org/10.1016/j.apsusc.2016.04.0731694332https://repository.urosario.edu.co/handle/10336/22655engElsevier B.V.392386Applied Surface ScienceVol. 384Applied Surface Science, ISSN:1694332, Vol.384,(2016); pp. 386-392https://www.scopus.com/inward/record.uri?eid=2-s2.0-84971264821&doi=10.1016%2fj.apsusc.2016.04.073&partnerID=40&md5=fed69e8e212ab6d923b6477357b90567Abierto (Texto Completo)http://purl.org/coar/access_right/c_abf2instname:Universidad del Rosarioreponame:Repositorio Institucional EdocURCopper compoundsDepositionThin filmsTin compoundsZinc compoundsCztseDeposition temperaturesElectrical conductivityElectrical transportMorphological characterizationPhotovoltaic applicationsRamanVariable range hoppingSelenium compoundsCztseElectrical transportRamanThin filmsXRDOptoelectrical, structural and morphological characterization of Cu 2 ZnSnSe 4 compound used in photovoltaic applicationsarticleArtículohttp://purl.org/coar/version/c_970fb48d4fbd8a85http://purl.org/coar/resource_type/c_6501Mesa F.Leguizamon A.Dussan A.Gordillo G.10336/22655oai:repository.urosario.edu.co:10336/226552022-05-02 07:37:20.561476https://repository.urosario.edu.coRepositorio institucional EdocURedocur@urosario.edu.co
dc.title.spa.fl_str_mv Optoelectrical, structural and morphological characterization of Cu 2 ZnSnSe 4 compound used in photovoltaic applications
title Optoelectrical, structural and morphological characterization of Cu 2 ZnSnSe 4 compound used in photovoltaic applications
spellingShingle Optoelectrical, structural and morphological characterization of Cu 2 ZnSnSe 4 compound used in photovoltaic applications
Copper compounds
Deposition
Thin films
Tin compounds
Zinc compounds
Cztse
Deposition temperatures
Electrical conductivity
Electrical transport
Morphological characterization
Photovoltaic applications
Raman
Variable range hopping
Selenium compounds
Cztse
Electrical transport
Raman
Thin films
XRD
title_short Optoelectrical, structural and morphological characterization of Cu 2 ZnSnSe 4 compound used in photovoltaic applications
title_full Optoelectrical, structural and morphological characterization of Cu 2 ZnSnSe 4 compound used in photovoltaic applications
title_fullStr Optoelectrical, structural and morphological characterization of Cu 2 ZnSnSe 4 compound used in photovoltaic applications
title_full_unstemmed Optoelectrical, structural and morphological characterization of Cu 2 ZnSnSe 4 compound used in photovoltaic applications
title_sort Optoelectrical, structural and morphological characterization of Cu 2 ZnSnSe 4 compound used in photovoltaic applications
dc.subject.keyword.spa.fl_str_mv Copper compounds
Deposition
Thin films
Tin compounds
Zinc compounds
Cztse
Deposition temperatures
Electrical conductivity
Electrical transport
Morphological characterization
Photovoltaic applications
Raman
Variable range hopping
Selenium compounds
Cztse
Electrical transport
Raman
Thin films
XRD
topic Copper compounds
Deposition
Thin films
Tin compounds
Zinc compounds
Cztse
Deposition temperatures
Electrical conductivity
Electrical transport
Morphological characterization
Photovoltaic applications
Raman
Variable range hopping
Selenium compounds
Cztse
Electrical transport
Raman
Thin films
XRD
description In this work, results are reported concerning the effect of the deposition parameters on the structural properties of Cu 2 ZnSnSe 4 (CZTSe) thin films, grown through a chemical reaction of the metallic precursors by co-evaporation in a two-stage process. XRD measurements revealed that the samples deposited by selenization of Cu and Sn grow in the kesterite phase (CZTSe), respectively. Effect of the deposition temperature and mass ratio Cu/ZnSe on the transport properties of CZTSe films were analyzed. It was also found that the electrical conductivity of the thin films is affected by the transport of free carriers in extended states of the conduction band as well as for variable range hopping transport mechanisms, each one predominating in a different temperature range. The molecular and morphological effect on the compound through Raman and AFM measurements was studied. © 2016 Elsevier B.V.
publishDate 2016
dc.date.created.spa.fl_str_mv 2016
dc.date.accessioned.none.fl_str_mv 2020-05-25T23:57:23Z
dc.date.available.none.fl_str_mv 2020-05-25T23:57:23Z
dc.type.eng.fl_str_mv article
dc.type.coarversion.fl_str_mv http://purl.org/coar/version/c_970fb48d4fbd8a85
dc.type.coar.fl_str_mv http://purl.org/coar/resource_type/c_6501
dc.type.spa.spa.fl_str_mv Artículo
dc.identifier.doi.none.fl_str_mv https://doi.org/10.1016/j.apsusc.2016.04.073
dc.identifier.issn.none.fl_str_mv 1694332
dc.identifier.uri.none.fl_str_mv https://repository.urosario.edu.co/handle/10336/22655
url https://doi.org/10.1016/j.apsusc.2016.04.073
https://repository.urosario.edu.co/handle/10336/22655
identifier_str_mv 1694332
dc.language.iso.spa.fl_str_mv eng
language eng
dc.relation.citationEndPage.none.fl_str_mv 392
dc.relation.citationStartPage.none.fl_str_mv 386
dc.relation.citationTitle.none.fl_str_mv Applied Surface Science
dc.relation.citationVolume.none.fl_str_mv Vol. 384
dc.relation.ispartof.spa.fl_str_mv Applied Surface Science, ISSN:1694332, Vol.384,(2016); pp. 386-392
dc.relation.uri.spa.fl_str_mv https://www.scopus.com/inward/record.uri?eid=2-s2.0-84971264821&doi=10.1016%2fj.apsusc.2016.04.073&partnerID=40&md5=fed69e8e212ab6d923b6477357b90567
dc.rights.coar.fl_str_mv http://purl.org/coar/access_right/c_abf2
dc.rights.acceso.spa.fl_str_mv Abierto (Texto Completo)
rights_invalid_str_mv Abierto (Texto Completo)
http://purl.org/coar/access_right/c_abf2
dc.format.mimetype.none.fl_str_mv application/pdf
dc.publisher.spa.fl_str_mv Elsevier B.V.
institution Universidad del Rosario
dc.source.instname.spa.fl_str_mv instname:Universidad del Rosario
dc.source.reponame.spa.fl_str_mv reponame:Repositorio Institucional EdocUR
repository.name.fl_str_mv Repositorio institucional EdocUR
repository.mail.fl_str_mv edocur@urosario.edu.co
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