Optoelectrical, structural and morphological characterization of Cu 2 ZnSnSe 4 compound used in photovoltaic applications
In this work, results are reported concerning the effect of the deposition parameters on the structural properties of Cu 2 ZnSnSe 4 (CZTSe) thin films, grown through a chemical reaction of the metallic precursors by co-evaporation in a two-stage process. XRD measurements revealed that the samples de...
- Autores:
- Tipo de recurso:
- Fecha de publicación:
- 2016
- Institución:
- Universidad del Rosario
- Repositorio:
- Repositorio EdocUR - U. Rosario
- Idioma:
- eng
- OAI Identifier:
- oai:repository.urosario.edu.co:10336/22655
- Acceso en línea:
- https://doi.org/10.1016/j.apsusc.2016.04.073
https://repository.urosario.edu.co/handle/10336/22655
- Palabra clave:
- Copper compounds
Deposition
Thin films
Tin compounds
Zinc compounds
Cztse
Deposition temperatures
Electrical conductivity
Electrical transport
Morphological characterization
Photovoltaic applications
Raman
Variable range hopping
Selenium compounds
Cztse
Electrical transport
Raman
Thin films
XRD
- Rights
- License
- Abierto (Texto Completo)
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oai:repository.urosario.edu.co:10336/22655 |
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Repositorio EdocUR - U. Rosario |
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13169185-4401-4ef0-836e-55ddc5b782cb-1e96cab77-54c2-45c5-93e5-62e946e941c8-12066645c-bed7-4285-859b-d4865a297372-1f566d894-9660-41ea-bc89-95c30802e5bc-12020-05-25T23:57:23Z2020-05-25T23:57:23Z2016In this work, results are reported concerning the effect of the deposition parameters on the structural properties of Cu 2 ZnSnSe 4 (CZTSe) thin films, grown through a chemical reaction of the metallic precursors by co-evaporation in a two-stage process. XRD measurements revealed that the samples deposited by selenization of Cu and Sn grow in the kesterite phase (CZTSe), respectively. Effect of the deposition temperature and mass ratio Cu/ZnSe on the transport properties of CZTSe films were analyzed. It was also found that the electrical conductivity of the thin films is affected by the transport of free carriers in extended states of the conduction band as well as for variable range hopping transport mechanisms, each one predominating in a different temperature range. The molecular and morphological effect on the compound through Raman and AFM measurements was studied. © 2016 Elsevier B.V.application/pdfhttps://doi.org/10.1016/j.apsusc.2016.04.0731694332https://repository.urosario.edu.co/handle/10336/22655engElsevier B.V.392386Applied Surface ScienceVol. 384Applied Surface Science, ISSN:1694332, Vol.384,(2016); pp. 386-392https://www.scopus.com/inward/record.uri?eid=2-s2.0-84971264821&doi=10.1016%2fj.apsusc.2016.04.073&partnerID=40&md5=fed69e8e212ab6d923b6477357b90567Abierto (Texto Completo)http://purl.org/coar/access_right/c_abf2instname:Universidad del Rosarioreponame:Repositorio Institucional EdocURCopper compoundsDepositionThin filmsTin compoundsZinc compoundsCztseDeposition temperaturesElectrical conductivityElectrical transportMorphological characterizationPhotovoltaic applicationsRamanVariable range hoppingSelenium compoundsCztseElectrical transportRamanThin filmsXRDOptoelectrical, structural and morphological characterization of Cu 2 ZnSnSe 4 compound used in photovoltaic applicationsarticleArtículohttp://purl.org/coar/version/c_970fb48d4fbd8a85http://purl.org/coar/resource_type/c_6501Mesa F.Leguizamon A.Dussan A.Gordillo G.10336/22655oai:repository.urosario.edu.co:10336/226552022-05-02 07:37:20.561476https://repository.urosario.edu.coRepositorio institucional EdocURedocur@urosario.edu.co |
dc.title.spa.fl_str_mv |
Optoelectrical, structural and morphological characterization of Cu 2 ZnSnSe 4 compound used in photovoltaic applications |
title |
Optoelectrical, structural and morphological characterization of Cu 2 ZnSnSe 4 compound used in photovoltaic applications |
spellingShingle |
Optoelectrical, structural and morphological characterization of Cu 2 ZnSnSe 4 compound used in photovoltaic applications Copper compounds Deposition Thin films Tin compounds Zinc compounds Cztse Deposition temperatures Electrical conductivity Electrical transport Morphological characterization Photovoltaic applications Raman Variable range hopping Selenium compounds Cztse Electrical transport Raman Thin films XRD |
title_short |
Optoelectrical, structural and morphological characterization of Cu 2 ZnSnSe 4 compound used in photovoltaic applications |
title_full |
Optoelectrical, structural and morphological characterization of Cu 2 ZnSnSe 4 compound used in photovoltaic applications |
title_fullStr |
Optoelectrical, structural and morphological characterization of Cu 2 ZnSnSe 4 compound used in photovoltaic applications |
title_full_unstemmed |
Optoelectrical, structural and morphological characterization of Cu 2 ZnSnSe 4 compound used in photovoltaic applications |
title_sort |
Optoelectrical, structural and morphological characterization of Cu 2 ZnSnSe 4 compound used in photovoltaic applications |
dc.subject.keyword.spa.fl_str_mv |
Copper compounds Deposition Thin films Tin compounds Zinc compounds Cztse Deposition temperatures Electrical conductivity Electrical transport Morphological characterization Photovoltaic applications Raman Variable range hopping Selenium compounds Cztse Electrical transport Raman Thin films XRD |
topic |
Copper compounds Deposition Thin films Tin compounds Zinc compounds Cztse Deposition temperatures Electrical conductivity Electrical transport Morphological characterization Photovoltaic applications Raman Variable range hopping Selenium compounds Cztse Electrical transport Raman Thin films XRD |
description |
In this work, results are reported concerning the effect of the deposition parameters on the structural properties of Cu 2 ZnSnSe 4 (CZTSe) thin films, grown through a chemical reaction of the metallic precursors by co-evaporation in a two-stage process. XRD measurements revealed that the samples deposited by selenization of Cu and Sn grow in the kesterite phase (CZTSe), respectively. Effect of the deposition temperature and mass ratio Cu/ZnSe on the transport properties of CZTSe films were analyzed. It was also found that the electrical conductivity of the thin films is affected by the transport of free carriers in extended states of the conduction band as well as for variable range hopping transport mechanisms, each one predominating in a different temperature range. The molecular and morphological effect on the compound through Raman and AFM measurements was studied. © 2016 Elsevier B.V. |
publishDate |
2016 |
dc.date.created.spa.fl_str_mv |
2016 |
dc.date.accessioned.none.fl_str_mv |
2020-05-25T23:57:23Z |
dc.date.available.none.fl_str_mv |
2020-05-25T23:57:23Z |
dc.type.eng.fl_str_mv |
article |
dc.type.coarversion.fl_str_mv |
http://purl.org/coar/version/c_970fb48d4fbd8a85 |
dc.type.coar.fl_str_mv |
http://purl.org/coar/resource_type/c_6501 |
dc.type.spa.spa.fl_str_mv |
Artículo |
dc.identifier.doi.none.fl_str_mv |
https://doi.org/10.1016/j.apsusc.2016.04.073 |
dc.identifier.issn.none.fl_str_mv |
1694332 |
dc.identifier.uri.none.fl_str_mv |
https://repository.urosario.edu.co/handle/10336/22655 |
url |
https://doi.org/10.1016/j.apsusc.2016.04.073 https://repository.urosario.edu.co/handle/10336/22655 |
identifier_str_mv |
1694332 |
dc.language.iso.spa.fl_str_mv |
eng |
language |
eng |
dc.relation.citationEndPage.none.fl_str_mv |
392 |
dc.relation.citationStartPage.none.fl_str_mv |
386 |
dc.relation.citationTitle.none.fl_str_mv |
Applied Surface Science |
dc.relation.citationVolume.none.fl_str_mv |
Vol. 384 |
dc.relation.ispartof.spa.fl_str_mv |
Applied Surface Science, ISSN:1694332, Vol.384,(2016); pp. 386-392 |
dc.relation.uri.spa.fl_str_mv |
https://www.scopus.com/inward/record.uri?eid=2-s2.0-84971264821&doi=10.1016%2fj.apsusc.2016.04.073&partnerID=40&md5=fed69e8e212ab6d923b6477357b90567 |
dc.rights.coar.fl_str_mv |
http://purl.org/coar/access_right/c_abf2 |
dc.rights.acceso.spa.fl_str_mv |
Abierto (Texto Completo) |
rights_invalid_str_mv |
Abierto (Texto Completo) http://purl.org/coar/access_right/c_abf2 |
dc.format.mimetype.none.fl_str_mv |
application/pdf |
dc.publisher.spa.fl_str_mv |
Elsevier B.V. |
institution |
Universidad del Rosario |
dc.source.instname.spa.fl_str_mv |
instname:Universidad del Rosario |
dc.source.reponame.spa.fl_str_mv |
reponame:Repositorio Institucional EdocUR |
repository.name.fl_str_mv |
Repositorio institucional EdocUR |
repository.mail.fl_str_mv |
edocur@urosario.edu.co |
_version_ |
1814167725828734976 |