Effect of Acidity, Basicity and ZrO2 Phases of Cu-Ni/ZrO2 Catalysts on the Direct Synthesis of Diethyl Carbonate from CO2 and Ethanol
Cu-Ni/ZrO2 catalysts with different Cu:Ni molar ratios were synthesized and tested in the direct synthesis of diethyl carbonate from carbon dioxide and ethanol. The effect of Cu:Ni molar ratio on the acidity and basicity of the catalysts was investigated using NH3 and CO2-TPD, respectively. Experime...
- Autores:
-
Arbeláez Pérez, Oscar Felipe
Orrego A.
Bustamante F.
Villa A.L.
- Tipo de recurso:
- Article of journal
- Fecha de publicación:
- 2016
- Institución:
- Universidad Cooperativa de Colombia
- Repositorio:
- Repositorio UCC
- Idioma:
- OAI Identifier:
- oai:repository.ucc.edu.co:20.500.12494/41383
- Acceso en línea:
- https://doi.org/10.1007/s10953-013-0058-y
https://hdl.handle.net/20.500.12494/41383
- Palabra clave:
- Carbon dioxide
Carbonation
Catalyst activity
Catalyst selectivity
Catalysts
Ethanol
Zirconia
Zirconium alloys
Bimetallic catalysts
Crystalline properties
Diethyl carbonates
Direct synthesis
Equilibrium conversion
High selectivity
Molar ratio
Raman studies
Nickel
- Rights
- closedAccess
- License
- http://purl.org/coar/access_right/c_14cb