Preferential solvation of tricin in {ethanol (1) + water (2)} mixtures at several temperatures

Los parámetros de solvatación preferencial del tricina en mezclas {etanol (1) + agua (2)} se obtuvieron a partir de las propiedades termodinámicas de solución, mediante el método de las integrales inversas de Kirkwood-Buff. La tricina es muy sensible a los efectos de solvatación específicos, por lo...

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Autores:: Sandoval Castro, Juan José
Ortiz, Claudia Patricia
Rodríguez Rubiano, Juan Diego
Rodríguez Rodríguez, Gerson Andrés
Delgado, Daniel Ricardo

Tipo de recurso:: Article of journal

Fecha de publicación:: 2018

Institución:: Universidad Cooperativa de Colombia

Repositorio:: Repositorio UCC

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network_acronym_str	COOPER2
network_name_str	Repositorio UCC
repository_id_str
dc.title.spa.fl_str_mv	Preferential solvation of tricin in {ethanol (1) + water (2)} mixtures at several temperatures
title	Preferential solvation of tricin in {ethanol (1) + water (2)} mixtures at several temperatures
spellingShingle	Preferential solvation of tricin in {ethanol (1) + water (2)} mixtures at several temperatures Tricin IKBI Preferential solvation Ethanol ethanol Preferential solvation Ticin IKBI
title_short	Preferential solvation of tricin in {ethanol (1) + water (2)} mixtures at several temperatures
title_full	Preferential solvation of tricin in {ethanol (1) + water (2)} mixtures at several temperatures
title_fullStr	Preferential solvation of tricin in {ethanol (1) + water (2)} mixtures at several temperatures
title_full_unstemmed	Preferential solvation of tricin in {ethanol (1) + water (2)} mixtures at several temperatures
title_sort	Preferential solvation of tricin in {ethanol (1) + water (2)} mixtures at several temperatures
dc.creator.fl_str_mv	Sandoval Castro, Juan José Ortiz, Claudia Patricia Rodríguez Rubiano, Juan Diego Rodríguez Rodríguez, Gerson Andrés Delgado, Daniel Ricardo
dc.contributor.author.none.fl_str_mv	Sandoval Castro, Juan José Ortiz, Claudia Patricia Rodríguez Rubiano, Juan Diego Rodríguez Rodríguez, Gerson Andrés Delgado, Daniel Ricardo
dc.subject.spa.fl_str_mv	Tricin IKBI Preferential solvation Ethanol
topic	Tricin IKBI Preferential solvation Ethanol ethanol Preferential solvation Ticin IKBI
dc.subject.other.spa.fl_str_mv	ethanol Preferential solvation Ticin IKBI
description	Los parámetros de solvatación preferencial del tricina en mezclas {etanol (1) + agua (2)} se obtuvieron a partir de las propiedades termodinámicas de solución, mediante el método de las integrales inversas de Kirkwood-Buff. La tricina es muy sensible a los efectos de solvatación específicos, por lo que el parámetro de solvatación preferencial, δx 1,3 es negativo en las mezclas ricas en agua, pero positivo en todas las otras composiciones a temperaturas desde 293,15 hasta 313,15 K. Se puede establecer que en mezclas ricas en agua la hidratación hidrofóbica alrededor de los grupos aromáticos y metilo del fármaco tiene un papel relevante en la solvatación. La mayor solvatación del fármaco por etanol se presenta en mezclas de proporción intermedia y en mezclas ricas en etanol, esto podría deberse principalmente a los efectos de la polaridad. En estas mezclas, el fármaco actuaría como ácido de Lewis con las moléculas de etanol, puesto que este codisolvente es más básico que el agua.
publishDate	2018
dc.date.issued.none.fl_str_mv	2018-08-01
dc.date.accessioned.none.fl_str_mv	2021-01-19T21:35:09Z
dc.date.available.none.fl_str_mv	2021-01-19T21:35:09Z
dc.type.none.fl_str_mv	Artículo
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dc.identifier.issn.spa.fl_str_mv	19096356
dc.identifier.uri.spa.fl_str_mv	https://doi.org/10.15446/rcciquifa.v47n2.73933
dc.identifier.uri.none.fl_str_mv	https://hdl.handle.net/20.500.12494/32653
dc.identifier.bibliographicCitation.spa.fl_str_mv	Sandoval Castro, J. J., Ortiz, C. P., Rodríguez-Rubiano, J. D., Rodríguez-Rodríguez, G. A., & Delgado, D. R. (2018). Preferential solvation of tricin in {ethanol (1) + water (2)} mixtures at several temperatures. Revista Colombiana de Ciencias Químico-Farmacéuticas, 47(2), 135-148. https://doi.org/10.15446/rcciquifa.v47n2.73933
identifier_str_mv	19096356 Sandoval Castro, J. J., Ortiz, C. P., Rodríguez-Rubiano, J. D., Rodríguez-Rodríguez, G. A., & Delgado, D. R. (2018). Preferential solvation of tricin in {ethanol (1) + water (2)} mixtures at several temperatures. Revista Colombiana de Ciencias Químico-Farmacéuticas, 47(2), 135-148. https://doi.org/10.15446/rcciquifa.v47n2.73933
url	https://doi.org/10.15446/rcciquifa.v47n2.73933 https://hdl.handle.net/20.500.12494/32653
dc.relation.isversionof.spa.fl_str_mv	https://revistas.unal.edu.co/index.php/rccquifa/article/view/73933
dc.relation.ispartofjournal.spa.fl_str_mv	Revista Colombiana de Ciencias Químico-Farmacéuticas
dc.relation.references.spa.fl_str_mv	H. Cai, M. Al-Fayez, R.G. Tunstall, S. Platton, P. Greaves, W.P. Steward, A.J. Gescher, The rice bran constituent tricin potently inhibits cyclooxygenase enzymes and interferes with intestinal carcinogenesis in ApcMin mice, Mol. Cancer Ther ., 4, 1287-1292 (2005). T. Oyama, Y. Yasui, S. Sugie, M. Koketsu, K. Watanabe, T. Tanaka, Dietary tricin suppresses inflammation-related colon carcinogenesis in male Crj: CD-1 mice, Cancer Prev. Res ., 2, 1031-1038 (2009). M. Li, Y. Pu, C.G. Yoo, A.J. Ragauskas, The occurrence of tricin and its derivatives in plants, Green Chem ., 18, 1439-1454 (2016). V.A. Moscatelli, Química y farmacología de una planta medicinal argentina: Artemisia copa, Dominguezia, 31, 5-13 (2015). A. Moheb, M. Grondin, R.K. Ibrahim, R. Roy, F. Sarhan, Winter wheat hull (husk) is a valuable source for tricin, a potential selective cytotoxic agent, Food Chem., 138, 931-973 (2013). W. Lan, J. Rencoret, F. Lu, S.D. Karlen, B.G. Smith, P.J. Harris, J.C. del Rio, J. Ralph, Tricinlignins: Occurrence and quantitation of tricin in relation to phy-logeny, Plant J, 88, 1046-1057 (2016). A. Jouyban, W.E. Acree, Mathematical derivation of the Jouyban-Acree model to represent solute solubility data in mixed solvents at various temperatures, J. Mol. Liq, 256, 541-547 (2018). N.A. Bowden, D. Méndez-Sevillano, J.P.M. Sanders, M.E. Bruins, Modelling the effects ofethanol on the solubility ofthe proteinogenic amino acids with the NRTL, Gude and Jouyban-Acree models, Fluid Phase Equilib ., 459, 158-169 (2018). M.A. Kalam, A.A. Khan, A. Alshamsan, A. Haque, F. Shakeel; Solubility of a poorly soluble immunosuppressant in different pure solvents: Measurement, correlation, thermodynamics and molecular interactions, J. Mol. Liq ., 249, 53-60 (2018) E. Rahimpour, M. Barzegar-Jalali, A. Shayanfar, A. Jouyban , Generally trained models to predict drug solubility in N-methyl-2-pyrrolidone + water mixtures at various temperatures, J. Mol. Liq ., 254, 34-38 (2018). A. Fathi-Azarbayjani, M.A. Jalil-Vaez-Gharamaleki, A. Jouyban , Measurement and correlation of deferiprone solubility: Investigation of solubility parameter and application of van't Hoff equation and Jouyban-Acree model, J. Mol. Liq ., 215, 339-344 (2016). M.A. Ruidiaz, D.R. Delgado, C.P. Mora, A. Yurquina, F. Martínez, Estimation of the indomethacin solubility in ethanol + water mixtures by the extended Hildebrand solubility approach, Rev. Colomb. Cienc. Quím. Farm ., 39, 79-95 (2010). Y. Cheng, Z. Wang, S. Ding, J. Li, Determination and correlation of the solubility of tricin in water and ethanol mixtures, J. Chem. Thermodyn ., 89, 89-92 (2015). G. Chen, J. Chen, C. Cheng, Y. Cong, C. Du, H. Zhao, Solubility and preferential solvation of econazole nitrate in binary solvent mixtures of methanol, ethanol and 1,4-dioxane in water, J. Chem. Thermodyn ., 111, 228-237 (2017). J. Chen , G. Chen , Y. Cong , C. Du, H. Zhao, Solubility modelling and preferential solvation of paclobutrazol in co-solvent mixtures of (ethanol, n-propanol and 1,4-dioxane) + water, J. Chem. Thermodyn ., 112, 249-258 (2017). A. Jouyban , W.E. Acree Jr. , F. Martínez , Modeling the solubility and preferential solvation of gallic acid in cosolvent + water mixtures, J. Mol. Liq ., 224, 502-506 (2016). Y. Marcus, "Solvent Mixtures: Properties and Selective Solvation", Marcel Dekker, Inc., New York, 2002. Y. Marcus , Preferential solvation of ibuprofen and naproxen in aqueous 1,2-pro-panediol, Acta Chim. Slov ., 56, 40-44 (2009). Y. Marcus, On the preferential solvation of drugs and PAHs in binary solvent mixtures, J. Mol. Liq ., 140, 61-67 (2008). D.I. Caviedes Rubio, R.G. Sotomayor, D.R. Delgado , Solvatación preferencial de la naringina en mezclas cosolventes etanol + agua mediante el método de las integrales inversas de Kirkwood-Buff, Rev. Colomb. Cienc. Quím. Farm ., 44, 220-235 (2015). D.R. Delgado , E.F. Vargas, F. Martínez , Preferential solvation of xylitol in ethanol + water solvent mixtures according to the IKBI and QLQC methods, Rev. Colomb. Quím ., 42, 59-66 (2013). D.R. Delgado , F. Martínez . Solubility and preferential solvation of sulfadiazine in methanol + water mixtures at several temperatures, Fluid Phase Equilib ., 379, 128-138 (2015). D.R. Delgado , M.A. Peña, F. Martínez , Preferential solvation of some sulfon-amides in propylene glycol + water solvent mixtures according to the IKBI and QLQC methods, J. Solution Chem, 43, 360-374 (2014). D.R. Delgado , M.Á. Peña, F. Martínez , Preferential solvation of acetaminophen in ethanol + water solvent mixtures according to the inverse Kirkwood-Buff integrals method, Rev. Colomb. Cienc. Quím. Farm ., 42, 298-314 (2013). A.C. Gaviria-Castillo, J.D. Artunduaga-Tole, J.D. Rodríguez-Rubiano, J.A. Zúñiga-Andrade, D.R. Delgado , A. Jouyban , F. Martínez , Solution thermodynamics and preferential solvation of triclocarban in {1, 4-dioxane (1) + water (2)} mixtures at 298.15 K, Phys. Chem. Liq, Forthcoming 2018, doi: 10.1080/00319104.2017.1416613. J.A. Lasso, D.I. Caviedes, D.R. Delgado , Preferential solvation of 4-hydroxy-2,5-dimethyl-3(2H)-furanone (DMHF) in ethanol + water mixtures according to IKBI and QLQC methods, Ingeniería y Región, 13, 139-147 (2015). A. Jouyban , S. Nozohouri, F. Martínez , Solubility of celecoxib in {2-propanol (1) + water (2)} mixtures at various temperatures: Experimental data and ther-modynamic analysis J. Mol. Liq , 254, 1-7 (2018). A.F.M. Barton, "Handbook of Solubility parameters and Other Cohesion Parameter", 2nd edition, CRC Press, Inc., New York, 1991. R.F. Fedors, A method for estimating both the solubility parameters and molar volumes of liquids, Polym. Eng. Sci ., 14, 147-154 (1974). D.M. Jimenez, Z.J. Cárdenas, D.R. Delgado , M.Á. Peña , F. Martínez , Solubility temperature dependence and preferential solvation of sulfadiazine in 1,4-dioxane + water co-solvent mixtures, Fluid Phase Equilib ., 397, 26-36 (2015). D.R. Delgado , A.R. Holguín, O.A. Almanza, F. Martínez , Y. Marcus , Solubility and preferential solvation of meloxicam in ethanol + water mixtures, Fluid Phase Equilib , 305, 88-95 (2011). D.R. Delgado , F. Martínez , Solubility and preferential solvation of sulfadiazine in methanol + water mixtures at several temperatures, Fluid Phase Equilib ., 379, 128-138 (2014). D.R. Delgado , F. Martínez , Solubility and solution thermodynamics of sulfamerazine and sulfamethazine in some ethanol + water mixtures, Fluid Phase Equilib , 360, 88-96 (2013)
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dc.coverage.temporal.spa.fl_str_mv	Vol. 47 N. 2
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spelling	Sandoval Castro, Juan JoséOrtiz, Claudia PatriciaRodríguez Rubiano, Juan DiegoRodríguez Rodríguez, Gerson AndrésDelgado, Daniel RicardoVol. 47 N. 22021-01-19T21:35:09Z2021-01-19T21:35:09Z2018-08-0119096356https://doi.org/10.15446/rcciquifa.v47n2.73933https://hdl.handle.net/20.500.12494/32653Sandoval Castro, J. J., Ortiz, C. P., Rodríguez-Rubiano, J. D., Rodríguez-Rodríguez, G. A., & Delgado, D. R. (2018). Preferential solvation of tricin in {ethanol (1) + water (2)} mixtures at several temperatures. Revista Colombiana de Ciencias Químico-Farmacéuticas, 47(2), 135-148. https://doi.org/10.15446/rcciquifa.v47n2.73933Los parámetros de solvatación preferencial del tricina en mezclas {etanol (1) + agua (2)} se obtuvieron a partir de las propiedades termodinámicas de solución, mediante el método de las integrales inversas de Kirkwood-Buff. La tricina es muy sensible a los efectos de solvatación específicos, por lo que el parámetro de solvatación preferencial, δx 1,3 es negativo en las mezclas ricas en agua, pero positivo en todas las otras composiciones a temperaturas desde 293,15 hasta 313,15 K. Se puede establecer que en mezclas ricas en agua la hidratación hidrofóbica alrededor de los grupos aromáticos y metilo del fármaco tiene un papel relevante en la solvatación. La mayor solvatación del fármaco por etanol se presenta en mezclas de proporción intermedia y en mezclas ricas en etanol, esto podría deberse principalmente a los efectos de la polaridad. En estas mezclas, el fármaco actuaría como ácido de Lewis con las moléculas de etanol, puesto que este codisolvente es más básico que el agua.The preferential solvation parameters of tricin in {ethanol (1) + water (2)} binary mixtures were obtained from their thermodynamic properties by means of the inverse Kirkwood-Buff integrals method. Tricin is very sensitive to specific solvation effects, so the preferential solvation parameter by ethanol (1), δx 1,3 is negative in the water-rich mixtures but positive in all the other compositions at temperatures from 293.15, to 313.15 K. It is conjecturable that in water-rich mixtures the hydrophobic hydration around the aromatic and methyl groups of the drug plays a relevant role in the solvation. The higher drug solvation by ethanol in mixtures of similar solvent proportions and in ethanol-rich mixtures could be due mainly to polarity effects. In these mixtures, the drug would be acting as Lewis acid with the ethanol molecules because this co-solvent is more basic than water.Abstract. -- Keywords. -- 1. Introduction. -- 2. Experimental section. -- 3. Results and discussion. -- 4. Conclusions. -- Declaration of Competing Interest. -- Acknowledgments. -- Appendix A. Supplementary data. -- References.http://scienti.colciencias.gov.co:8081/cvlac/visualizador/generarCurriculoCv.do?cod_rh=0001402116https://orcid.org/0000-0002-4835-9739https://scienti.minciencias.gov.co/gruplac/jsp/visualiza/visualizagr.jsp?nro=00000000004151danielr.delgado@campusucc.edu.cohttps://scholar.google.es/citations?user=OW0mejcAAAAJ&hl=es135-148Universidad Nacional de ColombiaUniversidad Cooperativa de Colombia, Facultad de Ingenierías, Ingeniería Industrial, NeivaIngeniería IndustrialNeivahttps://revistas.unal.edu.co/index.php/rccquifa/article/view/73933Revista Colombiana de Ciencias Químico-FarmacéuticasH. Cai, M. Al-Fayez, R.G. Tunstall, S. Platton, P. Greaves, W.P. Steward, A.J. Gescher, The rice bran constituent tricin potently inhibits cyclooxygenase enzymes and interferes with intestinal carcinogenesis in ApcMin mice, Mol. Cancer Ther ., 4, 1287-1292 (2005).T. Oyama, Y. Yasui, S. Sugie, M. Koketsu, K. Watanabe, T. Tanaka, Dietary tricin suppresses inflammation-related colon carcinogenesis in male Crj: CD-1 mice, Cancer Prev. Res ., 2, 1031-1038 (2009).M. Li, Y. Pu, C.G. Yoo, A.J. Ragauskas, The occurrence of tricin and its derivatives in plants, Green Chem ., 18, 1439-1454 (2016).V.A. Moscatelli, Química y farmacología de una planta medicinal argentina: Artemisia copa, Dominguezia, 31, 5-13 (2015).A. Moheb, M. Grondin, R.K. Ibrahim, R. Roy, F. Sarhan, Winter wheat hull (husk) is a valuable source for tricin, a potential selective cytotoxic agent, Food Chem., 138, 931-973 (2013).W. Lan, J. Rencoret, F. Lu, S.D. Karlen, B.G. Smith, P.J. Harris, J.C. del Rio, J. Ralph, Tricinlignins: Occurrence and quantitation of tricin in relation to phy-logeny, Plant J, 88, 1046-1057 (2016).A. Jouyban, W.E. Acree, Mathematical derivation of the Jouyban-Acree model to represent solute solubility data in mixed solvents at various temperatures, J. Mol. Liq, 256, 541-547 (2018).N.A. Bowden, D. Méndez-Sevillano, J.P.M. Sanders, M.E. Bruins, Modelling the effects ofethanol on the solubility ofthe proteinogenic amino acids with the NRTL, Gude and Jouyban-Acree models, Fluid Phase Equilib ., 459, 158-169 (2018).M.A. Kalam, A.A. Khan, A. Alshamsan, A. Haque, F. Shakeel; Solubility of a poorly soluble immunosuppressant in different pure solvents: Measurement, correlation, thermodynamics and molecular interactions, J. Mol. Liq ., 249, 53-60 (2018)E. Rahimpour, M. Barzegar-Jalali, A. Shayanfar, A. Jouyban , Generally trained models to predict drug solubility in N-methyl-2-pyrrolidone + water mixtures at various temperatures, J. Mol. Liq ., 254, 34-38 (2018).A. Fathi-Azarbayjani, M.A. Jalil-Vaez-Gharamaleki, A. Jouyban , Measurement and correlation of deferiprone solubility: Investigation of solubility parameter and application of van't Hoff equation and Jouyban-Acree model, J. Mol. Liq ., 215, 339-344 (2016).M.A. Ruidiaz, D.R. Delgado, C.P. Mora, A. Yurquina, F. Martínez, Estimation of the indomethacin solubility in ethanol + water mixtures by the extended Hildebrand solubility approach, Rev. Colomb. Cienc. Quím. Farm ., 39, 79-95 (2010).Y. Cheng, Z. Wang, S. Ding, J. Li, Determination and correlation of the solubility of tricin in water and ethanol mixtures, J. Chem. Thermodyn ., 89, 89-92 (2015).G. Chen, J. Chen, C. Cheng, Y. Cong, C. Du, H. Zhao, Solubility and preferential solvation of econazole nitrate in binary solvent mixtures of methanol, ethanol and 1,4-dioxane in water, J. Chem. Thermodyn ., 111, 228-237 (2017).J. Chen , G. Chen , Y. Cong , C. Du, H. Zhao, Solubility modelling and preferential solvation of paclobutrazol in co-solvent mixtures of (ethanol, n-propanol and 1,4-dioxane) + water, J. Chem. Thermodyn ., 112, 249-258 (2017).A. Jouyban , W.E. Acree Jr. , F. Martínez , Modeling the solubility and preferential solvation of gallic acid in cosolvent + water mixtures, J. Mol. Liq ., 224, 502-506 (2016).Y. Marcus, "Solvent Mixtures: Properties and Selective Solvation", Marcel Dekker, Inc., New York, 2002.Y. Marcus , Preferential solvation of ibuprofen and naproxen in aqueous 1,2-pro-panediol, Acta Chim. Slov ., 56, 40-44 (2009).Y. Marcus, On the preferential solvation of drugs and PAHs in binary solvent mixtures, J. Mol. Liq ., 140, 61-67 (2008).D.I. Caviedes Rubio, R.G. Sotomayor, D.R. Delgado , Solvatación preferencial de la naringina en mezclas cosolventes etanol + agua mediante el método de las integrales inversas de Kirkwood-Buff, Rev. Colomb. Cienc. Quím. Farm ., 44, 220-235 (2015).D.R. Delgado , E.F. Vargas, F. Martínez , Preferential solvation of xylitol in ethanol + water solvent mixtures according to the IKBI and QLQC methods, Rev. Colomb. Quím ., 42, 59-66 (2013).D.R. Delgado , F. Martínez . Solubility and preferential solvation of sulfadiazine in methanol + water mixtures at several temperatures, Fluid Phase Equilib ., 379, 128-138 (2015).D.R. Delgado , M.A. Peña, F. Martínez , Preferential solvation of some sulfon-amides in propylene glycol + water solvent mixtures according to the IKBI and QLQC methods, J. Solution Chem, 43, 360-374 (2014).D.R. Delgado , M.Á. Peña, F. Martínez , Preferential solvation of acetaminophen in ethanol + water solvent mixtures according to the inverse Kirkwood-Buff integrals method, Rev. Colomb. Cienc. Quím. Farm ., 42, 298-314 (2013).A.C. Gaviria-Castillo, J.D. Artunduaga-Tole, J.D. Rodríguez-Rubiano, J.A. Zúñiga-Andrade, D.R. Delgado , A. Jouyban , F. Martínez , Solution thermodynamics and preferential solvation of triclocarban in {1, 4-dioxane (1) + water (2)} mixtures at 298.15 K, Phys. Chem. Liq, Forthcoming 2018, doi: 10.1080/00319104.2017.1416613.J.A. Lasso, D.I. Caviedes, D.R. Delgado , Preferential solvation of 4-hydroxy-2,5-dimethyl-3(2H)-furanone (DMHF) in ethanol + water mixtures according to IKBI and QLQC methods, Ingeniería y Región, 13, 139-147 (2015).A. Jouyban , S. Nozohouri, F. Martínez , Solubility of celecoxib in {2-propanol (1) + water (2)} mixtures at various temperatures: Experimental data and ther-modynamic analysis J. Mol. Liq , 254, 1-7 (2018).A.F.M. Barton, "Handbook of Solubility parameters and Other Cohesion Parameter", 2nd edition, CRC Press, Inc., New York, 1991.R.F. Fedors, A method for estimating both the solubility parameters and molar volumes of liquids, Polym. Eng. Sci ., 14, 147-154 (1974).D.M. Jimenez, Z.J. Cárdenas, D.R. Delgado , M.Á. Peña , F. Martínez , Solubility temperature dependence and preferential solvation of sulfadiazine in 1,4-dioxane + water co-solvent mixtures, Fluid Phase Equilib ., 397, 26-36 (2015).D.R. Delgado , A.R. Holguín, O.A. Almanza, F. Martínez , Y. Marcus , Solubility and preferential solvation of meloxicam in ethanol + water mixtures, Fluid Phase Equilib , 305, 88-95 (2011).D.R. Delgado , F. Martínez , Solubility and preferential solvation of sulfadiazine in methanol + water mixtures at several temperatures, Fluid Phase Equilib ., 379, 128-138 (2014).D.R. Delgado , F. Martínez , Solubility and solution thermodynamics of sulfamerazine and sulfamethazine in some ethanol + water mixtures, Fluid Phase Equilib , 360, 88-96 (2013)TricinIKBIPreferential solvationEthanolethanolPreferential solvationTicinIKBIPreferential solvation of tricin in {ethanol (1) + water (2)} mixtures at several temperaturesArtículohttp://purl.org/coar/resource_type/c_6501http://purl.org/coar/resource_type/c_2df8fbb1http://purl.org/coar/version/c_970fb48d4fbd8a85info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionAtribucióninfo:eu-repo/semantics/openAccesshttp://purl.org/coar/access_right/c_abf2PublicationLICENSElicense.txtlicense.txttext/plain; charset=utf-84334https://repository.ucc.edu.co/bitstreams/d6dbb012-abd1-4b21-bdd6-0acc99a296a6/download3bce4f7ab09dfc588f126e1e36e98a45MD5220.500.12494/32653oai:repository.ucc.edu.co:20.500.12494/326532024-08-10 21:01:33.977metadata.onlyhttps://repository.ucc.edu.coRepositorio Institucional Universidad Cooperativa de 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

Preferential solvation of tricin in {ethanol (1) + water (2)} mixtures at several temperatures

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