Solution thermodynamics and preferential solvation of sulfamethazine in (methanol + water) mixtures

The solubility of sulfamethazine (SMT) in {methanol (1) + water (2)} co-solvent mixtures was determined at five different temperatures from (293.15 to 313.15) K. The sulfonamide exhibited its highest mole fraction solubility in pure methanol (d1 = 29.6 MPa1/2) and its lowest mole fraction solubility...

Full description

Autores:
Delgado, Daniel Ricardo
Almanza O.A.
Martínez F.
Peña M.A.
Jouyban A.
Acree W.E.
Jr.
Tipo de recurso:
Article of journal
Fecha de publicación:
2016
Institución:
Universidad Cooperativa de Colombia
Repositorio:
Repositorio UCC
Idioma:
OAI Identifier:
oai:repository.ucc.edu.co:20.500.12494/41486
Acceso en línea:
https://doi.org/10.1016/j.rcp.2015.05.015
https://www.scopus.com/inward/record.uri?eid=2-s2.0-85077184762&doi=10.3989%2farbor.2019.794n4007&partnerID=40&md5=ea7685d2d4d32a8dda43031a0c54feec
https://hdl.handle.net/20.500.12494/41486
Palabra clave:
Activity coefficients
Enthalpy
Entropy
Gibbs free energy
Methanol
Mixing
Mixtures
Solubility
Solvation
Sulfur compounds
Thermodynamics
Enthalpy-entropy relationship
Jouyban-Acree model
Kirkwood-Buff integrals
Preferential solvation
Solution thermodynamics
Sulfamethazine
Thermodynamic functions
Thermodynamic quantities
Organic solvents
Rights
closedAccess
License
http://purl.org/coar/access_right/c_14cb