Agro-Industrial Waste from Cocoa Pod Husk (Theobroma cacao L.), as a Potential Raw Material for Preparation of Cellulose Nanocrystals
Obtaining cellulose from agro-industrial waste offers the possibility of generating added value to solid biomass that is currently deposited in sanitary landfills. This research performed the evaluation of a residue from cocoa husk pods (Theobroma cacao L.), from the agricultural industry. The cellu...
- Autores:
-
Herrera-Barrios, Adriana
Puello-Mendez, Juliana
Pasqualino, Jorgelina C.
Lambis-Miranda, Henry A.
- Tipo de recurso:
- Fecha de publicación:
- 2022
- Institución:
- Universidad Tecnológica de Bolívar
- Repositorio:
- Repositorio Institucional UTB
- Idioma:
- eng
- OAI Identifier:
- oai:repositorio.utb.edu.co:20.500.12585/12167
- Acceso en línea:
- https://hdl.handle.net/20.500.12585/12167
- Palabra clave:
- Nanocellulose;
Nanocrystal;
Nanowhiskers
- Rights
- openAccess
- License
- http://creativecommons.org/licenses/by-nc-nd/4.0/
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Agro-Industrial Waste from Cocoa Pod Husk (Theobroma cacao L.), as a Potential Raw Material for Preparation of Cellulose Nanocrystals |
| title |
Agro-Industrial Waste from Cocoa Pod Husk (Theobroma cacao L.), as a Potential Raw Material for Preparation of Cellulose Nanocrystals |
| spellingShingle |
Agro-Industrial Waste from Cocoa Pod Husk (Theobroma cacao L.), as a Potential Raw Material for Preparation of Cellulose Nanocrystals Nanocellulose; Nanocrystal; Nanowhiskers |
| title_short |
Agro-Industrial Waste from Cocoa Pod Husk (Theobroma cacao L.), as a Potential Raw Material for Preparation of Cellulose Nanocrystals |
| title_full |
Agro-Industrial Waste from Cocoa Pod Husk (Theobroma cacao L.), as a Potential Raw Material for Preparation of Cellulose Nanocrystals |
| title_fullStr |
Agro-Industrial Waste from Cocoa Pod Husk (Theobroma cacao L.), as a Potential Raw Material for Preparation of Cellulose Nanocrystals |
| title_full_unstemmed |
Agro-Industrial Waste from Cocoa Pod Husk (Theobroma cacao L.), as a Potential Raw Material for Preparation of Cellulose Nanocrystals |
| title_sort |
Agro-Industrial Waste from Cocoa Pod Husk (Theobroma cacao L.), as a Potential Raw Material for Preparation of Cellulose Nanocrystals |
| dc.creator.fl_str_mv |
Herrera-Barrios, Adriana Puello-Mendez, Juliana Pasqualino, Jorgelina C. Lambis-Miranda, Henry A. |
| dc.contributor.author.none.fl_str_mv |
Herrera-Barrios, Adriana Puello-Mendez, Juliana Pasqualino, Jorgelina C. Lambis-Miranda, Henry A. |
| dc.subject.keywords.spa.fl_str_mv |
Nanocellulose; Nanocrystal; Nanowhiskers |
| topic |
Nanocellulose; Nanocrystal; Nanowhiskers |
| description |
Obtaining cellulose from agro-industrial waste offers the possibility of generating added value to solid biomass that is currently deposited in sanitary landfills. This research performed the evaluation of a residue from cocoa husk pods (Theobroma cacao L.), from the agricultural industry. The cellulose fiber was obtained through chemical treatments with KOH at 5% w/v to remove non-cellulosic components and then the fiber was bleached with 3% v/v hydrogen peroxide. The changes in chemical structure were determined through Fourier transform infrared spectroscopy (FTIR). The FTIR analysis confirms the progressive decrease of lignin and hemicellulose after applying chemical treatment. The morphological changes in the surface of the fiber were characterized using the SEM technique. The mass percentage of cellulose increases up to 68 %. It is expected that the Nano Crystals (NCC) extracted from the biomass of the cocoa husk pods, present a high index of crystallinity and that they are also in suitable conditions to be useful as reinforcing agents in polymeric or mineral matrices, and may have potential application for technology transfer. |
| publishDate |
2022 |
| dc.date.issued.none.fl_str_mv |
2022 |
| dc.date.accessioned.none.fl_str_mv |
2023-07-19T21:10:44Z |
| dc.date.available.none.fl_str_mv |
2023-07-19T21:10:44Z |
| dc.date.submitted.none.fl_str_mv |
2023 |
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info:eu-repo/semantics/article |
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info:eu-repo/semantics/draft |
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http://purl.org/coar/resource_type/c_6501 |
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draft |
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Filho, R. M., Ranzi, E., Tognotti, L., Herrera-Barrios, A., Puello-Mendez, J., Pasqualino, J. C., & Lambis-Miranda, H. A. (s/f). Agro-industrial waste from cocoa pod husk (Theobroma cacao L.), as a potential raw material for preparation of cellulose nanocrystals. Chemical engineering transactions. https://doi.org/10.3303/CET2292035 |
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https://hdl.handle.net/20.500.12585/12167 |
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10.3303/CET2292035 |
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Universidad Tecnológica de Bolívar |
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Repositorio Universidad Tecnológica de Bolívar |
| identifier_str_mv |
Filho, R. M., Ranzi, E., Tognotti, L., Herrera-Barrios, A., Puello-Mendez, J., Pasqualino, J. C., & Lambis-Miranda, H. A. (s/f). Agro-industrial waste from cocoa pod husk (Theobroma cacao L.), as a potential raw material for preparation of cellulose nanocrystals. Chemical engineering transactions. https://doi.org/10.3303/CET2292035 10.3303/CET2292035 Universidad Tecnológica de Bolívar Repositorio Universidad Tecnológica de Bolívar |
| url |
https://hdl.handle.net/20.500.12585/12167 |
| dc.language.iso.spa.fl_str_mv |
eng |
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eng |
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Attribution-NonCommercial-NoDerivatives 4.0 Internacional |
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openAccess |
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6 páginas |
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application/pdf |
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Cartagena de Indias |
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Chemical Engineering Transactions |
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Herrera-Barrios, Adriana8d034f07-2a0f-44e8-96d7-bb185a554149Puello-Mendez, Juliana50b404d9-6711-4dbe-8772-dd63811673faPasqualino, Jorgelina C.e94d2336-cf72-4a4d-938c-bf42b3da0710Lambis-Miranda, Henry A.c7e379f6-aaa4-4a7b-af48-df42c001fa372023-07-19T21:10:44Z2023-07-19T21:10:44Z20222023Filho, R. M., Ranzi, E., Tognotti, L., Herrera-Barrios, A., Puello-Mendez, J., Pasqualino, J. C., & Lambis-Miranda, H. A. (s/f). Agro-industrial waste from cocoa pod husk (Theobroma cacao L.), as a potential raw material for preparation of cellulose nanocrystals. Chemical engineering transactions. https://doi.org/10.3303/CET2292035https://hdl.handle.net/20.500.12585/1216710.3303/CET2292035Universidad Tecnológica de BolívarRepositorio Universidad Tecnológica de BolívarObtaining cellulose from agro-industrial waste offers the possibility of generating added value to solid biomass that is currently deposited in sanitary landfills. This research performed the evaluation of a residue from cocoa husk pods (Theobroma cacao L.), from the agricultural industry. The cellulose fiber was obtained through chemical treatments with KOH at 5% w/v to remove non-cellulosic components and then the fiber was bleached with 3% v/v hydrogen peroxide. The changes in chemical structure were determined through Fourier transform infrared spectroscopy (FTIR). The FTIR analysis confirms the progressive decrease of lignin and hemicellulose after applying chemical treatment. The morphological changes in the surface of the fiber were characterized using the SEM technique. The mass percentage of cellulose increases up to 68 %. It is expected that the Nano Crystals (NCC) extracted from the biomass of the cocoa husk pods, present a high index of crystallinity and that they are also in suitable conditions to be useful as reinforcing agents in polymeric or mineral matrices, and may have potential application for technology transfer.6 páginasapplication/pdfenghttp://creativecommons.org/licenses/by-nc-nd/4.0/info:eu-repo/semantics/openAccessAttribution-NonCommercial-NoDerivatives 4.0 Internacionalhttp://purl.org/coar/access_right/c_abf2Chemical Engineering TransactionsAgro-Industrial Waste from Cocoa Pod Husk (Theobroma cacao L.), as a Potential Raw Material for Preparation of Cellulose Nanocrystalsinfo:eu-repo/semantics/articleinfo:eu-repo/semantics/drafthttp://purl.org/coar/resource_type/c_6501http://purl.org/coar/version/c_b1a7d7d4d402bccehttp://purl.org/coar/resource_type/c_2df8fbb1Nanocellulose;Nanocrystal;NanowhiskersCartagena de IndiasAlemdar, A., Sain, M. Isolation and characterization of nanofibers from agricultural residues - Wheat straw and soy hulls (2008) Bioresource Technology, 99 (6), pp. 1664-1671. Cited 1377 times. doi: 10.1016/j.biortech.2007.04.029Álvarez-Álvarez, P., Pizarro, C., Barrio-Anta, M., Cámara-Obregón, A., María Bueno, J.L., Álvarez, A., Gutiérrez, I., (...), Burslem, D.F.R.P. Evaluation of tree species for biomass energy production in Northwest Spain (2018) Forests, 9 (4), art. no. 160. Cited 62 times. http://www.mdpi.com/1999-4907/9/4/160/pdf doi: 10.3390/f9040160Bian, H., Gao, Y., Luo, J., Jiao, L., Wu, W., Fang, G., Dai, H. Lignocellulosic nanofibrils produced using wheat straw and their pulping solid residue: From agricultural waste to cellulose nanomaterials (2019) Waste Management, 91, pp. 1-8. Cited 78 times. www.elsevier.com/locate/wasman doi: 10.1016/j.wasman.2019.04.052Dence, C. W. The determination of lignin (1992) Methods in lignin chemistry, pp. 33-61. Cited 678 times. Springer, Berlin, Heidelberg, GermanyFerreira-Villadiego, J., García-Echeverri, J., Vidal, M.V., Pasqualino, J., Meza-Castellar, P., Lambis-Miranda, H.A. Chemical modification and characterization of starch derived from plantain (Musa paradisiaca) peel waste, as a source of biodegradable material (2018) Chemical Engineering Transactions, 65, pp. 763-768. Cited 18 times. http://www.aidic.it/cet/18/65/128.pdf ISBN: 978-889560862-4 doi: 10.3303/CET1865128Heidarian, P., Behzad, T., Karimi, K. Isolation and characterization of bagasse cellulose nanofibrils by optimized sulfur-free chemical delignification (2016) Wood Science and Technology, 50 (5), pp. 1071-1088. Cited 17 times. doi: 10.1007/s00226-016-0820-6Lu, F., Rodriguez-Garcia, J., Van Damme, I., Westwood, N.J., Shaw, L., Robinson, J.S., Warren, G., (...), Charalampopoulos, D. Valorisation strategies for cocoa pod husk and its fractions (2018) Current Opinion in Green and Sustainable Chemistry, 14, pp. 80-88. Cited 73 times. http://www.journals.elsevier.com/current-opinion-in-green-and-sustainable-chemistry doi: 10.1016/j.cogsc.2018.07.007Lu, H., Gui, Y., Zheng, L., Liu, X. Morphological, crystalline, thermal and physicochemical properties of cellulose nanocrystals obtained from sweet potato residue (2013) Food Research International, 50 (1), pp. 121-128. Cited 163 times. doi: 10.1016/j.foodres.2012.10.013Lu, Q.-L., Tang, L.-R., Wang, S., Huang, B., Chen, Y.-D., Chen, X.-R. An investigation on the characteristics of cellulose nanocrystals from Pennisetum sinese (2014) Biomass and Bioenergy, 70, pp. 267-272. Cited 56 times. http://www.journals.elsevier.com/biomass-and-bioenergy/ doi: 10.1016/j.biombioe.2014.09.012Mansur, D., Tago, T., Masuda, T., Abimanyu, H. Conversion of cacao pod husks by pyrolysis and catalytic reaction to produce useful chemicals (2014) Biomass and Bioenergy, 66, pp. 275-285. Cited 52 times. www.elsevier.com/inca/publications/store/9/8/6 doi: 10.1016/j.biombioe.2014.03.065Martínez-Ángel, J.D., Villamizar-Gallardo, R.A., Ortíz-Rodríguez, O.O. Characterization and evaluation of cocoa (Theobroma cacao L.) pod husk as a renewable energy source (2015) Agrociencia, 49 (3), pp. 329-345. Cited 29 times. http://www.colpos.mx/agrocien/Bimestral/2015/abr-may/art-8.pdfOgunsuyi, H. O., Olawale, C. A. Evaluation of Plantain Biomass (Musa paradisiaca L.), as Feedstock for Bio-Ethanol Production (2021) Green and Sustainable Chemistry, 11, pp. 59-71. Cited 2 times.Pelissari, F.M., Sobral, P.J.D.A., Menegalli, F.C. Isolation and characterization of cellulose nanofibers from banana peels (Open Access) (2014) Cellulose, 21 (1), pp. 417-432. Cited 222 times. doi: 10.1007/s10570-013-0138-6Obi Reddy, K., Guduri, B.R., Rajulu, A.V. Structural characterization and tensile properties of Borassus fruit fibers (Open Access) (2009) Journal of Applied Polymer Science, 114 (1), pp. 603-611. Cited 108 times. http://www3.interscience.wiley.com/cgi-bin/fulltext/122441979/PDFSTART doi: 10.1002/app.30584Srivastava, N.K., Majumder, C.B. Novel biofiltration methods for the treatment of heavy metals from industrial wastewater (2008) Journal of Hazardous Materials, 151 (1), pp. 1-8. Cited 561 times. doi: 10.1016/j.jhazmat.2007.09.101(2011) Lignin in Wood and Pulp, pp. 1-7. T222 Om-02, accessed 20.06.2021Tian, D., Shen, F., Hu, J., Huang, M., Zhao, L., He, J., Li, Q., (...), Shen, F. Complete conversion of lignocellulosic biomass into three high-value nanomaterials through a versatile integrated technical platform (2022) Chemical Engineering Journal, 428, art. no. 131373. 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