Hybrid Materials Based on Nanoparticles Functionalized with Alkylsilanes Covalently Anchored to Epoxy Matrices
In this work, the surface modification of zinc oxide nanoparticles (ZnO-NPs) with 3-glycidyloxy-propyl-trimethoxysilane (GPTMS) was investigated. The ZnO-NPs were synthesized using the physical method of continuous arc discharge in controlled atmosphere (DARC-AC). The surface modification was carrie...
- Autores:
-
Salas, Alexis
Jaramillo, Andrés Felipe
Palacio, Daniel Andrés
Díaz-Gómez, Andrés
Rojas, David
Medina, Carlos
Pérez-Tijerina, Eduardo
Solís-Pomar, Francisco
Meléndrez, Manuel Francisco
- Tipo de recurso:
- Fecha de publicación:
- 2022
- Institución:
- Universidad Tecnológica de Bolívar
- Repositorio:
- Repositorio Institucional UTB
- Idioma:
- eng
- OAI Identifier:
- oai:repositorio.utb.edu.co:20.500.12585/12216
- Acceso en línea:
- https://hdl.handle.net/20.500.12585/12216
- Palabra clave:
- Organic Coatings;
Corrosion Protection;
Corrosion
LEMB
- Rights
- openAccess
- License
- http://purl.org/coar/access_right/c_abf2
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| dc.title.spa.fl_str_mv |
Hybrid Materials Based on Nanoparticles Functionalized with Alkylsilanes Covalently Anchored to Epoxy Matrices |
| title |
Hybrid Materials Based on Nanoparticles Functionalized with Alkylsilanes Covalently Anchored to Epoxy Matrices |
| spellingShingle |
Hybrid Materials Based on Nanoparticles Functionalized with Alkylsilanes Covalently Anchored to Epoxy Matrices Organic Coatings; Corrosion Protection; Corrosion LEMB |
| title_short |
Hybrid Materials Based on Nanoparticles Functionalized with Alkylsilanes Covalently Anchored to Epoxy Matrices |
| title_full |
Hybrid Materials Based on Nanoparticles Functionalized with Alkylsilanes Covalently Anchored to Epoxy Matrices |
| title_fullStr |
Hybrid Materials Based on Nanoparticles Functionalized with Alkylsilanes Covalently Anchored to Epoxy Matrices |
| title_full_unstemmed |
Hybrid Materials Based on Nanoparticles Functionalized with Alkylsilanes Covalently Anchored to Epoxy Matrices |
| title_sort |
Hybrid Materials Based on Nanoparticles Functionalized with Alkylsilanes Covalently Anchored to Epoxy Matrices |
| dc.creator.fl_str_mv |
Salas, Alexis Jaramillo, Andrés Felipe Palacio, Daniel Andrés Díaz-Gómez, Andrés Rojas, David Medina, Carlos Pérez-Tijerina, Eduardo Solís-Pomar, Francisco Meléndrez, Manuel Francisco |
| dc.contributor.author.none.fl_str_mv |
Salas, Alexis Jaramillo, Andrés Felipe Palacio, Daniel Andrés Díaz-Gómez, Andrés Rojas, David Medina, Carlos Pérez-Tijerina, Eduardo Solís-Pomar, Francisco Meléndrez, Manuel Francisco |
| dc.subject.keywords.spa.fl_str_mv |
Organic Coatings; Corrosion Protection; Corrosion |
| topic |
Organic Coatings; Corrosion Protection; Corrosion LEMB |
| dc.subject.armarc.none.fl_str_mv |
LEMB |
| description |
In this work, the surface modification of zinc oxide nanoparticles (ZnO-NPs) with 3-glycidyloxy-propyl-trimethoxysilane (GPTMS) was investigated. The ZnO-NPs were synthesized using the physical method of continuous arc discharge in controlled atmosphere (DARC-AC). The surface modification was carried out using a chemical method with constant agitation for 24 h at room temperature. This surface functionalization of zinc oxide nanoparticles (ZnO-NPs-GPTMS) was experimentally confirmed by infrared spectroscopy (FT-IR), TGA, and XRD, and its morphological characterization was performed with SEM. The increase in mechanical bending properties in the two final hybrid materials compared to the base polymers was verified. An average increase of 67% was achieved with a moderate decrease in ductility. In the case of compressive strength, they showed mixed results, maintaining the properties. With respect to thermal properties, it was observed that inorganic reinforcement conferred resistance to degradation on the base material, giving a greater resistance to high temperatures. © 2022 by the authors. Licensee MDPI, Basel, Switzerland. |
| publishDate |
2022 |
| dc.date.issued.none.fl_str_mv |
2022 |
| dc.date.accessioned.none.fl_str_mv |
2023-07-19T21:22:39Z |
| dc.date.available.none.fl_str_mv |
2023-07-19T21:22:39Z |
| dc.date.submitted.none.fl_str_mv |
2023 |
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http://purl.org/coar/version/c_b1a7d7d4d402bcce |
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http://purl.org/coar/resource_type/c_2df8fbb1 |
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info:eu-repo/semantics/article |
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info:eu-repo/semantics/draft |
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http://purl.org/coar/resource_type/c_6501 |
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draft |
| dc.identifier.citation.spa.fl_str_mv |
Salas, A., Jaramillo, A. F., Palacio, D. A., Díaz-Gómez, A., Rojas, D., Medina, C., ... & Meléndrez, M. F. (2022). Hybrid Materials Based on Nanoparticles Functionalized with Alkylsilanes Covalently Anchored to Epoxy Matrices. Polymers, 14(8), 1579. |
| dc.identifier.uri.none.fl_str_mv |
https://hdl.handle.net/20.500.12585/12216 |
| dc.identifier.doi.none.fl_str_mv |
10.3390/polym14081579 |
| dc.identifier.instname.spa.fl_str_mv |
Universidad Tecnológica de Bolívar |
| dc.identifier.reponame.spa.fl_str_mv |
Repositorio Universidad Tecnológica de Bolívar |
| identifier_str_mv |
Salas, A., Jaramillo, A. F., Palacio, D. A., Díaz-Gómez, A., Rojas, D., Medina, C., ... & Meléndrez, M. F. (2022). Hybrid Materials Based on Nanoparticles Functionalized with Alkylsilanes Covalently Anchored to Epoxy Matrices. Polymers, 14(8), 1579. 10.3390/polym14081579 Universidad Tecnológica de Bolívar Repositorio Universidad Tecnológica de Bolívar |
| url |
https://hdl.handle.net/20.500.12585/12216 |
| dc.language.iso.spa.fl_str_mv |
eng |
| language |
eng |
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http://purl.org/coar/access_right/c_abf2 |
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info:eu-repo/semantics/openAccess |
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openAccess |
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http://purl.org/coar/access_right/c_abf2 |
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18 páginas |
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application/pdf |
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Cartagena de Indias |
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Polymers |
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Universidad Tecnológica de Bolívar |
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Salas, Alexis257f04bc-cad1-4681-a11f-e4edc997647eJaramillo, Andrés Felipe71df81a9-6cd5-4d8d-b12f-a1db4a7fde71Palacio, Daniel Andrés14938efa-451b-4734-aa29-f368a9f2ee91Díaz-Gómez, Andrésab5f2230-a3ca-42fc-a344-3f731702be21Rojas, David8c920364-d787-4be1-9490-4819ced3ac15Medina, Carlos47fbd2f6-8221-43da-8310-4eb09ed5b222Pérez-Tijerina, Eduardo292b2ddc-6ea8-40df-a3bc-8478262d5361Solís-Pomar, Francisco8f359f73-1df8-42c8-8abb-c33816bd251cMeléndrez, Manuel Francisco40d6e913-b733-4a56-aed0-e7db68c0551d2023-07-19T21:22:39Z2023-07-19T21:22:39Z20222023Salas, A., Jaramillo, A. F., Palacio, D. A., Díaz-Gómez, A., Rojas, D., Medina, C., ... & Meléndrez, M. F. (2022). Hybrid Materials Based on Nanoparticles Functionalized with Alkylsilanes Covalently Anchored to Epoxy Matrices. Polymers, 14(8), 1579.https://hdl.handle.net/20.500.12585/1221610.3390/polym14081579Universidad Tecnológica de BolívarRepositorio Universidad Tecnológica de BolívarIn this work, the surface modification of zinc oxide nanoparticles (ZnO-NPs) with 3-glycidyloxy-propyl-trimethoxysilane (GPTMS) was investigated. The ZnO-NPs were synthesized using the physical method of continuous arc discharge in controlled atmosphere (DARC-AC). The surface modification was carried out using a chemical method with constant agitation for 24 h at room temperature. This surface functionalization of zinc oxide nanoparticles (ZnO-NPs-GPTMS) was experimentally confirmed by infrared spectroscopy (FT-IR), TGA, and XRD, and its morphological characterization was performed with SEM. The increase in mechanical bending properties in the two final hybrid materials compared to the base polymers was verified. An average increase of 67% was achieved with a moderate decrease in ductility. In the case of compressive strength, they showed mixed results, maintaining the properties. With respect to thermal properties, it was observed that inorganic reinforcement conferred resistance to degradation on the base material, giving a greater resistance to high temperatures. © 2022 by the authors. Licensee MDPI, Basel, Switzerland.18 páginasapplication/pdfengPolymersHybrid Materials Based on Nanoparticles Functionalized with Alkylsilanes Covalently Anchored to Epoxy Matricesinfo:eu-repo/semantics/articleinfo:eu-repo/semantics/drafthttp://purl.org/coar/resource_type/c_6501http://purl.org/coar/version/c_b1a7d7d4d402bccehttp://purl.org/coar/resource_type/c_2df8fbb1Organic Coatings;Corrosion Protection;CorrosionLEMBinfo:eu-repo/semantics/openAccesshttp://purl.org/coar/access_right/c_abf2Cartagena de IndiasKango, S., Kalia, S., Celli, A., Njuguna, J., Habibi, Y., Kumar, R. Surface modification of inorganic nanoparticles for development of organic-inorganic nanocomposites - A review (2013) Progress in Polymer Science, 38 (8), pp. 1232-1261. Cited 1631 times. doi: 10.1016/j.progpolymsci.2013.02.003Bakkardouch, F.E., Atmani, H., El Khalloufi, M., Jouaiti, A., Laallam, L. Modified cellulose-based hybrid materials: Effect of ZnO and CuO nanoparticles on the thermal insulation property (2021) Materials Chemistry and Physics, 271, art. no. 124881. Cited 5 times. http://www.journals.elsevier.com/materials-chemistry-and-physics doi: 10.1016/j.matchemphys.2021.124881Afshari, A., Akbari, M., Toghraie, D., Yazdi, M.E. Experimental investigation of rheological behavior of the hybrid nanofluid of MWCNT–alumina/water (80%)–ethylene-glycol (20%): New correlation and margin of deviation (2018) Journal of Thermal Analysis and Calorimetry, 132 (2), pp. 1001-1015. 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Cited 46 times. www.elsevier.com/locate/powtec doi: 10.1016/j.powtec.2015.09.042Ji, T., Ma, C., Brisbin, L., Mu, L., Robertson, C.G., Dong, Y., Zhu, J. Organosilane grafted silica: Quantitative correlation of microscopic surface characters and macroscopic surface properties (2017) Applied Surface Science, 399, pp. 565-572. Cited 21 times. http://www.journals.elsevier.com/applied-surface-science/ doi: 10.1016/j.apsusc.2016.11.241Jaramillo, A.F., Riquelme, S.A., Sánchez-Sanhueza, G., Medina, C., Solís-Pomar, F., Rojas, D., Montalba, C., (...), Pérez-Tijerina, E. Comparative Study of the Antimicrobial Effect of Nanocomposites and Composite Based on Poly(butylene adipate-co-terephthalate) Using Cu and Cu/Cu2O Nanoparticles and CuSO4 (2019) Nanoscale Research Letters, 14, art. no. 158. Cited 23 times. http://www.springer.com/materials/nanotechnology/journal/11671 doi: 10.1186/s11671-019-2987-xLi, W., Song, B., Zhang, S., Zhang, F., Liu, C., Zhang, N., Yao, H., (...), Shi, Y. 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Estimation of the surface interaction mechanism of ZnO nanoparticles modified with organosilane groups by Raman Spectroscopy (2017) Ceramics International, 43 (15), pp. 11838-11847. Cited 73 times. doi: 10.1016/j.ceramint.2017.06.027MedinaM, C., Rojas, D., Flores, P., Peréz-Tijerina, E., Meléndrez, M.F. Effect of ZnO nanoparticles obtained by arc discharge on thermo-mechanical properties of matrix thermoset nanocomposites (2016) Journal of Applied Polymer Science, 133 (30), art. no. 43631. Cited 13 times. http://onlinelibrary.wiley.com/journal/10.1002/(ISSN)1097-4628 doi: 10.1002/app.43631Amaria, A., Nuryono, N., Suyanta, S. Preparation of L-arginine-modified silica-coated magnetite nanoparticles for Au(III) adsorption (2017) Oriental Journal of Chemistry, 33 (1), pp. 384-395. Cited 13 times. http://www.orientjchem.org/pdf/vol33no1/OJC_Vol33_No1_p_384-395.pdf doi: 10.13005/ojc/330146González, M.G., Cabanelas, J.C., Baselga, J. 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