Quantification of the Synthetic Phenolic Antioxidant Cyanox 1790 in Bottled Water with SPE-HPLC/MS/MS and Determination of the Impact of the Use of Recycled Packaging on Its Generation
One route of exposure to SPAs is through bottled water since the polymers used to make plastic bottles contain these SPAs, which migrate from the plastic to the water. Solid-phase extraction (SPE), HPLC-MS, FTIR, and DSC are used to identify and quantify these SPAs in water. Interday measurements of...
- Autores:
-
Hernández Fernández, Joaquín
Ortega-Toro, Rodrigo
Castro-Suarez, John R .
- Tipo de recurso:
- Fecha de publicación:
- 2023
- Institución:
- Universidad Tecnológica de Bolívar
- Repositorio:
- Repositorio Institucional UTB
- Idioma:
- eng
- OAI Identifier:
- oai:repositorio.utb.edu.co:20.500.12585/11956
- Palabra clave:
- Bottled water
Synthetic phenolic antioxidant
Cyanox 1790
Recycled packaging
Non-recycled packaging
Additive migration
LEMB
- Rights
- openAccess
- License
- http://creativecommons.org/licenses/by-nc-nd/4.0/
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dc.title.spa.fl_str_mv |
Quantification of the Synthetic Phenolic Antioxidant Cyanox 1790 in Bottled Water with SPE-HPLC/MS/MS and Determination of the Impact of the Use of Recycled Packaging on Its Generation |
title |
Quantification of the Synthetic Phenolic Antioxidant Cyanox 1790 in Bottled Water with SPE-HPLC/MS/MS and Determination of the Impact of the Use of Recycled Packaging on Its Generation |
spellingShingle |
Quantification of the Synthetic Phenolic Antioxidant Cyanox 1790 in Bottled Water with SPE-HPLC/MS/MS and Determination of the Impact of the Use of Recycled Packaging on Its Generation Bottled water Synthetic phenolic antioxidant Cyanox 1790 Recycled packaging Non-recycled packaging Additive migration LEMB |
title_short |
Quantification of the Synthetic Phenolic Antioxidant Cyanox 1790 in Bottled Water with SPE-HPLC/MS/MS and Determination of the Impact of the Use of Recycled Packaging on Its Generation |
title_full |
Quantification of the Synthetic Phenolic Antioxidant Cyanox 1790 in Bottled Water with SPE-HPLC/MS/MS and Determination of the Impact of the Use of Recycled Packaging on Its Generation |
title_fullStr |
Quantification of the Synthetic Phenolic Antioxidant Cyanox 1790 in Bottled Water with SPE-HPLC/MS/MS and Determination of the Impact of the Use of Recycled Packaging on Its Generation |
title_full_unstemmed |
Quantification of the Synthetic Phenolic Antioxidant Cyanox 1790 in Bottled Water with SPE-HPLC/MS/MS and Determination of the Impact of the Use of Recycled Packaging on Its Generation |
title_sort |
Quantification of the Synthetic Phenolic Antioxidant Cyanox 1790 in Bottled Water with SPE-HPLC/MS/MS and Determination of the Impact of the Use of Recycled Packaging on Its Generation |
dc.creator.fl_str_mv |
Hernández Fernández, Joaquín Ortega-Toro, Rodrigo Castro-Suarez, John R . |
dc.contributor.author.none.fl_str_mv |
Hernández Fernández, Joaquín Ortega-Toro, Rodrigo Castro-Suarez, John R . |
dc.subject.keywords.spa.fl_str_mv |
Bottled water Synthetic phenolic antioxidant Cyanox 1790 Recycled packaging Non-recycled packaging Additive migration |
topic |
Bottled water Synthetic phenolic antioxidant Cyanox 1790 Recycled packaging Non-recycled packaging Additive migration LEMB |
dc.subject.armarc.none.fl_str_mv |
LEMB |
description |
One route of exposure to SPAs is through bottled water since the polymers used to make plastic bottles contain these SPAs, which migrate from the plastic to the water. Solid-phase extraction (SPE), HPLC-MS, FTIR, and DSC are used to identify and quantify these SPAs in water. Interday measurements of cyanox 1790 in water with HPLC showed RSD, error, and R2 lower than 3.78, 9.3,and 0.99995, respectively. For intraday measurements of cyanox 1790 in water, the RSD, error, and R2 were less than 4.1, 11.2, and 0.99995, respectively. Concentrations of Cyanox 1790 in water from non-recycled bottles ranged from 0.01 ± 0.0004 to 4.15 ± 0. 14 ppm, while the levels of cyanox 1790 in water in recycled bottles ranged between 0.01 ± 0.0005 and 11.27 ± 0.12 ppm. In the tests carried out, an increase in the migration of Cyanox 1790 from plastic bottles to water was identified, since the ppm of Cyanox increased in the water as the days of storage increased at 40 ◦C. |
publishDate |
2023 |
dc.date.accessioned.none.fl_str_mv |
2023-05-30T14:04:30Z |
dc.date.available.none.fl_str_mv |
2023-05-30T14:04:30Z |
dc.date.issued.none.fl_str_mv |
2023-02-28 |
dc.date.submitted.none.fl_str_mv |
2023-05-25 |
dc.type.coarversion.fl_str_mv |
http://purl.org/coar/version/c_b1a7d7d4d402bcce |
dc.type.driver.spa.fl_str_mv |
info:eu-repo/semantics/article |
dc.type.hasversion.spa.fl_str_mv |
info:eu-repo/semantics/draft |
dc.type.spa.spa.fl_str_mv |
http://purl.org/coar/resource_type/c_2df8fbb1 |
status_str |
draft |
dc.identifier.citation.spa.fl_str_mv |
Hernández-Fernández, J.;Ortega-Toro, R.; Castro-Suarez, J.R.Quantification of the Synthetic Phenolic Antioxidant Cyanox 1790 in Bottled Water with SPE-HPLC/ MS/MS and Determination of the Impact of the Use of Recycled Packaging on Its Generation. Water 2023, 15, 933. https://doi.org/10.3390/w15050933 |
dc.identifier.uri.none.fl_str_mv |
https://hdl.handle.net/20.500.12585/11956 |
dc.identifier.doi.none.fl_str_mv |
https://doi.org/10.3390/w15050933 |
dc.identifier.instname.spa.fl_str_mv |
Universidad Tecnológica de Bolívar |
dc.identifier.reponame.spa.fl_str_mv |
Repositorio Universidad Tecnológica de Bolívar |
identifier_str_mv |
Hernández-Fernández, J.;Ortega-Toro, R.; Castro-Suarez, J.R.Quantification of the Synthetic Phenolic Antioxidant Cyanox 1790 in Bottled Water with SPE-HPLC/ MS/MS and Determination of the Impact of the Use of Recycled Packaging on Its Generation. Water 2023, 15, 933. https://doi.org/10.3390/w15050933 Universidad Tecnológica de Bolívar Repositorio Universidad Tecnológica de Bolívar |
url |
https://hdl.handle.net/20.500.12585/11956 https://doi.org/10.3390/w15050933 |
dc.language.iso.spa.fl_str_mv |
eng |
language |
eng |
dc.rights.coar.fl_str_mv |
http://purl.org/coar/access_right/c_abf2 |
dc.rights.uri.*.fl_str_mv |
http://creativecommons.org/licenses/by-nc-nd/4.0/ |
dc.rights.accessrights.spa.fl_str_mv |
info:eu-repo/semantics/openAccess |
dc.rights.cc.*.fl_str_mv |
Attribution-NonCommercial-NoDerivatives 4.0 Internacional Attribution-NonCommercial-NoDerivatives 4.0 Internacional |
rights_invalid_str_mv |
http://creativecommons.org/licenses/by-nc-nd/4.0/ Attribution-NonCommercial-NoDerivatives 4.0 Internacional http://purl.org/coar/access_right/c_abf2 |
eu_rights_str_mv |
openAccess |
dc.format.extent.none.fl_str_mv |
15 Páginas |
dc.format.mimetype.spa.fl_str_mv |
application/pdf |
dc.publisher.place.spa.fl_str_mv |
Cartagena de Indias |
dc.publisher.sede.spa.fl_str_mv |
Campus Tecnológico |
dc.source.spa.fl_str_mv |
Water - Vol. 15 No. 5 (2023) |
institution |
Universidad Tecnológica de Bolívar |
bitstream.url.fl_str_mv |
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Hernández Fernández, Joaquínbc85d77e-b89b-40f6-a090-a475dc6dc160Ortega-Toro, Rodrigod594d4c1-6ec9-4782-a84b-cee2853ea359Castro-Suarez, John R .e2326948-21b0-4572-aa06-ed6fc206a6e92023-05-30T14:04:30Z2023-05-30T14:04:30Z2023-02-282023-05-25Hernández-Fernández, J.;Ortega-Toro, R.; Castro-Suarez, J.R.Quantification of the Synthetic Phenolic Antioxidant Cyanox 1790 in Bottled Water with SPE-HPLC/ MS/MS and Determination of the Impact of the Use of Recycled Packaging on Its Generation. Water 2023, 15, 933. https://doi.org/10.3390/w15050933https://hdl.handle.net/20.500.12585/11956https://doi.org/10.3390/w15050933Universidad Tecnológica de BolívarRepositorio Universidad Tecnológica de BolívarOne route of exposure to SPAs is through bottled water since the polymers used to make plastic bottles contain these SPAs, which migrate from the plastic to the water. Solid-phase extraction (SPE), HPLC-MS, FTIR, and DSC are used to identify and quantify these SPAs in water. Interday measurements of cyanox 1790 in water with HPLC showed RSD, error, and R2 lower than 3.78, 9.3,and 0.99995, respectively. For intraday measurements of cyanox 1790 in water, the RSD, error, and R2 were less than 4.1, 11.2, and 0.99995, respectively. Concentrations of Cyanox 1790 in water from non-recycled bottles ranged from 0.01 ± 0.0004 to 4.15 ± 0. 14 ppm, while the levels of cyanox 1790 in water in recycled bottles ranged between 0.01 ± 0.0005 and 11.27 ± 0.12 ppm. In the tests carried out, an increase in the migration of Cyanox 1790 from plastic bottles to water was identified, since the ppm of Cyanox increased in the water as the days of storage increased at 40 ◦C.15 Páginasapplication/pdfenghttp://creativecommons.org/licenses/by-nc-nd/4.0/info:eu-repo/semantics/openAccessAttribution-NonCommercial-NoDerivatives 4.0 InternacionalAttribution-NonCommercial-NoDerivatives 4.0 Internacionalhttp://purl.org/coar/access_right/c_abf2Water - Vol. 15 No. 5 (2023)Quantification of the Synthetic Phenolic Antioxidant Cyanox 1790 in Bottled Water with SPE-HPLC/MS/MS and Determination of the Impact of the Use of Recycled Packaging on Its Generationinfo:eu-repo/semantics/articleinfo:eu-repo/semantics/drafthttp://purl.org/coar/resource_type/c_2df8fbb1http://purl.org/coar/version/c_b1a7d7d4d402bcceBottled waterSynthetic phenolic antioxidantCyanox 1790Recycled packagingNon-recycled packagingAdditive migrationLEMBCartagena de IndiasCampus TecnológicoPúblico generalFortune Business Insights. 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