Volatile organic compounds in the atmosphere of Mexico City

The Mexico City Metropolitan Area (MCMA) is one of the most polluted megacities in North America. Therefore, it is an excellent benchmark city to understand atmospheric chemistry and to implement pilot countermeasures. Air quality in the MCMA is not within acceptable levels, mainly due to high groun...

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Fecha de publicación:: 2015

Institución:: Universidad Tecnológica de Bolívar

Repositorio:: Repositorio Institucional UTB

Idioma:: eng

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dc.title.none.fl_str_mv	Volatile organic compounds in the atmosphere of Mexico City
title	Volatile organic compounds in the atmosphere of Mexico City
spellingShingle	Volatile organic compounds in the atmosphere of Mexico City Ozone Ozone formation potential Toxic volatile organic compound Volatile organic compound Acetone Air quality Atmospheric chemistry Benzene Cost effectiveness Gas chromatography Industrial emissions Ionization of gases Liquefied petroleum gas Nitrogen oxides Organic compounds Ozone Toluene Troposphere Average concentration Correlation analysis Emission sources Environmental Authority Industrial sources Mexico City metropolitan areas Ozone formation potentials Vehicular emission Volatile organic compounds 1,3 butadiene 1,4 dichlorobenzene Acetone Alcohol Benzene Ethylbenzene Gasoline Methyl chloride Ozone Petroleum derivative Propane Styrene Toluene Volatile organic compound Xylene Air quality Atmospheric chemistry Benchmarking Benzene Concentration (composition) Correlation Cost-benefit analysis Health risk Liquefied petroleum gas Metropolitan area Nitrogen oxides Ozone Public health Toluene Toxic substance Troposphere Volatile organic compound Article Atmosphere City Controlled study Correlation analysis Human Mexican Mexico Motor vehicle Priority journal Federal District [Mexico] Mexico City Mexico [North America]
title_short	Volatile organic compounds in the atmosphere of Mexico City
title_full	Volatile organic compounds in the atmosphere of Mexico City
title_fullStr	Volatile organic compounds in the atmosphere of Mexico City
title_full_unstemmed	Volatile organic compounds in the atmosphere of Mexico City
title_sort	Volatile organic compounds in the atmosphere of Mexico City
dc.subject.keywords.none.fl_str_mv	Ozone Ozone formation potential Toxic volatile organic compound Volatile organic compound Acetone Air quality Atmospheric chemistry Benzene Cost effectiveness Gas chromatography Industrial emissions Ionization of gases Liquefied petroleum gas Nitrogen oxides Organic compounds Ozone Toluene Troposphere Average concentration Correlation analysis Emission sources Environmental Authority Industrial sources Mexico City metropolitan areas Ozone formation potentials Vehicular emission Volatile organic compounds 1,3 butadiene 1,4 dichlorobenzene Acetone Alcohol Benzene Ethylbenzene Gasoline Methyl chloride Ozone Petroleum derivative Propane Styrene Toluene Volatile organic compound Xylene Air quality Atmospheric chemistry Benchmarking Benzene Concentration (composition) Correlation Cost-benefit analysis Health risk Liquefied petroleum gas Metropolitan area Nitrogen oxides Ozone Public health Toluene Toxic substance Troposphere Volatile organic compound Article Atmosphere City Controlled study Correlation analysis Human Mexican Mexico Motor vehicle Priority journal Federal District [Mexico] Mexico City Mexico [North America]
topic	Ozone Ozone formation potential Toxic volatile organic compound Volatile organic compound Acetone Air quality Atmospheric chemistry Benzene Cost effectiveness Gas chromatography Industrial emissions Ionization of gases Liquefied petroleum gas Nitrogen oxides Organic compounds Ozone Toluene Troposphere Average concentration Correlation analysis Emission sources Environmental Authority Industrial sources Mexico City metropolitan areas Ozone formation potentials Vehicular emission Volatile organic compounds 1,3 butadiene 1,4 dichlorobenzene Acetone Alcohol Benzene Ethylbenzene Gasoline Methyl chloride Ozone Petroleum derivative Propane Styrene Toluene Volatile organic compound Xylene Air quality Atmospheric chemistry Benchmarking Benzene Concentration (composition) Correlation Cost-benefit analysis Health risk Liquefied petroleum gas Metropolitan area Nitrogen oxides Ozone Public health Toluene Toxic substance Troposphere Volatile organic compound Article Atmosphere City Controlled study Correlation analysis Human Mexican Mexico Motor vehicle Priority journal Federal District [Mexico] Mexico City Mexico [North America]
description	The Mexico City Metropolitan Area (MCMA) is one of the most polluted megacities in North America. Therefore, it is an excellent benchmark city to understand atmospheric chemistry and to implement pilot countermeasures. Air quality in the MCMA is not within acceptable levels, mainly due to high ground levels of ozone (O3). Tropospheric O3 is a secondary pollutant formed from the oxidation of volatile organic compounds (VOCs) in the presence of nitrogen oxides and sunlight. To gain a better understanding of O3 formation in megacities, evaluate the effectiveness of already-implemented countermeasures, and identify new cost-effective alternatives to reduce tropospheric O3 concentrations, researchers and environmental authorities require updated concentrations for a broader range of VOCs. Moreover, in an effort to protect human health and the environment, it is important to understand which VOCs exceed reference safe values or most contribute to O3 formation, as well as to identify the most probable emission sources of those VOCs. In this work, 64 VOCs, including 36 toxic VOCs, were measured at four sites in the MCMA during 2011-2012. VOCs related to liquefied petroleum gas leakages exhibited the highest concentrations. Toxic VOCs with the highest average concentrations were acetone and ethanol. The toxic VOC benzene represented the highest risk to Mexican citizens, and toluene contributed the most to O3 formation. Correlation analysis indicated that the measured VOCs come from vehicular emissions and solvent-related industrial sources. VOC measurements revealed that compounds related to liquefied petroleum gas leakages are the most abundant, the toxic VOC benzene represents the highest risk to citizens, and toluene is the greatest VOC contributor to O3 formation in Mexico City. © 2015 Elsevier Ltd.
publishDate	2015
dc.date.issued.none.fl_str_mv	2015
dc.date.accessioned.none.fl_str_mv	2019-11-06T19:05:18Z
dc.date.available.none.fl_str_mv	2019-11-06T19:05:18Z
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dc.type.spa.none.fl_str_mv	Artículo
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dc.identifier.citation.none.fl_str_mv	Atmospheric Environment; Vol. 119, pp. 415-429
dc.identifier.issn.none.fl_str_mv	1352-2310
dc.identifier.uri.none.fl_str_mv	https://hdl.handle.net/20.500.12585/8752
dc.identifier.doi.none.fl_str_mv	10.1016/j.atmosenv.2015.08.014
dc.identifier.instname.none.fl_str_mv	Universidad Tecnológica de Bolívar
dc.identifier.reponame.none.fl_str_mv	Repositorio UTB
identifier_str_mv	Atmospheric Environment; Vol. 119, pp. 415-429 1352-2310 10.1016/j.atmosenv.2015.08.014 Universidad Tecnológica de Bolívar Repositorio UTB
url	https://hdl.handle.net/20.500.12585/8752
dc.language.iso.none.fl_str_mv	eng
language	eng
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dc.publisher.none.fl_str_mv	Elsevier Ltd
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spelling	2019-11-06T19:05:18Z2019-11-06T19:05:18Z2015Atmospheric Environment; Vol. 119, pp. 415-4291352-2310https://hdl.handle.net/20.500.12585/875210.1016/j.atmosenv.2015.08.014Universidad Tecnológica de BolívarRepositorio UTBThe Mexico City Metropolitan Area (MCMA) is one of the most polluted megacities in North America. Therefore, it is an excellent benchmark city to understand atmospheric chemistry and to implement pilot countermeasures. Air quality in the MCMA is not within acceptable levels, mainly due to high ground levels of ozone (O3). Tropospheric O3 is a secondary pollutant formed from the oxidation of volatile organic compounds (VOCs) in the presence of nitrogen oxides and sunlight. To gain a better understanding of O3 formation in megacities, evaluate the effectiveness of already-implemented countermeasures, and identify new cost-effective alternatives to reduce tropospheric O3 concentrations, researchers and environmental authorities require updated concentrations for a broader range of VOCs. Moreover, in an effort to protect human health and the environment, it is important to understand which VOCs exceed reference safe values or most contribute to O3 formation, as well as to identify the most probable emission sources of those VOCs. In this work, 64 VOCs, including 36 toxic VOCs, were measured at four sites in the MCMA during 2011-2012. VOCs related to liquefied petroleum gas leakages exhibited the highest concentrations. Toxic VOCs with the highest average concentrations were acetone and ethanol. The toxic VOC benzene represented the highest risk to Mexican citizens, and toluene contributed the most to O3 formation. Correlation analysis indicated that the measured VOCs come from vehicular emissions and solvent-related industrial sources. VOC measurements revealed that compounds related to liquefied petroleum gas leakages are the most abundant, the toxic VOC benzene represents the highest risk to citizens, and toluene is the greatest VOC contributor to O3 formation in Mexico City. © 2015 Elsevier Ltd.Japan Science and Technology Agency, Science and Technology Research Partnership for Sustainable Development, Japan International Cooperation Agency1,3 butadiene, 106-99-0, 25339-57-5; 1,4 dichlorobenzene, 106-46-7; acetone, 67-64-1; alcohol, 64-17-5; benzene, 71-43-2; ethylbenzene, 100-41-4; gasoline, 86290-81-5; methyl chloride, 74-87-3; ozone, 10028-15-6; propane, 74-98-6; styrene, 100-42-5; toluene, 108-88-3; xylene, 1330-20-7Recurso electrónicoapplication/pdfengElsevier Ltdhttp://creativecommons.org/licenses/by-nc-nd/4.0/info:eu-repo/semantics/openAccessAtribución-NoComercial 4.0 Internacionalhttp://purl.org/coar/access_right/c_abf2https://www2.scopus.com/inward/record.uri?eid=2-s2.0-84940477852&doi=10.1016%2fj.atmosenv.2015.08.014&partnerID=40&md5=e3e3e3503765915e28cc7d85c2539f3aScopus 55382377200Scopus 7103267573Scopus 9639625300Scopus 54402814900Scopus 55993708900Scopus 12809336300Scopus 7404539667Scopus 7006407675Scopus 22957247600Volatile organic compounds in the atmosphere of Mexico Cityinfo:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionArtículohttp://purl.org/coar/version/c_970fb48d4fbd8a85http://purl.org/coar/resource_type/c_2df8fbb1OzoneOzone formation potentialToxic volatile organic compoundVolatile organic compoundAcetoneAir qualityAtmospheric chemistryBenzeneCost effectivenessGas chromatographyIndustrial emissionsIonization of gasesLiquefied petroleum gasNitrogen oxidesOrganic compoundsOzoneTolueneTroposphereAverage concentrationCorrelation analysisEmission sourcesEnvironmental AuthorityIndustrial sourcesMexico City metropolitan areasOzone formation potentialsVehicular emissionVolatile organic compounds1,3 butadiene1,4 dichlorobenzeneAcetoneAlcoholBenzeneEthylbenzeneGasolineMethyl chlorideOzonePetroleum derivativePropaneStyreneTolueneVolatile organic compoundXyleneAir qualityAtmospheric chemistryBenchmarkingBenzeneConcentration (composition)CorrelationCost-benefit analysisHealth riskLiquefied petroleum gasMetropolitan areaNitrogen oxidesOzonePublic healthTolueneToxic substanceTroposphereVolatile organic compoundArticleAtmosphereCityControlled studyCorrelation analysisHumanMexicanMexicoMotor vehiclePriority journalFederal District [Mexico]Mexico CityMexico [North America]Garzón, J.P.Huertas, J.I.Magaña, M.Huertas, M.E.Cárdenas, B.Watanabe, T.Maeda, T.Wakamatsu, S.Blanco, S.Apel, E.C., Emmons, L.K., Karl, T., Flocke, F., Hills, A.J., Madronich, S., Lee-Taylor, J., Riemer, D.D., Chemical evolution of volatile organic compounds in the outflow of the Mexico City Metropolitan Area (2010) Atmos. 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Environ., 70, pp. 521-531http://purl.org/coar/resource_type/c_6501ORIGINALDOI10_1016j_atmosenv_2015_08_014.pdfapplication/pdf3474454https://repositorio.utb.edu.co/bitstream/20.500.12585/8752/1/DOI10_1016j_atmosenv_2015_08_014.pdf4202a7f96aa57968470e07dd32ccf929MD51TEXTDOI10_1016j_atmosenv_2015_08_014.pdf.txtDOI10_1016j_atmosenv_2015_08_014.pdf.txtExtracted texttext/plain79455https://repositorio.utb.edu.co/bitstream/20.500.12585/8752/4/DOI10_1016j_atmosenv_2015_08_014.pdf.txt64d7b69c15e08a6a47670f4da82125bcMD54THUMBNAILDOI10_1016j_atmosenv_2015_08_014.pdf.jpgDOI10_1016j_atmosenv_2015_08_014.pdf.jpgGenerated Thumbnailimage/jpeg76819https://repositorio.utb.edu.co/bitstream/20.500.12585/8752/5/DOI10_1016j_atmosenv_2015_08_014.pdf.jpga8c12fe642ebdf691d939d55b0ec43adMD5520.500.12585/8752oai:repositorio.utb.edu.co:20.500.12585/87522020-10-23 04:47:50.809Repositorio Institucional UTBrepositorioutb@utb.edu.co

Volatile organic compounds in the atmosphere of Mexico City

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