Valoration of the Synthetic Antioxidant Tris-(Diterbutyl-Phenol)-Phosphite (Irgafos P-168) from Industrial Wastewater and Application in Polypropylene Matrices to Minimize Its Thermal Degradation

Industrial wastewater from petrochemical processes is an essential source of the synthetic phenolic phosphite antioxidant (Irgafos P-168), which negatively affects the environment. For the determination and analysis of Irgafos P-168, DSC, HPLC-MS, and FTIR methodologies were used. Solid phase extrac...

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Autores:
Hernández-Fernández, Joaquín
Cano, Heidis
Reyes, Ana Fonseca
Tipo de recurso:
Fecha de publicación:
2023
Institución:
Universidad Tecnológica de Bolívar
Repositorio:
Repositorio Institucional UTB
Idioma:
eng
OAI Identifier:
oai:repositorio.utb.edu.co:20.500.12585/12157
Acceso en línea:
https://hdl.handle.net/20.500.12585/12157
Palabra clave:
Valoration
Synthetic antioxidant
Irgafos P-168
Industrial wastewater
Polypropylene
Thermal degradation
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openAccess
License
http://creativecommons.org/licenses/by-nc-nd/4.0/
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network_acronym_str UTB2
network_name_str Repositorio Institucional UTB
repository_id_str
dc.title.spa.fl_str_mv Valoration of the Synthetic Antioxidant Tris-(Diterbutyl-Phenol)-Phosphite (Irgafos P-168) from Industrial Wastewater and Application in Polypropylene Matrices to Minimize Its Thermal Degradation
title Valoration of the Synthetic Antioxidant Tris-(Diterbutyl-Phenol)-Phosphite (Irgafos P-168) from Industrial Wastewater and Application in Polypropylene Matrices to Minimize Its Thermal Degradation
spellingShingle Valoration of the Synthetic Antioxidant Tris-(Diterbutyl-Phenol)-Phosphite (Irgafos P-168) from Industrial Wastewater and Application in Polypropylene Matrices to Minimize Its Thermal Degradation
Valoration
Synthetic antioxidant
Irgafos P-168
Industrial wastewater
Polypropylene
Thermal degradation
title_short Valoration of the Synthetic Antioxidant Tris-(Diterbutyl-Phenol)-Phosphite (Irgafos P-168) from Industrial Wastewater and Application in Polypropylene Matrices to Minimize Its Thermal Degradation
title_full Valoration of the Synthetic Antioxidant Tris-(Diterbutyl-Phenol)-Phosphite (Irgafos P-168) from Industrial Wastewater and Application in Polypropylene Matrices to Minimize Its Thermal Degradation
title_fullStr Valoration of the Synthetic Antioxidant Tris-(Diterbutyl-Phenol)-Phosphite (Irgafos P-168) from Industrial Wastewater and Application in Polypropylene Matrices to Minimize Its Thermal Degradation
title_full_unstemmed Valoration of the Synthetic Antioxidant Tris-(Diterbutyl-Phenol)-Phosphite (Irgafos P-168) from Industrial Wastewater and Application in Polypropylene Matrices to Minimize Its Thermal Degradation
title_sort Valoration of the Synthetic Antioxidant Tris-(Diterbutyl-Phenol)-Phosphite (Irgafos P-168) from Industrial Wastewater and Application in Polypropylene Matrices to Minimize Its Thermal Degradation
dc.creator.fl_str_mv Hernández-Fernández, Joaquín
Cano, Heidis
Reyes, Ana Fonseca
dc.contributor.author.none.fl_str_mv Hernández-Fernández, Joaquín
Cano, Heidis
Reyes, Ana Fonseca
dc.subject.keywords.spa.fl_str_mv Valoration
Synthetic antioxidant
Irgafos P-168
Industrial wastewater
Polypropylene
Thermal degradation
topic Valoration
Synthetic antioxidant
Irgafos P-168
Industrial wastewater
Polypropylene
Thermal degradation
description Industrial wastewater from petrochemical processes is an essential source of the synthetic phenolic phosphite antioxidant (Irgafos P-168), which negatively affects the environment. For the determination and analysis of Irgafos P-168, DSC, HPLC-MS, and FTIR methodologies were used. Solid phase extraction (SPE) proved to be the best technique for extracting Irgafos from wastewater. HPLC-MS and SPE determined the repeatability, reproducibility, and linearity of the method and the SPE of the standards and samples. The relative standard deviations, errors, and correlation coefficients for the repeatability and reproducibility of the calibration curves were less than 4.4% and 4.2% and greater than 0.99955, respectively. The analysis of variance (ANOVA), using the Fisher method with confidence in 95% of the data, did not reveal significant differences between the mentioned parameters. The removal of the antioxidant from the wastewater by SPE showed recovery percentages higher than 91.03%, and the chemical characterization of this antioxidant by FTIR spectroscopy, DSC, TGA, and MS showed it to be structurally the same as the Irgafos P-168 molecule. The recovered Irgafos was added to the polypropylene matrix, significantly improving its oxidation times. An OIT analysis, performed using DSC, showed that the recovered Irgafos-blended polypropylene (PP) demonstrated oxidative degradation at 8 min. With the addition of the Irgafos, the oxidation time was 13 min. This increases the polypropylene’s useful life and minimizes the environmental impact of the wastewater.
publishDate 2023
dc.date.accessioned.none.fl_str_mv 2023-07-19T12:55:06Z
dc.date.available.none.fl_str_mv 2023-07-19T12:55:06Z
dc.date.issued.none.fl_str_mv 2023-04-02
dc.date.submitted.none.fl_str_mv 2023-07
dc.type.coarversion.fl_str_mv http://purl.org/coar/version/c_b1a7d7d4d402bcce
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dc.identifier.citation.spa.fl_str_mv Hernández-Fernández, J.; Cano, H.; Reyes, A.F. Valoration of the Synthetic Antioxidant Tris-(Diterbutyl- henol)-Phosphite (Irgafos P-168) from Industrial Wastewater and Application in Polypropylene Matrices to Minimize Its Thermal Degradation. Molecules 2023, 28, 3163. https://doi.org/10.3390/molecules28073163
dc.identifier.uri.none.fl_str_mv https://hdl.handle.net/20.500.12585/12157
dc.identifier.doi.none.fl_str_mv 10.3390/molecules28073163
dc.identifier.instname.spa.fl_str_mv Universidad Tecnológica de Bolívar
dc.identifier.reponame.spa.fl_str_mv Repositorio Universidad Tecnológica de Bolívar
identifier_str_mv Hernández-Fernández, J.; Cano, H.; Reyes, A.F. Valoration of the Synthetic Antioxidant Tris-(Diterbutyl- henol)-Phosphite (Irgafos P-168) from Industrial Wastewater and Application in Polypropylene Matrices to Minimize Its Thermal Degradation. Molecules 2023, 28, 3163. https://doi.org/10.3390/molecules28073163
10.3390/molecules28073163
Universidad Tecnológica de Bolívar
Repositorio Universidad Tecnológica de Bolívar
url https://hdl.handle.net/20.500.12585/12157
dc.language.iso.spa.fl_str_mv eng
language eng
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dc.rights.accessrights.spa.fl_str_mv info:eu-repo/semantics/openAccess
dc.rights.cc.*.fl_str_mv Attribution-NonCommercial-NoDerivatives 4.0 Internacional
rights_invalid_str_mv http://creativecommons.org/licenses/by-nc-nd/4.0/
Attribution-NonCommercial-NoDerivatives 4.0 Internacional
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eu_rights_str_mv openAccess
dc.format.extent.none.fl_str_mv 21 páginas
dc.format.medium.none.fl_str_mv Pdf
dc.format.mimetype.spa.fl_str_mv application/pdf
dc.publisher.place.spa.fl_str_mv Cartagena de Indias
dc.publisher.sede.spa.fl_str_mv Campus Tecnológico
dc.source.spa.fl_str_mv Molecules - Vol. 28 No. 7 (2023)
institution Universidad Tecnológica de Bolívar
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spelling Hernández-Fernández, Joaquínbc85d77e-b89b-40f6-a090-a475dc6dc160Cano, Heidis9bed059b-3803-4c24-b13c-1500bcb79359Reyes, Ana Fonseca18625724-11b8-4d35-947b-4c7615f4dc5a2023-07-19T12:55:06Z2023-07-19T12:55:06Z2023-04-022023-07Hernández-Fernández, J.; Cano, H.; Reyes, A.F. Valoration of the Synthetic Antioxidant Tris-(Diterbutyl- henol)-Phosphite (Irgafos P-168) from Industrial Wastewater and Application in Polypropylene Matrices to Minimize Its Thermal Degradation. Molecules 2023, 28, 3163. https://doi.org/10.3390/molecules28073163https://hdl.handle.net/20.500.12585/1215710.3390/molecules28073163Universidad Tecnológica de BolívarRepositorio Universidad Tecnológica de BolívarIndustrial wastewater from petrochemical processes is an essential source of the synthetic phenolic phosphite antioxidant (Irgafos P-168), which negatively affects the environment. For the determination and analysis of Irgafos P-168, DSC, HPLC-MS, and FTIR methodologies were used. Solid phase extraction (SPE) proved to be the best technique for extracting Irgafos from wastewater. HPLC-MS and SPE determined the repeatability, reproducibility, and linearity of the method and the SPE of the standards and samples. The relative standard deviations, errors, and correlation coefficients for the repeatability and reproducibility of the calibration curves were less than 4.4% and 4.2% and greater than 0.99955, respectively. The analysis of variance (ANOVA), using the Fisher method with confidence in 95% of the data, did not reveal significant differences between the mentioned parameters. The removal of the antioxidant from the wastewater by SPE showed recovery percentages higher than 91.03%, and the chemical characterization of this antioxidant by FTIR spectroscopy, DSC, TGA, and MS showed it to be structurally the same as the Irgafos P-168 molecule. The recovered Irgafos was added to the polypropylene matrix, significantly improving its oxidation times. An OIT analysis, performed using DSC, showed that the recovered Irgafos-blended polypropylene (PP) demonstrated oxidative degradation at 8 min. With the addition of the Irgafos, the oxidation time was 13 min. This increases the polypropylene’s useful life and minimizes the environmental impact of the wastewater.21 páginasPdfapplication/pdfenghttp://creativecommons.org/licenses/by-nc-nd/4.0/info:eu-repo/semantics/openAccessAttribution-NonCommercial-NoDerivatives 4.0 Internacionalhttp://purl.org/coar/access_right/c_abf2Molecules - Vol. 28 No. 7 (2023)Valoration of the Synthetic Antioxidant Tris-(Diterbutyl-Phenol)-Phosphite (Irgafos P-168) from Industrial Wastewater and Application in Polypropylene Matrices to Minimize Its Thermal Degradationinfo:eu-repo/semantics/articleinfo:eu-repo/semantics/drafthttp://purl.org/coar/resource_type/c_6501http://purl.org/coar/version/c_b1a7d7d4d402bccehttp://purl.org/coar/resource_type/c_2df8fbb1ValorationSynthetic antioxidantIrgafos P-168Industrial wastewaterPolypropyleneThermal degradationCartagena de IndiasCampus TecnológicoHazarika, M.; Dixit, U.S.; Davim, J.P. History of Production and Industrial Engineering through Contributions of Stalwarts. Manuf. 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