Identifying, Quantifying, and Recovering a Sorbitol-Type Petrochemical Additive in Industrial Wastewater and Its Subsequent Application in a Polymeric Matrix as a Nucleating Agent
Currently, polypropylene (PP) is highlighted using sorbitol-based clarifying agents since these agents are high quality, low cost, and work as a barrier against moisture, which makes PP ideal for packaging food, beverages, and medical products, among others. The use of analytical methods capable of...
- Autores:
-
Hernández-Fernández, Joaquín
Puello-Polo, Esneyder
Marquez, Edgar
- Tipo de recurso:
- Fecha de publicación:
- 2023
- Institución:
- Universidad Tecnológica de Bolívar
- Repositorio:
- Repositorio Institucional UTB
- Idioma:
- eng
- OAI Identifier:
- oai:repositorio.utb.edu.co:20.500.12585/12413
- Acceso en línea:
- https://hdl.handle.net/20.500.12585/12413
- Palabra clave:
- clarifying agent;
Crystallization; degradation;
Millad NX 8000;
Polypropylene;
Purity;
Recovery;
Solid phase extraction
LEMB
- Rights
- openAccess
- License
- http://creativecommons.org/licenses/by-nc-nd/4.0/
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Identifying, Quantifying, and Recovering a Sorbitol-Type Petrochemical Additive in Industrial Wastewater and Its Subsequent Application in a Polymeric Matrix as a Nucleating Agent |
| title |
Identifying, Quantifying, and Recovering a Sorbitol-Type Petrochemical Additive in Industrial Wastewater and Its Subsequent Application in a Polymeric Matrix as a Nucleating Agent |
| spellingShingle |
Identifying, Quantifying, and Recovering a Sorbitol-Type Petrochemical Additive in Industrial Wastewater and Its Subsequent Application in a Polymeric Matrix as a Nucleating Agent clarifying agent; Crystallization; degradation; Millad NX 8000; Polypropylene; Purity; Recovery; Solid phase extraction LEMB |
| title_short |
Identifying, Quantifying, and Recovering a Sorbitol-Type Petrochemical Additive in Industrial Wastewater and Its Subsequent Application in a Polymeric Matrix as a Nucleating Agent |
| title_full |
Identifying, Quantifying, and Recovering a Sorbitol-Type Petrochemical Additive in Industrial Wastewater and Its Subsequent Application in a Polymeric Matrix as a Nucleating Agent |
| title_fullStr |
Identifying, Quantifying, and Recovering a Sorbitol-Type Petrochemical Additive in Industrial Wastewater and Its Subsequent Application in a Polymeric Matrix as a Nucleating Agent |
| title_full_unstemmed |
Identifying, Quantifying, and Recovering a Sorbitol-Type Petrochemical Additive in Industrial Wastewater and Its Subsequent Application in a Polymeric Matrix as a Nucleating Agent |
| title_sort |
Identifying, Quantifying, and Recovering a Sorbitol-Type Petrochemical Additive in Industrial Wastewater and Its Subsequent Application in a Polymeric Matrix as a Nucleating Agent |
| dc.creator.fl_str_mv |
Hernández-Fernández, Joaquín Puello-Polo, Esneyder Marquez, Edgar |
| dc.contributor.author.none.fl_str_mv |
Hernández-Fernández, Joaquín Puello-Polo, Esneyder Marquez, Edgar |
| dc.subject.keywords.spa.fl_str_mv |
clarifying agent; Crystallization; degradation; Millad NX 8000; Polypropylene; Purity; Recovery; Solid phase extraction |
| topic |
clarifying agent; Crystallization; degradation; Millad NX 8000; Polypropylene; Purity; Recovery; Solid phase extraction LEMB |
| dc.subject.armarc.none.fl_str_mv |
LEMB |
| description |
Currently, polypropylene (PP) is highlighted using sorbitol-based clarifying agents since these agents are high quality, low cost, and work as a barrier against moisture, which makes PP ideal for packaging food, beverages, and medical products, among others. The use of analytical methods capable of recovering these additives in wastewater streams and then reusing them in the PP clarification stage represents an innovative methodology that makes a substantial contribution to the circular economy of the PP production industry. In this study, a method of extraction and recovery of the Millad NX 8000 was developed. The additive was recovered using GC-MS and extracted with an activated carbon column plus glass fiber, using an injection molded sample, obtaining a recovery rate greater than 96%. TGA, DSC, and FTIR were used to evaluate the recovered additive’s glass transitions and purity. The thermal degradation of the recovered additive was found to be between 340 and 420 °C, with a melting temperature of 246 °C, adopting the same behavior as the pure additive. In FTIR, the characteristic absorption peak of Millad NX 8000 was observed at 1073 cm−1, which indicates the purity of the extracted compound. Therefore, this work develops a new additive recovery methodology with high purity to regulate the crystallization behavior and of PP. © 2023 by the authors. |
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2023 |
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2023-07-24T20:47:54Z |
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2023-07-24T20:47:54Z |
| dc.date.issued.none.fl_str_mv |
2023 |
| dc.date.submitted.none.fl_str_mv |
2023 |
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http://purl.org/coar/version/c_b1a7d7d4d402bcce |
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http://purl.org/coar/resource_type/c_2df8fbb1 |
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info:eu-repo/semantics/article |
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info:eu-repo/semantics/draft |
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http://purl.org/coar/resource_type/c_6501 |
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draft |
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Hernández-Fernández, J., Puello-Polo, E., & Marquez, E. (2023). Identifying, Quantifying, and Recovering a Sorbitol-Type Petrochemical Additive in Industrial Wastewater and Its Subsequent Application in a Polymeric Matrix as a Nucleating Agent. Molecules, 28(13), 4948. |
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https://hdl.handle.net/20.500.12585/12413 |
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10.3390/molecules28134948 |
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Universidad Tecnológica de Bolívar |
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Repositorio Universidad Tecnológica de Bolívar |
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Hernández-Fernández, J., Puello-Polo, E., & Marquez, E. (2023). Identifying, Quantifying, and Recovering a Sorbitol-Type Petrochemical Additive in Industrial Wastewater and Its Subsequent Application in a Polymeric Matrix as a Nucleating Agent. Molecules, 28(13), 4948. 10.3390/molecules28134948 Universidad Tecnológica de Bolívar Repositorio Universidad Tecnológica de Bolívar |
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https://hdl.handle.net/20.500.12585/12413 |
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eng |
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eng |
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Attribution-NonCommercial-NoDerivatives 4.0 Internacional |
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openAccess |
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18 páginas |
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Hernández-Fernández, Joaquínbc85d77e-b89b-40f6-a090-a475dc6dc160Puello-Polo, Esneyderc7c2c83b-c3c0-4db0-a37b-0e98f7da05c0Marquez, Edgar89b04eaf-a0a4-4a6c-95fe-30b68a6ed20d2023-07-24T20:47:54Z2023-07-24T20:47:54Z20232023Hernández-Fernández, J., Puello-Polo, E., & Marquez, E. (2023). Identifying, Quantifying, and Recovering a Sorbitol-Type Petrochemical Additive in Industrial Wastewater and Its Subsequent Application in a Polymeric Matrix as a Nucleating Agent. Molecules, 28(13), 4948.https://hdl.handle.net/20.500.12585/1241310.3390/molecules28134948Universidad Tecnológica de BolívarRepositorio Universidad Tecnológica de BolívarCurrently, polypropylene (PP) is highlighted using sorbitol-based clarifying agents since these agents are high quality, low cost, and work as a barrier against moisture, which makes PP ideal for packaging food, beverages, and medical products, among others. The use of analytical methods capable of recovering these additives in wastewater streams and then reusing them in the PP clarification stage represents an innovative methodology that makes a substantial contribution to the circular economy of the PP production industry. In this study, a method of extraction and recovery of the Millad NX 8000 was developed. The additive was recovered using GC-MS and extracted with an activated carbon column plus glass fiber, using an injection molded sample, obtaining a recovery rate greater than 96%. TGA, DSC, and FTIR were used to evaluate the recovered additive’s glass transitions and purity. The thermal degradation of the recovered additive was found to be between 340 and 420 °C, with a melting temperature of 246 °C, adopting the same behavior as the pure additive. In FTIR, the characteristic absorption peak of Millad NX 8000 was observed at 1073 cm−1, which indicates the purity of the extracted compound. Therefore, this work develops a new additive recovery methodology with high purity to regulate the crystallization behavior and of PP. © 2023 by the authors.18 páginasapplication/pdfenghttp://creativecommons.org/licenses/by-nc-nd/4.0/info:eu-repo/semantics/openAccessAttribution-NonCommercial-NoDerivatives 4.0 Internacionalhttp://purl.org/coar/access_right/c_abf2MoleculesIdentifying, Quantifying, and Recovering a Sorbitol-Type Petrochemical Additive in Industrial Wastewater and Its Subsequent Application in a Polymeric Matrix as a Nucleating Agentinfo:eu-repo/semantics/articleinfo:eu-repo/semantics/drafthttp://purl.org/coar/resource_type/c_6501http://purl.org/coar/version/c_b1a7d7d4d402bccehttp://purl.org/coar/resource_type/c_2df8fbb1clarifying agent;Crystallization; degradation;Millad NX 8000;Polypropylene;Purity;Recovery;Solid phase extractionLEMBCartagena de IndiasMarquès, M., Domingo, J.L., Nadal, M., Schuhmacher, M. Health risks for the population living near petrochemical industrial complexes. 2. Adverse health outcomes other than cancer (2020) Science of the Total Environment, 730, art. no. 139122. Cited 45 times. www.elsevier.com/locate/scitotenv doi: 10.1016/j.scitotenv.2020.139122Fernández, J.H., Guerra, Y., Cano, H. Detection of Bisphenol A and Four Analogues in Atmospheric Emissions in Petrochemical Complexes Producing Polypropylene in South America (2022) Molecules, 27 (15), art. no. 4832. Cited 10 times. http://www.mdpi.com/journal/molecules doi: 10.3390/molecules27154832Nyashina, G.S., Kuznetsov, G.V., Strizhak, P.A. Effects of plant additives on the concentration of sulfur and nitrogen oxides in the combustion products of coal-water slurries containing petrochemicals (2020) Environmental Pollution, 258, art. no. 113682. Cited 31 times. https://www.journals.elsevier.com/environmental-pollution doi: 10.1016/j.envpol.2019.113682Hernández-Fernández, J., Guerra, Y., Espinosa, E. Development and Application of a Principal Component Analysis Model to Quantify the Green Ethylene Content in Virgin Impact Copolymer Resins During Their Synthesis on an Industrial Scale (2022) Journal of Polymers and the Environment, 30 (11), pp. 4800-4808. Cited 9 times. https://www.springer.com/journal/10924 doi: 10.1007/s10924-022-02557-4Hernández-Fernández, J., Cano-Cuadro, H., Puello-Polo, E. Emission of Bisphenol A and Four New Analogs from Industrial Wastewater Treatment Plants in the Production Processes of Polypropylene and Polyethylene Terephthalate in South America (2022) Sustainability (Switzerland), 14 (17), art. no. 10919. Cited 4 times. http://www.mdpi.com/journal/sustainability/ doi: 10.3390/su141710919Fernández, J.H., Cano, H., Guerra, Y., Polo, E.P., Ríos-Rojas, J.F., Vivas-Reyes, R., Oviedo, J. Identification and Quantification of Microplastics in Effluents of Wastewater Treatment Plant by Differential Scanning Calorimetry (DSC) (2022) Sustainability (Switzerland), 14 (9), art. no. 4920. Cited 15 times. https://www.mdpi.com/2071-1050/14/9/4920/pdf doi: 10.3390/su14094920Binsbergen, F.L., de Lange, B.G.M. Heterogeneous nucleation in the crystallization of polyolefins: Part 2. Kinetics of crystallization of nucleated polypropylene (Open Access) (1970) Polymer, 11 (6), pp. 309-332. Cited 132 times. doi: 10.1016/0032-3861(70)90071-6Kristiansen, M., Tervoort, T., Smith, P., Goossens, H. Mechanical properties of sorbitol-clarified isotactic polypropylene: Influence of additive concentration on polymer structure and yield behavior (Open Access) (2005) Macromolecules, 38 (25), pp. 10461-10465. Cited 90 times. doi: 10.1021/ma0517401Nogales, A., Mitchell, G.R., Vaughan, A.S. 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