Recovery of an Antioxidant Derived from a Phenolic Diphosphite from Wastewater during the Production of a Polypropylene Compound: A Step towards Sustainable Management
Organic phosphoester (OPE) antioxidants are currently required due to their contribution to enhancing the quality of polymers, including polypropylene (PP). In this research, an integral methodology is presented for the efficient extraction of bis(2,4-dicumylphenyl) pentaerythritol diphosphite from...
- Autores:
-
Hernandez Fernandez, Joaquin
Bello-Leon, Elias
Carrascal, Juan
- Tipo de recurso:
- Fecha de publicación:
- 2024
- Institución:
- Universidad Tecnológica de Bolívar
- Repositorio:
- Repositorio Institucional UTB
- Idioma:
- eng
- OAI Identifier:
- oai:repositorio.utb.edu.co:20.500.12585/12709
- Acceso en línea:
- https://hdl.handle.net/20.500.12585/12709
- Palabra clave:
- Extraction
Organic
Antioxidants phenolics phosphoesters
Polypropylene
Industrial
Wastewater
LEMB
- Rights
- openAccess
- License
- http://creativecommons.org/publicdomain/zero/1.0/
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Recovery of an Antioxidant Derived from a Phenolic Diphosphite from Wastewater during the Production of a Polypropylene Compound: A Step towards Sustainable Management |
| title |
Recovery of an Antioxidant Derived from a Phenolic Diphosphite from Wastewater during the Production of a Polypropylene Compound: A Step towards Sustainable Management |
| spellingShingle |
Recovery of an Antioxidant Derived from a Phenolic Diphosphite from Wastewater during the Production of a Polypropylene Compound: A Step towards Sustainable Management Extraction Organic Antioxidants phenolics phosphoesters Polypropylene Industrial Wastewater LEMB |
| title_short |
Recovery of an Antioxidant Derived from a Phenolic Diphosphite from Wastewater during the Production of a Polypropylene Compound: A Step towards Sustainable Management |
| title_full |
Recovery of an Antioxidant Derived from a Phenolic Diphosphite from Wastewater during the Production of a Polypropylene Compound: A Step towards Sustainable Management |
| title_fullStr |
Recovery of an Antioxidant Derived from a Phenolic Diphosphite from Wastewater during the Production of a Polypropylene Compound: A Step towards Sustainable Management |
| title_full_unstemmed |
Recovery of an Antioxidant Derived from a Phenolic Diphosphite from Wastewater during the Production of a Polypropylene Compound: A Step towards Sustainable Management |
| title_sort |
Recovery of an Antioxidant Derived from a Phenolic Diphosphite from Wastewater during the Production of a Polypropylene Compound: A Step towards Sustainable Management |
| dc.creator.fl_str_mv |
Hernandez Fernandez, Joaquin Bello-Leon, Elias Carrascal, Juan |
| dc.contributor.author.none.fl_str_mv |
Hernandez Fernandez, Joaquin Bello-Leon, Elias Carrascal, Juan |
| dc.subject.keywords.spa.fl_str_mv |
Extraction Organic Antioxidants phenolics phosphoesters Polypropylene Industrial Wastewater |
| topic |
Extraction Organic Antioxidants phenolics phosphoesters Polypropylene Industrial Wastewater LEMB |
| dc.subject.armarc.none.fl_str_mv |
LEMB |
| description |
Organic phosphoester (OPE) antioxidants are currently required due to their contribution to enhancing the quality of polymers, including polypropylene (PP). In this research, an integral methodology is presented for the efficient extraction of bis(2,4-dicumylphenyl) pentaerythritol diphosphite from industrial wastewater. Upon employing the solid-phase extraction (SPE) technique, the recovered compound is subjected to a comprehensive analysis of the recovered compound using high-performance liquid chromatography (HPLC), mass spectrometry (MS), thermal analysis (TGA), Fourier transforms infrared spectroscopy (FTIR), and differential scanning calorimetry (DSC). Subsequently, purified Bis(2,4-dicumylphenyl) pentaerythritol diphosphite was evaluated as a thermooxidative stabilizer after incorporation into PP resins. The relative standard deviation (RSD), Error (Er), linearity (R2), and percentage (%) recovery were less than 2.6, 2.5, more significant than 0.9995, and greater than 96%, respectively, for the inter-day and intra-day tests of the chromatographic method and the SPE. Except for chloroform, which was necessary due to the solubility properties of the investigated analyte, the use of environmentally friendly solvents, such as methanol and acetonitrile, was considered during the development of this research. The OPE extracted from industrial wastewater was characterized by FTIR, UV–Vis, DSC, TGA, and MS, allowing the elucidation of the structure of Bis(2,4-dicumylphenyl) pentaerythritol diphosphite (BDPD). The recovered OPE was mixed with PP resins, allowing it to improve its thermal properties and minimize its thermo-oxidative degradation. Organophosphorus flame retardant (OPE)’ concentration in wastewater is alarming, ranging from 1179.0 to 4709.6 mg L−1. These exceed toxicity thresholds for aquatic organisms, emphasizing global environmental risks. Using a validated solid-phase extraction (SPE) technique with over 94% recovery, the study addresses concerns by removing organic contaminants and supporting circular economy principles. The high economic and environmental significance of recovering BDPD underscores the need for urgent global attention and intervention. |
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2024 |
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2024-08-14T12:15:59Z |
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2024-08-14T12:15:59Z |
| dc.date.issued.none.fl_str_mv |
2024-06-11 |
| dc.date.submitted.none.fl_str_mv |
2024-08-13 |
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http://purl.org/coar/version/c_970fb48d4fbd8a85 |
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info:eu-repo/semantics/article |
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http://purl.org/coar/resource_type/c_2df8fbb1 |
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publishedVersion |
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Hernández-Fernández, J.; Bello-Leon, E.; Carrascal, J. Recovery of an Antioxidant Derived from a Phenolic Diphosphite from Wastewater during the Production of a Polypropylene Compound: A Step towards Sustainable Management. Molecules 2024, 29, 2780. https:// doi.org/10.3390/molecules29122780 |
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https://hdl.handle.net/20.500.12585/12709 |
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10.3390/molecules29122780 |
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Universidad Tecnológica de Bolívar |
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Repositorio Universidad Tecnológica de Bolívar |
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Hernández-Fernández, J.; Bello-Leon, E.; Carrascal, J. Recovery of an Antioxidant Derived from a Phenolic Diphosphite from Wastewater during the Production of a Polypropylene Compound: A Step towards Sustainable Management. Molecules 2024, 29, 2780. https:// doi.org/10.3390/molecules29122780 10.3390/molecules29122780 Universidad Tecnológica de Bolívar Repositorio Universidad Tecnológica de Bolívar |
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https://hdl.handle.net/20.500.12585/12709 |
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eng |
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eng |
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Hernandez Fernandez, Joaquine572e424-8c7f-4b36-ade7-2c94d29e3c79Bello-Leon, Elias578b51e9-b1de-4b43-b433-5a855bfa1954Carrascal, Juanfbd9ee70-9362-44f6-8f09-537f72f97c822024-08-14T12:15:59Z2024-08-14T12:15:59Z2024-06-112024-08-13Hernández-Fernández, J.; Bello-Leon, E.; Carrascal, J. Recovery of an Antioxidant Derived from a Phenolic Diphosphite from Wastewater during the Production of a Polypropylene Compound: A Step towards Sustainable Management. Molecules 2024, 29, 2780. https:// doi.org/10.3390/molecules29122780https://hdl.handle.net/20.500.12585/1270910.3390/molecules29122780Universidad Tecnológica de BolívarRepositorio Universidad Tecnológica de BolívarOrganic phosphoester (OPE) antioxidants are currently required due to their contribution to enhancing the quality of polymers, including polypropylene (PP). In this research, an integral methodology is presented for the efficient extraction of bis(2,4-dicumylphenyl) pentaerythritol diphosphite from industrial wastewater. Upon employing the solid-phase extraction (SPE) technique, the recovered compound is subjected to a comprehensive analysis of the recovered compound using high-performance liquid chromatography (HPLC), mass spectrometry (MS), thermal analysis (TGA), Fourier transforms infrared spectroscopy (FTIR), and differential scanning calorimetry (DSC). Subsequently, purified Bis(2,4-dicumylphenyl) pentaerythritol diphosphite was evaluated as a thermooxidative stabilizer after incorporation into PP resins. The relative standard deviation (RSD), Error (Er), linearity (R2), and percentage (%) recovery were less than 2.6, 2.5, more significant than 0.9995, and greater than 96%, respectively, for the inter-day and intra-day tests of the chromatographic method and the SPE. Except for chloroform, which was necessary due to the solubility properties of the investigated analyte, the use of environmentally friendly solvents, such as methanol and acetonitrile, was considered during the development of this research. The OPE extracted from industrial wastewater was characterized by FTIR, UV–Vis, DSC, TGA, and MS, allowing the elucidation of the structure of Bis(2,4-dicumylphenyl) pentaerythritol diphosphite (BDPD). The recovered OPE was mixed with PP resins, allowing it to improve its thermal properties and minimize its thermo-oxidative degradation. Organophosphorus flame retardant (OPE)’ concentration in wastewater is alarming, ranging from 1179.0 to 4709.6 mg L−1. These exceed toxicity thresholds for aquatic organisms, emphasizing global environmental risks. Using a validated solid-phase extraction (SPE) technique with over 94% recovery, the study addresses concerns by removing organic contaminants and supporting circular economy principles. The high economic and environmental significance of recovering BDPD underscores the need for urgent global attention and intervention.20 paginasapplication/pdfenghttp://creativecommons.org/publicdomain/zero/1.0/info:eu-repo/semantics/openAccessCC0 1.0 Universalhttp://purl.org/coar/access_right/c_abf2MoleculesRecovery of an Antioxidant Derived from a Phenolic Diphosphite from Wastewater during the Production of a Polypropylene Compound: A Step towards Sustainable Managementinfo:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_2df8fbb1http://purl.org/coar/version/c_970fb48d4fbd8a85ExtractionOrganicAntioxidants phenolics phosphoestersPolypropyleneIndustrialWastewaterLEMBCartagena de IndiasCampus TecnológicoInvestigadoresVila-Costa, M.; Martinez-Varela, A.; Rivas, D.; Martinez, P.; Pérez-López, C.; Zonja, B.; Montemurro, N.; Tauler, R.; Barceló, D.; Ginebreda, A. 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