Recovery of (Z)-13-Docosenamide from IndustrialWastewater and Its Application in the Production of Virgin Polypropylene to Improve the Coefficient of Friction in Film Type Applications
Abstract: Additives play an important role in the production of plastic materials through their application, in which the mechanical, thermal, and physical properties of polymers are improved, making them last longer and be more resistant. During the synthesis of polypropylene resins, the remains of...
- Autores:
-
Hernandez-Fernandez, Joaquín
Puello-Polo, Esneyder
Lopez-Martinez, Juan
- Tipo de recurso:
- Fecha de publicación:
- 2023
- Institución:
- Universidad Tecnológica de Bolívar
- Repositorio:
- Repositorio Institucional UTB
- Idioma:
- eng
- OAI Identifier:
- oai:repositorio.utb.edu.co:20.500.12585/12407
- Palabra clave:
- erucamide
polypropylene
coefficient of friction
recovery
wastewater
- Rights
- openAccess
- License
- http://creativecommons.org/licenses/by-nc-nd/4.0/
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Recovery of (Z)-13-Docosenamide from IndustrialWastewater and Its Application in the Production of Virgin Polypropylene to Improve the Coefficient of Friction in Film Type Applications |
| title |
Recovery of (Z)-13-Docosenamide from IndustrialWastewater and Its Application in the Production of Virgin Polypropylene to Improve the Coefficient of Friction in Film Type Applications |
| spellingShingle |
Recovery of (Z)-13-Docosenamide from IndustrialWastewater and Its Application in the Production of Virgin Polypropylene to Improve the Coefficient of Friction in Film Type Applications erucamide polypropylene coefficient of friction recovery wastewater |
| title_short |
Recovery of (Z)-13-Docosenamide from IndustrialWastewater and Its Application in the Production of Virgin Polypropylene to Improve the Coefficient of Friction in Film Type Applications |
| title_full |
Recovery of (Z)-13-Docosenamide from IndustrialWastewater and Its Application in the Production of Virgin Polypropylene to Improve the Coefficient of Friction in Film Type Applications |
| title_fullStr |
Recovery of (Z)-13-Docosenamide from IndustrialWastewater and Its Application in the Production of Virgin Polypropylene to Improve the Coefficient of Friction in Film Type Applications |
| title_full_unstemmed |
Recovery of (Z)-13-Docosenamide from IndustrialWastewater and Its Application in the Production of Virgin Polypropylene to Improve the Coefficient of Friction in Film Type Applications |
| title_sort |
Recovery of (Z)-13-Docosenamide from IndustrialWastewater and Its Application in the Production of Virgin Polypropylene to Improve the Coefficient of Friction in Film Type Applications |
| dc.creator.fl_str_mv |
Hernandez-Fernandez, Joaquín Puello-Polo, Esneyder Lopez-Martinez, Juan |
| dc.contributor.author.none.fl_str_mv |
Hernandez-Fernandez, Joaquín Puello-Polo, Esneyder Lopez-Martinez, Juan |
| dc.subject.keywords.spa.fl_str_mv |
erucamide polypropylene coefficient of friction recovery wastewater |
| topic |
erucamide polypropylene coefficient of friction recovery wastewater |
| description |
Abstract: Additives play an important role in the production of plastic materials through their application, in which the mechanical, thermal, and physical properties of polymers are improved, making them last longer and be more resistant. During the synthesis of polypropylene resins, the remains of additives that are not absorbed by the resin are removed in the purification stage and end up in the wastewater. In this article, the recovery of (Z)-13-docosenamide from the wastewater from the process, its purification, and its application in the process was carried out. For the extraction of the additive, solid phase extraction (SPE) was used, and to guarantee the purity of (Z)-13-docosenamide, techniques such as high performance liquid chromatography (HPLC), Fourier transform infrared (FTIR), gas chromatography-mass spectrometry (GC/MS), thermogravimetric (TG) coupled with a gas chromatography-mass spectrometry (GC/MS), and differential scanning calorimetry (DSC) were used. The recovered erucamide was added to the PP between 0.05 and 0.3% w/w. The effects of the properties of the virgin polypropylene with the recovered additive were also evaluated to determine its effectiveness in improving the properties of the material by measuring the coefficient of friction (CoF) as well as the mechanical properties and wettability through atomic force microscopy (AFM) and the contact angle, respectively. It was discovered that using these techniques, it is possible to recover approximately 95% of the additive present in the water while keeping the material’s properties within the desired limits. |
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2023 |
| dc.date.accessioned.none.fl_str_mv |
2023-07-24T18:49:30Z |
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2023-07-24T18:49:30Z |
| dc.date.issued.none.fl_str_mv |
2023-01-09 |
| dc.date.submitted.none.fl_str_mv |
2023-07-12 |
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http://purl.org/coar/version/c_b1a7d7d4d402bcce |
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info:eu-repo/semantics/article |
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info:eu-repo/semantics/draft |
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http://purl.org/coar/resource_type/c_2df8fbb1 |
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draft |
| dc.identifier.citation.spa.fl_str_mv |
Hernández-Fernández, J.; Puello-Polo, E.; López-Martínez, J.Recovery of (Z)-13-Docosenamide from Industrial Wastewater and Its Application in the Production of Virgin Polypropylene to Improve the Coefficient of Friction in Film Type Applications. Sustainability 2023, 151247. https://doi.org/10.3390/su15021247 |
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https://hdl.handle.net/20.500.12585/12407 |
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https://doi.org/10.3390/ su15021247 |
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Universidad Tecnológica de Bolívar |
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Repositorio Universidad Tecnológica de Bolívar |
| identifier_str_mv |
Hernández-Fernández, J.; Puello-Polo, E.; López-Martínez, J.Recovery of (Z)-13-Docosenamide from Industrial Wastewater and Its Application in the Production of Virgin Polypropylene to Improve the Coefficient of Friction in Film Type Applications. Sustainability 2023, 151247. https://doi.org/10.3390/su15021247 Universidad Tecnológica de Bolívar Repositorio Universidad Tecnológica de Bolívar |
| url |
https://hdl.handle.net/20.500.12585/12407 https://doi.org/10.3390/ su15021247 |
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eng |
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eng |
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info:eu-repo/semantics/openAccess |
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Attribution-NonCommercial-NoDerivatives 4.0 Internacional Attribution-NonCommercial-NoDerivatives 4.0 Internacional Attribution-NonCommercial-NoDerivatives 4.0 Internacional |
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16 páginas |
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Cartagena de Indias |
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Hernandez-Fernandez, Joaquín3d23cc40-8b37-40e5-b3e2-314ba827d68dPuello-Polo, Esneyderc7c2c83b-c3c0-4db0-a37b-0e98f7da05c0Lopez-Martinez, Juan89d41ef5-b3d0-4272-8fa4-4eb5f9789bef2023-07-24T18:49:30Z2023-07-24T18:49:30Z2023-01-092023-07-12Hernández-Fernández, J.; Puello-Polo, E.; López-Martínez, J.Recovery of (Z)-13-Docosenamide from Industrial Wastewater and Its Application in the Production of Virgin Polypropylene to Improve the Coefficient of Friction in Film Type Applications. Sustainability 2023, 151247. https://doi.org/10.3390/su15021247https://hdl.handle.net/20.500.12585/12407https://doi.org/10.3390/ su15021247Universidad Tecnológica de BolívarRepositorio Universidad Tecnológica de BolívarAbstract: Additives play an important role in the production of plastic materials through their application, in which the mechanical, thermal, and physical properties of polymers are improved, making them last longer and be more resistant. During the synthesis of polypropylene resins, the remains of additives that are not absorbed by the resin are removed in the purification stage and end up in the wastewater. In this article, the recovery of (Z)-13-docosenamide from the wastewater from the process, its purification, and its application in the process was carried out. For the extraction of the additive, solid phase extraction (SPE) was used, and to guarantee the purity of (Z)-13-docosenamide, techniques such as high performance liquid chromatography (HPLC), Fourier transform infrared (FTIR), gas chromatography-mass spectrometry (GC/MS), thermogravimetric (TG) coupled with a gas chromatography-mass spectrometry (GC/MS), and differential scanning calorimetry (DSC) were used. The recovered erucamide was added to the PP between 0.05 and 0.3% w/w. The effects of the properties of the virgin polypropylene with the recovered additive were also evaluated to determine its effectiveness in improving the properties of the material by measuring the coefficient of friction (CoF) as well as the mechanical properties and wettability through atomic force microscopy (AFM) and the contact angle, respectively. It was discovered that using these techniques, it is possible to recover approximately 95% of the additive present in the water while keeping the material’s properties within the desired limits.16 páginasapplication/pdfenghttp://creativecommons.org/licenses/by-nc-nd/4.0/info:eu-repo/semantics/openAccessAttribution-NonCommercial-NoDerivatives 4.0 InternacionalAttribution-NonCommercial-NoDerivatives 4.0 InternacionalAttribution-NonCommercial-NoDerivatives 4.0 Internacionalhttp://purl.org/coar/access_right/c_abf2SustainabilityRecovery of (Z)-13-Docosenamide from IndustrialWastewater and Its Application in the Production of Virgin Polypropylene to Improve the Coefficient of Friction in Film Type Applicationsinfo:eu-repo/semantics/articleinfo:eu-repo/semantics/drafthttp://purl.org/coar/resource_type/c_2df8fbb1http://purl.org/coar/version/c_b1a7d7d4d402bcceerucamidepolypropylenecoefficient of frictionrecoverywastewaterCartagena de IndiasCampus TecnológicoPúblico generalChamas, A.; Moon, H.; Zheng, J.; Qiu, Y.; Tabassum, T.; Jang, J.H.; Abu-Omar, M.; Scott, S.L.; Suh, S. Degradation Rates of Plastics in the Environment. ACS Sustain. Chem. Eng. 2020, 8, 3494–3511. [Hahladakis, J.N.; Velis, C.A.; Weber, R.; Iacovidou, E.; Purnell, P. An Overview of Chemical Additives Present in Plastics: Migration, Release, Fate and Environmental Impact during Their Use, Disposal and Recycling. J. Hazard. Mater. 2018, 344, 179–199.Bashir, I.; Lone, F.A.; Bhat, R.A.; Mir, S.A.; Dar, Z.A.; Dar, S.A. Concerns and Threats of Contamination on Aquatic Ecosystems. In Bioremediation and Biotechnology; Springer: Cham, Switzerland, 2020; pp. 1–26.Jaiswal, S.; Kumar Gupta, G.; Panchal, K.; Mandeep; Shukla, P. Synthetic Organic Compounds from Paper Industry Wastes: Integrated Biotechnological Interventions. Front. Bioeng. Biotechnol. 2021, 8, 592939.US EPA. Persistent Organic Pollutants: A Global Issue, A Global Response. Available online: https://www.epa.gov/internationalcooperation/ persistent-organic-pollutants-global-issue-global-response (accessed on 11 August 2022).Grobelak, A.; Kowalska, A. Chapter 2—Emerging Environmental Contaminants—Current Status, Challenges, and Technological Solutions. In Emerging Contaminants in the Environment; Sarma, H., Dominguez, D.C., Lee, W.-Y., Eds.; Elsevier: Amsterdam, The Netherlands, 2022; pp. 39–53. ISBN 978-0-323-85160-2.Hernández-Fernandez, J.; Rodríguez, E. Determination of Phenolic Antioxidants Additives in Industrial Wastewater from Polypropylene Production Using Solid Phase Extraction with High-Performance Liquid Chromatography. J. Chromatogr. A 2019, 1607, 460442.Daughton, C.G. Non-Regulated Water Contaminants: Emerging Research. Environ. Impact Assess. Rev. 2004, 24, 711–732.Hurtado, C.; Domínguez, C.; Pérez-Babace, L.; Cañameras, N.; Comas, J.; Bayona, J.M. 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Polymers 2022, 14, 3123Hernández-Fernández, J.; López-Martínez, J. Experimental Study of the Auto-Catalytic Effect of Triethylaluminum and TiCl4 Residuals at the Onset of Non-Additive Polypropylene Degradation and Their Impact on Thermo-Oxidative Degradation and Pyrolysis. J. Anal. Appl. Pyrolysis 2021, 155, 105052Hernández-Fernández, J.; Rayón, E.; López, J.; Arrieta, M.P. Enhancing the Thermal Stability of Polypropylene by Blending with Low Amounts of Natural Antioxidants. Macromol. Mater. Eng. 2019, 304, 1900379Standard Test Method for Static and Kinetic Coefficients of Friction of Plastic Film and Sheeting. Available online: https://www.astm.org/d1894-08.html (accessed on 11 August 2022).Joshi, N.B.; Hirt, D.E. Evaluating Bulk-to-Surface Partitioning of Erucamide in LLDPE Films Using FT-IR Microspectroscopy. Appl. Spectrosc. 1999, 53, 11–16.Huang, Y.; Xiong, Y.; Liu, C.; Li, L.; Xu, D.; Lin, Y.-H.; Nan, C.-W. 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