Furan as Impurity in Green Ethylene and Its Effects on the Productivity of Random Ethylene–Propylene Copolymer Synthesis and Its Thermal and Mechanical Properties

The presence of impurities such as H2S, thiols, ketones, and permanent gases in propylene of fossil origin and their use in the polypropylene production process affect the efficiency of the synthesis and the mechanical properties of the polymer and generate millions of losses worldwide. This creates...

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Autores:
Hernández-Fernández, Joaquín
Puello-Polo, Esneyder
Márquez, Edgar
Tipo de recurso:
Fecha de publicación:
2023
Institución:
Universidad Tecnológica de Bolívar
Repositorio:
Repositorio Institucional UTB
Idioma:
eng
OAI Identifier:
oai:repositorio.utb.edu.co:20.500.12585/12226
Acceso en línea:
https://hdl.handle.net/20.500.12585/12226
Palabra clave:
Plastics;
Marine Debris;
Litter
LEMB
Rights
openAccess
License
http://creativecommons.org/licenses/by-nc-nd/4.0/
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dc.title.spa.fl_str_mv Furan as Impurity in Green Ethylene and Its Effects on the Productivity of Random Ethylene–Propylene Copolymer Synthesis and Its Thermal and Mechanical Properties
title Furan as Impurity in Green Ethylene and Its Effects on the Productivity of Random Ethylene–Propylene Copolymer Synthesis and Its Thermal and Mechanical Properties
spellingShingle Furan as Impurity in Green Ethylene and Its Effects on the Productivity of Random Ethylene–Propylene Copolymer Synthesis and Its Thermal and Mechanical Properties
Plastics;
Marine Debris;
Litter
LEMB
title_short Furan as Impurity in Green Ethylene and Its Effects on the Productivity of Random Ethylene–Propylene Copolymer Synthesis and Its Thermal and Mechanical Properties
title_full Furan as Impurity in Green Ethylene and Its Effects on the Productivity of Random Ethylene–Propylene Copolymer Synthesis and Its Thermal and Mechanical Properties
title_fullStr Furan as Impurity in Green Ethylene and Its Effects on the Productivity of Random Ethylene–Propylene Copolymer Synthesis and Its Thermal and Mechanical Properties
title_full_unstemmed Furan as Impurity in Green Ethylene and Its Effects on the Productivity of Random Ethylene–Propylene Copolymer Synthesis and Its Thermal and Mechanical Properties
title_sort Furan as Impurity in Green Ethylene and Its Effects on the Productivity of Random Ethylene–Propylene Copolymer Synthesis and Its Thermal and Mechanical Properties
dc.creator.fl_str_mv Hernández-Fernández, Joaquín
Puello-Polo, Esneyder
Márquez, Edgar
dc.contributor.author.none.fl_str_mv Hernández-Fernández, Joaquín
Puello-Polo, Esneyder
Márquez, Edgar
dc.subject.keywords.spa.fl_str_mv Plastics;
Marine Debris;
Litter
topic Plastics;
Marine Debris;
Litter
LEMB
dc.subject.armarc.none.fl_str_mv LEMB
description The presence of impurities such as H2S, thiols, ketones, and permanent gases in propylene of fossil origin and their use in the polypropylene production process affect the efficiency of the synthesis and the mechanical properties of the polymer and generate millions of losses worldwide. This creates an urgent need to know the families of inhibitors and their concentration levels. This article uses ethylene green to synthesize an ethylene–propylene copolymer. It describes the impact of trace impurities of furan in ethylene green and how this furan influences the loss of properties such as thermal and mechanical properties of the random copolymer. For the development of the investigation, 12 runs were carried out, each in triplicate. The results show an evident influence of furan on the productivity of the Ziegler–Natta catalyst (ZN); productivity losses of 10, 20, and 41% were obtained for the copolymers synthesized with ethylene rich in 6, 12, and 25 ppm of furan, respectively. PP0 (without furan) did not present losses. Likewise, as the concentration of furan increased, it was observed that the melt flow index (MFI), thermal (TGA), and mechanical properties (tensile, bending, and impact) decreased significantly. Therefore, it can be affirmed that furan should be a substance to be controlled in the purification processes of green ethylene. © 2023 by the authors.
publishDate 2023
dc.date.accessioned.none.fl_str_mv 2023-07-19T21:23:50Z
dc.date.available.none.fl_str_mv 2023-07-19T21:23:50Z
dc.date.issued.none.fl_str_mv 2023
dc.date.submitted.none.fl_str_mv 2023
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dc.identifier.uri.none.fl_str_mv https://hdl.handle.net/20.500.12585/12226
dc.identifier.doi.none.fl_str_mv 10.3390/polym15102264
dc.identifier.instname.spa.fl_str_mv Universidad Tecnológica de Bolívar
dc.identifier.reponame.spa.fl_str_mv Repositorio Universidad Tecnológica de Bolívar
url https://hdl.handle.net/20.500.12585/12226
identifier_str_mv 10.3390/polym15102264
Universidad Tecnológica de Bolívar
Repositorio Universidad Tecnológica de Bolívar
dc.language.iso.spa.fl_str_mv eng
language eng
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dc.format.extent.none.fl_str_mv 13 páginas
dc.format.mimetype.spa.fl_str_mv application/pdf
dc.publisher.place.spa.fl_str_mv Cartagena de Indias
dc.source.spa.fl_str_mv Polymers
institution Universidad Tecnológica de Bolívar
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spelling Hernández-Fernández, Joaquínbc85d77e-b89b-40f6-a090-a475dc6dc160Puello-Polo, Esneyderc7c2c83b-c3c0-4db0-a37b-0e98f7da05c0Márquez, Edgar40a7752a-5e75-4abb-98e5-b31316be98042023-07-19T21:23:50Z2023-07-19T21:23:50Z20232023https://hdl.handle.net/20.500.12585/1222610.3390/polym15102264Universidad Tecnológica de BolívarRepositorio Universidad Tecnológica de BolívarThe presence of impurities such as H2S, thiols, ketones, and permanent gases in propylene of fossil origin and their use in the polypropylene production process affect the efficiency of the synthesis and the mechanical properties of the polymer and generate millions of losses worldwide. This creates an urgent need to know the families of inhibitors and their concentration levels. This article uses ethylene green to synthesize an ethylene–propylene copolymer. It describes the impact of trace impurities of furan in ethylene green and how this furan influences the loss of properties such as thermal and mechanical properties of the random copolymer. For the development of the investigation, 12 runs were carried out, each in triplicate. The results show an evident influence of furan on the productivity of the Ziegler–Natta catalyst (ZN); productivity losses of 10, 20, and 41% were obtained for the copolymers synthesized with ethylene rich in 6, 12, and 25 ppm of furan, respectively. PP0 (without furan) did not present losses. Likewise, as the concentration of furan increased, it was observed that the melt flow index (MFI), thermal (TGA), and mechanical properties (tensile, bending, and impact) decreased significantly. Therefore, it can be affirmed that furan should be a substance to be controlled in the purification processes of green ethylene. © 2023 by the authors.13 páginasapplication/pdfenghttp://creativecommons.org/licenses/by-nc-nd/4.0/info:eu-repo/semantics/openAccessAttribution-NonCommercial-NoDerivatives 4.0 Internacionalhttp://purl.org/coar/access_right/c_abf2PolymersFuran as Impurity in Green Ethylene and Its Effects on the Productivity of Random Ethylene–Propylene Copolymer Synthesis and Its Thermal and Mechanical Propertiesinfo:eu-repo/semantics/articleinfo:eu-repo/semantics/drafthttp://purl.org/coar/resource_type/c_6501http://purl.org/coar/version/c_b1a7d7d4d402bccehttp://purl.org/coar/resource_type/c_2df8fbb1Plastics;Marine Debris;LitterLEMBCartagena de IndiasHernández-Fernández, J., Guerra, Y., Espinosa, E. Development and Application of a Principal Component Analysis Model to Quantify the Green Ethylene Content in Virgin Impact Copolymer Resins During Their Synthesis on an Industrial Scale (2022) Journal of Polymers and the Environment, 30 (11), pp. 4800-4808. Cited 8 times. https://www.springer.com/journal/10924 doi: 10.1007/s10924-022-02557-4Hernández-Fernandez, J., Rodríguez, E. Determination of phenolic antioxidants additives in industrial wastewater from polypropylene production using solid phase extraction with high-performance liquid chromatography (2019) Journal of Chromatography A, 1607, art. no. 460442. Cited 29 times. www.elsevier.com/locate/chroma doi: 10.1016/j.chroma.2019.460442Joaquin, H.-F., Juan, L. Quantification of poisons for Ziegler Natta catalysts and effects on the production of polypropylene by gas chromatographic with simultaneous detection: Pulsed discharge helium ionization, mass spectrometry and flame ionization (2020) Journal of Chromatography A, 1614, art. no. 460736. Cited 23 times. www.elsevier.com/locate/chroma doi: 10.1016/j.chroma.2019.460736Fernández, J.H., Cano, H., Guerra, Y., Polo, E.P., Ríos-Rojas, J.F., Vivas-Reyes, R., Oviedo, J. Identification and Quantification of Microplastics in Effluents of Wastewater Treatment Plant by Differential Scanning Calorimetry (DSC) (2022) Sustainability (Switzerland), 14 (9), art. no. 4920. Cited 14 times. https://www.mdpi.com/2071-1050/14/9/4920/pdf doi: 10.3390/su14094920Picó, Y., Soursou, V., Alfarhan, A.H., El-Sheikh, M.A., Barceló, D. First evidence of microplastics occurrence in mixed surface and treated wastewater from two major Saudi Arabian cities and assessment of their ecological risk (2021) Journal of Hazardous Materials, 416, art. no. 125747. Cited 22 times. www.elsevier.com/locate/jhazmat doi: 10.1016/j.jhazmat.2021.125747Mallow, O., Spacek, S., Schwarzböck, T., Fellner, J., Rechberger, H. A new thermoanalytical method for the quantification of microplastics in industrial wastewater (2020) Environmental Pollution, 259, art. no. 113862. Cited 28 times. https://www.journals.elsevier.com/environmental-pollution doi: 10.1016/j.envpol.2019.113862Vajravel, S., Sirin, S., Kosourov, S., Allahverdiyeva, Y. Towards sustainable ethylene production with cyanobacterial artificial biofilms (2020) Green Chemistry, 22 (19), pp. 6404-6414. Cited 21 times. http://pubs.rsc.org/en/journals/journal/gc doi: 10.1039/d0gc01830aWang, Z., Shi, R., Zhang, T. Three-phase electrochemistry for green ethylene production (2021) Current Opinion in Electrochemistry, 30, art. no. 100789. Cited 6 times. www.journals.elsevier.com/current-opinion-in-electrochemistry doi: 10.1016/j.coelec.2021.100789Penteado, A.T., Kim, M., Godini, H.R., Esche, E., Repke, J.-U. Biogas as a renewable feedstock for green ethylene production via oxidative coupling of methane: Preliminary feasibility study (2017) Chemical Engineering Transactions, 61, pp. 589-594. Cited 16 times. http://www.aidic.it/cet/ doi: 10.3303/CET1761096Hernández-Fernández, J., Guerra, Y., Puello-Polo, E., Marquez, E. Effects of Different Concentrations of Arsine on the Synthesis and Final Properties of Polypropylene (2022) Polymers, 14 (15), art. no. 3123. Cited 14 times. http://www.mdpi.com/journal/polymers doi: 10.3390/polym14153123Hernández-Fernández, J., López-Martínez, J. Experimental study of the auto-catalytic effect of triethylaluminum and TiCl4 residuals at the onset of non-additive polypropylene degradation and their impact on thermo-oxidative degradation and pyrolysis (2021) Journal of Analytical and Applied Pyrolysis, 155, art. no. 105052. Cited 17 times. https://www.journals.elsevier.com/journal-of-analytical-and-applied-pyrolysis doi: 10.1016/j.jaap.2021.105052Ruiz, M.L. (2007) Tesis Sobre Determinación y Evaluación de las Emisiones de Dioxinas y Furanos en la Producción de Cemento en España Universidad Complutense de Madrid (UCM), Madrid, SpainAlsabri, A., Tahir, F., Al-Ghamdi, S.G. Life-cycle assessment of polypropylene production in the gulf cooperation council (Gcc) region (2021) Polymers, 13 (21), art. no. 3793. Cited 20 times. https://www.mdpi.com/2073-4360/13/21/3793/pdf doi: 10.3390/polym13213793Cáceres, C.A.C., Canevarolo, S.V. Correlation between Melt Flow Index and chain scission distribution function during the thermo-mechanical degradation of polypropylene (Open Access) (2006) Polimeros, 16 (4), pp. 294-298. Cited 12 times. http://www.scielo.br/pdf/po/v16n4/06.pdf doi: 10.1590/s0104-14282006000400008Ferg, E.E., Bolo, L.L. A correlation between the variable melt flow index and the molecular mass distribution of virgin and recycled polypropylene used in the manufacturing of battery cases (2013) Polymer Testing, 32 (8), pp. 1452-1459. Cited 46 times. doi: 10.1016/j.polymertesting.2013.09.009Hao, Y.-P., Yang, H.-L., Zhang, G.-B., Zhang, H.-L., Gao, G., Dong, L.-S. Rheological, thermal and mechanical properties of biodegradable poly(propylene carbonate)/polylactide/Poly(1,2-propylene glycol adipate) blown films (2015) Chinese Journal of Polymer Science (English Edition), 33 (12), pp. 1702-1712. Cited 10 times. http://www.springerlink.com/content/0256-7679 doi: 10.1007/s10118-015-1714-zKaranjikar, S.R., Lakade, S.S. Evaluation of mechanical properties of polypropylene - Acrylonitrile butadiene styrene blend reinforced with cowrie shell [Cypraeidae] powder (2021) Materials Today: Proceedings, Part 5 50, pp. 1644-1652. Cited 3 times. https://www.sciencedirect.com/journal/materials-today-proceedings doi: 10.1016/j.matpr.2021.09.134Chacon, H., Cano, H., Fernández, J.H., Guerra, Y., Puello-Polo, E., Ríos-Rojas, J.F., Ruiz, Y. Effect of Addition of Polyurea as an Aggregate in Mortars: Analysis of Microstructure and Strength (Open Access) (2022) Polymers, 14 (9), art. no. 1753. Cited 7 times. https://www.mdpi.com/2073-4360/14/9/1753/pdf doi: 10.3390/polym14091753Hernández-Fernández, J., Castro-Suarez, J.R., Toloza, C.A.T. Iron Oxide Powder as Responsible for the Generation of Industrial Polypropylene Waste and as a Co-Catalyst for the Pyrolysis of Non-Additive Resins (Open Access) (2022) International Journal of Molecular Sciences, 23 (19), art. no. 11708. Cited 7 times. http://www.mdpi.com/journal/ijms doi: 10.3390/ijms231911708Hernández-Fernández, J., Rayón, E., López, J., Arrieta, M.P. Enhancing the Thermal Stability of Polypropylene by Blending with Low Amounts of Natural Antioxidants (Open Access) (2019) Macromolecular Materials and Engineering, 304 (11), art. no. 1900379. Cited 32 times. http://onlinelibrary.wiley.com/journal/10.1002/(ISSN)1439-2054 doi: 10.1002/mame.201900379Hernández-Fernández, J. Quantification of oxygenates, sulphides, thiols and permanent gases in propylene. A multiple linear regression model to predict the loss of efficiency in polypropylene production on an industrial scale (2020) Journal of Chromatography A, 1628, art. no. 461478. Cited 21 times. www.elsevier.com/locate/chroma doi: 10.1016/j.chroma.2020.461478Joaquin, H.-F., Juan, L.-M. Autocatalytic influence of different levels of arsine on the thermal stability and pyrolysis of polypropylene (Open Access) (2022) Journal of Analytical and Applied Pyrolysis, 161, art. no. 105385. Cited 16 times. https://www.journals.elsevier.com/journal-of-analytical-and-applied-pyrolysis doi: 10.1016/j.jaap.2021.105385Hernández-Fernández, J., Cano, H., Aldas, M. Impact of Traces of Hydrogen Sulfide on the Efficiency of Ziegler–Natta Catalyst on the Final Properties of Polypropylene (2022) Polymers, 14 (18), art. no. 3910. Cited 7 times. http://www.mdpi.com/journal/polymers doi: 10.3390/polym14183910Hernández-Fernández, J., Ortega-Toro, R., Castro-Suarez, J.R. Theoretical–Experimental Study of the Action of Trace Amounts of Formaldehyde, Propionaldehyde, and Butyraldehyde as Inhibitors of the Ziegler–Natta Catalyst and the Synthesis of an Ethylene–Propylene Copolymer (Open Access) (2023) Polymers, 15 (5), art. no. 1098. http://www.mdpi.com/journal/polymers doi: 10.3390/polym15051098Hernández-Fernández, J., Vivas-Reyes, R., Toloza, C.A.T. Experimental Study of the Impact of Trace Amounts of Acetylene and Methylacetylene on the Synthesis, Mechanical and Thermal Properties of Polypropylene (2022) International Journal of Molecular Sciences, 23 (20), art. no. 12148. 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