Effect of potassium sorbate as an interface agent in biodegradable bi-layers polymers

Studies that are focused on the design and development of biodegradable materials with promising physicochemical properties forindustrial use have been of great importance. In this research, bilayer materials were developed using thermoplastic starch (TPS)monolayers assembled with monolayers sheets...

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Autores:
Tipo de recurso:
Article of journal
Fecha de publicación:
2020
Institución:
Universidad de Bogotá Jorge Tadeo Lozano
Repositorio:
Expeditio: repositorio UTadeo
Idioma:
eng
OAI Identifier:
oai:expeditiorepositorio.utadeo.edu.co:20.500.12010/27978
Acceso en línea:
https://doi.org/10.24275/rmiq/Alim1999
http://hdl.handle.net/20.500.12010/27978
http://expeditiorepositorio.utadeo.edu.co
Palabra clave:
Bilayer sheets
Interfacial agent
Physicochemical properties
Polímeros
Biopolímeros
Macromoléculas
Rights
License
Abierto (Texto Completo)
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oai_identifier_str oai:expeditiorepositorio.utadeo.edu.co:20.500.12010/27978
network_acronym_str UTADEO2
network_name_str Expeditio: repositorio UTadeo
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dc.title.spa.fl_str_mv Effect of potassium sorbate as an interface agent in biodegradable bi-layers polymers
dc.title.alternative.spa.fl_str_mv Efecto de sorbato de potasio como agente de interfase en bicapas a base de polímeros biodegradables
title Effect of potassium sorbate as an interface agent in biodegradable bi-layers polymers
spellingShingle Effect of potassium sorbate as an interface agent in biodegradable bi-layers polymers
Bilayer sheets
Interfacial agent
Physicochemical properties
Polímeros
Biopolímeros
Macromoléculas
title_short Effect of potassium sorbate as an interface agent in biodegradable bi-layers polymers
title_full Effect of potassium sorbate as an interface agent in biodegradable bi-layers polymers
title_fullStr Effect of potassium sorbate as an interface agent in biodegradable bi-layers polymers
title_full_unstemmed Effect of potassium sorbate as an interface agent in biodegradable bi-layers polymers
title_sort Effect of potassium sorbate as an interface agent in biodegradable bi-layers polymers
dc.subject.spa.fl_str_mv Bilayer sheets
Interfacial agent
Physicochemical properties
topic Bilayer sheets
Interfacial agent
Physicochemical properties
Polímeros
Biopolímeros
Macromoléculas
dc.subject.lemb.spa.fl_str_mv Polímeros
Biopolímeros
Macromoléculas
description Studies that are focused on the design and development of biodegradable materials with promising physicochemical properties forindustrial use have been of great importance. In this research, bilayer materials were developed using thermoplastic starch (TPS)monolayers assembled with monolayers sheets of amorphous polylactic acid (PLAa) and polycaprolactone (PCL). Potassiumsorbate was evaluated as an interfacial adhesion material. Structural properties of the laminated materials (FTIR and SEM),behaviour with water (rate of water vapour transmission, solubility in water and moisture content) and biodegradation of thematerials were evaluated. Potassium sorbate was found to act as a promising interface agent by increasing adhesion betweenpolymer layers (SEM). The FTIR showed marked changes in the bands of the hydroxyl and carbonyl groups. Due to PLAaand PCL’s hydrophobic character, all bilayers showed excellent barrier properties against water vapor. Finally, the bilayers thatdegrade the fastest are PCL/TPS. These laminated materials are a great alternative to the decrease in the use of conventionalplastics and are applicable as packaging in the food industry.
publishDate 2020
dc.date.created.none.fl_str_mv 2020
dc.date.accessioned.none.fl_str_mv 2022-08-22T16:50:57Z
dc.date.available.none.fl_str_mv 2022-08-22T16:50:57Z
dc.type.coar.fl_str_mv http://purl.org/coar/resource_type/c_2df8fbb1
dc.type.local.spa.fl_str_mv Artículo
dc.type.driver.spa.fl_str_mv info:eu-repo/semantics/article
dc.type.coar.spa.fl_str_mv http://purl.org/coar/resource_type/c_6501
format http://purl.org/coar/resource_type/c_6501
dc.identifier.issn.spa.fl_str_mv 2395-8472
dc.identifier.other.spa.fl_str_mv https://doi.org/10.24275/rmiq/Alim1999
dc.identifier.uri.none.fl_str_mv http://hdl.handle.net/20.500.12010/27978
dc.identifier.repourl.spa.fl_str_mv http://expeditiorepositorio.utadeo.edu.co
dc.identifier.doi.spa.fl_str_mv https://doi.org/10.24275/rmiq/Alim1999
dc.identifier.orcid.spa.fl_str_mv
identifier_str_mv 2395-8472

url https://doi.org/10.24275/rmiq/Alim1999
http://hdl.handle.net/20.500.12010/27978
http://expeditiorepositorio.utadeo.edu.co
dc.language.iso.spa.fl_str_mv eng
language eng
dc.rights.coar.fl_str_mv http://purl.org/coar/access_right/c_abf2
dc.rights.local.spa.fl_str_mv Abierto (Texto Completo)
rights_invalid_str_mv Abierto (Texto Completo)
http://purl.org/coar/access_right/c_abf2
dc.format.extent.spa.fl_str_mv 10 páginas
dc.format.mimetype.spa.fl_str_mv application/pdf
dc.format.rda.spa.fl_str_mv 1 recurso en línea (archivo de texto)
dc.coverage.spatial.spa.fl_str_mv Colombia
dc.publisher.spa.fl_str_mv Revista Mexicana de Ingeniería Química
institution Universidad de Bogotá Jorge Tadeo Lozano
bitstream.url.fl_str_mv https://expeditiorepositorio.utadeo.edu.co/bitstream/20.500.12010/27978/2/license.txt
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bitstream.checksumAlgorithm.fl_str_mv MD5
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repository.name.fl_str_mv Repositorio Institucional - Universidad Jorge Tadeo Lozano
repository.mail.fl_str_mv expeditiorepositorio@utadeo.edu.co
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spelling Colombia2022-08-22T16:50:57Z2022-08-22T16:50:57Z20202395-8472https://doi.org/10.24275/rmiq/Alim1999http://hdl.handle.net/20.500.12010/27978http://expeditiorepositorio.utadeo.edu.cohttps://doi.org/10.24275/rmiq/Alim1999Studies that are focused on the design and development of biodegradable materials with promising physicochemical properties forindustrial use have been of great importance. In this research, bilayer materials were developed using thermoplastic starch (TPS)monolayers assembled with monolayers sheets of amorphous polylactic acid (PLAa) and polycaprolactone (PCL). Potassiumsorbate was evaluated as an interfacial adhesion material. Structural properties of the laminated materials (FTIR and SEM),behaviour with water (rate of water vapour transmission, solubility in water and moisture content) and biodegradation of thematerials were evaluated. Potassium sorbate was found to act as a promising interface agent by increasing adhesion betweenpolymer layers (SEM). The FTIR showed marked changes in the bands of the hydroxyl and carbonyl groups. Due to PLAaand PCL’s hydrophobic character, all bilayers showed excellent barrier properties against water vapor. Finally, the bilayers thatdegrade the fastest are PCL/TPS. These laminated materials are a great alternative to the decrease in the use of conventionalplastics and are applicable as packaging in the food industry.Estudios enfocados en el diseño y desarrollo de materiales biodegradables con propiedades fisicoquímicas prometedoras parasu uso industrial han sido de gran importancia. En esta investigación se desarrollaron materiales bicapa mediante monocapasde almidón termoplástico (TPS) ensambladas con monocapas de ácido poliláctico amorfo (PLAa) y policaprolactona (PCL). Elsorbato de potasio se evaluó como material de adherencia interfacial. Se evaluaron propiedades estructurales de los materialeslaminados (FTIR y SEM), comportamientos con el agua (tasa de transmisión del vapor de agua, solubilidad en agua y contenidode humedad) y biodegradación del material. Se encontró que el sorbato de potasio actúa como un agente de interfaz prometedoral aumentar la adhesión entre las capas de polímero (SEM). El FTIR mostró cambios marcados en las bandas de los gruposhidroxilo y carbonilo. Debido al carácter hidrófobo de PLAay PCL, todas las bicapas mostraron excelentes propiedades debarrera contra el vapor de agua. Finalmente, las bicapas que se degradan más rápido son PCL/TPS. Estos materiales laminadospresentan un gran potencial para el remplazo de plásticos de uso habitual y su aplicación como empaques en la industria dealimentos.10 páginasapplication/pdf1 recurso en línea (archivo de texto)engRevista Mexicana de Ingeniería QuímicaBilayer sheetsInterfacial agentPhysicochemical propertiesPolímerosBiopolímerosMacromoléculasEffect of potassium sorbate as an interface agent in biodegradable bi-layers polymersEfecto de sorbato de potasio como agente de interfase en bicapas a base de polímeros biodegradablesArtículoinfo:eu-repo/semantics/articlehttp://purl.org/coar/resource_type/c_6501http://purl.org/coar/resource_type/c_2df8fbb1Abierto (Texto Completo)http://purl.org/coar/access_right/c_abf2Díaz-Pedraza, A.Piñeros-Castro, Y.Ortega-Toro, R.LICENSElicense.txtlicense.txttext/plain; charset=utf-82938https://expeditiorepositorio.utadeo.edu.co/bitstream/20.500.12010/27978/2/license.txtbaba314677a6b940f072575a13bb6906MD52open accessORIGINALdocument.pdfdocument.pdfVer documentoapplication/pdf1649326https://expeditiorepositorio.utadeo.edu.co/bitstream/20.500.12010/27978/1/document.pdf2c06b6aa2867da7708bec76a437a8505MD51open accessTHUMBNAILdocument.pdf.jpgdocument.pdf.jpgIM Thumbnailimage/jpeg14636https://expeditiorepositorio.utadeo.edu.co/bitstream/20.500.12010/27978/3/document.pdf.jpgd6de55d144df6adc4ea3d07608c5e3f0MD53open access20.500.12010/27978oai:expeditiorepositorio.utadeo.edu.co:20.500.12010/279782022-08-23 03:00:55.297open accessRepositorio Institucional - Universidad Jorge Tadeo Lozanoexpeditiorepositorio@utadeo.edu.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