Artificial Neural Networks (ANNs) for Spectral Interference Correction Using a Large-Size Spectrometer and ANN-Based Deep Learning for a Miniature One

Artificial neural networks (ANNs) are evaluated for spectral interference correction using simulated and experimentally obtained spectral scans. Using the same data set (where possible), the predictive ability of shallow depth ANNs was validated against partial least squares (PLS, a traditional chem...

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Autores:
Tipo de recurso:
Book
Fecha de publicación:
2017
Institución:
Universidad de Bogotá Jorge Tadeo Lozano
Repositorio:
Expeditio: repositorio UTadeo
Idioma:
eng
OAI Identifier:
oai:expeditiorepositorio.utadeo.edu.co:20.500.12010/16802
Acceso en línea:
https://www.intechopen.com/books/advanced-applications-for-artificial-neural-networks/artificial-neural-networks-anns-for-spectral-interference-correction-using-a-large-size-spectrometer
http://hdl.handle.net/20.500.12010/16802
Palabra clave:
Biología
Redes neuronales artificiales
Inteligencia artificial -- Robótica
Espectrometría de emisión óptica portátil
Rights
License
Abierto (Texto Completo)
Description
Summary:Artificial neural networks (ANNs) are evaluated for spectral interference correction using simulated and experimentally obtained spectral scans. Using the same data set (where possible), the predictive ability of shallow depth ANNs was validated against partial least squares (PLS, a traditional chemometrics method). Spectral interference (in the form of overlaps between spectral lines) is a key problem in large-size, long focal length inductively coupled plasma-optical emission spectrometry (ICP-OES). Unless corrected, spectral interference can be sufficiently severe to the point of preventing precise and accurate analytical determinations. In miniaturized, microplasma-based optical emission spectrometry with a portable, short focal length spectrometer (having poorer resolution than its large-size counterpart), spectral interference becomes even more severe. To correct it, we are evaluating use of deep learning ANNs. Details are provided in this chapter.