Bi-layer materials based on thermoplastic corn starch, polylactic acid and modified polypropylene

Currently, the development of environmentally friendly materials with suitable properties for industrial use has become ofgreat importance. In this work, bilayer materials were developed by assembling thermoplastic- corn starch monolayers (TPS)combined with semi-crystalline polylactic acid (PLAs) mo...

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Autores:
Tipo de recurso:
Article of journal
Fecha de publicación:
2020
Institución:
Universidad de Bogotá Jorge Tadeo Lozano
Repositorio:
Expeditio: repositorio UTadeo
Idioma:
eng
OAI Identifier:
oai:expeditiorepositorio.utadeo.edu.co:20.500.12010/27513
Acceso en línea:
https://doi.org/10.24275/rmiq/Alim1655
http://hdl.handle.net/20.500.12010/27513
http://expeditiorepositorio.utadeo.edu.co
Palabra clave:
Bilayer films
Interfacial agent,
Physicochemical properties
Almidón
Almidón de maíz
Industria de almidones
Rights
License
Abierto (Texto Completo)
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oai_identifier_str oai:expeditiorepositorio.utadeo.edu.co:20.500.12010/27513
network_acronym_str UTADEO2
network_name_str Expeditio: repositorio UTadeo
repository_id_str
dc.title.spa.fl_str_mv Bi-layer materials based on thermoplastic corn starch, polylactic acid and modified polypropylene
dc.title.alternative.spa.fl_str_mv Materiales bicapas a base de almidón de maíz termoplástico, ácido poliláctico ypolipropileno modificado
title Bi-layer materials based on thermoplastic corn starch, polylactic acid and modified polypropylene
spellingShingle Bi-layer materials based on thermoplastic corn starch, polylactic acid and modified polypropylene
Bilayer films
Interfacial agent,
Physicochemical properties
Almidón
Almidón de maíz
Industria de almidones
title_short Bi-layer materials based on thermoplastic corn starch, polylactic acid and modified polypropylene
title_full Bi-layer materials based on thermoplastic corn starch, polylactic acid and modified polypropylene
title_fullStr Bi-layer materials based on thermoplastic corn starch, polylactic acid and modified polypropylene
title_full_unstemmed Bi-layer materials based on thermoplastic corn starch, polylactic acid and modified polypropylene
title_sort Bi-layer materials based on thermoplastic corn starch, polylactic acid and modified polypropylene
dc.subject.spa.fl_str_mv Bilayer films
Interfacial agent,
Physicochemical properties
topic Bilayer films
Interfacial agent,
Physicochemical properties
Almidón
Almidón de maíz
Industria de almidones
dc.subject.lemb.spa.fl_str_mv Almidón
Almidón de maíz
Industria de almidones
description Currently, the development of environmentally friendly materials with suitable properties for industrial use has become ofgreat importance. In this work, bilayer materials were developed by assembling thermoplastic- corn starch monolayers (TPS)combined with semi-crystalline polylactic acid (PLAs) monolayers and maleic anhydride grafted polypropylene (PPMA). Thepresence of a potassium sorbate solution was evaluated as interface material. Structural properties (FTIR and SEM), interactionswith water (water vapor transmission rate, solubility in water and moisture content) and biodegradation of the materials wereevaluated. FTIR spectra showed that potassium sorbate promotes chemical interactions between TPS monolayers (-OH group)and PLA monolayers (C=O group) or PPMA(C-O-C, C-O, C-H groups). For their part, SEM micrographs reveal that whenadding potassium sorbate, higher interfacial adhesion develops between TPS and PPMAthan between TPS and PLAs. As for theinteractions with water, when using a PLA or PPMAmonolayer, due to its hydrophobic characteristics, the high permeability towater vapour and the sensitivity to liquid water that starch-based materials present would be avoided. Finally, the biodegradationtest showed that TPS biodegrades faster than other materials, followed by PLA. The results obtained are interesting since theaddition of an adhesive material to assemble the low chemical affinity monolayers would be avoided. The developed materialsexhibit great potential for application as packaging in the food industry.
publishDate 2020
dc.date.created.none.fl_str_mv 2020
dc.date.accessioned.none.fl_str_mv 2022-07-11T19:54:52Z
dc.date.available.none.fl_str_mv 2022-07-11T19:54:52Z
dc.type.coar.fl_str_mv http://purl.org/coar/resource_type/c_2df8fbb1
dc.type.local.spa.fl_str_mv Artículo
dc.type.driver.spa.fl_str_mv info:eu-repo/semantics/article
dc.type.coar.spa.fl_str_mv http://purl.org/coar/resource_type/c_6501
format http://purl.org/coar/resource_type/c_6501
dc.identifier.issn.spa.fl_str_mv 2395-8472
dc.identifier.other.spa.fl_str_mv https://doi.org/10.24275/rmiq/Alim1655
dc.identifier.uri.none.fl_str_mv http://hdl.handle.net/20.500.12010/27513
dc.identifier.repourl.spa.fl_str_mv http://expeditiorepositorio.utadeo.edu.co
dc.identifier.doi.spa.fl_str_mv https://doi.org/10.24275/rmiq/Alim1655
dc.identifier.orcid.spa.fl_str_mv
identifier_str_mv 2395-8472

url https://doi.org/10.24275/rmiq/Alim1655
http://hdl.handle.net/20.500.12010/27513
http://expeditiorepositorio.utadeo.edu.co
dc.language.iso.spa.fl_str_mv eng
language eng
dc.rights.coar.fl_str_mv http://purl.org/coar/access_right/c_abf2
dc.rights.local.spa.fl_str_mv Abierto (Texto Completo)
rights_invalid_str_mv Abierto (Texto Completo)
http://purl.org/coar/access_right/c_abf2
dc.format.extent.spa.fl_str_mv 9 páginas
dc.format.mimetype.spa.fl_str_mv application/pdf
dc.format.rda.spa.fl_str_mv 1 recurso en línea (archivo de texto)
dc.coverage.spatial.spa.fl_str_mv Colombia
dc.publisher.spa.fl_str_mv Bogotá : Universidad de Bogotá Jorge Tadeo Lozano, 2020
institution Universidad de Bogotá Jorge Tadeo Lozano
bitstream.url.fl_str_mv https://expeditiorepositorio.utadeo.edu.co/bitstream/20.500.12010/27513/2/license.txt
https://expeditiorepositorio.utadeo.edu.co/bitstream/20.500.12010/27513/3/Captura.PNG
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repository.name.fl_str_mv Repositorio Institucional - Universidad Jorge Tadeo Lozano
repository.mail.fl_str_mv expeditiorepositorio@utadeo.edu.co
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spelling Colombia2022-07-11T19:54:52Z2022-07-11T19:54:52Z20202395-8472https://doi.org/10.24275/rmiq/Alim1655http://hdl.handle.net/20.500.12010/27513http://expeditiorepositorio.utadeo.edu.cohttps://doi.org/10.24275/rmiq/Alim1655Currently, the development of environmentally friendly materials with suitable properties for industrial use has become ofgreat importance. In this work, bilayer materials were developed by assembling thermoplastic- corn starch monolayers (TPS)combined with semi-crystalline polylactic acid (PLAs) monolayers and maleic anhydride grafted polypropylene (PPMA). Thepresence of a potassium sorbate solution was evaluated as interface material. Structural properties (FTIR and SEM), interactionswith water (water vapor transmission rate, solubility in water and moisture content) and biodegradation of the materials wereevaluated. FTIR spectra showed that potassium sorbate promotes chemical interactions between TPS monolayers (-OH group)and PLA monolayers (C=O group) or PPMA(C-O-C, C-O, C-H groups). For their part, SEM micrographs reveal that whenadding potassium sorbate, higher interfacial adhesion develops between TPS and PPMAthan between TPS and PLAs. As for theinteractions with water, when using a PLA or PPMAmonolayer, due to its hydrophobic characteristics, the high permeability towater vapour and the sensitivity to liquid water that starch-based materials present would be avoided. Finally, the biodegradationtest showed that TPS biodegrades faster than other materials, followed by PLA. The results obtained are interesting since theaddition of an adhesive material to assemble the low chemical affinity monolayers would be avoided. The developed materialsexhibit great potential for application as packaging in the food industry.En la actualidad ha cobrado gran importancia el desarrollo de materiales amigables con el medio ambiente y que tenganpropiedades fisicoquímicas adecuadas para su uso industrial. En este trabajo se desarrollaron materiales bicapa medianteel ensamblaje de monocapas de almidón de maíz termoplástico (TPS) combinadas con monocapas de ácido polilácticosemicristalino (PLAs) y polipropileno agrafado con anhídrido maleico (PPMA). Como material de interfase se evaluó la presenciade una disolución de sorbato de potasio. Se evaluaron propiedades estructurales (FTIR y SEM), interacciones con el agua(tasa de transmisión del vapor de agua, solubilidad en agua y contenido de humedad) y biodegradación de los materiales. Losespectros FTIR mostraron que el sorbato potasio promueve interacciones químicas entre los monocapas de TPS (grupo -OH) ylos monocapas de PLAs(grupo C=O) o PPMA(grupos C-O-C, C-O, C-H). Por su parte, las micrografías SEM revelan que, aladicionar sorbato de potasio, se desarrolla mayor adhesión interfacial entre TPS y PPMAque entre el TPS y PLAs. En cuantoa la interacciones con el agua, al usar un monocapa de PLAso PPMA, por sus características hidrofóbicas, se evitaría la altapermeabilidad al vapor de agua y sensibilidad al agua líquida que presentan los materiales a base de almidón. Finalmente, laprueba de biodegradación mostró que el TPS se biodegrada a mayor velocidad que los demás materiales, seguido por el PLAs.Los resultados obtenidos son interesantes puesto que se evitaría la adición de un material adhesivo para ensamblar los monocapasde baja afinidad química. Los materiales desarrollados presentan gran potencial de aplicación como empaques en la industria dealimentos.9 páginasapplication/pdf1 recurso en línea (archivo de texto)engBogotá : Universidad de Bogotá Jorge Tadeo Lozano, 2020Bilayer filmsInterfacial agent,Physicochemical propertiesAlmidónAlmidón de maízIndustria de almidonesBi-layer materials based on thermoplastic corn starch, polylactic acid and modified polypropyleneMateriales bicapas a base de almidón de maíz termoplástico, ácido poliláctico ypolipropileno modificadoArtículoinfo:eu-repo/semantics/articlehttp://purl.org/coar/resource_type/c_6501http://purl.org/coar/resource_type/c_2df8fbb1Abierto (Texto Completo)http://purl.org/coar/access_right/c_abf2Diaz-Pedraza, A.Piñeros-Castro, Y.Ortega-Toro, R.LICENSElicense.txtlicense.txttext/plain; charset=utf-82938https://expeditiorepositorio.utadeo.edu.co/bitstream/20.500.12010/27513/2/license.txtbaba314677a6b940f072575a13bb6906MD52open accessTHUMBNAILCaptura.PNGCaptura.PNGImagenimage/png164068https://expeditiorepositorio.utadeo.edu.co/bitstream/20.500.12010/27513/3/Captura.PNG8efb0d380aebb1c2c77f39aea195ce0aMD53open access20.500.12010/27513oai:expeditiorepositorio.utadeo.edu.co:20.500.12010/275132022-07-11 14:55:51.924metadata only accessRepositorio Institucional - Universidad Jorge Tadeo Lozanoexpeditiorepositorio@utadeo.edu.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