Design and construction of an equipment for the determination of solubility of gases in liquids

This paper presents the design and construction of a new isochoric saturation apparatus for the determination of gas solubility in liquids based on the gas drop pressure method. The major improvement of this design is the separation between the solubility and the gas cells. With this separation, the...

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Autores:
Tipo de recurso:
Fecha de publicación:
2017
Institución:
Universidad de Bogotá Jorge Tadeo Lozano
Repositorio:
Expeditio: repositorio UTadeo
Idioma:
OAI Identifier:
oai:expeditiorepositorio.utadeo.edu.co:20.500.12010/9267
Acceso en línea:
https://doi.org/10.1002/aic.15637
http://hdl.handle.net/20.500.12010/9267
Palabra clave:
Thermodynamics and Molecular-Scale Phenomena
Isochoric saturation equipment
Gas solubility
Drop pressure method
Aqueous
Dinámica de fluidos -- Investigaciones
Dinámica de gases -- Investigaciones
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Abierto (Texto Completo)
Description
Summary:This paper presents the design and construction of a new isochoric saturation apparatus for the determination of gas solubility in liquids based on the gas drop pressure method. The major improvement of this design is the separation between the solubility and the gas cells. With this separation, the change of pressure and temperature inside the system is minimum when the gas gets in contact with the liquid and it allows degassing the liquid in an easy way. The performance of the equipment was evaluated measuring the solubility of argon and nitrogen in pure water at (283.15, 288.15, 293.15 y 298.15) K. The gas solubility was calculated according to the Henry’s law. The results obtained and the comparison with literature values show that the equipment provides an accurate and precise method for determination of gas solubility in water.