Comparative Study of the Reaction Kinetics of Three Residual Biomasses
Kinetic analysis for the combustion of three agro-industrial biomass residues (coconut husk, corn husk, and rice husk) was carried out in order to provide information for the generation of energy from them. The analysis was performed using the results of the data obtained by thermogravimetric analys...
- Autores:
-
Martinez, Arnaldo
- Tipo de recurso:
- Fecha de publicación:
- 2020
- Institución:
- Universidad del Atlántico
- Repositorio:
- Repositorio Uniatlantico
- Idioma:
- eng
- OAI Identifier:
- oai:repositorio.uniatlantico.edu.co:20.500.12834/799
- Acceso en línea:
- https://hdl.handle.net/20.500.12834/799
- Palabra clave:
- Biomass; Combustion; Kinetic parameters; DAEM
- Rights
- openAccess
- License
- http://purl.org/coar/access_right/c_abf2
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Comparative Study of the Reaction Kinetics of Three Residual Biomasses |
| title |
Comparative Study of the Reaction Kinetics of Three Residual Biomasses |
| spellingShingle |
Comparative Study of the Reaction Kinetics of Three Residual Biomasses Biomass; Combustion; Kinetic parameters; DAEM |
| title_short |
Comparative Study of the Reaction Kinetics of Three Residual Biomasses |
| title_full |
Comparative Study of the Reaction Kinetics of Three Residual Biomasses |
| title_fullStr |
Comparative Study of the Reaction Kinetics of Three Residual Biomasses |
| title_full_unstemmed |
Comparative Study of the Reaction Kinetics of Three Residual Biomasses |
| title_sort |
Comparative Study of the Reaction Kinetics of Three Residual Biomasses |
| dc.creator.fl_str_mv |
Martinez, Arnaldo |
| dc.contributor.author.none.fl_str_mv |
Martinez, Arnaldo |
| dc.contributor.other.none.fl_str_mv |
Meriño, Lourdes Albis, Alberto Ortega, Jorge |
| dc.subject.keywords.spa.fl_str_mv |
Biomass; Combustion; Kinetic parameters; DAEM |
| topic |
Biomass; Combustion; Kinetic parameters; DAEM |
| description |
Kinetic analysis for the combustion of three agro-industrial biomass residues (coconut husk, corn husk, and rice husk) was carried out in order to provide information for the generation of energy from them. The analysis was performed using the results of the data obtained by thermogravimetric analysis (TGA) at three heating rates (10, 20, and 30 K/min). The biomass residues were characterized in terms of proximate analysis, elemental analysis, calorific value, lignin content, α-cellulose content, hemicellulose content, and holocellulose content. The biomass fuels were thermally degraded in an oxidative atmosphere. The results showed that the biomass thermal degradation process is comprised of the combustion of hemicellulose, cellulose, and lignin. The kinetic parameters of the distributed activation energy model indicated that the activation energy distribution for the pseudocomponents follows lignin, cellulose, and hemicellulose in descending order. The activation energy values for each set of reactions are similar between the heating rates, which suggests that it is independent of the heating rate between 10 K/min and 30 K/min. For all the biomass samples, the increased heating rate resulted in the overlap of the hemicellulose and cellulose degradation events |
| publishDate |
2020 |
| dc.date.submitted.none.fl_str_mv |
2020-10-08 |
| dc.date.issued.none.fl_str_mv |
2021-03-01 |
| dc.date.accessioned.none.fl_str_mv |
2022-11-15T19:21:34Z |
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2022-11-15T19:21:34Z |
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http://purl.org/coar/version/c_970fb48d4fbd8a85 |
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http://purl.org/coar/resource_type/c_2df8fbb1 |
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info:eu-repo/semantics/article |
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Artículo |
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publishedVersion |
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https://hdl.handle.net/20.500.12834/799 |
| dc.identifier.doi.none.fl_str_mv |
10.15376/biores.16.2.2891-2905 |
| dc.identifier.instname.spa.fl_str_mv |
Universidad del Atlántico |
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Repositorio Universidad del Atlántico |
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https://hdl.handle.net/20.500.12834/799 |
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10.15376/biores.16.2.2891-2905 Universidad del Atlántico Repositorio Universidad del Atlántico |
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eng |
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eng |
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Ingeniería Agroindustrial |
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Sede Norte |
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Universidad del Atlántico |
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Martinez, Arnaldo02e6b416-817c-4b56-9557-8573f35bd4ddMeriño, LourdesAlbis, AlbertoOrtega, Jorge2022-11-15T19:21:34Z2022-11-15T19:21:34Z2021-03-012020-10-08https://hdl.handle.net/20.500.12834/79910.15376/biores.16.2.2891-2905Universidad del AtlánticoRepositorio Universidad del AtlánticoKinetic analysis for the combustion of three agro-industrial biomass residues (coconut husk, corn husk, and rice husk) was carried out in order to provide information for the generation of energy from them. The analysis was performed using the results of the data obtained by thermogravimetric analysis (TGA) at three heating rates (10, 20, and 30 K/min). The biomass residues were characterized in terms of proximate analysis, elemental analysis, calorific value, lignin content, α-cellulose content, hemicellulose content, and holocellulose content. The biomass fuels were thermally degraded in an oxidative atmosphere. The results showed that the biomass thermal degradation process is comprised of the combustion of hemicellulose, cellulose, and lignin. The kinetic parameters of the distributed activation energy model indicated that the activation energy distribution for the pseudocomponents follows lignin, cellulose, and hemicellulose in descending order. The activation energy values for each set of reactions are similar between the heating rates, which suggests that it is independent of the heating rate between 10 K/min and 30 K/min. For all the biomass samples, the increased heating rate resulted in the overlap of the hemicellulose and cellulose degradation eventsBioresourcesapplication/pdfengComparative Study of the Reaction Kinetics of Three Residual BiomassesPúblico generalBiomass; Combustion; Kinetic parameters; DAEMinfo:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionArtículohttp://purl.org/coar/version/c_970fb48d4fbd8a85http://purl.org/coar/resource_type/c_2df8fbb1BarranquillaIngeniería AgroindustrialSede Norteinfo:eu-repo/semantics/openAccesshttp://purl.org/coar/access_right/c_abf2Arango-Muñoz, M., Arenas-Castiblanco, E., and Cortés-Correa, F. (2015). “Determinación de parámetros cinéticos para la pirólisis rápida de aserrín de pino pátula [Determination of kinetic parameters for the rapid pyrolysis of paddle pine sawdust],” Boletín del Grupo Español del Carbón 38, 9-11.ASTM D 3173. 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DOI: 10.1016/j.polymdegradstab.2007.10.012http://purl.org/coar/resource_type/c_6501ORIGINALBioRes_16_2_2891_Martinez_MAO_Comparat_Study_Reaction_Kinetics_3_Residual_Biomasses_18235.pdfBioRes_16_2_2891_Martinez_MAO_Comparat_Study_Reaction_Kinetics_3_Residual_Biomasses_18235.pdfapplication/pdf691721https://repositorio.uniatlantico.edu.co/bitstream/20.500.12834/799/1/BioRes_16_2_2891_Martinez_MAO_Comparat_Study_Reaction_Kinetics_3_Residual_Biomasses_18235.pdf7aeefda2632b269ab6dc32183c384636MD51LICENSElicense.txtlicense.txttext/plain; charset=utf-81306https://repositorio.uniatlantico.edu.co/bitstream/20.500.12834/799/2/license.txt67e239713705720ef0b79c50b2ececcaMD5220.500.12834/799oai:repositorio.uniatlantico.edu.co:20.500.12834/7992022-11-15 14:21:35.669DSpace de la Universidad de Atlánticosysadmin@mail.uniatlantico.edu.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 |