Effect of the Gallium and Vanadium on the Dibenzothiophene Hydrodesulfurization and Naphthalene Hydrogenation Activities Using Sulfided NiMo-V2O5/Al2O3-Ga2O3
The effect of Ga and V as support-modifier and promoter of NiMoV/Al2O3-Ga2O3 catalyst on hydrogenation (HYD) and hydrodesulfurization (HDS) activities was studied. The catalysts were characterized by elemental analysis, textural properties, XRD, XPS, EDS elemental mapping and High-resolution transmi...
- Autores:
-
Puello-Polo, Esneyder
- Tipo de recurso:
- Fecha de publicación:
- 2020
- Institución:
- Universidad del Atlántico
- Repositorio:
- Repositorio Uniatlantico
- Idioma:
- eng
- OAI Identifier:
- oai:repositorio.uniatlantico.edu.co:20.500.12834/850
- Acceso en línea:
- https://hdl.handle.net/20.500.12834/850
- Palabra clave:
- gallium; vanadium; hydrodesulfurization; hydrogenation; synthesis method
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- openAccess
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Effect of the Gallium and Vanadium on the Dibenzothiophene Hydrodesulfurization and Naphthalene Hydrogenation Activities Using Sulfided NiMo-V2O5/Al2O3-Ga2O3 |
| title |
Effect of the Gallium and Vanadium on the Dibenzothiophene Hydrodesulfurization and Naphthalene Hydrogenation Activities Using Sulfided NiMo-V2O5/Al2O3-Ga2O3 |
| spellingShingle |
Effect of the Gallium and Vanadium on the Dibenzothiophene Hydrodesulfurization and Naphthalene Hydrogenation Activities Using Sulfided NiMo-V2O5/Al2O3-Ga2O3 gallium; vanadium; hydrodesulfurization; hydrogenation; synthesis method |
| title_short |
Effect of the Gallium and Vanadium on the Dibenzothiophene Hydrodesulfurization and Naphthalene Hydrogenation Activities Using Sulfided NiMo-V2O5/Al2O3-Ga2O3 |
| title_full |
Effect of the Gallium and Vanadium on the Dibenzothiophene Hydrodesulfurization and Naphthalene Hydrogenation Activities Using Sulfided NiMo-V2O5/Al2O3-Ga2O3 |
| title_fullStr |
Effect of the Gallium and Vanadium on the Dibenzothiophene Hydrodesulfurization and Naphthalene Hydrogenation Activities Using Sulfided NiMo-V2O5/Al2O3-Ga2O3 |
| title_full_unstemmed |
Effect of the Gallium and Vanadium on the Dibenzothiophene Hydrodesulfurization and Naphthalene Hydrogenation Activities Using Sulfided NiMo-V2O5/Al2O3-Ga2O3 |
| title_sort |
Effect of the Gallium and Vanadium on the Dibenzothiophene Hydrodesulfurization and Naphthalene Hydrogenation Activities Using Sulfided NiMo-V2O5/Al2O3-Ga2O3 |
| dc.creator.fl_str_mv |
Puello-Polo, Esneyder |
| dc.contributor.author.none.fl_str_mv |
Puello-Polo, Esneyder |
| dc.contributor.other.none.fl_str_mv |
Pájaro, Yina Márquez, Edgar |
| dc.subject.keywords.spa.fl_str_mv |
gallium; vanadium; hydrodesulfurization; hydrogenation; synthesis method |
| topic |
gallium; vanadium; hydrodesulfurization; hydrogenation; synthesis method |
| description |
The effect of Ga and V as support-modifier and promoter of NiMoV/Al2O3-Ga2O3 catalyst on hydrogenation (HYD) and hydrodesulfurization (HDS) activities was studied. The catalysts were characterized by elemental analysis, textural properties, XRD, XPS, EDS elemental mapping and High-resolution transmission electron microscopy (HRTEM). The chemical analyses by X-ray Fluorescence (XRF) and CHNS-O elemental analysis showed results for all compounds in agreement, within experimental accuracy, according to stoichiometric values proposed to Mo/Ni = 6 and (V+Ni)/(V+Ni+Mo) = 0.35. The sol-gel synthesis method increased the surface area by incorporation of Ga3+ ions into the Al2O3 forming Ga-O-Al bonding; whereas the impregnation synthesis method leads to decrease by blocking of alumina pores, as follows NiMoV/Al-Ga(1%-I)< NiMoV/Al-Ga(1%-SG) < NiMo/Al2O3 < Al2O3-Ga2O3(1%-I) < Al2O3-Ga2O3(1%-SG) < Al2O3, propitiating Dp-BJH between 6.18 and 7.89 nm. XRD confirmed a bulk structure typical of (NH4)4[NiMo6O24H6]•5H2O and XPS the presence at the surface of Mo4+, Mo6+, NixSy, Ni2+, Ga3+ and V5+ species, respectively. The EDS elemental mapping confirmed that Ni, Mo, Al, Ga, V and S are well-distributed on Al2O3-Ga2O3(1%-SG) support. The HRTEM analysis shows that the length and stacking distribution of MoS2 crystallites varied from 5.07 to 5.94 nm and 2.74 to 3.58 with synthesis method (SG to I). The results of the characterization sulfided catalysts showed that the synthesis method via impregnation induced largest presence of gallium on the surface influencing the dispersion V5+ species, this effect improves the dispersion of the MoS2 phase and increasing the number of active sites, which correlates well with the dibenzothiophene HDS and naphthalene HYD activities. The dibenzothiophene HDS activities with overall pseudo-first-order rate constants’ values (kHDS) from 1.65 to 7.07 L/(h·mol·m2 ) follow the order: NiMoV-S/Al-Ga(1%-I) < NiMo-S/Al2O3 < NiMoV-S/Al-Ga(1%-SG), whereas the rate constants’ values (k) of naphthalene HYD from 0.022 to 2.23 L/(h·mol·m2 ) as follow: NiMoV-S/Al-Ga(1%-SG) < NiMo-S/Al2O3 < NiMoV-S/Al-Ga(1%-I). We consider that Ga and V act as structural promoters in the NiMo catalysts supported on Al2O3 that allows the largest generation of BRIM sites for HYD and CUS sites for DDS. |
| publishDate |
2020 |
| dc.date.issued.none.fl_str_mv |
2020-08-07 |
| dc.date.submitted.none.fl_str_mv |
2020-07-04 |
| dc.date.accessioned.none.fl_str_mv |
2022-11-15T19:44:48Z |
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2022-11-15T19:44:48Z |
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http://purl.org/coar/version/c_970fb48d4fbd8a85 |
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http://purl.org/coar/resource_type/c_2df8fbb1 |
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https://hdl.handle.net/20.500.12834/850 |
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10.3390/catal10080894 |
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Universidad del Atlántico |
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Repositorio Universidad del Atlántico |
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Puello-Polo, Esneydera7c82b72-a708-4365-9cfa-ebf6fbebfd96Pájaro, YinaMárquez, Edgar2022-11-15T19:44:48Z2022-11-15T19:44:48Z2020-08-072020-07-04https://hdl.handle.net/20.500.12834/85010.3390/catal10080894Universidad del AtlánticoRepositorio Universidad del AtlánticoThe effect of Ga and V as support-modifier and promoter of NiMoV/Al2O3-Ga2O3 catalyst on hydrogenation (HYD) and hydrodesulfurization (HDS) activities was studied. The catalysts were characterized by elemental analysis, textural properties, XRD, XPS, EDS elemental mapping and High-resolution transmission electron microscopy (HRTEM). The chemical analyses by X-ray Fluorescence (XRF) and CHNS-O elemental analysis showed results for all compounds in agreement, within experimental accuracy, according to stoichiometric values proposed to Mo/Ni = 6 and (V+Ni)/(V+Ni+Mo) = 0.35. The sol-gel synthesis method increased the surface area by incorporation of Ga3+ ions into the Al2O3 forming Ga-O-Al bonding; whereas the impregnation synthesis method leads to decrease by blocking of alumina pores, as follows NiMoV/Al-Ga(1%-I)< NiMoV/Al-Ga(1%-SG) < NiMo/Al2O3 < Al2O3-Ga2O3(1%-I) < Al2O3-Ga2O3(1%-SG) < Al2O3, propitiating Dp-BJH between 6.18 and 7.89 nm. XRD confirmed a bulk structure typical of (NH4)4[NiMo6O24H6]•5H2O and XPS the presence at the surface of Mo4+, Mo6+, NixSy, Ni2+, Ga3+ and V5+ species, respectively. The EDS elemental mapping confirmed that Ni, Mo, Al, Ga, V and S are well-distributed on Al2O3-Ga2O3(1%-SG) support. The HRTEM analysis shows that the length and stacking distribution of MoS2 crystallites varied from 5.07 to 5.94 nm and 2.74 to 3.58 with synthesis method (SG to I). The results of the characterization sulfided catalysts showed that the synthesis method via impregnation induced largest presence of gallium on the surface influencing the dispersion V5+ species, this effect improves the dispersion of the MoS2 phase and increasing the number of active sites, which correlates well with the dibenzothiophene HDS and naphthalene HYD activities. The dibenzothiophene HDS activities with overall pseudo-first-order rate constants’ values (kHDS) from 1.65 to 7.07 L/(h·mol·m2 ) follow the order: NiMoV-S/Al-Ga(1%-I) < NiMo-S/Al2O3 < NiMoV-S/Al-Ga(1%-SG), whereas the rate constants’ values (k) of naphthalene HYD from 0.022 to 2.23 L/(h·mol·m2 ) as follow: NiMoV-S/Al-Ga(1%-SG) < NiMo-S/Al2O3 < NiMoV-S/Al-Ga(1%-I). We consider that Ga and V act as structural promoters in the NiMo catalysts supported on Al2O3 that allows the largest generation of BRIM sites for HYD and CUS sites for DDS.application/pdfenghttp://creativecommons.org/licenses/by-nc/4.0/Attribution-NonCommercial 4.0 Internationalinfo:eu-repo/semantics/openAccesshttp://purl.org/coar/access_right/c_abf2CatalystsEffect of the Gallium and Vanadium on the Dibenzothiophene Hydrodesulfurization and Naphthalene Hydrogenation Activities Using Sulfided NiMo-V2O5/Al2O3-Ga2O3Público generalgallium; vanadium; hydrodesulfurization; hydrogenation; synthesis methodinfo:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionArtículohttp://purl.org/coar/version/c_970fb48d4fbd8a85http://purl.org/coar/resource_type/c_2df8fbb1BarranquillaQuímicaSede Norte1. Anderson, J.R.; Boudart, M. Catalysis: Science and Technology; Springer: Berlin/Heidelberg, Germany, 1996; ISBN 978-3-642-61040-0.2. Ras, eev, S.D. Thermal and Catalytic Processes in Petroleum Refining; Marcel Dekker: New York, NY, USA, 2003; ISBN 978-0-8247-0952-5.3. Lødeng, R.; Hannevold, L.; Bergem, H.; Stöcker, M. Catalytic Hydrotreatment of Bio-Oils for High-Quality Fuel Production. In The Role of Catalysis for the Sustainable Production of Bio-Fuels and Bio-Chemicals; Triantafyllidis, K.S., Lappas, A.A., Stöcker, M., Eds.; Elsevier: Amsterdam, The Netherlands, 2013; Chapter 11; pp. 351–396. ISBN 978-0-444-56330-9.4. Debecker, D.P.; Stoyanova, M.; Rodemerck, U.; Gaigneaux, E.M. Preparation of MoO3 /SiO2–Al2O3 metathesis catalysts via wet impregnation with different Mo precursors. J. Mol. Catal. Chem. 2011, 340, 65–76.5. Topsøe, H.; Clausen, B.S. Active sites and support effects in hydrodesulfurization catalysts. Appl. Catal. 1986, 25, 273–2936. Chianelli, R.R.; Siadati, M.H.; De la Rosa, M.P.; Berhault, G.; Wilcoxon, J.P.; Bearden, R.; Abrams, B.L. Catalytic Properties of Single Layers of Transition Metal Sulfide Catalytic Materials. Catal. Rev. 2006, 48, 1–41.7. Babich, I. Science and technology of novel processes for deep desulfurization of oil refinery streams: A review. Fuel 2003, 82, 607–6318. Ministerio de Ambiente y Desarrollo Sostenible, y Ministerio de Minas y Energías. Resolución 40619 2017 pág 1-3; Resolución 90963 2014, 5.9. Gutiérrez, O.Y.; Klimova, T. Effect of the support on the high activity of the (Ni)Mo/ZrO2–SBA-15 catalyst in the simultaneous hydrodesulfurization of DBT and 4,6-DMDBT. J. Catal. 2011, 281, 50–62.10. Rashidi, F.; Sasaki, T.; Rashidi, A.M.; Nemati Kharat, A.; Jozani, K.J. Ultradeep hydrodesulfurization of diesel fuels using highly efficient nanoalumina-supported catalysts: Impact of support, phosphorus, and/or boron on the structure and catalytic activity. J. Catal. 2013, 299, 321–33511. Chianelli, R.R. Fundamental Studies of Transition Metal Sulfide Hydrodesulfurization Catalysts. Catal. Rev. 1984, 26, 361–393.12. Topsøe, H.; Clausen, B.S.; Massoth, F.E. Hydrotreating Catalysis. In Catalysis; Anderson, J.R., Boudart, M., Eds.; Springer: Berlin/Heidelberg, Germany, 1996; pp. 1–269. ISBN 978-3-642-64666-913. Breysse, M.; Portefaix, J.L.; Vrinat, M. Support effects on hydrotreating catalysts. Catal. Today 1991, 10, 489–50514. Palcheva, R.; Kaluža, L.; Spojakina, A.; Jirátová, K.; Tyuliev, G. NiMo/γ-Al2O3 Catalysts from Ni Heteropolyoxomolybdate and Effect of Alumina Modification by B, Co, or Ni. Chin. J. Catal. 2012, 33, 952–961.15. Jirátová, K.; Kraus, M. Effect of support properties on the catalytic activity of HDS catalysts. Appl. Catal. 1986, 27, 21–2916. Saini, A.R.; Johnson, B.G.; Massoth, F.E. Studies of molybdena—Alumina catalysts XIV. Effect of Cation-Modified Aluminas. Appl. Catal. 1988, 40, 157–17217. Strohmeier, B. Surface spectroscopic characterization of the interaction between zinc ions and $gamma;-alumina. J. Catal. 1984, 86, 266–27918. Cabello, C.I.; Botto, I.L.; Thomas, H.J. Anderson type heteropolyoxomolybdates in catalysis:: 1. (NH4)3[CoMo6O24H6]·7H2O/γ-Al2O3 as alternative of Co-Mo/γ-Al2O3 hydrotreating catalysts. Appl. Catal. Gen. 2000, 197, 79–8619. Cabello, C.I.; Cabrerizo, F.M.; Alvarez, A.; Thomas, H.J. Decamolybdodicobaltate(III) heteropolyanion: Structural, spectroscopical, thermal and hydrotreating catalytic properties. J. Mol. Catal. Chem. 2002, 186, 89–10020. Altamirano, E.; de los Reyes, J.A.; Murrieta, F.; Vrinat, M. Hydrodesulfurization of 4,6-dimethyldibenzothiophene over Co(Ni)MoS2 catalysts supported on alumina: Effect of gallium as an additive. Catal. Today 2008, 133–135, 292–29821. Díaz de León, J.N.; Picquart, M.; Massin, L.; Vrinat, M.; de los Reyes, J.A. Hydrodesulfurization of sulfur refractory compounds: Effect of gallium as an additive in NiWS/γ-Al2O3 catalysts. J. Mol. Catal. Chem. 2012, 363–364, 311–32122. Cimino, A.; Lo Jacono, M.; Schiavello, M. Effect of zinc, gallium, and germanium ions on the structural and magnetic properties of nickel ions supported on alumina. J. Phys. Chem. 1975, 79, 243–249.23. Zepeda, T.A.; Pawelec, B.; Díaz de León, J.N.; de los Reyes, J.A.; Olivas, A. Effect of gallium loading on the hydrodesulfurization activity of unsupported Ga2S3/WS2 catalysts. Appl. Catal. B Environ. 2012, 111–112, 10–19.24. Petre, A.L.; Auroux, A.; Gervasini, A.; Caldararu, M.; Ionescu, N.I. Calorimetric Characterization of Surface Reactivity of Supported Ga2O3 Catalysts. J. Therm. Anal. Calorim. 2001, 64, 253–26025. Dejonghe, S.; Hubaut, R.; Grimblot, J.; Bonnelle, J.P.; Des Courieres, T.; Faure, D. Hydrodemetallation of a vanadylporphyrin over sulfided NiMoγAl2O3 , MoγAl2O3 , and γAl2O3 catalysts—Effect of the vanadium deposit on the toluene hydrogenation. Catal. Today 1990, 7, 569–58526. Rankel, L.; Rollmann, L. Catalytic activity of metals in petroleum and their removal. Fuel 1983, 62, 44–4627. Lacroix, M.; Boutarfa, N.; Guillard, C.; Vrinat, M.; Breysse, M. Hydrogenating properties of unsupported transition metal sulphides. J. Catal. 1989, 120, 473–47728. Betancourt, P.; Rives, A.; Scott, C.E.; Hubaut, R. Hydrotreating on mixed vanadium–nickel sulphides. Catal. Today 2000, 57, 201–20729. Betancourt, P.; Marrero, S.; Pinto-Castilla, S. V–Ni–Mo sulfide supported on Al2O3 : Preparation, characterization and LCO hydrotreating. Fuel Process. Technol. 2013, 114, 21–2530. Escalante, Y.; Méndez, F.J.; Díaz, Y.; Inojosa, M.; Morgado, M.; Delgado, M.; Bastardo-González, E.; Brito, J.L. MCM-41-supported vanadium catalysts structurally modified with Al or Zr for thiophene hydrodesulfurization. Appl. Petrochem. Res. 2019, 9, 47–5531. Ayala-G, M.; Puello, E.; Quintana, P.; González-García, G.; Diaz, C. Comparison between alumina supported catalytic precursors and their application in thiophene hydrodesulfurization: (NH4 ) [NiMo6O24H6 ]·5H2O/γ-Al2O3 and NiMoOx/γ-Al2O3 conventional systems. RSC Adv. 2015, 5, 102652–10266232. Thommes, M.; Kaneko, K.; Neimark, A.V.; Olivier, J.P.; Rodriguez-Reinoso, F.; Rouquerol, J.; Sing, K.S.W. Physisorption of gases, with special reference to the evaluation of surface area and pore size distribution (IUPAC Technical Report). Pure Appl. Chem. 2015, 87, 1051–106933. Sampieri, A.; Pronier, S.; Brunet, S.; Carrier, X.; Louis, C.; Blanchard, J.; Fajerwerg, K.; Breysse, M. Formation of heteropolymolybdates during the preparation of Mo and NiMo HDS catalysts supported on SBA-15: Influence on the dispersion of the active phase and on the HDS activity. Microporous Mesoporous Mater. 2010, 130, 130–14134. Haneda, M.; Kintaichi, Y.; Shimada, H.; Hamada, H. Selective Reduction of NO with Propene over Ga2O3–Al2O3: Effect of Sol–Gel Method on the Catalytic Performance. J. Catal. 2000, 192, 137–14835. Ueno, A.; Suzuki, H.; Kotera, Y. Particle-size distribution of nickel dispersed on silica and its effects on hydrogenation of propionaldehyde. J. Chem. Soc. Faraday Trans. 1 Phys. Chem. Condens Phases 1983, 79, 127.36. Puello-Polo, E.; Marquez, E.; Brito, J.L. One-pot synthesis of Nb-modified Al2O3 support for NiMo hydrodesulfurization catalysts. J. Sol-Gel Sci. Technol. 2018, 88, 90–9937. International Centre for Diffraction Data®(ICDD®). Power Diffraction File; ICDD: Newtown Square, PA, USA, 199538. Galtayries, A.; Wisniewski, S.; Grimblot, J. Formation of thin oxide and sulphide films on polycrystalline molybdenum foils: Characterization by XPS and surface potential variations. J. Electron Spectrosc. Relat. Phenom. 1997, 87, 31–4439. Weber, T.; Muijsers, J.C.; van Wolput, J.H.M.C.; Verhagen, C.P.J.; Niemantsverdriet, J.W. Basic Reaction Steps in the Sulfidation of Crystalline MoO3 to MoS2 , As Studied by X-ray Photoelectron and Infrared Emission Spectroscopy. J. Phys. Chem. 1996, 100, 14144–1415040. Aigler, J.M.; Brito, J.L.; Leach, P.A.; Houalla, M.; Proctor, A.; Cooper, N.J.; Hall, W.K.; Hercules, D.M. ESCA study of “model” allyl-based molybdenum/silica catalysts. J. Phys. Chem. 1993, 97, 5699–5702.41. Le, Z.; Afanasiev, P.; Li, D.; Long, X.; Vrinat, M. Solution synthesis of the unsupported Ni–W sulfide hydrotreating catalysts. Catal. Today 2008, 130, 24–3142. Wang, X.; Ozkan, U.S. Characterization of Active Sites over Reduced Ni−Mo/Al2O3 Catalysts for Hydrogenation of Linear Aldehydes. J. Phys. Chem. B 2005, 109, 1882–189043. Schön, G. Auger and direct electron spectra in X-ray photoelectron studies of zinc, zinc oxide, gallium and gallium oxide. J. Electron Spectrosc. Relat. Phenom. 1973, 2, 75–8644. Escaño, M.C.S.; Asubar, J.T.; Yatabe, Z.; David, M.Y.; Uenuma, M.; Tokuda, H.; Uraoka, Y.; Kuzuhara, M.; Tani, M. On the presence of Ga2O sub-oxide in high-pressure water vapor annealed AlGaN surface by combined XPS and first-principles methods. Appl. Surf. Sci. 2019, 481, 1120–112645. Rakmae, S.; Osakoo, N.; Pimsuta, M.; Deekamwong, K.; Keawkumay, C.; Butburee, T.; Faungnawakij, K.; Geantet, C.; Prayoonpokarach, S.; Wittayakun, J.; et al. Defining nickel phosphides supported on sodium mordenite for hydrodeoxygenation of palm oil. Fuel Process. Technol. 2020, 198, 10623646. Li, M.; Li, H.; Jiang, F.; Chu, Y.; Nie, H. The relation between morphology of (Co)MoS2 phases and selective hydrodesulfurization for CoMo catalysts. Catal. Today 2010, 149, 35–3947. Liu, H.; Liu, C.; Yin, C.; Liu, B.; Li, X.; Li, Y.; Chai, Y.; Liu, Y. Low temperature catalytic hydrogenation naphthalene to decalin over highly-loaded NiMo, NiW and NiMoW catalysts. Catal. Today 2016, 276, 46–5448. Barrett, E.P.; Joyner, L.G.; Halenda, P.P. The Determination of Pore Volume and Area Distributions in Porous Substances. I. Computations from Nitrogen Isotherms. J. Am. Chem. Soc. 1951, 73, 373–380.49. Farojr, A.; Dossantos, A. Cumene hydrocracking and thiophene HDS on niobia-supported Ni, Mo and Ni–Mo catalysts. Catal. Today 2006, 118, 402–40950. Froment, G.F.; De Wilde, J.; Bischoff, K.B. Chemical Reactor Analysis and Design, 3rd ed.; Wiley: Hoboken, NJ, USA, 2011; ISBN 978-0-470-56541-451. Moulijn, J.A.; Tarfaoui, A.; Kapteijn, F. General aspects of catalyst testing. Catal. Today 1991, 11, 1–1252. Farag, H. Kinetic Analysis of the Hydrodesulfurization of Dibenzothiophene: Approach Solution to the Reaction Network. Energy Fuels 2006, 20, 1815–182153. Vargas-Villagrán, H.; Ramírez-Suárez, D.; Ramírez-Muñoz, G.; Calzada, L.A.; González-García, G.; Klimova, y.T.E. Tuning of activity and selectivity of Ni/(Al)SBA-15 catalysts in naphthalene hydrogenation. Catal. 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