Detection of polarons in reduced vanadium oxide V2O(5-delta)
This project studied the change in magnetization of nanoparticles of pentoxide vanadium when subjected to controlled annealing. This study focuses on the induction of a stable net magnetic moment on the compound for applications such as spintronics and morphological computation. In addition, the stu...
- Autores:
-
Esquivel Sánchez, Andrea Steffania
- Tipo de recurso:
- Trabajo de grado de pregrado
- Fecha de publicación:
- 2022
- Institución:
- Universidad de los Andes
- Repositorio:
- Séneca: repositorio Uniandes
- Idioma:
- eng
- OAI Identifier:
- oai:repositorio.uniandes.edu.co:1992/59389
- Acceso en línea:
- http://hdl.handle.net/1992/59389
- Palabra clave:
- pentoxide vanadium
polarons
oxygen vacancies
nanoparticles
Small polaron hopping
Física
- Rights
- openAccess
- License
- Atribución-NoComercial-CompartirIgual 4.0 Internacional
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Detection of polarons in reduced vanadium oxide V2O(5-delta) |
| title |
Detection of polarons in reduced vanadium oxide V2O(5-delta) |
| spellingShingle |
Detection of polarons in reduced vanadium oxide V2O(5-delta) pentoxide vanadium polarons oxygen vacancies nanoparticles Small polaron hopping Física |
| title_short |
Detection of polarons in reduced vanadium oxide V2O(5-delta) |
| title_full |
Detection of polarons in reduced vanadium oxide V2O(5-delta) |
| title_fullStr |
Detection of polarons in reduced vanadium oxide V2O(5-delta) |
| title_full_unstemmed |
Detection of polarons in reduced vanadium oxide V2O(5-delta) |
| title_sort |
Detection of polarons in reduced vanadium oxide V2O(5-delta) |
| dc.creator.fl_str_mv |
Esquivel Sánchez, Andrea Steffania |
| dc.contributor.advisor.none.fl_str_mv |
Ramírez Rojas, Juan Gabriel |
| dc.contributor.author.none.fl_str_mv |
Esquivel Sánchez, Andrea Steffania |
| dc.contributor.jury.none.fl_str_mv |
Hernández Pico, Yenny Rocío |
| dc.contributor.researchgroup.es_CO.fl_str_mv |
Grupo de nanomagnetismo |
| dc.subject.keyword.none.fl_str_mv |
pentoxide vanadium polarons oxygen vacancies nanoparticles Small polaron hopping |
| topic |
pentoxide vanadium polarons oxygen vacancies nanoparticles Small polaron hopping Física |
| dc.subject.themes.es_CO.fl_str_mv |
Física |
| description |
This project studied the change in magnetization of nanoparticles of pentoxide vanadium when subjected to controlled annealing. This study focuses on the induction of a stable net magnetic moment on the compound for applications such as spintronics and morphological computation. In addition, the study of the physical explanation of the change in magnetization is focused on the presence of polarons. These polarons in the sample were detected using a superconductor magnet. The project also includes studies of Raman spectroscopy, relaxation times, magnetization, and analysis of the presence of polarons on the crystal lattice. |
| publishDate |
2022 |
| dc.date.accessioned.none.fl_str_mv |
2022-07-29T21:42:42Z |
| dc.date.available.none.fl_str_mv |
2022-07-29T21:42:42Z |
| dc.date.issued.none.fl_str_mv |
2022-07-29 |
| dc.type.es_CO.fl_str_mv |
Trabajo de grado - Pregrado |
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info:eu-repo/semantics/bachelorThesis |
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info:eu-repo/semantics/acceptedVersion |
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http://purl.org/coar/resource_type/c_7a1f |
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Text |
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http://purl.org/redcol/resource_type/TP |
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http://purl.org/coar/resource_type/c_7a1f |
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acceptedVersion |
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http://hdl.handle.net/1992/59389 |
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instname:Universidad de los Andes |
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reponame:Repositorio Institucional Séneca |
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| dc.language.iso.es_CO.fl_str_mv |
eng |
| language |
eng |
| dc.relation.references.es_CO.fl_str_mv |
Vanadium pentoxide (v2o5): Their obtaining methods and wide applications. Transition Metal Compounds - Synthesis, Properties, and Application, 2021. Dandan Chen, Jiangfeng Li, and Qingsheng Wu. Review of V2O5-based nanomaterials as electrode for supercapacitor, 2019. Wenwu Zhong, Jingdong Huang, Shuquan Liang, Jun Liu, Yejing Li, Gemei Cai, Yong Jiang, and Jun Liu. New prelithiated V2O5 superstructure for Lithium-Ion batteries with Long Cycle Life and High Power. ACS Energy Letters, 5, 2020 Xunhui Xiong, Zhixing Wang, Guochun Yan, Huajun Guo, and Xinhai Li. Role of V2O5 coating on LiNiO2 based materials for lithium ion battery. Journal of Power Sources, 245, 2014. Dipanwita Majumdar, Manas Mandal, and Swapan K. Bhattacharya. V2O5 and its carbon-based nanocomposites for supercapacitor applications, 2019. B. Saravanakumar, Kamatchi K. Purushothaman, and G. Muralidharan. Interconnected V2O5 nanoporous network for high-performance supercapacitors. ACS Applied Materials and Interfaces, 4, 2012. P. Umadevi, C. L. Nagendra, and G. K.M. Thutupalli. Structural, electrical and infrared optical properties of vanadium pentoxide (V2O5) thick-film thermistors. Sensors and Actuators: A. Physical, 39, 1993. Sergio Andrés Correal. Efecto del cambio estructural y de vacancias de oxígeno en las propiedades ópticas y electrónicas del V2O5 mediante primeros principios. Universidad de los Andes, 2020 R. P. Blum, H. Niehus, C. Hucho, R. Fortrie, M. V. Ganduglia-Pirovano, J. Sauer, S. Shaikhutdinov, and H. J. Freund. Surface metal-insulator transition on a vanadium pentoxide (001) single crystal. Physical Review Letters, 99, 2007 Tathagata Sarkar, Soumya Biswas, Sonali Kakkar, Appu Vengattoor Raghu, Chan dan Bera, and Vinayak B Kamble. Polaronic correlations in magnetic behavior of oxygen deficient V2O5, 2021. Milan Gacic, Gerhard Jakob, Christian Herbort, Hermann Adrian, Thomas Tietze, Sebastian Br¨uck, and Eberhard Goering. Magnetism of Co-doped ZnO thin films. Physical Review B - Condensed Matter and Materials Physics, 75, 2007. Zulfiqar, Muhammad Zubair, Aurangzeb Khan, Tang Hua, Nasir Ilyas, Simbarashe Fashu, Amir Muhammad Afzal, Main Akif Safeen, and Rajwali Khan. Oxygen vacancies induced room temperature ferromagnetism and enhanced dielectric properties in Co and Mn co-doped ZnO nanoparticles. Journal of Materials Science: Materials in Electronics, 32, 2021. D. S. Volzhenskii and V. G. Savitskii. Polarons of small radius in vanadium pentoxide i. polaron absorption in vanadium pentoxide. Soviet Physics Journal, 18, 1975. Vitaly V. Porsev, Andrei V. Bandura, and Robert A. Evarestov. Hybrid hartreefock-density functional theory study of V2O5 three phases: Comparison of bulk and layer stability, electron and phonon properties. Acta Materialia, 75, 2014. Jason S. Lupoi, Erica Gjersing, and Mark F. Davis. Evaluating lignocellulosic biomass, its derivatives, and downstream products with raman spectroscopy. Frontiers in Bioengineering and Biotechnology, 3, 2015. Edinburgh Instruments. What is Raman Spectroscopy?, url =https://www.edinst.com/blog/what-is-raman-spectroscopy/, note = Accessed:2022-05-09. P. Balog, D. Orosel, Zeljko Cancarevic, and C. Sch¨on. V2o5 phase diagram revisited at high pressures and high temperatures. Journal of Alloys and Compounds, 05, 2007. Daniel Hernandez. Confinamiento del pentóxido de vanadio v2o5 y la influencia del tamaño en sus propiedades ópticas. Universidad de Los Andes, 2021. Arvids Stashans, Sheyla Serrano, and P. Medina. Estudio químico-cuántico de los defectos producidos por las vacancias de oxígeno en los cristales de titanato de plomo PbTiO3. Ingenius, 2008. Charles Kittel. Introduction to Solid State Physics. John Wiley & Sons, 1953. Oxygen vacancies: The (in)visible friend of oxide electronics, 2020. Recent advances on spin-polarized two-dimensional electron gases at oxide interfaces, 2021. Arumugam Venkatesan, Nagamuthu Raja Krishna Chandar, Arumugam Kandasamy, Madhu Karl Chinnu, Kalusalingam Nagappan Marimuthu, Rangasamy Mohan Kumar, and Ramasamy Jayavel. Luminescence and electrochemical properties of rare earth (Gd, Nd) doped V2O5 nanostructures synthesized by a non-aqueous sol-gel route. RSC Advances, 5, 2015. Cesare Franchini, Michele Reticcioli, Martin Setvin, and Ulrike Diebold. Polarons in materials, 2021. P. Mandal, B. Bandyopadhyay, and B. Ghosh. Resistivity anomaly in the vicinity of a structural phase transition in La1¿xSrxMnO3. Phys. Rev. B, 64:180405, Oct 2001. J. BATES, C. HINMAN, and T. KAWADA. Electrical conductivity of uranium dioxide. Journal of the American Ceramic Society, 50:652 -656, 06 2006. C. Crevecoeur and H.J. De Wit. Electrical conductivity of li doped mno. Journal of Physics and Chemistry of Solids, 31(4):783-791, 1970. José De Teresa, M. Ibarra, Pedro Algarabel, C. Ritter, C. Marquina, Javier Blasco, J. García, A. Delmoral, and Zdenek Arnold. Evidence for magnetic polarons in the magnetoresistive perovskites. Nature, 386:256-259, 03 1997. Daniele Cortecchia, Jun Yin, Paola Lova, Subodh Mhaisalkar, Gagik Gurzadyan, Annalisa Bruno, and Cesare Soci. Polaron self-localization in white-light emitting hybrid perovskites. 03 2016. Hyuntaek Rho, C Snow, S. Cooper, Zachary Fisk, A Comment, and Jean-Philippe Ansermet. Evolution of magnetic polarons and spin-carrier interactions through the metal-insulator transition in eu 1 x gd x o. Physical review letters, 88:127401, 03 2002. David Emin. Small polarons. Physics Today, 35(6):34-40, 1982 F. A. Ibrahim. Influence of tungsten dopants on structural and electrical properties of solgel derived V2O5-MoO3 nanocrystalline films. Applied Physics A, 126(11):847, 2020. Raktima Basu, Arun K. Prasad, Sandip Dhara, and A. Das. Role of vanadyl oxygen in understanding metallic behavior of VO(001) nanorods. The Journal of Physical Chemistry C, 120(46):26539-26543, November 2016. Tathagata Sarkar, Soumya Biswas, Sonali Kakkar, Appu Vengattoor Raghu, Chan dan Bera, and Vinayak B Kamble. Polaronic correlations in magnetic behavior of oxygen deficient v2o5, 2021. C Sanchez, M Henry, J C Grenet, and J Livage. Free and bound polarons in vanadium pentoxide. Journal of Physics C: Solid State Physics, 15(35):7133-7141, 1982. |
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Atribución-NoComercial-CompartirIgual 4.0 Internacionalhttp://creativecommons.org/licenses/by-nc-sa/4.0/info:eu-repo/semantics/openAccesshttp://purl.org/coar/access_right/c_abf2Ramírez Rojas, Juan Gabrielvirtual::3445-1Esquivel Sánchez, Andrea Steffania62f2f8b4-4aca-4018-8ee5-c708012e049b600Hernández Pico, Yenny RocíoGrupo de nanomagnetismo2022-07-29T21:42:42Z2022-07-29T21:42:42Z2022-07-29http://hdl.handle.net/1992/59389instname:Universidad de los Andesreponame:Repositorio Institucional Sénecarepourl:https://repositorio.uniandes.edu.co/This project studied the change in magnetization of nanoparticles of pentoxide vanadium when subjected to controlled annealing. This study focuses on the induction of a stable net magnetic moment on the compound for applications such as spintronics and morphological computation. In addition, the study of the physical explanation of the change in magnetization is focused on the presence of polarons. These polarons in the sample were detected using a superconductor magnet. The project also includes studies of Raman spectroscopy, relaxation times, magnetization, and analysis of the presence of polarons on the crystal lattice.FísicoPregradoNanomagnetismoFísica del estado sólido37 páginasapplication/pdfengUniversidad de los AndesFísicaFacultad de CienciasDepartamento de FísicaDetection of polarons in reduced vanadium oxide V2O(5-delta)Trabajo de grado - Pregradoinfo:eu-repo/semantics/bachelorThesisinfo:eu-repo/semantics/acceptedVersionhttp://purl.org/coar/resource_type/c_7a1fTexthttp://purl.org/redcol/resource_type/TPpentoxide vanadiumpolaronsoxygen vacanciesnanoparticlesSmall polaron hoppingFísicaVanadium pentoxide (v2o5): Their obtaining methods and wide applications. Transition Metal Compounds - Synthesis, Properties, and Application, 2021.Dandan Chen, Jiangfeng Li, and Qingsheng Wu. Review of V2O5-based nanomaterials as electrode for supercapacitor, 2019.Wenwu Zhong, Jingdong Huang, Shuquan Liang, Jun Liu, Yejing Li, Gemei Cai, Yong Jiang, and Jun Liu. New prelithiated V2O5 superstructure for Lithium-Ion batteries with Long Cycle Life and High Power. ACS Energy Letters, 5, 2020Xunhui Xiong, Zhixing Wang, Guochun Yan, Huajun Guo, and Xinhai Li. Role of V2O5 coating on LiNiO2 based materials for lithium ion battery. Journal of Power Sources, 245, 2014.Dipanwita Majumdar, Manas Mandal, and Swapan K. Bhattacharya. V2O5 and its carbon-based nanocomposites for supercapacitor applications, 2019.B. Saravanakumar, Kamatchi K. Purushothaman, and G. Muralidharan. Interconnected V2O5 nanoporous network for high-performance supercapacitors. ACS Applied Materials and Interfaces, 4, 2012.P. Umadevi, C. L. Nagendra, and G. K.M. Thutupalli. Structural, electrical and infrared optical properties of vanadium pentoxide (V2O5) thick-film thermistors. Sensors and Actuators: A. Physical, 39, 1993.Sergio Andrés Correal. Efecto del cambio estructural y de vacancias de oxígeno en las propiedades ópticas y electrónicas del V2O5 mediante primeros principios. Universidad de los Andes, 2020R. P. Blum, H. Niehus, C. Hucho, R. Fortrie, M. V. Ganduglia-Pirovano, J. Sauer, S. Shaikhutdinov, and H. J. Freund. Surface metal-insulator transition on a vanadium pentoxide (001) single crystal. Physical Review Letters, 99, 2007Tathagata Sarkar, Soumya Biswas, Sonali Kakkar, Appu Vengattoor Raghu, Chan dan Bera, and Vinayak B Kamble. Polaronic correlations in magnetic behavior of oxygen deficient V2O5, 2021.Milan Gacic, Gerhard Jakob, Christian Herbort, Hermann Adrian, Thomas Tietze, Sebastian Br¨uck, and Eberhard Goering. Magnetism of Co-doped ZnO thin films. Physical Review B - Condensed Matter and Materials Physics, 75, 2007.Zulfiqar, Muhammad Zubair, Aurangzeb Khan, Tang Hua, Nasir Ilyas, Simbarashe Fashu, Amir Muhammad Afzal, Main Akif Safeen, and Rajwali Khan. Oxygen vacancies induced room temperature ferromagnetism and enhanced dielectric properties in Co and Mn co-doped ZnO nanoparticles. Journal of Materials Science: Materials in Electronics, 32, 2021.D. S. Volzhenskii and V. G. Savitskii. Polarons of small radius in vanadium pentoxide i. polaron absorption in vanadium pentoxide. Soviet Physics Journal, 18, 1975.Vitaly V. Porsev, Andrei V. Bandura, and Robert A. Evarestov. Hybrid hartreefock-density functional theory study of V2O5 three phases: Comparison of bulk and layer stability, electron and phonon properties. Acta Materialia, 75, 2014.Jason S. Lupoi, Erica Gjersing, and Mark F. Davis. Evaluating lignocellulosic biomass, its derivatives, and downstream products with raman spectroscopy. Frontiers in Bioengineering and Biotechnology, 3, 2015.Edinburgh Instruments. What is Raman Spectroscopy?, url =https://www.edinst.com/blog/what-is-raman-spectroscopy/, note = Accessed:2022-05-09.P. Balog, D. Orosel, Zeljko Cancarevic, and C. Sch¨on. V2o5 phase diagram revisited at high pressures and high temperatures. Journal of Alloys and Compounds, 05, 2007.Daniel Hernandez. Confinamiento del pentóxido de vanadio v2o5 y la influencia del tamaño en sus propiedades ópticas. Universidad de Los Andes, 2021.Arvids Stashans, Sheyla Serrano, and P. Medina. Estudio químico-cuántico de los defectos producidos por las vacancias de oxígeno en los cristales de titanato de plomo PbTiO3. Ingenius, 2008.Charles Kittel. Introduction to Solid State Physics. John Wiley & Sons, 1953.Oxygen vacancies: The (in)visible friend of oxide electronics, 2020.Recent advances on spin-polarized two-dimensional electron gases at oxide interfaces, 2021.Arumugam Venkatesan, Nagamuthu Raja Krishna Chandar, Arumugam Kandasamy, Madhu Karl Chinnu, Kalusalingam Nagappan Marimuthu, Rangasamy Mohan Kumar, and Ramasamy Jayavel. Luminescence and electrochemical properties of rare earth (Gd, Nd) doped V2O5 nanostructures synthesized by a non-aqueous sol-gel route. RSC Advances, 5, 2015.Cesare Franchini, Michele Reticcioli, Martin Setvin, and Ulrike Diebold. Polarons in materials, 2021.P. Mandal, B. Bandyopadhyay, and B. Ghosh. Resistivity anomaly in the vicinity of a structural phase transition in La1¿xSrxMnO3. Phys. Rev. B, 64:180405, Oct 2001.J. BATES, C. HINMAN, and T. KAWADA. Electrical conductivity of uranium dioxide. Journal of the American Ceramic Society, 50:652 -656, 06 2006.C. Crevecoeur and H.J. De Wit. Electrical conductivity of li doped mno. Journal of Physics and Chemistry of Solids, 31(4):783-791, 1970.José De Teresa, M. Ibarra, Pedro Algarabel, C. Ritter, C. Marquina, Javier Blasco, J. García, A. Delmoral, and Zdenek Arnold. Evidence for magnetic polarons in the magnetoresistive perovskites. Nature, 386:256-259, 03 1997.Daniele Cortecchia, Jun Yin, Paola Lova, Subodh Mhaisalkar, Gagik Gurzadyan, Annalisa Bruno, and Cesare Soci. Polaron self-localization in white-light emitting hybrid perovskites. 03 2016.Hyuntaek Rho, C Snow, S. Cooper, Zachary Fisk, A Comment, and Jean-Philippe Ansermet. Evolution of magnetic polarons and spin-carrier interactions through the metal-insulator transition in eu 1 x gd x o. Physical review letters, 88:127401, 03 2002.David Emin. Small polarons. Physics Today, 35(6):34-40, 1982F. A. Ibrahim. Influence of tungsten dopants on structural and electrical properties of solgel derived V2O5-MoO3 nanocrystalline films. Applied Physics A, 126(11):847, 2020.Raktima Basu, Arun K. Prasad, Sandip Dhara, and A. Das. Role of vanadyl oxygen in understanding metallic behavior of VO(001) nanorods. The Journal of Physical Chemistry C, 120(46):26539-26543, November 2016.Tathagata Sarkar, Soumya Biswas, Sonali Kakkar, Appu Vengattoor Raghu, Chan dan Bera, and Vinayak B Kamble. Polaronic correlations in magnetic behavior of oxygen deficient v2o5, 2021.C Sanchez, M Henry, J C Grenet, and J Livage. Free and bound polarons in vanadium pentoxide. 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