Study of monocomponent gas adsorption capacity of activated carbons obtained from cashew nutshell
The depletion of the world's oil reserves and the problem of climate change due to the increase in carbon dioxide levels in the atmosphere have led to an increasing search for new alternative sources of clean energy. The ideal fuel to produce energy would be hydrogen since its combustion would...
- Autores:
-
Fonseca Bermúdez, Óscar Javier
- Tipo de recurso:
- Doctoral thesis
- Fecha de publicación:
- 2024
- Institución:
- Universidad de los Andes
- Repositorio:
- Séneca: repositorio Uniandes
- Idioma:
- eng
- OAI Identifier:
- oai:repositorio.uniandes.edu.co:1992/75733
- Acceso en línea:
- https://hdl.handle.net/1992/75733
- Palabra clave:
- Gas adsorption
Cashew nutshell
Activated carbon
Hydrogen
Carbon dioxide
Methane
Ingeniería
Química
- Rights
- openAccess
- License
- Attribution-NonCommercial-NoDerivatives 4.0 International
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UNIANDES2 |
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| dc.title.eng.fl_str_mv |
Study of monocomponent gas adsorption capacity of activated carbons obtained from cashew nutshell |
| title |
Study of monocomponent gas adsorption capacity of activated carbons obtained from cashew nutshell |
| spellingShingle |
Study of monocomponent gas adsorption capacity of activated carbons obtained from cashew nutshell Gas adsorption Cashew nutshell Activated carbon Hydrogen Carbon dioxide Methane Ingeniería Química |
| title_short |
Study of monocomponent gas adsorption capacity of activated carbons obtained from cashew nutshell |
| title_full |
Study of monocomponent gas adsorption capacity of activated carbons obtained from cashew nutshell |
| title_fullStr |
Study of monocomponent gas adsorption capacity of activated carbons obtained from cashew nutshell |
| title_full_unstemmed |
Study of monocomponent gas adsorption capacity of activated carbons obtained from cashew nutshell |
| title_sort |
Study of monocomponent gas adsorption capacity of activated carbons obtained from cashew nutshell |
| dc.creator.fl_str_mv |
Fonseca Bermúdez, Óscar Javier |
| dc.contributor.advisor.none.fl_str_mv |
Giraldo Gutiérrez, Liliana Sierra Ramírez, Rocio Moreno Piraján, Juan Carlos |
| dc.contributor.author.none.fl_str_mv |
Fonseca Bermúdez, Óscar Javier |
| dc.contributor.jury.none.fl_str_mv |
Medellín Castillo, Nahum Andrés Vargas Delgadillo, Diana Paola Saldarriaga Elorza, Juan Fernando |
| dc.contributor.researchgroup.none.fl_str_mv |
Facultad de Ciencias |
| dc.subject.keyword.eng.fl_str_mv |
Gas adsorption Cashew nutshell Activated carbon Hydrogen Carbon dioxide Methane |
| topic |
Gas adsorption Cashew nutshell Activated carbon Hydrogen Carbon dioxide Methane Ingeniería Química |
| dc.subject.themes.none.fl_str_mv |
Ingeniería Química |
| description |
The depletion of the world's oil reserves and the problem of climate change due to the increase in carbon dioxide levels in the atmosphere have led to an increasing search for new alternative sources of clean energy. The ideal fuel to produce energy would be hydrogen since its combustion would produce a large amount of energy while the only biproduct is water. The low density of hydrogen at room temperature means it must be stored at very high pressures, which is not recommended for use in everyday transportation vehicles. One of the alternatives to reduce storage pressure is the use of adsorbent materials. Activated carbon presents advantages over other adsorbent materials since it can be obtained with a large specific surface area, has a low production cost, has fast adsorption/desorption kinetics, and its surface chemistry can be easily modified. The main goal of this study is to prepare microporous materials for hydrogen storage from the agricultural residue known as cashew nut shell and determine the best conditions that allow us to obtain such materials. The cashew nutshell is a residue. As cashew tree plantations are increasing throughout Colombia, this has resulted in a considerable amount of residue. These shells contain an inedible oil that does not degrade easily; in addition, this oil prevents the shell from being used as a source of energy due to the toxic components that are released when burned. Therefore, finding an effective way to use these shells would have a positive benefit for the cashew industry. In the production of activated carbons, different activating agents and activation temperatures are used for each agent. The activated carbons obtained are texturally and chemically characterized and are then subjected to high-pressure hydrogen adsorption tests. The performance for storing hydrogen of these activated carbons is compared with other materials. It was found that the adsorption of hydrogen at high pressures is not only favored by a high surface area and micropore volume but also the ratio of the microporous to the mesoporous. The porous network morphology of each material must also be taken into account, which can facilitate the access of the gas to the micropores, increasing their adsorption capacity. This network morphology was especially developed by directly activating the precursor with potassium carbonate. Additionally, the research explores the performance of the materials obtained in comparison to other gases of interest, such as CH4 and CO2. In both cases, the material that presented the highest uptake was the one that was activated in a single step with potassium carbonate. |
| publishDate |
2024 |
| dc.date.issued.none.fl_str_mv |
2024-12-12 |
| dc.date.accessioned.none.fl_str_mv |
2025-01-28T18:14:00Z |
| dc.date.available.none.fl_str_mv |
2025-01-28T18:14:00Z |
| dc.type.none.fl_str_mv |
Trabajo de grado - Doctorado |
| dc.type.driver.none.fl_str_mv |
info:eu-repo/semantics/doctoralThesis |
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info:eu-repo/semantics/acceptedVersion |
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http://purl.org/coar/resource_type/c_db06 |
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Text |
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https://purl.org/redcol/resource_type/TD |
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http://purl.org/coar/resource_type/c_db06 |
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acceptedVersion |
| dc.identifier.uri.none.fl_str_mv |
https://hdl.handle.net/1992/75733 |
| dc.identifier.instname.none.fl_str_mv |
instname:Universidad de los Andes |
| dc.identifier.reponame.none.fl_str_mv |
reponame:Repositorio Institucional Séneca |
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repourl:https://repositorio.uniandes.edu.co/ |
| url |
https://hdl.handle.net/1992/75733 |
| identifier_str_mv |
instname:Universidad de los Andes reponame:Repositorio Institucional Séneca repourl:https://repositorio.uniandes.edu.co/ |
| dc.language.iso.none.fl_str_mv |
eng |
| language |
eng |
| dc.relation.references.none.fl_str_mv |
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Lozano-Castelló D, Alcañiz-Monge J, de la Casa-Lillo MA, Cazorla-Amorós D, Linares-Solano A. Advances in the study of methane storage in porous carbonaceous materials. Fuel 2002;81:1777–803. https://doi.org/10.1016/S0016-2361(02)00124-2. Vargas DP, Giraldo L, Moreno-Piraján JC. Carbon dioxide and methane adsorption at high pressure on activated carbon materials. Adsorption 2013;19:1075–82. https://doi.org/10.1007/s10450-013-9532-5. Kemp KC, Baek S Bin, Lee W-G, Meyyappan M, Kim KS. Activated carbon derived from waste coffee grounds for stable methane storage. Nanotechnology 2015;26:385602. https://doi.org/10.1088/0957-4484/26/38/385602. Azevedo DCS, Araújo JCS, Bastos-Neto M, Torres AEB, Jaguaribe EF, Cavalcante CL. Microporous activated carbon prepared from coconut shells using chemical activation with zinc chloride. Microporous and Mesoporous Materials 2007;100:361–4. https://doi.org/10.1016/j.micromeso.2006.11.024. Bagheri N, Abedi J. Adsorption of methane on corn cobs based activated carbon. Chemical Engineering Research and Design 2011;89:2038–43. https://doi.org/10.1016/j.cherd.2011.02.002. Oguz Erdogan F. A comparative study on methane adsorption onto various adsorbents including activated carbons, zeolites, MWCNT, and MCM-41. International Journal of Coal Preparation and Utilization 2022;42:2078–98. https://doi.org/10.1080/19392699.2020.1798941. Casco ME, Martínez-Escandell M, Gadea-Ramos E, Kaneko K, Silvestre-Albero J, Rodríguez-Reinoso F. High-Pressure Methane Storage in Porous Materials: Are Carbon Materials in the Pole Position? Chemistry of Materials 2015;27:959–64. https://doi.org/10.1021/cm5042524. Myers AL, Prausnitz JM. Thermodynamics of mixed‐gas adsorption. AIChE Journal 1965;11:121–7. https://doi.org/10.1002/aic.690110125. Ray KG, Olmsted DL, Houndonougbo Y, Laird BB, Asta M. Origins of CH 4 /CO 2 Adsorption Selectivity in Zeolitic Imidazolate Frameworks: A van der Waals Density Functional Study. The Journal of Physical Chemistry C 2013;117:14642–51. https://doi.org/10.1021/jp404251m. Rios RB, Stragliotto FM, Peixoto HR, Torres AEB, Bastos-Neto M, Azevedo DCS, et al. Studies on the adsorption behavior of CO2-CH4 mixtures using activated carbon. Brazilian Journal of Chemical Engineering 2013;30:939–51. https://doi.org/10.1590/S0104-66322013000400024. Abdeljaoued A, Querejeta N, Durán I, Álvarez-Gutiérrez N, Pevida C, Chahbani M. Preparation and Evaluation of a Coconut Shell-Based Activated Carbon for CO2/CH4 Separation. Energies (Basel) 2018;11:1748. https://doi.org/10.3390/en11071748. Khalili S, Khoshandam B, Jahanshahi M. A comparative study of CO2 and CH4 adsorption using activated carbon prepared from pine cone by phosphoric acid activation. Korean Journal of Chemical Engineering 2016;33:2943–52. https://doi.org/10.1007/s11814-016-0138-y. Abdul Kareem FA, Shariff AM, Ullah S, Mellon N, Keong LK. Adsorption of pure and predicted binary (CO2:CH4) mixtures on 13X-Zeolite: Equilibrium and kinetic properties at offshore conditions. Microporous and Mesoporous Materials 2018;267:221–34. https://doi.org/10.1016/j.micromeso.2018.04.007. Mofarahi M, Gholipour F. Gas adsorption separation of CO2/CH4 system using zeolite 5A. Microporous and Mesoporous Materials 2014;200:1–10. https://doi.org/10.1016/j.micromeso.2014.08.022. Arefi Pour A, Sharifnia S, Neishabori Salehi R, Ghodrati M. Adsorption separation of CO2 /CH 4 on the synthesized NaA zeolite shaped with montmorillonite clay in natural gas purification process. J Nat Gas Sci Eng 2016;36:630–43. https://doi.org/10.1016/j.jngse.2016.11.006. Parinyakit S, Worathanakul P. Static and Dynamic Simulation of Single and Binary Component Adsorption of CO2 and CH4 on Fixed Bed Using Molecular Sieve of Zeolite 4A. Processes 2021;9:1250. https://doi.org/10.3390/pr9071250. Shen J, Wang X, Chen Y. 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Giraldo Gutiérrez, LilianaSierra Ramírez, Rociovirtual::22700-1Moreno Piraján, Juan Carlosvirtual::22701-1Fonseca Bermúdez, Óscar JavierMedellín Castillo, Nahum AndrésVargas Delgadillo, Diana PaolaSaldarriaga Elorza, Juan FernandoFacultad de Ciencias2025-01-28T18:14:00Z2025-01-28T18:14:00Z2024-12-12https://hdl.handle.net/1992/75733instname:Universidad de los Andesreponame:Repositorio Institucional Sénecarepourl:https://repositorio.uniandes.edu.co/The depletion of the world's oil reserves and the problem of climate change due to the increase in carbon dioxide levels in the atmosphere have led to an increasing search for new alternative sources of clean energy. The ideal fuel to produce energy would be hydrogen since its combustion would produce a large amount of energy while the only biproduct is water. The low density of hydrogen at room temperature means it must be stored at very high pressures, which is not recommended for use in everyday transportation vehicles. One of the alternatives to reduce storage pressure is the use of adsorbent materials. Activated carbon presents advantages over other adsorbent materials since it can be obtained with a large specific surface area, has a low production cost, has fast adsorption/desorption kinetics, and its surface chemistry can be easily modified. The main goal of this study is to prepare microporous materials for hydrogen storage from the agricultural residue known as cashew nut shell and determine the best conditions that allow us to obtain such materials. The cashew nutshell is a residue. As cashew tree plantations are increasing throughout Colombia, this has resulted in a considerable amount of residue. These shells contain an inedible oil that does not degrade easily; in addition, this oil prevents the shell from being used as a source of energy due to the toxic components that are released when burned. Therefore, finding an effective way to use these shells would have a positive benefit for the cashew industry. In the production of activated carbons, different activating agents and activation temperatures are used for each agent. The activated carbons obtained are texturally and chemically characterized and are then subjected to high-pressure hydrogen adsorption tests. The performance for storing hydrogen of these activated carbons is compared with other materials. It was found that the adsorption of hydrogen at high pressures is not only favored by a high surface area and micropore volume but also the ratio of the microporous to the mesoporous. The porous network morphology of each material must also be taken into account, which can facilitate the access of the gas to the micropores, increasing their adsorption capacity. This network morphology was especially developed by directly activating the precursor with potassium carbonate. Additionally, the research explores the performance of the materials obtained in comparison to other gases of interest, such as CH4 and CO2. In both cases, the material that presented the highest uptake was the one that was activated in a single step with potassium carbonate.Apoyo Financiero para Doctorados de la Universidad de Los AndesDoctorado133 páginasapplication/pdfengUniversidad de los AndesDoctorado en IngenieríaFacultad de IngenieríaDepartamento de Ingeniería Química y de AlimentosAttribution-NonCommercial-NoDerivatives 4.0 Internationalhttp://creativecommons.org/licenses/by-nc-nd/4.0/info:eu-repo/semantics/openAccesshttp://purl.org/coar/access_right/c_abf2Study of monocomponent gas adsorption capacity of activated carbons obtained from cashew nutshellTrabajo de grado - Doctoradoinfo:eu-repo/semantics/doctoralThesisinfo:eu-repo/semantics/acceptedVersionhttp://purl.org/coar/resource_type/c_db06Texthttps://purl.org/redcol/resource_type/TDGas adsorptionCashew nutshellActivated carbonHydrogenCarbon dioxideMethaneIngenieríaQuímicaMorante JR, Andreu T, García G, Guilera J, Tarancón A, Torrell M. Hidrógeno, vector energético de una economía descarbonizada. Madrid, España.: 2020.Rodríguez-Reinoso F, & KK. Nanoporous materials for gas storage. Singapore: Springer ; 2019.US DOE. Fuel Cell Technologies Office of the US DOE (Hydrogen storage) 2017.Ahn C, GRH, & BJRC. Enhanced Hydrogen Dipole Physisorption. . 2005 Annual Merit Review Proceedings of the US Department of Energy 2005.CNG United. How you can benefit from CNG conversion 2018. http://www.cngunited.com/support/howyoucanbenefitfromcngconversion (accessed March 4, 2024).Wegrzyn J, Gurevich M. Adsorbent storage of natural gas. Appl Energy 1996;55:71–83. https://doi.org/10.1016/S0306-2619(96)00015-3.Burchell T, Rogers M. Low pressure storage of natural gas for vehicular applications. Journal of Fuels and Lubricants 2000;109:2242–6.Veziroglu TN, Barbir F. Hydrogen: the wonder fuel. Int J Hydrogen Energy 1992;17:391–404. https://doi.org/10.1016/0360-3199(92)90183-W.Tsai WT, Chang CY, Wang SY, Chang CF, Chien SF, Sun HF. Cleaner production of carbon adsorbents by utilizing agricultural waste corn cob. Resour Conserv Recycl 2001;32:43–53. https://doi.org/10.1016/S0921-3449(00)00093-8.Cruz-Reina LJ. Valorization of cashew nut agricultural residues from Vichada: biorefinery approach, sustainability analysis, and perspectives. Universidad de Los Andes, 2023.Agrosavia. El marañón, una excelente proyección para el campo 2022.Duarte FND, Rodrigues JB, da Costa Lima M, Lima M dos S, Pacheco MTB, Pintado MME, et al. Potential prebiotic properties of cashew apple (Anacardium occidentale L.) agro-industrial byproduct on Lactobacillus species. J Sci Food Agric 2017;97:3712–9. https://doi.org/10.1002/JSFA.8232.Das P, Ganesh A. Bio-oil from pyrolysis of cashew nut shell—a near fuel. Biomass Bioenergy 2003;25:113–7. https://doi.org/10.1016/S0961-9534(02)00182-4.Almeida MO, Bezerra TT, Lima NMA, Sousa AF, Trevisan MTS, Ribeiro VGP, et al. Cardol-Derived Organophosphorothioates as Inhibitors of Acetylcholinesterase for Dengue Vector Control. J Braz Chem Soc 2019;30:2634–41. https://doi.org/10.21577/0103-5053.20190181.Sanger SH, Mohod AG, Khandetode YP, Shrirame HY, Deshmukh AS. Study of Carbonization for Cashew Nut Shell. Research Journal of Chemical Sciences 2011;1:43–55.Sharma P, Gaur VK, Sirohi R, Larroche C, Kim SH, Pandey A. Valorization of cashew nut processing residues for industrial applications. Ind Crops Prod 2020;152:112550. https://doi.org/10.1016/j.indcrop.2020.112550.Azelis. Grow the Bio-Based Content in your Formulas with CNSL Technology 2022. https://explore.azelis.com/en_US/ca_case/grow-the-bio-based-content-in-your-formulas-with-cnsl-technology (accessed March 5, 2024).Singh B, Singh V V, Boopathi M, Shah D. Pressure Swing Adsorption Based Air Filtration/Purification Systems for NBC Collective Protection. Def Life Sci J 2016;1:127. https://doi.org/10.14429/dlsj.1.10737.Truong LVA, Abatzoglou N. A H2S reactive adsorption process for the purification of biogas prior to its use as a bioenergy vector. Biomass Bioenergy 2005;29:142–51. https://doi.org/10.1016/J.BIOMBIOE.2005.03.001.Wang X, Ma X, Sun L, Song C. A nanoporous polymeric sorbent for deep removal of H2S from gas mixtures for hydrogen purification. Green Chemistry 2007;9:695–702. https://doi.org/10.1039/B614621J.Tellez-Juarez M. Almacenamiento de hidrógeno en carbones porosos. Instituto Politécnico Nacional, 2013.Marsh H, Rodríguez-Reinoso F. Activated Carbon. Activated Carbon 2006:1–536. https://doi.org/10.1016/B978-0-08-044463-5.X5013-4.Lim WC, Srinivasakannan C, Balasubramanian N. Activation of palm shells by phosphoric acid impregnation for high yielding activated carbon. J Anal Appl Pyrolysis 2010;88:181–6. https://doi.org/10.1016/J.JAAP.2010.04.004.Figueiredo JL, Pereira MFR, Freitas MMA, Órfão JJM. Modification of the surface chemistry of activated carbons. 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