Surface functionalization of magnetic micro-robots for Removal of Nickel, Lithium and Chromium from wastewater
This paper presents the feasibility of heavy metal (Ni, Li, Cr) polluted wastewater treatment with functionalized micro-robots. A cross like design of magnetic micro-robots, with suggested material as aluminum (Al), where ensembled and functionalized. The type of functionalization was APTES and Laca...
- Autores:
-
Rojas Cárdenas, Sofía Valentina
- Tipo de recurso:
- Trabajo de grado de pregrado
- Fecha de publicación:
- 2022
- Institución:
- Universidad de los Andes
- Repositorio:
- Séneca: repositorio Uniandes
- Idioma:
- eng
- OAI Identifier:
- oai:repositorio.uniandes.edu.co:1992/59040
- Acceso en línea:
- http://hdl.handle.net/1992/59040
- Palabra clave:
- Microrobots
Wastewater treatment
Adsorption
Chromium
Nickel
Lithium
Aptes
Laccase immobilization
Ingeniería
- Rights
- openAccess
- License
- Attribution-NonCommercial-NoDerivatives 4.0 Internacional
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| dc.title.none.fl_str_mv |
Surface functionalization of magnetic micro-robots for Removal of Nickel, Lithium and Chromium from wastewater |
| dc.title.alternative.none.fl_str_mv |
Funcionalización superficial de micro-robots magnéticos para la remoción de Níquel, Litio y Cromo de aguas residuales |
| title |
Surface functionalization of magnetic micro-robots for Removal of Nickel, Lithium and Chromium from wastewater |
| spellingShingle |
Surface functionalization of magnetic micro-robots for Removal of Nickel, Lithium and Chromium from wastewater Microrobots Wastewater treatment Adsorption Chromium Nickel Lithium Aptes Laccase immobilization Ingeniería |
| title_short |
Surface functionalization of magnetic micro-robots for Removal of Nickel, Lithium and Chromium from wastewater |
| title_full |
Surface functionalization of magnetic micro-robots for Removal of Nickel, Lithium and Chromium from wastewater |
| title_fullStr |
Surface functionalization of magnetic micro-robots for Removal of Nickel, Lithium and Chromium from wastewater |
| title_full_unstemmed |
Surface functionalization of magnetic micro-robots for Removal of Nickel, Lithium and Chromium from wastewater |
| title_sort |
Surface functionalization of magnetic micro-robots for Removal of Nickel, Lithium and Chromium from wastewater |
| dc.creator.fl_str_mv |
Rojas Cárdenas, Sofía Valentina |
| dc.contributor.advisor.none.fl_str_mv |
Osma Cruz, Johann Faccelo |
| dc.contributor.author.none.fl_str_mv |
Rojas Cárdenas, Sofía Valentina |
| dc.contributor.other.none.fl_str_mv |
Rivas Hernández, Ricardo Eusebio |
| dc.contributor.jury.none.fl_str_mv |
Giraldo Trujillo, Luis Felipe |
| dc.contributor.researchgroup.es_CO.fl_str_mv |
Biomicrosystems |
| dc.subject.keyword.none.fl_str_mv |
Microrobots Wastewater treatment Adsorption Chromium Nickel Lithium Aptes Laccase immobilization |
| topic |
Microrobots Wastewater treatment Adsorption Chromium Nickel Lithium Aptes Laccase immobilization Ingeniería |
| dc.subject.themes.es_CO.fl_str_mv |
Ingeniería |
| description |
This paper presents the feasibility of heavy metal (Ni, Li, Cr) polluted wastewater treatment with functionalized micro-robots. A cross like design of magnetic micro-robots, with suggested material as aluminum (Al), where ensembled and functionalized. The type of functionalization was APTES and Lacasse, the last one was tested under and indirect enzyme activity test. Simulation of polluted wastewater with Ni, Cr and Li, at four different concentrations, was tested with micro-robots for five hours. Additional test was carried out for Cadmium (Cd) and Lead (Pb) as contaminants for eight hours. Results show no variation in heavy metal removal, after ANOVA variance analysis was carried out. |
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2022 |
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2022-07-22T19:01:22Z |
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2022-07-22T19:01:22Z |
| dc.date.issued.none.fl_str_mv |
2022 |
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Trabajo de grado - Pregrado |
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info:eu-repo/semantics/bachelorThesis |
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eng |
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Olafisoye, Oladunni & Adefioye, Tejumade & Osibote, Otolorin. (2013). Heavy Metals Contamination of Water, Soil, and Plants around an Electronic Waste Dumpsite. Polish Journal of Environmental Studies. 22. 1431-1439. K. Rehman, F. Fatima, I. Waheed and M. Akash, Prevalence of exposure of heavy metals and their impact on health consequences, Journal of Cellular Biochemistry, vol. 119, no. 1, pp. 157-184, 2017. Available: 10.1002/jcb.26234 [Accessed 3 April 2022]. M. Sankhla, M. Kumari, M. Nandan, R. Kumar and P. Agrawal, Heavy Metals Contamination in Water and their Hazardous Effect on Human Health-A Review, International Journal of Current Microbiology and Applied Sciences, vol. 5, no. 10, pp. 759-766, 2016. Available: 10.20546/ijcmas.2016.510.082 [Accessed 8 May 2022]. Y. Guo, C. Huang, H. Zhang and Q. Dong, Heavy Metal Contamination from Electronic Waste Recycling at Guiyu, Southeastern China, Journal of Environmental Quality, vol. 38, no. 4, pp. 1617-1626, 2009. Available: 10.2134/jeq2008.0398 [Accessed 3 April 2022]. E. Melchor-Martínez, R. Macias-Garbett, A. Malacara-Becerra, H. Iqbal, J. Sosa-Hernández and R. Parra-Saldívar, "Environmental impact of emerging contaminants from battery waste: A mini review", Case Studies in Chemical and Environmental Engineering, vol. 3, p. 100104, 2021. Available: 10.1016/j.cscee.2021.100104 [Accessed 8 May 2022]. Gunatilake, Sunethra. (2015). Methods of Removing Heavy Metals from Industrial Wastewater. Journal of Multidiciplinary Engineering Science Studies. 1. M. Nur-E-Alam, M. Mia, F. Ahmad and M. Rahman, An overview of chromium removal techniques from tannery effluent, Applied Water Science, vol. 10, no. 9, 2020. Available: 10.1007/s13201-020-01286-0 [Accessed 8 May 2022]. D. Giri, M. Shah, N. Srivastava, A. Hashem, E. Abd_Allah and D. Pal, Sustainable Chromium Recovery From Wastewater Using Mango and Jackfruit Seed Kernel Bio-Adsorbents, Frontiers in Microbiology, vol. 12, 2021. Available: 10.3389/fmicb.2021.717848 [Accessed 8 May 2022]. D. ¿pekçi et al., Application of heterogeneous ion exchange membranes for simultaneous separation and recovery of lithium and boron from aqueous solution with bipolar membrane electrodialysis (EDBM), Desalination, vol. 479, p. 114313, 2020. Available: 10.1016/j.desal.2020.114313 [Accessed 5 May 2022]. S. Nishihama, K. Onishi and K. Yoshizuka, Selective Recovery Process of Lithium from Seawater Using Integrated Ion Exchange Methods, Solvent Extraction and Ion Exchange, vol. 29, no. 3, pp. 421-431, 2011. Available: 10.1080/07366299.2011.573435 [Accessed 5 May 2022]. S. Kim, J. Kim, S. Kim, J. Lee and J. Yoon, Electrochemical lithium recovery and organic pollutant removal from industrial wastewater of a battery recycling plant, Environmental Science: Water Research & Technology, vol. 4, no. 2, pp. 175-182, 2018. Available: 10.1039/c7ew00454k [Accessed 5 May 2022]. H. Es-sahbany et al., Removal of heavy metals (nickel) contained in wastewater-models by the adsorption technique on natural clay, Materials Today: Proceedings, vol. 13, pp. 866-875, 2019. Available: 10.1016/j.matpr.2019.04.050. J. Kumar, H. Joshi and S. Malyan, Removal of Copper, Nickel, and Zinc Ions from an Aqueous Solution through Electrochemical and Nanofiltration Membrane Processes, Applied Sciences, vol. 12, no. 1, p. 280, 2021. Available: 10.3390/app12010280 [Accessed 8 May 2022]. K. Horikawa and I. Hirasawa, Removal and recovery of nickel ion from wastewater of electroless plating by reduction crystallization, Korean Journal of Chemical Engineering, vol. 17, no. 6, pp. 629-632, 2000. Available: 10.1007/bf02699108. P. Peñaranda, Magnetic micro-robots with surface functionalization of silanes and laccase for wastewater treatment with heavy metals and dyes.. Bogotá: Universidad de los Andes, 2022, p. 21. S. More, R. P. S., P. K., S. M., S. Malini and V. S. M., Isolation, Purification, and Characterization of Fungal Laccase from <i>Pleurotus</i> sp., Enzyme Research, vol. 2011, pp. 1-7, 2011. Available: 10.4061/2011/248735 [Accessed 4 May 2022]. R. Bourbonnais, D. Leech and M. Paice, "Electrochemical analysis of the interactions of laccase mediators with lignin model compounds", Biochimica et Biophysica Acta (BBA) - General Subjects, vol. 1379, no. 3, pp. 381-390, 1998. Available: 10.1016/s0304-4165(97)00117-7 [Accessed 4 May 2022]. L. St»hle and S. Wold, Analysis of variance (ANOVA), Chemometrics and Intelligent Laboratory Systems, vol. 6, no. 4, pp. 259-272, 1989. Available: 10.1016/0169-7439(89)80095-4 [Accessed 4 May 2022]. H. Thompson, R. Mera and C. Prasad, The Analysis of Variance (ANOVA), Nutritional Neuroscience, vol. 2, no. 1, pp. 43-55, 1999. Available: 10.1080/1028415x.1999.11747262 [Accessed 4 May 2022]. J. Kerry, Aluminium foil packaging, Packaging Technology, pp. 163-177, 2012. Available: 10.1533/9780857095701.2.163 [Accessed 9 May 2022]. A. Campaña, A. Guillén, R. Rivas, V. Akle, J. Cruz and J. Osma, Functionalization and Evaluation of Inorganic Adsorbents for the Removal of Cadmium in Wastewater, Molecules, vol. 26, no. 14, p. 4150, 2021. Available: 10.3390/molecules26144150 [Accessed 9 May 2022]. |
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Attribution-NonCommercial-NoDerivatives 4.0 Internacionalhttp://creativecommons.org/licenses/by-nc-nd/4.0/info:eu-repo/semantics/openAccesshttp://purl.org/coar/access_right/c_abf2Osma Cruz, Johann Faccelovirtual::538-1Rojas Cárdenas, Sofía Valentinac2a83aac-1815-4cf5-a523-a5486b45e343600Rivas Hernández, Ricardo EusebioGiraldo Trujillo, Luis FelipeBiomicrosystems2022-07-22T19:01:22Z2022-07-22T19:01:22Z2022http://hdl.handle.net/1992/59040instname:Universidad de los Andesreponame:Repositorio Institucional Sénecarepourl:https://repositorio.uniandes.edu.co/This paper presents the feasibility of heavy metal (Ni, Li, Cr) polluted wastewater treatment with functionalized micro-robots. A cross like design of magnetic micro-robots, with suggested material as aluminum (Al), where ensembled and functionalized. The type of functionalization was APTES and Lacasse, the last one was tested under and indirect enzyme activity test. Simulation of polluted wastewater with Ni, Cr and Li, at four different concentrations, was tested with micro-robots for five hours. Additional test was carried out for Cadmium (Cd) and Lead (Pb) as contaminants for eight hours. Results show no variation in heavy metal removal, after ANOVA variance analysis was carried out.Ingeniero ElectrónicoPregrado13 páginasapplication/pdfengUniversidad de los AndesIngeniería ElectrónicaFacultad de IngenieríaDepartamento de Ingeniería Eléctrica y ElectrónicaSurface functionalization of magnetic micro-robots for Removal of Nickel, Lithium and Chromium from wastewaterFuncionalización superficial de micro-robots magnéticos para la remoción de Níquel, Litio y Cromo de aguas residualesTrabajo de grado - Pregradoinfo:eu-repo/semantics/bachelorThesisinfo:eu-repo/semantics/acceptedVersionhttp://purl.org/coar/resource_type/c_7a1fTexthttp://purl.org/redcol/resource_type/TPMicrorobotsWastewater treatmentAdsorptionChromiumNickelLithiumAptesLaccase immobilizationIngenieríaOlafisoye, Oladunni & Adefioye, Tejumade & Osibote, Otolorin. (2013). Heavy Metals Contamination of Water, Soil, and Plants around an Electronic Waste Dumpsite. Polish Journal of Environmental Studies. 22. 1431-1439.K. Rehman, F. Fatima, I. Waheed and M. Akash, Prevalence of exposure of heavy metals and their impact on health consequences, Journal of Cellular Biochemistry, vol. 119, no. 1, pp. 157-184, 2017. Available: 10.1002/jcb.26234 [Accessed 3 April 2022].M. Sankhla, M. Kumari, M. Nandan, R. Kumar and P. Agrawal, Heavy Metals Contamination in Water and their Hazardous Effect on Human Health-A Review, International Journal of Current Microbiology and Applied Sciences, vol. 5, no. 10, pp. 759-766, 2016. Available: 10.20546/ijcmas.2016.510.082 [Accessed 8 May 2022].Y. Guo, C. Huang, H. Zhang and Q. Dong, Heavy Metal Contamination from Electronic Waste Recycling at Guiyu, Southeastern China, Journal of Environmental Quality, vol. 38, no. 4, pp. 1617-1626, 2009. Available: 10.2134/jeq2008.0398 [Accessed 3 April 2022].E. Melchor-Martínez, R. Macias-Garbett, A. Malacara-Becerra, H. Iqbal, J. Sosa-Hernández and R. Parra-Saldívar, "Environmental impact of emerging contaminants from battery waste: A mini review", Case Studies in Chemical and Environmental Engineering, vol. 3, p. 100104, 2021. Available: 10.1016/j.cscee.2021.100104 [Accessed 8 May 2022].Gunatilake, Sunethra. (2015). Methods of Removing Heavy Metals from Industrial Wastewater. Journal of Multidiciplinary Engineering Science Studies. 1.M. Nur-E-Alam, M. Mia, F. Ahmad and M. Rahman, An overview of chromium removal techniques from tannery effluent, Applied Water Science, vol. 10, no. 9, 2020. Available: 10.1007/s13201-020-01286-0 [Accessed 8 May 2022].D. Giri, M. Shah, N. Srivastava, A. Hashem, E. Abd_Allah and D. Pal, Sustainable Chromium Recovery From Wastewater Using Mango and Jackfruit Seed Kernel Bio-Adsorbents, Frontiers in Microbiology, vol. 12, 2021. Available: 10.3389/fmicb.2021.717848 [Accessed 8 May 2022].D. ¿pekçi et al., Application of heterogeneous ion exchange membranes for simultaneous separation and recovery of lithium and boron from aqueous solution with bipolar membrane electrodialysis (EDBM), Desalination, vol. 479, p. 114313, 2020. Available: 10.1016/j.desal.2020.114313 [Accessed 5 May 2022].S. Nishihama, K. Onishi and K. Yoshizuka, Selective Recovery Process of Lithium from Seawater Using Integrated Ion Exchange Methods, Solvent Extraction and Ion Exchange, vol. 29, no. 3, pp. 421-431, 2011. Available: 10.1080/07366299.2011.573435 [Accessed 5 May 2022].S. Kim, J. Kim, S. Kim, J. Lee and J. Yoon, Electrochemical lithium recovery and organic pollutant removal from industrial wastewater of a battery recycling plant, Environmental Science: Water Research & Technology, vol. 4, no. 2, pp. 175-182, 2018. Available: 10.1039/c7ew00454k [Accessed 5 May 2022].H. Es-sahbany et al., Removal of heavy metals (nickel) contained in wastewater-models by the adsorption technique on natural clay, Materials Today: Proceedings, vol. 13, pp. 866-875, 2019. Available: 10.1016/j.matpr.2019.04.050.J. Kumar, H. Joshi and S. Malyan, Removal of Copper, Nickel, and Zinc Ions from an Aqueous Solution through Electrochemical and Nanofiltration Membrane Processes, Applied Sciences, vol. 12, no. 1, p. 280, 2021. Available: 10.3390/app12010280 [Accessed 8 May 2022].K. Horikawa and I. Hirasawa, Removal and recovery of nickel ion from wastewater of electroless plating by reduction crystallization, Korean Journal of Chemical Engineering, vol. 17, no. 6, pp. 629-632, 2000. Available: 10.1007/bf02699108.P. Peñaranda, Magnetic micro-robots with surface functionalization of silanes and laccase for wastewater treatment with heavy metals and dyes.. Bogotá: Universidad de los Andes, 2022, p. 21.S. More, R. P. S., P. K., S. M., S. Malini and V. S. M., Isolation, Purification, and Characterization of Fungal Laccase from <i>Pleurotus</i> sp., Enzyme Research, vol. 2011, pp. 1-7, 2011. Available: 10.4061/2011/248735 [Accessed 4 May 2022].R. Bourbonnais, D. Leech and M. Paice, "Electrochemical analysis of the interactions of laccase mediators with lignin model compounds", Biochimica et Biophysica Acta (BBA) - General Subjects, vol. 1379, no. 3, pp. 381-390, 1998. Available: 10.1016/s0304-4165(97)00117-7 [Accessed 4 May 2022].L. St»hle and S. Wold, Analysis of variance (ANOVA), Chemometrics and Intelligent Laboratory Systems, vol. 6, no. 4, pp. 259-272, 1989. Available: 10.1016/0169-7439(89)80095-4 [Accessed 4 May 2022].H. Thompson, R. Mera and C. Prasad, The Analysis of Variance (ANOVA), Nutritional Neuroscience, vol. 2, no. 1, pp. 43-55, 1999. Available: 10.1080/1028415x.1999.11747262 [Accessed 4 May 2022].J. Kerry, Aluminium foil packaging, Packaging Technology, pp. 163-177, 2012. Available: 10.1533/9780857095701.2.163 [Accessed 9 May 2022].A. Campaña, A. Guillén, R. Rivas, V. Akle, J. Cruz and J. Osma, Functionalization and Evaluation of Inorganic Adsorbents for the Removal of Cadmium in Wastewater, Molecules, vol. 26, no. 14, p. 4150, 2021. 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