Processing of thermoplastic elastomers (TPE) by in-situ ground tire rubber (GTR) vulcanization using waste ethylene-vinyl-acetate (wEVA) and dicumyl peroxide (DCP)

Tire rubber waste (TRW) is a complex mixture of materials, such as rubbers, steel, textile fibers, carbon black, and other additives. Its polluting capacity is a severe environmental problem, especially in landfills and waste management processes. As a practical solution to mitigate TRW’s environmen...

Full description

Autores:
Suarez Loor, J.
Lazo, M.
Rigail, A.
Adrian, E.
Vera, J.
Tipo de recurso:
Conferencia (Ponencia)
Fecha de publicación:
2024
Institución:
Universidad de los Andes
Repositorio:
Séneca: repositorio Uniandes
Idioma:
eng
OAI Identifier:
oai:repositorio.uniandes.edu.co:1992/76055
Acceso en línea:
https://hdl.handle.net/1992/76055
https://doi.org/10.51573/Andes.PPS39.GS.RE.2
https://repositorio.uniandes.edu.co/
Palabra clave:
Thermoplastic Elastomers, , ,
Vulcanization
Waste Plastic
Ground Tire Rubber
Ingeniería
Rights
openAccess
License
https://repositorio.uniandes.edu.co/static/pdf/aceptacion_uso_es.pdf
id UNIANDES2_68548273cdf0b61901dc5c49f299d654
oai_identifier_str oai:repositorio.uniandes.edu.co:1992/76055
network_acronym_str UNIANDES2
network_name_str Séneca: repositorio Uniandes
repository_id_str
dc.title.eng.fl_str_mv Processing of thermoplastic elastomers (TPE) by in-situ ground tire rubber (GTR) vulcanization using waste ethylene-vinyl-acetate (wEVA) and dicumyl peroxide (DCP)
title Processing of thermoplastic elastomers (TPE) by in-situ ground tire rubber (GTR) vulcanization using waste ethylene-vinyl-acetate (wEVA) and dicumyl peroxide (DCP)
spellingShingle Processing of thermoplastic elastomers (TPE) by in-situ ground tire rubber (GTR) vulcanization using waste ethylene-vinyl-acetate (wEVA) and dicumyl peroxide (DCP)
Thermoplastic Elastomers, , ,
Vulcanization
Waste Plastic
Ground Tire Rubber
Ingeniería
title_short Processing of thermoplastic elastomers (TPE) by in-situ ground tire rubber (GTR) vulcanization using waste ethylene-vinyl-acetate (wEVA) and dicumyl peroxide (DCP)
title_full Processing of thermoplastic elastomers (TPE) by in-situ ground tire rubber (GTR) vulcanization using waste ethylene-vinyl-acetate (wEVA) and dicumyl peroxide (DCP)
title_fullStr Processing of thermoplastic elastomers (TPE) by in-situ ground tire rubber (GTR) vulcanization using waste ethylene-vinyl-acetate (wEVA) and dicumyl peroxide (DCP)
title_full_unstemmed Processing of thermoplastic elastomers (TPE) by in-situ ground tire rubber (GTR) vulcanization using waste ethylene-vinyl-acetate (wEVA) and dicumyl peroxide (DCP)
title_sort Processing of thermoplastic elastomers (TPE) by in-situ ground tire rubber (GTR) vulcanization using waste ethylene-vinyl-acetate (wEVA) and dicumyl peroxide (DCP)
dc.creator.fl_str_mv Suarez Loor, J.
Lazo, M.
Rigail, A.
Adrian, E.
Vera, J.
dc.contributor.author.none.fl_str_mv Suarez Loor, J.
Lazo, M.
Rigail, A.
Adrian, E.
Vera, J.
dc.contributor.editor.none.fl_str_mv Salcedo, Felipe
Perilla, Jairo Ernesto
Sierra, Cesar
Medina, Jorge Alberto
dc.subject.keyword.eng.fl_str_mv Thermoplastic Elastomers, , ,
Vulcanization
Waste Plastic
Ground Tire Rubber
topic Thermoplastic Elastomers, , ,
Vulcanization
Waste Plastic
Ground Tire Rubber
Ingeniería
dc.subject.themes.none.fl_str_mv Ingeniería
description Tire rubber waste (TRW) is a complex mixture of materials, such as rubbers, steel, textile fibers, carbon black, and other additives. Its polluting capacity is a severe environmental problem, especially in landfills and waste management processes. As a practical solution to mitigate TRW’s environmental impact, thermoplastic elastomers (TPE) commonly reuse the ground tire rubber (GTR). This work presents an in-situ devulcanization of ground tire rubber (DGTR) and re-vulcanization of devulcanized ground tire rubber using dicumyl peroxide (DCP) and waste ethylene-vinyl-acetate (wEVA). The GTR was devulcanized through thermo-mechanical action and then blended with waste ethylene-vinyl-acetate (wEVA) and dicumyl peroxide (DCP) to produce the thermoplastic elastomer (TPE). This blending process was monitored using a torque rheometer and analyzed with differential scanning calorimetry (DSC) to evaluate the crosslinking reactions and kinetic behavior. The results indicated that in-situ vulcanization took place within the rheometer mixing chamber, evidenced by an increase in torque. DSC analysis of the DGTR-DCP-wEVA system confirmed the curing reaction prior to vulcanization. The resulting in-situ vulcanized TPE ensures improved component adhesion. This research offers practical insights into a scalable, non-advanced process for local plastics industries in developing countries to incorporate vulcanized TPEs, thereby enhancing their knowledge and understanding of this innovative approach.
publishDate 2024
dc.date.issued.none.fl_str_mv 2024-12
dc.date.accessioned.none.fl_str_mv 2025-02-07T19:34:40Z
dc.date.available.none.fl_str_mv 2025-02-07T19:34:40Z
dc.type.none.fl_str_mv Documento de Conferencia
dc.type.coar.fl_str_mv http://purl.org/coar/resource_type/c_c94f
dc.type.driver.none.fl_str_mv info:eu-repo/semantics/conferenceObject
dc.type.version.none.fl_str_mv info:eu-repo/semantics/publishedVersion
dc.type.coar.none.fl_str_mv http://purl.org/coar/resource_type/c_8544
dc.type.coarversion.none.fl_str_mv http://purl.org/coar/version/c_970fb48d4fbd8a85
dc.type.content.none.fl_str_mv Text
format http://purl.org/coar/resource_type/c_8544
status_str publishedVersion
dc.identifier.isbn.none.fl_str_mv 978-958-798-779-9
dc.identifier.uri.none.fl_str_mv https://hdl.handle.net/1992/76055
dc.identifier.doi.none.fl_str_mv https://doi.org/10.51573/Andes.PPS39.GS.RE.2
dc.identifier.instname.none.fl_str_mv Universidad de los Andes
dc.identifier.reponame.none.fl_str_mv Repositorio Institucional Séneca
dc.identifier.repourl.none.fl_str_mv https://repositorio.uniandes.edu.co/
identifier_str_mv 978-958-798-779-9
Universidad de los Andes
Repositorio Institucional Séneca
url https://hdl.handle.net/1992/76055
https://doi.org/10.51573/Andes.PPS39.GS.RE.2
https://repositorio.uniandes.edu.co/
dc.language.iso.none.fl_str_mv eng
language eng
dc.relation.conferencedate.none.fl_str_mv 05-19-2024/05-23-2024
dc.relation.conferenceplace.none.fl_str_mv Cartagena de Indias, Colombia
dc.relation.ispartofconference.none.fl_str_mv Proceedings of the 39th International Conference of the Polymer Processing Society (PPS-39)
dc.rights.uri.none.fl_str_mv https://repositorio.uniandes.edu.co/static/pdf/aceptacion_uso_es.pdf
dc.rights.accessrights.none.fl_str_mv info:eu-repo/semantics/openAccess
dc.rights.coar.none.fl_str_mv http://purl.org/coar/access_right/c_abf2
rights_invalid_str_mv https://repositorio.uniandes.edu.co/static/pdf/aceptacion_uso_es.pdf
http://purl.org/coar/access_right/c_abf2
eu_rights_str_mv openAccess
dc.format.extent.none.fl_str_mv 9 páginas
dc.format.mimetype.none.fl_str_mv application/pdf
dc.publisher.none.fl_str_mv Ediciones Uniandes
dc.publisher.faculty.none.fl_str_mv Facultad de Ingeniería
dc.publisher.place.none.fl_str_mv Bogotá
publisher.none.fl_str_mv Ediciones Uniandes
institution Universidad de los Andes
bitstream.url.fl_str_mv https://repositorio.uniandes.edu.co/bitstreams/cf0ca74c-1300-4b48-bb37-e8ca2e2e3e3d/download
https://repositorio.uniandes.edu.co/bitstreams/895cfe5a-71e3-40fd-b484-a26d672008c0/download
https://repositorio.uniandes.edu.co/bitstreams/6354bfe1-7023-4458-aca3-3fa8e1c0f36d/download
https://repositorio.uniandes.edu.co/bitstreams/1e0790a3-309c-42d3-87e9-782f7aa8f803/download
https://repositorio.uniandes.edu.co/bitstreams/656f1183-326c-470e-9c70-231453a859a6/download
https://repositorio.uniandes.edu.co/bitstreams/55202e59-00a7-4f84-b1c8-97434d06ba28/download
https://repositorio.uniandes.edu.co/bitstreams/16443d80-7463-47d6-8dab-19b0bb307d20/download
bitstream.checksum.fl_str_mv 34b9b5fd0c4b6822b649c42b761d169a
eda70aa6b69e9d97e691f113b8724458
ae9e573a68e7f92501b6913cc846c39f
3a7a314d6f27d0cd5a55822d9df9881d
79fc1ef0101ac359ebdd7668343c0382
e7b5d9b561afa3941d32f19dc26fdea5
1700c0cecca456afc84d986ca115924e
bitstream.checksumAlgorithm.fl_str_mv MD5
MD5
MD5
MD5
MD5
MD5
MD5
repository.name.fl_str_mv Repositorio institucional Séneca
repository.mail.fl_str_mv adminrepositorio@uniandes.edu.co
_version_ 1828159230572494848
spelling Suarez Loor, J.Lazo, M.Rigail, A.Adrian, E.Vera, J.Salcedo, FelipePerilla, Jairo ErnestoSierra, CesarMedina, Jorge Alberto2025-02-07T19:34:40Z2025-02-07T19:34:40Z2024-12978-958-798-779-9https://hdl.handle.net/1992/76055https://doi.org/10.51573/Andes.PPS39.GS.RE.2Universidad de los AndesRepositorio Institucional Sénecahttps://repositorio.uniandes.edu.co/Tire rubber waste (TRW) is a complex mixture of materials, such as rubbers, steel, textile fibers, carbon black, and other additives. Its polluting capacity is a severe environmental problem, especially in landfills and waste management processes. As a practical solution to mitigate TRW’s environmental impact, thermoplastic elastomers (TPE) commonly reuse the ground tire rubber (GTR). This work presents an in-situ devulcanization of ground tire rubber (DGTR) and re-vulcanization of devulcanized ground tire rubber using dicumyl peroxide (DCP) and waste ethylene-vinyl-acetate (wEVA). The GTR was devulcanized through thermo-mechanical action and then blended with waste ethylene-vinyl-acetate (wEVA) and dicumyl peroxide (DCP) to produce the thermoplastic elastomer (TPE). This blending process was monitored using a torque rheometer and analyzed with differential scanning calorimetry (DSC) to evaluate the crosslinking reactions and kinetic behavior. The results indicated that in-situ vulcanization took place within the rheometer mixing chamber, evidenced by an increase in torque. DSC analysis of the DGTR-DCP-wEVA system confirmed the curing reaction prior to vulcanization. The resulting in-situ vulcanized TPE ensures improved component adhesion. This research offers practical insights into a scalable, non-advanced process for local plastics industries in developing countries to incorporate vulcanized TPEs, thereby enhancing their knowledge and understanding of this innovative approach.9 páginasapplication/pdfengEdiciones UniandesFacultad de IngenieríaBogotáhttps://repositorio.uniandes.edu.co/static/pdf/aceptacion_uso_es.pdfinfo:eu-repo/semantics/openAccesshttp://purl.org/coar/access_right/c_abf2Processing of thermoplastic elastomers (TPE) by in-situ ground tire rubber (GTR) vulcanization using waste ethylene-vinyl-acetate (wEVA) and dicumyl peroxide (DCP)Documento de Conferenciainfo:eu-repo/semantics/conferenceObjectinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_8544http://purl.org/coar/resource_type/c_c94fhttp://purl.org/coar/version/c_970fb48d4fbd8a85TextThermoplastic Elastomers, , ,VulcanizationWaste PlasticGround Tire RubberIngeniería05-19-2024/05-23-2024Cartagena de Indias, ColombiaProceedings of the 39th International Conference of the Polymer Processing Society (PPS-39)ORIGINALPPS-39 - Processing of Thermoplastic Elastomers (TPE) by In-Situ Ground Tire Rubber (GTR) Vulcanization using Waste Ethylene-Vinyl-Acetate (wEVA) a.pdfPPS-39 - Processing of Thermoplastic Elastomers (TPE) by In-Situ Ground Tire Rubber (GTR) Vulcanization using Waste Ethylene-Vinyl-Acetate (wEVA) a.pdfapplication/pdf1049374https://repositorio.uniandes.edu.co/bitstreams/cf0ca74c-1300-4b48-bb37-e8ca2e2e3e3d/download34b9b5fd0c4b6822b649c42b761d169aMD51S17_260_LICENCIA Processing of thermoplastic elastomers.pdfHIDEapplication/pdf37882https://repositorio.uniandes.edu.co/bitstreams/895cfe5a-71e3-40fd-b484-a26d672008c0/downloadeda70aa6b69e9d97e691f113b8724458MD55LICENSElicense.txtlicense.txttext/plain; charset=utf-82535https://repositorio.uniandes.edu.co/bitstreams/6354bfe1-7023-4458-aca3-3fa8e1c0f36d/downloadae9e573a68e7f92501b6913cc846c39fMD52TEXTPPS-39 - Processing of Thermoplastic Elastomers (TPE) by In-Situ Ground Tire Rubber (GTR) Vulcanization using Waste Ethylene-Vinyl-Acetate (wEVA) a.pdf.txtPPS-39 - Processing of Thermoplastic Elastomers (TPE) by In-Situ Ground Tire Rubber (GTR) Vulcanization using Waste Ethylene-Vinyl-Acetate (wEVA) a.pdf.txtExtracted texttext/plain20487https://repositorio.uniandes.edu.co/bitstreams/1e0790a3-309c-42d3-87e9-782f7aa8f803/download3a7a314d6f27d0cd5a55822d9df9881dMD53S17_260_LICENCIA Processing of thermoplastic elastomers.pdf.txtS17_260_LICENCIA Processing of thermoplastic elastomers.pdf.txtExtracted texttext/plain2177https://repositorio.uniandes.edu.co/bitstreams/656f1183-326c-470e-9c70-231453a859a6/download79fc1ef0101ac359ebdd7668343c0382MD56THUMBNAILPPS-39 - Processing of Thermoplastic Elastomers (TPE) by In-Situ Ground Tire Rubber (GTR) Vulcanization using Waste Ethylene-Vinyl-Acetate (wEVA) a.pdf.jpgPPS-39 - Processing of Thermoplastic Elastomers (TPE) by In-Situ Ground Tire Rubber (GTR) Vulcanization using Waste Ethylene-Vinyl-Acetate (wEVA) a.pdf.jpgGenerated Thumbnailimage/jpeg8590https://repositorio.uniandes.edu.co/bitstreams/55202e59-00a7-4f84-b1c8-97434d06ba28/downloade7b5d9b561afa3941d32f19dc26fdea5MD54S17_260_LICENCIA Processing of thermoplastic elastomers.pdf.jpgS17_260_LICENCIA Processing of thermoplastic elastomers.pdf.jpgGenerated Thumbnailimage/jpeg13281https://repositorio.uniandes.edu.co/bitstreams/16443d80-7463-47d6-8dab-19b0bb307d20/download1700c0cecca456afc84d986ca115924eMD571992/76055oai:repositorio.uniandes.edu.co:1992/760552025-03-05 10:11:57.551https://repositorio.uniandes.edu.co/static/pdf/aceptacion_uso_es.pdfopen.accesshttps://repositorio.uniandes.edu.coRepositorio institucional Sénecaadminrepositorio@uniandes.edu.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