Estudio del comportamiento visco-elástico de emulsiones inversas concentradas y altamente concentradas a través de un enfoque multiescala
In this study highly concentrated inverse emulsions (W/O) were characterized by using a multiscale approach. For this, the surfactants Span 80 and Tween 20 were used and the procedures were done with a concentration range of 70-90 (%/w). Likewise, the behavior was measured in macroscopic and molecul...
- Autores:
-
Velandia Rodríguez, Santiago Felipe
- Tipo de recurso:
- Trabajo de grado de pregrado
- Fecha de publicación:
- 2017
- Institución:
- Universidad de los Andes
- Repositorio:
- Séneca: repositorio Uniandes
- Idioma:
- spa
- OAI Identifier:
- oai:repositorio.uniandes.edu.co:1992/61172
- Acceso en línea:
- http://hdl.handle.net/1992/61172
- Palabra clave:
- Agentes tensoactivos
Emulsiones
- Rights
- openAccess
- License
- http://creativecommons.org/licenses/by-nc-nd/4.0/
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Al consultar y hacer uso de este recurso, está aceptando las condiciones de uso establecidas por los autores.http://creativecommons.org/licenses/by-nc-nd/4.0/info:eu-repo/semantics/openAccesshttp://purl.org/coar/access_right/c_abf2Álvarez Solano, Óscar Albertoeb205ea7-e16b-4eae-a3be-d14a7082691d400Velandia Rodríguez, Santiago Feliped47b823e-7ca5-4d7b-af74-26b2de4ac88c500Pradilla Raguá, Diego Camilo2022-09-26T22:10:57Z2022-09-26T22:10:57Z2017http://hdl.handle.net/1992/61172instname:Universidad de los Andesreponame:Repositorio Institucional Sénecarepourl:https://repositorio.uniandes.edu.co/794821-1001In this study highly concentrated inverse emulsions (W/O) were characterized by using a multiscale approach. For this, the surfactants Span 80 and Tween 20 were used and the procedures were done with a concentration range of 70-90 (%/w). Likewise, the behavior was measured in macroscopic and molecular scale, at an interfacial level, and the variation of disperse phase concentration over the properties in both scales was studied. Emulsions were characterized in terms of their modules G' and G'' for the macro scale, the interfacial modules G' and G'' and the interfacial tension for the molecular scale. The results showed that elastic response predominates over viscous response in highly concentrated inverse emulsions. Besides, the same behavior was confirmed as in the emulsion and the fluids interface. In addition, it was found that, given an increase in the dispersed phase in the system, there is an increase in the value of G' for the macroscopic and molecular scale.En este trabajo se caracterizaron emulsiones inversas (W/O) a altas concentraciones por medio de un enfoque multiescala. Para esto, se utilizaron los surfactantes Span 80 y Tween 20 y se trabajó en un rango de concentraciones de 70-90 (%p/p). Del mismo modo, se evaluó el comportamiento en escalas macroscópica y molecular, a nivel interfacial, y se estudió el efecto de la variación en concentración de fase dispersa sobre las propiedades de ambas escalas. Las emulsiones fueron caracterizadas en términos de sus módulos G' y G'' para la escala macro, los módulos interfaciales G' y G'' y la tensión interfacial a escala molecular. Los resultados encontrados permiten identificar que para sistemas de emulsiones inversas a altas concentraciones la respuesta elástica predomina sobre la respuesta viscosa. Además, el mismo comportamiento se confirmó tanto en la emulsión como en la interfase entre fluidos. También, se encontró que, ante un aumento de la fase dispersa en el sistema, hay un aumento en el valor de G' para la escala macroscópica y molecular...Ingeniero QuímicoPregrado9 hojasapplication/pdfspaUniversidad de los AndesIngeniería QuímicaFacultad de IngenieríaDepartamento de Ingeniería Química y de AlimentosEstudio del comportamiento visco-elástico de emulsiones inversas concentradas y altamente concentradas a través de un enfoque multiescalaTrabajo de grado - Pregradoinfo:eu-repo/semantics/bachelorThesisinfo:eu-repo/semantics/acceptedVersionhttp://purl.org/coar/resource_type/c_7a1fTexthttp://purl.org/redcol/resource_type/TPAgentes tensoactivosEmulsiones201327881PublicationORIGINAL12408.pdfapplication/pdf1201939https://repositorio.uniandes.edu.co/bitstreams/a6391da1-1205-4fbf-afcb-3de309e68744/downloadd7d0b31794e62bf38359c1ad40fe80afMD51TEXT12408.pdf.txt12408.pdf.txtExtracted texttext/plain28515https://repositorio.uniandes.edu.co/bitstreams/75f0835e-03b7-4111-b6d5-d7ad30856fe0/download55fedc2c72f2ff58c7babc0b32c8fa3aMD52THUMBNAIL12408.pdf.jpg12408.pdf.jpgIM Thumbnailimage/jpeg30767https://repositorio.uniandes.edu.co/bitstreams/fd976eea-2847-4ce7-95b8-7407d87a7b87/downloadafe615bb9af38270584bac957c31dfbeMD531992/61172oai:repositorio.uniandes.edu.co:1992/611722023-10-10 16:43:53.515http://creativecommons.org/licenses/by-nc-nd/4.0/open.accesshttps://repositorio.uniandes.edu.coRepositorio institucional Sénecaadminrepositorio@uniandes.edu.co |
dc.title.spa.fl_str_mv |
Estudio del comportamiento visco-elástico de emulsiones inversas concentradas y altamente concentradas a través de un enfoque multiescala |
title |
Estudio del comportamiento visco-elástico de emulsiones inversas concentradas y altamente concentradas a través de un enfoque multiescala |
spellingShingle |
Estudio del comportamiento visco-elástico de emulsiones inversas concentradas y altamente concentradas a través de un enfoque multiescala Agentes tensoactivos Emulsiones |
title_short |
Estudio del comportamiento visco-elástico de emulsiones inversas concentradas y altamente concentradas a través de un enfoque multiescala |
title_full |
Estudio del comportamiento visco-elástico de emulsiones inversas concentradas y altamente concentradas a través de un enfoque multiescala |
title_fullStr |
Estudio del comportamiento visco-elástico de emulsiones inversas concentradas y altamente concentradas a través de un enfoque multiescala |
title_full_unstemmed |
Estudio del comportamiento visco-elástico de emulsiones inversas concentradas y altamente concentradas a través de un enfoque multiescala |
title_sort |
Estudio del comportamiento visco-elástico de emulsiones inversas concentradas y altamente concentradas a través de un enfoque multiescala |
dc.creator.fl_str_mv |
Velandia Rodríguez, Santiago Felipe |
dc.contributor.advisor.none.fl_str_mv |
Álvarez Solano, Óscar Alberto |
dc.contributor.author.none.fl_str_mv |
Velandia Rodríguez, Santiago Felipe |
dc.contributor.jury.none.fl_str_mv |
Pradilla Raguá, Diego Camilo |
dc.subject.keyword.spa.fl_str_mv |
Agentes tensoactivos Emulsiones |
topic |
Agentes tensoactivos Emulsiones |
description |
In this study highly concentrated inverse emulsions (W/O) were characterized by using a multiscale approach. For this, the surfactants Span 80 and Tween 20 were used and the procedures were done with a concentration range of 70-90 (%/w). Likewise, the behavior was measured in macroscopic and molecular scale, at an interfacial level, and the variation of disperse phase concentration over the properties in both scales was studied. Emulsions were characterized in terms of their modules G' and G'' for the macro scale, the interfacial modules G' and G'' and the interfacial tension for the molecular scale. The results showed that elastic response predominates over viscous response in highly concentrated inverse emulsions. Besides, the same behavior was confirmed as in the emulsion and the fluids interface. In addition, it was found that, given an increase in the dispersed phase in the system, there is an increase in the value of G' for the macroscopic and molecular scale. |
publishDate |
2017 |
dc.date.issued.spa.fl_str_mv |
2017 |
dc.date.accessioned.none.fl_str_mv |
2022-09-26T22:10:57Z |
dc.date.available.none.fl_str_mv |
2022-09-26T22:10:57Z |
dc.type.spa.fl_str_mv |
Trabajo de grado - Pregrado |
dc.type.driver.spa.fl_str_mv |
info:eu-repo/semantics/bachelorThesis |
dc.type.version.spa.fl_str_mv |
info:eu-repo/semantics/acceptedVersion |
dc.type.coar.spa.fl_str_mv |
http://purl.org/coar/resource_type/c_7a1f |
dc.type.content.spa.fl_str_mv |
Text |
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http://purl.org/redcol/resource_type/TP |
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http://purl.org/coar/resource_type/c_7a1f |
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acceptedVersion |
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http://hdl.handle.net/1992/61172 |
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instname:Universidad de los Andes |
dc.identifier.reponame.spa.fl_str_mv |
reponame:Repositorio Institucional Séneca |
dc.identifier.repourl.spa.fl_str_mv |
repourl:https://repositorio.uniandes.edu.co/ |
dc.identifier.local.spa.fl_str_mv |
794821-1001 |
url |
http://hdl.handle.net/1992/61172 |
identifier_str_mv |
instname:Universidad de los Andes reponame:Repositorio Institucional Séneca repourl:https://repositorio.uniandes.edu.co/ 794821-1001 |
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spa |
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spa |
dc.rights.uri.*.fl_str_mv |
http://creativecommons.org/licenses/by-nc-nd/4.0/ |
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info:eu-repo/semantics/openAccess |
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openAccess |
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9 hojas |
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application/pdf |
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Universidad de los Andes |
dc.publisher.program.spa.fl_str_mv |
Ingeniería Química |
dc.publisher.faculty.spa.fl_str_mv |
Facultad de Ingeniería |
dc.publisher.department.spa.fl_str_mv |
Departamento de Ingeniería Química y de Alimentos |
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Universidad de los Andes |
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