Estudio del comportamiento visco-elástico de emulsiones inversas concentradas y altamente concentradas a través de un enfoque multiescala

In this study highly concentrated inverse emulsions (W/O) were characterized by using a multiscale approach. For this, the surfactants Span 80 and Tween 20 were used and the procedures were done with a concentration range of 70-90 (%/w). Likewise, the behavior was measured in macroscopic and molecul...

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Autores:
Velandia Rodríguez, Santiago Felipe
Tipo de recurso:
Trabajo de grado de pregrado
Fecha de publicación:
2017
Institución:
Universidad de los Andes
Repositorio:
Séneca: repositorio Uniandes
Idioma:
spa
OAI Identifier:
oai:repositorio.uniandes.edu.co:1992/61172
Acceso en línea:
http://hdl.handle.net/1992/61172
Palabra clave:
Agentes tensoactivos
Emulsiones
Rights
openAccess
License
http://creativecommons.org/licenses/by-nc-nd/4.0/
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spelling Al consultar y hacer uso de este recurso, está aceptando las condiciones de uso establecidas por los autores.http://creativecommons.org/licenses/by-nc-nd/4.0/info:eu-repo/semantics/openAccesshttp://purl.org/coar/access_right/c_abf2Álvarez Solano, Óscar Albertoeb205ea7-e16b-4eae-a3be-d14a7082691d400Velandia Rodríguez, Santiago Feliped47b823e-7ca5-4d7b-af74-26b2de4ac88c500Pradilla Raguá, Diego Camilo2022-09-26T22:10:57Z2022-09-26T22:10:57Z2017http://hdl.handle.net/1992/61172instname:Universidad de los Andesreponame:Repositorio Institucional Sénecarepourl:https://repositorio.uniandes.edu.co/794821-1001In this study highly concentrated inverse emulsions (W/O) were characterized by using a multiscale approach. For this, the surfactants Span 80 and Tween 20 were used and the procedures were done with a concentration range of 70-90 (%/w). Likewise, the behavior was measured in macroscopic and molecular scale, at an interfacial level, and the variation of disperse phase concentration over the properties in both scales was studied. Emulsions were characterized in terms of their modules G' and G'' for the macro scale, the interfacial modules G' and G'' and the interfacial tension for the molecular scale. The results showed that elastic response predominates over viscous response in highly concentrated inverse emulsions. Besides, the same behavior was confirmed as in the emulsion and the fluids interface. In addition, it was found that, given an increase in the dispersed phase in the system, there is an increase in the value of G' for the macroscopic and molecular scale.En este trabajo se caracterizaron emulsiones inversas (W/O) a altas concentraciones por medio de un enfoque multiescala. Para esto, se utilizaron los surfactantes Span 80 y Tween 20 y se trabajó en un rango de concentraciones de 70-90 (%p/p). Del mismo modo, se evaluó el comportamiento en escalas macroscópica y molecular, a nivel interfacial, y se estudió el efecto de la variación en concentración de fase dispersa sobre las propiedades de ambas escalas. Las emulsiones fueron caracterizadas en términos de sus módulos G' y G'' para la escala macro, los módulos interfaciales G' y G'' y la tensión interfacial a escala molecular. Los resultados encontrados permiten identificar que para sistemas de emulsiones inversas a altas concentraciones la respuesta elástica predomina sobre la respuesta viscosa. Además, el mismo comportamiento se confirmó tanto en la emulsión como en la interfase entre fluidos. También, se encontró que, ante un aumento de la fase dispersa en el sistema, hay un aumento en el valor de G' para la escala macroscópica y molecular...Ingeniero QuímicoPregrado9 hojasapplication/pdfspaUniversidad de los AndesIngeniería QuímicaFacultad de IngenieríaDepartamento de Ingeniería Química y de AlimentosEstudio del comportamiento visco-elástico de emulsiones inversas concentradas y altamente concentradas a través de un enfoque multiescalaTrabajo de grado - Pregradoinfo:eu-repo/semantics/bachelorThesisinfo:eu-repo/semantics/acceptedVersionhttp://purl.org/coar/resource_type/c_7a1fTexthttp://purl.org/redcol/resource_type/TPAgentes tensoactivosEmulsiones201327881PublicationORIGINAL12408.pdfapplication/pdf1201939https://repositorio.uniandes.edu.co/bitstreams/a6391da1-1205-4fbf-afcb-3de309e68744/downloadd7d0b31794e62bf38359c1ad40fe80afMD51TEXT12408.pdf.txt12408.pdf.txtExtracted texttext/plain28515https://repositorio.uniandes.edu.co/bitstreams/75f0835e-03b7-4111-b6d5-d7ad30856fe0/download55fedc2c72f2ff58c7babc0b32c8fa3aMD52THUMBNAIL12408.pdf.jpg12408.pdf.jpgIM Thumbnailimage/jpeg30767https://repositorio.uniandes.edu.co/bitstreams/fd976eea-2847-4ce7-95b8-7407d87a7b87/downloadafe615bb9af38270584bac957c31dfbeMD531992/61172oai:repositorio.uniandes.edu.co:1992/611722023-10-10 16:43:53.515http://creativecommons.org/licenses/by-nc-nd/4.0/open.accesshttps://repositorio.uniandes.edu.coRepositorio institucional Sénecaadminrepositorio@uniandes.edu.co
dc.title.spa.fl_str_mv Estudio del comportamiento visco-elástico de emulsiones inversas concentradas y altamente concentradas a través de un enfoque multiescala
title Estudio del comportamiento visco-elástico de emulsiones inversas concentradas y altamente concentradas a través de un enfoque multiescala
spellingShingle Estudio del comportamiento visco-elástico de emulsiones inversas concentradas y altamente concentradas a través de un enfoque multiescala
Agentes tensoactivos
Emulsiones
title_short Estudio del comportamiento visco-elástico de emulsiones inversas concentradas y altamente concentradas a través de un enfoque multiescala
title_full Estudio del comportamiento visco-elástico de emulsiones inversas concentradas y altamente concentradas a través de un enfoque multiescala
title_fullStr Estudio del comportamiento visco-elástico de emulsiones inversas concentradas y altamente concentradas a través de un enfoque multiescala
title_full_unstemmed Estudio del comportamiento visco-elástico de emulsiones inversas concentradas y altamente concentradas a través de un enfoque multiescala
title_sort Estudio del comportamiento visco-elástico de emulsiones inversas concentradas y altamente concentradas a través de un enfoque multiescala
dc.creator.fl_str_mv Velandia Rodríguez, Santiago Felipe
dc.contributor.advisor.none.fl_str_mv Álvarez Solano, Óscar Alberto
dc.contributor.author.none.fl_str_mv Velandia Rodríguez, Santiago Felipe
dc.contributor.jury.none.fl_str_mv Pradilla Raguá, Diego Camilo
dc.subject.keyword.spa.fl_str_mv Agentes tensoactivos
Emulsiones
topic Agentes tensoactivos
Emulsiones
description In this study highly concentrated inverse emulsions (W/O) were characterized by using a multiscale approach. For this, the surfactants Span 80 and Tween 20 were used and the procedures were done with a concentration range of 70-90 (%/w). Likewise, the behavior was measured in macroscopic and molecular scale, at an interfacial level, and the variation of disperse phase concentration over the properties in both scales was studied. Emulsions were characterized in terms of their modules G' and G'' for the macro scale, the interfacial modules G' and G'' and the interfacial tension for the molecular scale. The results showed that elastic response predominates over viscous response in highly concentrated inverse emulsions. Besides, the same behavior was confirmed as in the emulsion and the fluids interface. In addition, it was found that, given an increase in the dispersed phase in the system, there is an increase in the value of G' for the macroscopic and molecular scale.
publishDate 2017
dc.date.issued.spa.fl_str_mv 2017
dc.date.accessioned.none.fl_str_mv 2022-09-26T22:10:57Z
dc.date.available.none.fl_str_mv 2022-09-26T22:10:57Z
dc.type.spa.fl_str_mv Trabajo de grado - Pregrado
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dc.publisher.spa.fl_str_mv Universidad de los Andes
dc.publisher.program.spa.fl_str_mv Ingeniería Química
dc.publisher.faculty.spa.fl_str_mv Facultad de Ingeniería
dc.publisher.department.spa.fl_str_mv Departamento de Ingeniería Química y de Alimentos
institution Universidad de los Andes
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