Obtención de BHET a partir de residuos de botellas plásticas de PET mediante glicólisis catalizada con ceniza de cáscara de naranja

Se realizó la depolimerización de PET post consumo a partir de glicólisis catalizada con residuos de cáscara de naranja. Se obtuvo BHET, el cual puede ser utilizado como materia prima para la polimerización de plásticos. Se realizaron diferentes caracterizaciones al material obtenido el cual fue com...

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Autores:
Ayalde Valderrama, Manuela
Tipo de recurso:
Trabajo de grado de pregrado
Fecha de publicación:
2022
Institución:
Universidad de los Andes
Repositorio:
Séneca: repositorio Uniandes
Idioma:
spa
OAI Identifier:
oai:repositorio.uniandes.edu.co:1992/60421
Acceso en línea:
http://hdl.handle.net/1992/60421
Palabra clave:
Reciclaje químico
Glicólisis
PET
BHET
FTIR
Ingeniería
Rights
openAccess
License
Atribución 4.0 Internacional
id UNIANDES2_53fa55b1185b4a6b425a04b07d5930e9
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dc.title.none.fl_str_mv Obtención de BHET a partir de residuos de botellas plásticas de PET mediante glicólisis catalizada con ceniza de cáscara de naranja
title Obtención de BHET a partir de residuos de botellas plásticas de PET mediante glicólisis catalizada con ceniza de cáscara de naranja
spellingShingle Obtención de BHET a partir de residuos de botellas plásticas de PET mediante glicólisis catalizada con ceniza de cáscara de naranja
Reciclaje químico
Glicólisis
PET
BHET
FTIR
Ingeniería
title_short Obtención de BHET a partir de residuos de botellas plásticas de PET mediante glicólisis catalizada con ceniza de cáscara de naranja
title_full Obtención de BHET a partir de residuos de botellas plásticas de PET mediante glicólisis catalizada con ceniza de cáscara de naranja
title_fullStr Obtención de BHET a partir de residuos de botellas plásticas de PET mediante glicólisis catalizada con ceniza de cáscara de naranja
title_full_unstemmed Obtención de BHET a partir de residuos de botellas plásticas de PET mediante glicólisis catalizada con ceniza de cáscara de naranja
title_sort Obtención de BHET a partir de residuos de botellas plásticas de PET mediante glicólisis catalizada con ceniza de cáscara de naranja
dc.creator.fl_str_mv Ayalde Valderrama, Manuela
dc.contributor.advisor.none.fl_str_mv Salcedo Galán, Felipe
dc.contributor.author.none.fl_str_mv Ayalde Valderrama, Manuela
dc.subject.keyword.none.fl_str_mv Reciclaje químico
Glicólisis
PET
BHET
FTIR
topic Reciclaje químico
Glicólisis
PET
BHET
FTIR
Ingeniería
dc.subject.themes.es_CO.fl_str_mv Ingeniería
description Se realizó la depolimerización de PET post consumo a partir de glicólisis catalizada con residuos de cáscara de naranja. Se obtuvo BHET, el cual puede ser utilizado como materia prima para la polimerización de plásticos. Se realizaron diferentes caracterizaciones al material obtenido el cual fue comparado con BHET comercial.
publishDate 2022
dc.date.accessioned.none.fl_str_mv 2022-09-05T16:20:07Z
dc.date.available.none.fl_str_mv 2022-09-05T16:20:07Z
dc.date.issued.none.fl_str_mv 2022-09-02
dc.type.es_CO.fl_str_mv Trabajo de grado - Pregrado
dc.type.driver.none.fl_str_mv info:eu-repo/semantics/bachelorThesis
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dc.identifier.uri.none.fl_str_mv http://hdl.handle.net/1992/60421
dc.identifier.instname.es_CO.fl_str_mv instname:Universidad de los Andes
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dc.language.iso.es_CO.fl_str_mv spa
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dc.relation.references.es_CO.fl_str_mv [1] A. L. Andrady and M. A. Neal, Applications and societal benefits of plastics, Philos. Trans. R. Soc. , 2009, doi: 10.1098/rstb.2008.0304.
[2] P. Clunies-Ross, Plastics in the Environment, R. Soc. Te Ap¿rangi, vol. 35, no. 4, pp. 230-230, 2019, doi: 10.2307/4444330.
[3] ASTM D883, Standard Terminology relating to Plastics, 2020.
[4] N. L. Thomas, J. Clarke, A. R. McLauchlin, and S. G. Patrick, Oxo-degradable plastics: Degradation, environmental impact and recycling, Proc. Inst. Civ. Eng. Waste Resour. Manag., vol. 165, no. 3, pp. 133-140, Aug. 2012, doi: 10.1680/WARM.11.00014.
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[8] A. D5338, Standard Test Method for Determining Aerobic Biodegradation of Plastic Materials Under Controlled Composting Conditions , Incorporating thermophilic temperatures, vol. 15, no. Reapproved, pp. 4-9, 2021, doi: 10.1520/D5338-15R21.Copyright.
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[23] F. I. Chowdhury, Sustainable resin systems for polymer composites, in Advances in Sustainable Polymer Composites, Woodhead Publishing, 2021, pp. 89-108.
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[25] A. M. Al-Sabagh, F. Z. Yehia, G. Eshaq, A. M. Rabie, and A. E. ElMetwally, Greener routes for recycling of polyethylene terephthalate, Egypt. J. Pet., vol. 25, no. 1, pp. 53-64, 2016, doi: 10.1016/j.ejpe.2015.03.001.
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[29] M. Han, Depolymerization of PET Bottle via Methanolysis and Hydrolysis, Recycl. Polyethyl. Terephthalate Bottles, pp. 85-108, Jan. 2019, doi: 10.1016/B978-0-12-811361-5.00005-5.
[30] S. D. Mancini and M. Zanin, Post consumer pet depolymerization by acid hydrolysis, Polym. - Plast. Technol. Eng., vol. 46, no. 2, pp. 135-144, Feb. 2007, doi: 10.1080/03602550601152945.
[31] M. J. Kang, H. J. Yu, J. Jegal, H. S. Kim, and H. G. Cha, Depolymerization of PET into terephthalic acid in neutral media catalyzed by the ZSM-5 acidic catalyst, Chem. Eng. J., vol. 398, no. May, p.125655, 2020, doi: 10.1016/j.cej.2020.125655.
[32] G. P. Karayannidis, A. P. Chatziavgoustis, and D. S. Achilias, Poly(ethylene terephthalate) recycling and recovery of pure terephthalic acid by alkaline hydrolysis, Adv. Polym. Technol., vol. 21, no. 4, pp. 250-259, Dec. 2002, doi: 10.1002/ADV.10029.
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[55] C. V. G. Silva et al., PET glycolysis optimization using ionic liquid [Bmin]ZnCl 3 as catalyst and kinetic evaluation, Polimeros, vol. 28, no. 5, pp. 450-459, 2018, doi: 10.1590/0104-1428.00418.
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spelling Atribución 4.0 Internacionalhttp://creativecommons.org/licenses/by/4.0/info:eu-repo/semantics/openAccesshttp://purl.org/coar/access_right/c_abf2Salcedo Galán, Felipevirtual::16160-1Ayalde Valderrama, Manuelabf0e4303-e1d4-405d-99e0-f36fd86677906002022-09-05T16:20:07Z2022-09-05T16:20:07Z2022-09-02http://hdl.handle.net/1992/60421instname:Universidad de los Andesreponame:Repositorio Institucional Sénecarepourl:https://repositorio.uniandes.edu.co/Se realizó la depolimerización de PET post consumo a partir de glicólisis catalizada con residuos de cáscara de naranja. Se obtuvo BHET, el cual puede ser utilizado como materia prima para la polimerización de plásticos. Se realizaron diferentes caracterizaciones al material obtenido el cual fue comparado con BHET comercial.Uno de los principales problemas ambientales actualmente es el de la contaminación por residuos plásticos y una de las soluciones planteadas es la del reciclaje químico. En el presente proyecto se trabajó la glicólisis como reacción para la depolimerización PET, en el cual se utilizaron residuos de botellas plásticas y etilenglicol como reactivos, obteniendo el monómero BHET. Se obtuvo una conversión del 70.49% del PET y una recuperación del 25.7% de BHET. Se utilizó un catalizador fabricado con cenizas de cáscara de naranja, el cual, a diferencia de otros catalizadores reportados en la literatura, es económico y amigable con el medio ambiente. El monómero BHET es frecuentemente utilizado en la industria para la síntesis del polímero PET y se corroboró la identidad del material a partir de caracterizaciones químicas y térmicas. Las caracterizaciones realizadas fueron: FTIR, TGA, DSC, tanto para el PET como para el BHET.Ingeniero QuímicoPregrado60 páginasapplication/pdfspaUniversidad de los AndesIngeniería QuímicaFacultad de IngenieríaDepartamento de Ingeniería Química y de AlimentosObtención de BHET a partir de residuos de botellas plásticas de PET mediante glicólisis catalizada con ceniza de cáscara de naranjaTrabajo de grado - Pregradoinfo:eu-repo/semantics/bachelorThesisinfo:eu-repo/semantics/acceptedVersionhttp://purl.org/coar/resource_type/c_7a1fTexthttp://purl.org/redcol/resource_type/TPReciclaje químicoGlicólisisPETBHETFTIRIngeniería[1] A. L. Andrady and M. A. Neal, Applications and societal benefits of plastics, Philos. Trans. R. Soc. , 2009, doi: 10.1098/rstb.2008.0304.[2] P. Clunies-Ross, Plastics in the Environment, R. Soc. Te Ap¿rangi, vol. 35, no. 4, pp. 230-230, 2019, doi: 10.2307/4444330.[3] ASTM D883, Standard Terminology relating to Plastics, 2020.[4] N. L. Thomas, J. Clarke, A. R. 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Silva et al., PET glycolysis optimization using ionic liquid [Bmin]ZnCl 3 as catalyst and kinetic evaluation, Polimeros, vol. 28, no. 5, pp. 450-459, 2018, doi: 10.1590/0104-1428.00418.201729100Publicationhttps://scholar.google.es/citations?user=zb2UEw8AAAAJvirtual::16160-10000-0002-7039-6448virtual::16160-1https://scienti.minciencias.gov.co/cvlac/visualizador/generarCurriculoCv.do?cod_rh=0000909068virtual::16160-1a7927f54-d3f3-447b-b397-ebe41f3c822avirtual::16160-1a7927f54-d3f3-447b-b397-ebe41f3c822avirtual::16160-1CC-LICENSElicense_rdflicense_rdfapplication/rdf+xml; charset=utf-8908https://repositorio.uniandes.edu.co/bitstreams/e2d8de04-2e49-410c-b268-5a29b8859c62/download0175ea4a2d4caec4bbcc37e300941108MD52THUMBNAILObtención de BHET a partir de residuos de botellas plásticas de PET mediante glicólisis catalizada con ceniza de cáscara de naranja.pdf.jpgObtención de BHET a partir de residuos de botellas plásticas de PET mediante glicólisis catalizada con ceniza de cáscara de naranja.pdf.jpgIM Thumbnailimage/jpeg5358https://repositorio.uniandes.edu.co/bitstreams/6473e58f-7180-4485-bfa8-8a658e8e1721/download9b56c8572739c0581dc26b948bbc292cMD56FORMATO DE AUTORIZACIÓN Y ENTREGA DE TESIS.pdf.jpgFORMATO DE AUTORIZACIÓN Y ENTREGA DE TESIS.pdf.jpgIM Thumbnailimage/jpeg15790https://repositorio.uniandes.edu.co/bitstreams/8ed1b460-26e8-46ca-99ca-ba5ad3a44837/download4cdd46240adeacd5ef579a2e1ae2b177MD58ORIGINALObtención de BHET a partir de residuos de botellas plásticas de PET mediante glicólisis catalizada con ceniza de cáscara de naranja.pdfObtención de BHET a partir de residuos de botellas plásticas de PET mediante glicólisis catalizada con ceniza de cáscara de naranja.pdfTrabajo de gradoapplication/pdf2924277https://repositorio.uniandes.edu.co/bitstreams/e268db27-f8cf-4ce0-9330-2234663a4946/downloadb51690f02fb12a5af3409a6fa9202c8eMD53FORMATO DE AUTORIZACIÓN Y ENTREGA DE TESIS.pdfFORMATO DE AUTORIZACIÓN Y ENTREGA DE TESIS.pdfHIDEapplication/pdf179803https://repositorio.uniandes.edu.co/bitstreams/db21b550-1ca3-49df-aad8-fa841ab79541/downloade8abbdb3ebc54b0a98e48dbf0e526ce9MD54LICENSElicense.txtlicense.txttext/plain; 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