Spectral prints in charcoals: reconstructing the eruptive history of Doña Juana volcano
Low-latitude volcanoes impose significant challenges for reconstructing their geological histories due to heavy precipitation and weathering, dense vegetation, complex topography and scarce outcrops, limiting traditional approaches and mapping techniques. Developing alternative tools to address thes...
- Autores:
-
Reinoso, Santiago
- Tipo de recurso:
- Trabajo de grado de pregrado
- Fecha de publicación:
- 2024
- Institución:
- Universidad de los Andes
- Repositorio:
- Séneca: repositorio Uniandes
- Idioma:
- eng
- OAI Identifier:
- oai:repositorio.uniandes.edu.co:1992/75931
- Acceso en línea:
- https://hdl.handle.net/1992/75931
- Palabra clave:
- Volcano
FTIR
Spectra
Doña Juana Volcanic complex
Biología
- Rights
- openAccess
- License
- Attribution 4.0 International
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Spectral prints in charcoals: reconstructing the eruptive history of Doña Juana volcano |
| dc.title.alternative.spa.fl_str_mv |
Huellas espectrales en carbones: reconstrucción de la historia eruptiva del volcán Doña Juana |
| title |
Spectral prints in charcoals: reconstructing the eruptive history of Doña Juana volcano |
| spellingShingle |
Spectral prints in charcoals: reconstructing the eruptive history of Doña Juana volcano Volcano FTIR Spectra Doña Juana Volcanic complex Biología |
| title_short |
Spectral prints in charcoals: reconstructing the eruptive history of Doña Juana volcano |
| title_full |
Spectral prints in charcoals: reconstructing the eruptive history of Doña Juana volcano |
| title_fullStr |
Spectral prints in charcoals: reconstructing the eruptive history of Doña Juana volcano |
| title_full_unstemmed |
Spectral prints in charcoals: reconstructing the eruptive history of Doña Juana volcano |
| title_sort |
Spectral prints in charcoals: reconstructing the eruptive history of Doña Juana volcano |
| dc.creator.fl_str_mv |
Reinoso, Santiago |
| dc.contributor.advisor.none.fl_str_mv |
González Arango, Catalina |
| dc.contributor.author.none.fl_str_mv |
Reinoso, Santiago |
| dc.contributor.other.none.fl_str_mv |
Pardo Villaveces, Natalia |
| dc.contributor.jury.none.fl_str_mv |
Santos Vega, Oscar Mauricio |
| dc.contributor.researchgroup.none.fl_str_mv |
Facultad de Ciencias::Palinología y Paleoecología Tropical |
| dc.subject.keyword.eng.fl_str_mv |
Volcano FTIR Spectra Doña Juana Volcanic complex |
| topic |
Volcano FTIR Spectra Doña Juana Volcanic complex Biología |
| dc.subject.themes.eng.fl_str_mv |
Biología |
| description |
Low-latitude volcanoes impose significant challenges for reconstructing their geological histories due to heavy precipitation and weathering, dense vegetation, complex topography and scarce outcrops, limiting traditional approaches and mapping techniques. Developing alternative tools to address these challenges is critical for risk assessment and volcanic hazard in these regions. Organic materials, such as buried woods and ancient charcoal, frequently preserved in these environments, emerge as viable archives for understanding volcanic histories including flow and pyroclastic density currents (PDCs) temperatures, topography changes, and ages of eruptions. This study explores the application of Fourier Transform Infrared Spectroscopy (FTIR-IR) to reconstruct chemical changes of charcoal (n=40) collected from the Doña Juana Volcanic Complex (Nariño, Colombia) associated to different topographic settings and different eruption phases during the Holocene. Samples span diverse ages, altitude gradients, and locations, with a modern charcoal database aiding the identification of temperature-topography associations. Key chemical spectral patterns were analyzed using Linear Discriminant Analysis (LDA) and Principal Component Analysis (PCA), revealing a model with ~60% predictive accuracy and robust confidence intervals. This accessible, low-cost approach demonstrates significant potential for regions with underdeveloped methodologies, offering a practical solution for refining sampling strategies and improving volcanic hazard assessments, with predictive power expected to increase as more data become available. |
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2024 |
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2024-12-12 |
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2025-01-31T19:00:41Z |
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2025-01-31T19:00:41Z |
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Trabajo de grado - Pregrado |
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info:eu-repo/semantics/bachelorThesis |
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eng |
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Bhatia, S. C. (2014). Biomass gasification. Advanced Renewable Energy Systems, 473–489. https://doi.org/10.1016/b978-1-78242-269-3.50018-8 Espinosa, A. 2012. Enciclopedia de Desastres Naturales Históricos en Colombia, Academia Colombiana de Ciencias Exactas, Físicas y Naturales-Universidad del Quindío, 2nded., 1840p., Pereira, Colombia. ISBN: 978-958-920-59-4. Fox J, Weisberg S (2019). An R Companion to Applied Regression, Third edition. Sage, Thousand Oaks CA. https://www.john-fox.ca/Companion/. Gosling, W. D., Cornelissen, H. L., & McMichael, C. N. H. (2019). Reconstructing past fire temperatures from ancient charcoal material. Palaeogeography, Palaeoclimatology, Palaeoecology, 520, 128–137. https://doi.org/10.1016/j.palaeo.2019.01.029 Guo, Y., Hastie, T., & Tibshirani, R. (2007). Regularized linear discriminant analysis and its application in microarrays. Biostatistics, 8(1), 86–100. https://doi.org/10.1093/biostatistics/kxj035 Hanson, B. A. (2024). Exploratory Chemometrics for Spectroscopy [R package ChemoSpec version 6.1.10]. R-Project.org. https://cran.r-project.org/package=ChemoSpec Hasburgh, L. E., Stone, D. S., Zelinka, S. L., & Plaza, N. Z. (2020). Characterization of Wood Chemical Changes Caused by Pyrolysis During Flaming Combustion Using X-Ray Photoelectron Spectroscopy. Springer EBooks, 22–27. https://doi.org/10.1007/978-3-030-41235-7_4 Hasburgh, L.E. (2020). Chemical and Mechanical Characterization of Pyrolysis in Wood. Madison, WI: University of Wisconsin-Madison. 119 p +appendix. Ph.D. dissertation. Jerram, D. (2021). Introducing Volcanology. Liverpool University Press. https://doi.org/10.2307/jj.12949053 Katarína Dúbravská, Viera Kučerová, Jaroslava Štefková, & Ol’ga Mišíková. (2024). Charring of and Chemical Changes in Historical Wood under Thermal Loading. Forests, 15(7), 1189–1189. https://doi.org/10.3390/f15071189 Karátson, D. (2012). D. Jerram: Introducing volcanology—A Guide to Hot Rocks. Bulletin of Volcanology, 74(6), 1575–1576. https://doi.org/10.1007/s00445-012-0607-z Pardo, N., Mónica Lucía Espinosa, González-Arango, C., Miguel Angel Cabrera, Salazar, S., Archila, S., Palacios, N., Prieto, D., Camacho, R., & Parra-Agudelo, L. (2021). Worlding resilience in the Doña Juana Volcano-Páramo, Northern Andes (Colombia): A transdisciplinary view. Natural Hazards, 107(2), 1845–1880. https://doi.org/10.1007/s11069-021-04662-4 Pardo, N., Pulgarín, B., Betancourt, V., Lucchi, F., & Valencia, L. J. (2019). Facing geological mapping at low-latitude volcanoes: The Doña Juana Volcanic Complex study-case, SW-Colombia. Journal of Volcanology and Geothermal Research, 385, 46–67. https://doi.org/10.1016/j.jvolgeores.2018.04.016 Pardo, N., Sulpizio, R., Lucchi, F., Giordano, G., Cronin, S. J., Pulgarín, B., Matteo Roverato, Ana María Correa-Tamayo, Camacho, R., & Miguel Angel Cabrera. (2023). Late Holocene volcanic stratigraphy and eruption chronology of the dacitic Young Doña Juana volcano, Colombia. Geological Society of America Bulletin. https://doi.org/10.1130/b36557.1 Pensa, A., Capra, L., Giordano, G., & Corrado, S. (2018). Emplacement temperature estimation of the 2015 dome collapse of Volcán de Colima as key proxy for flow dynamics of confined and unconfined pyroclastic density currents. Journal of Volcanology and Geothermal Research, 357, 321–338. https://doi.org/10.1016/j.jvolgeores.2018.05.010 Pensa, A., Capra, L., & Giordano, G. (2019). Ash clouds temperature estimation. Implication on dilute and concentrated PDCs coupling and topography confinement. Nature, 9(1). https://doi.org/10.1038/s41598-019-42035-x Pensa, A., Corrado, S., & Giordano, G. (2020). Assessment of maximum flow and emplacement temperatures reached by PDCs using charred wood fragments. EGU General Assembly. https://doi.org/10.5194/egusphere-egu2020-8632 S. Yoshi Maezumi, Gosling, W. D., Kirschner, J., Chevalier, M., Cornelissen, H. L., Heinecke, T., & Crystal N.H. McMichael. (2021). A modern analogue matching approach to characterize fire temperatures and plant species from charcoal. Palaeogeography, Palaeoclimatology, Palaeoecology, 578, 110580–110580. https://doi.org/10.1016/j.palaeo.2021.110580 Salazar-Jaramillo, S., Camacho, R., Villota, S., Pardo, N., Andrés Velásquez, Cabrera, M. A., & Pulgarín, B. (2022). Geomorphology of the SW flank of the Doña Juana Volcanic Complex, Colombia: interplay of fluvial, denudational, structural, and volcanic processes. Journal of Maps, 18(2), 508–518. https://doi.org/10.1080/17445647.2022.2101948 Scrucca L, Fraley C, Murphy TB, Raftery AE (2023). Model-Based Clustering, Classification, and Density Estimation Using mclust in R. Chapman and Hall/CRC. ISBN 978-1032234953, doi:10.1201/9781003277965, https://mclust-org.github.io/book/. Simpson G (2007). “Analogue Methods in Palaeoecology: Using the analogue Package.” Journal of Statistical Software, 22(2), 1–29. Varmuza, K., & Filzmoser, P. (2016). Introduction to Multivariate Statistical Analysis in Chemometrics. CRC Press. https://doi.org/10.1201/9781420059496 |
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González Arango, Catalinavirtual::23003-1Reinoso, SantiagoPardo Villaveces, NataliaSantos Vega, Oscar MauricioFacultad de Ciencias::Palinología y Paleoecología Tropical2025-01-31T19:00:41Z2025-01-31T19:00:41Z2024-12-12https://hdl.handle.net/1992/75931instname:Universidad de los Andesreponame:Repositorio Institucional Sénecarepourl:https://repositorio.uniandes.edu.co/Low-latitude volcanoes impose significant challenges for reconstructing their geological histories due to heavy precipitation and weathering, dense vegetation, complex topography and scarce outcrops, limiting traditional approaches and mapping techniques. Developing alternative tools to address these challenges is critical for risk assessment and volcanic hazard in these regions. Organic materials, such as buried woods and ancient charcoal, frequently preserved in these environments, emerge as viable archives for understanding volcanic histories including flow and pyroclastic density currents (PDCs) temperatures, topography changes, and ages of eruptions. This study explores the application of Fourier Transform Infrared Spectroscopy (FTIR-IR) to reconstruct chemical changes of charcoal (n=40) collected from the Doña Juana Volcanic Complex (Nariño, Colombia) associated to different topographic settings and different eruption phases during the Holocene. Samples span diverse ages, altitude gradients, and locations, with a modern charcoal database aiding the identification of temperature-topography associations. Key chemical spectral patterns were analyzed using Linear Discriminant Analysis (LDA) and Principal Component Analysis (PCA), revealing a model with ~60% predictive accuracy and robust confidence intervals. This accessible, low-cost approach demonstrates significant potential for regions with underdeveloped methodologies, offering a practical solution for refining sampling strategies and improving volcanic hazard assessments, with predictive power expected to increase as more data become available.Pregrado16application/pdfengUniversidad de los AndesBiologíaFacultad de CienciasDepartamento de Ciencias BiológicasAttribution 4.0 Internationalhttp://creativecommons.org/licenses/by/4.0/info:eu-repo/semantics/openAccesshttp://purl.org/coar/access_right/c_abf2Spectral prints in charcoals: reconstructing the eruptive history of Doña Juana volcanoHuellas espectrales en carbones: reconstrucción de la historia eruptiva del volcán Doña JuanaTrabajo de grado - Pregradoinfo:eu-repo/semantics/bachelorThesisinfo:eu-repo/semantics/acceptedVersionhttp://purl.org/coar/resource_type/c_7a1fTexthttp://purl.org/redcol/resource_type/TPVolcanoFTIRSpectraDoña Juana Volcanic complexBiologíaBhatia, S. C. (2014). Biomass gasification. Advanced Renewable Energy Systems, 473–489. https://doi.org/10.1016/b978-1-78242-269-3.50018-8Espinosa, A. 2012. Enciclopedia de Desastres Naturales Históricos en Colombia, Academia Colombiana de Ciencias Exactas, Físicas y Naturales-Universidad del Quindío, 2nded., 1840p., Pereira, Colombia. ISBN: 978-958-920-59-4.Fox J, Weisberg S (2019). An R Companion to Applied Regression, Third edition. Sage, Thousand Oaks CA. https://www.john-fox.ca/Companion/.Gosling, W. D., Cornelissen, H. L., & McMichael, C. N. H. (2019). Reconstructing past fire temperatures from ancient charcoal material. Palaeogeography, Palaeoclimatology, Palaeoecology, 520, 128–137. https://doi.org/10.1016/j.palaeo.2019.01.029Guo, Y., Hastie, T., & Tibshirani, R. (2007). Regularized linear discriminant analysis and its application in microarrays. Biostatistics, 8(1), 86–100. https://doi.org/10.1093/biostatistics/kxj035Hanson, B. A. (2024). Exploratory Chemometrics for Spectroscopy [R package ChemoSpec version 6.1.10]. R-Project.org. https://cran.r-project.org/package=ChemoSpecHasburgh, L. E., Stone, D. S., Zelinka, S. L., & Plaza, N. Z. (2020). Characterization of Wood Chemical Changes Caused by Pyrolysis During Flaming Combustion Using X-Ray Photoelectron Spectroscopy. Springer EBooks, 22–27. https://doi.org/10.1007/978-3-030-41235-7_4Hasburgh, L.E. (2020). Chemical and Mechanical Characterization of Pyrolysis in Wood. Madison, WI: University of Wisconsin-Madison. 119 p +appendix. Ph.D. dissertation.Jerram, D. (2021). Introducing Volcanology. Liverpool University Press. https://doi.org/10.2307/jj.12949053Katarína Dúbravská, Viera Kučerová, Jaroslava Štefková, & Ol’ga Mišíková. (2024). Charring of and Chemical Changes in Historical Wood under Thermal Loading. Forests, 15(7), 1189–1189. https://doi.org/10.3390/f15071189Karátson, D. (2012). D. Jerram: Introducing volcanology—A Guide to Hot Rocks. Bulletin of Volcanology, 74(6), 1575–1576. https://doi.org/10.1007/s00445-012-0607-zPardo, N., Mónica Lucía Espinosa, González-Arango, C., Miguel Angel Cabrera, Salazar, S., Archila, S., Palacios, N., Prieto, D., Camacho, R., & Parra-Agudelo, L. (2021). Worlding resilience in the Doña Juana Volcano-Páramo, Northern Andes (Colombia): A transdisciplinary view. Natural Hazards, 107(2), 1845–1880. https://doi.org/10.1007/s11069-021-04662-4Pardo, N., Pulgarín, B., Betancourt, V., Lucchi, F., & Valencia, L. J. (2019). Facing geological mapping at low-latitude volcanoes: The Doña Juana Volcanic Complex study-case, SW-Colombia. Journal of Volcanology and Geothermal Research, 385, 46–67. https://doi.org/10.1016/j.jvolgeores.2018.04.016Pardo, N., Sulpizio, R., Lucchi, F., Giordano, G., Cronin, S. J., Pulgarín, B., Matteo Roverato, Ana María Correa-Tamayo, Camacho, R., & Miguel Angel Cabrera. (2023). Late Holocene volcanic stratigraphy and eruption chronology of the dacitic Young Doña Juana volcano, Colombia. Geological Society of America Bulletin. https://doi.org/10.1130/b36557.1Pensa, A., Capra, L., Giordano, G., & Corrado, S. (2018). Emplacement temperature estimation of the 2015 dome collapse of Volcán de Colima as key proxy for flow dynamics of confined and unconfined pyroclastic density currents. Journal of Volcanology and Geothermal Research, 357, 321–338. https://doi.org/10.1016/j.jvolgeores.2018.05.010Pensa, A., Capra, L., & Giordano, G. (2019). Ash clouds temperature estimation. Implication on dilute and concentrated PDCs coupling and topography confinement. Nature, 9(1). https://doi.org/10.1038/s41598-019-42035-xPensa, A., Corrado, S., & Giordano, G. (2020). Assessment of maximum flow and emplacement temperatures reached by PDCs using charred wood fragments. EGU General Assembly. https://doi.org/10.5194/egusphere-egu2020-8632S. Yoshi Maezumi, Gosling, W. D., Kirschner, J., Chevalier, M., Cornelissen, H. L., Heinecke, T., & Crystal N.H. McMichael. (2021). A modern analogue matching approach to characterize fire temperatures and plant species from charcoal. Palaeogeography, Palaeoclimatology, Palaeoecology, 578, 110580–110580. https://doi.org/10.1016/j.palaeo.2021.110580Salazar-Jaramillo, S., Camacho, R., Villota, S., Pardo, N., Andrés Velásquez, Cabrera, M. A., & Pulgarín, B. (2022). Geomorphology of the SW flank of the Doña Juana Volcanic Complex, Colombia: interplay of fluvial, denudational, structural, and volcanic processes. Journal of Maps, 18(2), 508–518. https://doi.org/10.1080/17445647.2022.2101948Scrucca L, Fraley C, Murphy TB, Raftery AE (2023). Model-Based Clustering, Classification, and Density Estimation Using mclust in R. Chapman and Hall/CRC. ISBN 978-1032234953, doi:10.1201/9781003277965, https://mclust-org.github.io/book/.Simpson G (2007). “Analogue Methods in Palaeoecology: Using the analogue Package.” Journal of Statistical Software, 22(2), 1–29.Varmuza, K., & Filzmoser, P. (2016). Introduction to Multivariate Statistical Analysis in Chemometrics. 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