Síntesis de redes metal-orgánicas heteroestructurales con ligandos mixtos.

Ilustraciones

Autores:
Cardona González, Daniela
Tipo de recurso:
Fecha de publicación:
2021
Institución:
Universidad Nacional de Colombia
Repositorio:
Universidad Nacional de Colombia
Idioma:
spa
OAI Identifier:
oai:repositorio.unal.edu.co:unal/79694
Acceso en línea:
https://repositorio.unal.edu.co/handle/unal/79694
https://repositorio.unal.edu.co/
Palabra clave:
540 - Química y ciencias afines::546 - Química inorgánica
Metales - Características físico-químicas
MOF
Porosidad
Metal-organic frameworks
Adsorption
Redes metal-orgánicas
Porosidad
Adsorción
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openAccess
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Atribución-NoComercial-SinDerivadas 4.0 Internacional
id UNACIONAL2_fa528ddb7a94be52b542c400792caba0
oai_identifier_str oai:repositorio.unal.edu.co:unal/79694
network_acronym_str UNACIONAL2
network_name_str Universidad Nacional de Colombia
repository_id_str
dc.title.spa.fl_str_mv Síntesis de redes metal-orgánicas heteroestructurales con ligandos mixtos.
dc.title.translated.eng.fl_str_mv Synthesis of heterostructural mixed-ligand metal-organic frameworks
title Síntesis de redes metal-orgánicas heteroestructurales con ligandos mixtos.
spellingShingle Síntesis de redes metal-orgánicas heteroestructurales con ligandos mixtos.
540 - Química y ciencias afines::546 - Química inorgánica
Metales - Características físico-químicas
MOF
Porosidad
Metal-organic frameworks
Adsorption
Redes metal-orgánicas
Porosidad
Adsorción
title_short Síntesis de redes metal-orgánicas heteroestructurales con ligandos mixtos.
title_full Síntesis de redes metal-orgánicas heteroestructurales con ligandos mixtos.
title_fullStr Síntesis de redes metal-orgánicas heteroestructurales con ligandos mixtos.
title_full_unstemmed Síntesis de redes metal-orgánicas heteroestructurales con ligandos mixtos.
title_sort Síntesis de redes metal-orgánicas heteroestructurales con ligandos mixtos.
dc.creator.fl_str_mv Cardona González, Daniela
dc.contributor.advisor.none.fl_str_mv Muñoz Acevedo, Juan Carlos
Pabón Gelves, Elizabeth
dc.contributor.author.none.fl_str_mv Cardona González, Daniela
dc.contributor.researchgroup.spa.fl_str_mv Ciencia de Materiales Avanzados
dc.subject.ddc.spa.fl_str_mv 540 - Química y ciencias afines::546 - Química inorgánica
topic 540 - Química y ciencias afines::546 - Química inorgánica
Metales - Características físico-químicas
MOF
Porosidad
Metal-organic frameworks
Adsorption
Redes metal-orgánicas
Porosidad
Adsorción
dc.subject.lemb.none.fl_str_mv Metales - Características físico-químicas
dc.subject.proposal.eng.fl_str_mv MOF
Porosidad
Metal-organic frameworks
Adsorption
dc.subject.proposal.spa.fl_str_mv Redes metal-orgánicas
Porosidad
Adsorción
description Ilustraciones
publishDate 2021
dc.date.accessioned.none.fl_str_mv 2021-06-23T21:04:47Z
dc.date.available.none.fl_str_mv 2021-06-23T21:04:47Z
dc.date.issued.none.fl_str_mv 2021
dc.type.spa.fl_str_mv Trabajo de grado - Maestría
dc.type.driver.spa.fl_str_mv info:eu-repo/semantics/masterThesis
dc.type.version.spa.fl_str_mv info:eu-repo/semantics/acceptedVersion
dc.type.content.spa.fl_str_mv Text
dc.type.redcol.spa.fl_str_mv http://purl.org/redcol/resource_type/TM
status_str acceptedVersion
dc.identifier.uri.none.fl_str_mv https://repositorio.unal.edu.co/handle/unal/79694
dc.identifier.instname.spa.fl_str_mv Universidad Nacional de Colombia
dc.identifier.reponame.spa.fl_str_mv Repositorio Institucional Universidad Nacional de Colombia
dc.identifier.repourl.spa.fl_str_mv https://repositorio.unal.edu.co/
url https://repositorio.unal.edu.co/handle/unal/79694
https://repositorio.unal.edu.co/
identifier_str_mv Universidad Nacional de Colombia
Repositorio Institucional Universidad Nacional de Colombia
dc.language.iso.spa.fl_str_mv spa
language spa
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dc.publisher.spa.fl_str_mv Universidad Nacional de Colombia
dc.publisher.program.spa.fl_str_mv Medellín - Ciencias - Maestría en Ciencias - Química
dc.publisher.department.spa.fl_str_mv Escuela de química
dc.publisher.faculty.spa.fl_str_mv Facultad de Ciencias
dc.publisher.place.spa.fl_str_mv Medellín, Colombia
dc.publisher.branch.spa.fl_str_mv Universidad Nacional de Colombia - Sede Medellín
institution Universidad Nacional de Colombia
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spelling Atribución-NoComercial-SinDerivadas 4.0 Internacionalhttp://creativecommons.org/licenses/by-nc-nd/4.0/info:eu-repo/semantics/openAccesshttp://purl.org/coar/access_right/c_abf2Muñoz Acevedo, Juan Carlos9febf6fa56a6f9b8cf7adb1c171a1540Pabón Gelves, Elizabeth29dab4728be81c8d9276a582c19c9b32600Cardona González, Daniela5507becd9027a057c68ac381b32bd5d3Ciencia de Materiales Avanzados2021-06-23T21:04:47Z2021-06-23T21:04:47Z2021https://repositorio.unal.edu.co/handle/unal/79694Universidad Nacional de ColombiaRepositorio Institucional Universidad Nacional de Colombiahttps://repositorio.unal.edu.co/IlustracionesLas redes metal-orgánicas (MOFs) son materiales porosos con aplicaciones en diversas áreas de la industria, tecnología y medio ambiente. El diseño molecular de MOFs ha estado ligado a la naturaleza química del centro metálico, al tipo de ligandos orgánicos, a la relación de la interacción metal-ligando y a su geometría, lo que implica que para garantizar la estabilidad y la supramolecularidad de la red es necesario explorar con ligandos, las condiciones con las cuales se puede obtener una estructura tipo MOF. Se sintetizaron redes metal-orgánicas por medio de una estrategia de ligandos mixtos heteroestructurales; usando los ácidos trans,trans-mucónico (MA) y sulfosuccínico (SSA), acompañados del conector 4,4’-bipiridina (4B) con metales como el Cu (II) y Zn (II). Los compuestos se prepararon por diversas rutas de síntesis a reflujo, solvotermal y agitación y se caracterizaron las propiedades morfológicas, estructurales, térmicas y superficiales por medio de microscopía óptica, FT-IR, XRPD y TGA. Adicionalmente se usó análisis de SC-XRD para la determinación estructural de una nueva estructura 1D de fórmula molecular [Cu(HSSA)(4B)(H2O)2]n·H2O con espacios entre las cadenas con alta polarizabilidad y por lo tanto promisorias para la adsorción selectiva de CO2. Tomado de la fuente)Metal-organic frameworks (MOF) are porous materials with applications in diverse areas like industry, technology and environment. The molecular design of MOFs can be linked to the nature of the metal, organic linker, metal-linker interaction and geometry, implying that is necessary the exploration of synthetic conditions with the linkers to ensure the stability and supramolecularity of the framework. This work presents the synthesis of metal-organic frameworks via heterostructural mixed-linker strategy with trans,trans-muconic acid (MA), sulfosuccinic acid (SSA) and the auxiliary linker 4,4’-bipyridine (4B) coordinated to Cu (II) and Zn(II). The compounds have been synthesized by reflux, solvothermal and agitation conditions and the morphology, structure, thermic and surface area properties were characterized with optic microscopy, FT-IR, XRPD and TGA. SC-XRD analysis was additionally used to determinate the new 1D structure of molecurlar formula [Cu(HSSA)(4B)(H2O)2]n·H2O with free inter-chain spaces, high polarizability and potential selective adsorption properties for CO2 capture. 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Acta 402, 25–32 (2013).EspecializadoLICENSElicense.txtlicense.txttext/plain; charset=utf-83964https://repositorio.unal.edu.co/bitstream/unal/79694/1/license.txtcccfe52f796b7c63423298c2d3365fc6MD51ORIGINAL1152447599.2021.pdf1152447599.2021.pdfTesis de Maestría en Ciencias - Químicaapplication/pdf4506253https://repositorio.unal.edu.co/bitstream/unal/79694/2/1152447599.2021.pdfe153711438c7f51f209b2d336fe3ddc8MD52THUMBNAIL1152447599.2021.pdf.jpg1152447599.2021.pdf.jpgGenerated Thumbnailimage/jpeg4583https://repositorio.unal.edu.co/bitstream/unal/79694/3/1152447599.2021.pdf.jpg0f83a04ad2447aa9cba2dc7328293358MD53unal/79694oai:repositorio.unal.edu.co:unal/796942024-07-23 23:33:36.171Repositorio Institucional Universidad Nacional de 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