Producción de acetato de fusel por destilación reactiva
En este trabajo se investigan las trayectorias directas de procesos de destilación reactiva (DR) para la síntesis de acetatos a partir de la esterificación de ácido acético con aceite de fusel (AF). El problema se encuentra limitado a una descripción aproximada donde el AF se considera como una mezc...
- Autores:
-
Sánchez Correa, César Augusto
- Tipo de recurso:
- Book
- Fecha de publicación:
- 2020
- Institución:
- Universidad Nacional de Colombia
- Repositorio:
- Universidad Nacional de Colombia
- Idioma:
- spa
- OAI Identifier:
- oai:repositorio.unal.edu.co:unal/77741
- Acceso en línea:
- https://repositorio.unal.edu.co/handle/unal/77741
- Palabra clave:
- 660 - Ingeniería química::664 - Tecnología de alimentos
660 - Ingeniería química
fusel oil
isoamyl acetate
ethyl acetate
reactive distillation
aceite de fusel
acetato de isoamilo
acetato de etilo
destilación reactiva
- Rights
- openAccess
- License
- Atribución-SinDerivadas 4.0 Internacional
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| dc.title.spa.fl_str_mv |
Producción de acetato de fusel por destilación reactiva |
| dc.title.alternative.spa.fl_str_mv |
Fusel acetate production by reactive distillation |
| title |
Producción de acetato de fusel por destilación reactiva |
| spellingShingle |
Producción de acetato de fusel por destilación reactiva 660 - Ingeniería química::664 - Tecnología de alimentos 660 - Ingeniería química fusel oil isoamyl acetate ethyl acetate reactive distillation aceite de fusel acetato de isoamilo acetato de etilo destilación reactiva |
| title_short |
Producción de acetato de fusel por destilación reactiva |
| title_full |
Producción de acetato de fusel por destilación reactiva |
| title_fullStr |
Producción de acetato de fusel por destilación reactiva |
| title_full_unstemmed |
Producción de acetato de fusel por destilación reactiva |
| title_sort |
Producción de acetato de fusel por destilación reactiva |
| dc.creator.fl_str_mv |
Sánchez Correa, César Augusto |
| dc.contributor.advisor.spa.fl_str_mv |
Rodríguez Niño, Gerardo Gil Chaves, Iván Darío |
| dc.contributor.author.spa.fl_str_mv |
Sánchez Correa, César Augusto |
| dc.contributor.researchgroup.spa.fl_str_mv |
Grupo de Investigación en Procesos Químicos y Bioquímicos |
| dc.subject.ddc.spa.fl_str_mv |
660 - Ingeniería química::664 - Tecnología de alimentos 660 - Ingeniería química |
| topic |
660 - Ingeniería química::664 - Tecnología de alimentos 660 - Ingeniería química fusel oil isoamyl acetate ethyl acetate reactive distillation aceite de fusel acetato de isoamilo acetato de etilo destilación reactiva |
| dc.subject.proposal.eng.fl_str_mv |
fusel oil isoamyl acetate ethyl acetate reactive distillation |
| dc.subject.proposal.spa.fl_str_mv |
aceite de fusel acetato de isoamilo acetato de etilo destilación reactiva |
| description |
En este trabajo se investigan las trayectorias directas de procesos de destilación reactiva (DR) para la síntesis de acetatos a partir de la esterificación de ácido acético con aceite de fusel (AF). El problema se encuentra limitado a una descripción aproximada donde el AF se considera como una mezcla de alcohol isoamílico + agua + etanol. Esta versión simplificada del problema puede ocurrir aproximadamente en la práctica. En este contexto el objetivo principal del trabajo consistió en diseñar un proceso de DR para la producción de acetato de fusel. Los objetivos específicos son: a) desarrollar un modelo termodinámico adecuado para predecir los equilibrios de fases líquido – vapor y líquido – líquido – vapor del sistema multicomponente a partir de la información experimental (generada y recopilada en la literatura) de los subsistemas binarios y ternarios; b) desarrollar un modelo cinético apropiado para describir la esterificación directa del ácido acético con aceite de fusel en fase líquida; c) sintetizar a nivel conceptual alternativas de proceso para la tecnología de DR; y d) calcular los tamaños de los equipos y el costo total anualizado para alternativas de proceso técnicamente factibles. Desde el punto de vista experimental, se generó información nueva en dos casos: a) para el equilibrio líquido – vapor de las mezclas binarias de acetatos; y b) datos de velocidad de reacción para la esterificación de ácido acético con alcohol isoamílico (y con mezclas de alcohol isoamílico y etanol) utilizando la resina Amberlyst 70 como catalizador. La información experimental se utilizó para correlacionar y validar los modelos termodinámico y cinético. Desde el punto de vista teórico se desarrolló la caracterización termodinámica completa del sistema multicomponente reactivo, y se usaron los planos de fases reactivos para sintetizar estructuras de proceso que se caracterizaron utilizando los estados estacionarios de máxima conversión. Se encontró que es posible implementar un proceso de DR con alimentos en la proporción estequiométrica, altas conversiones (~99%) y alta recuperación de los acetatos (≥99%). |
| publishDate |
2020 |
| dc.date.accessioned.spa.fl_str_mv |
2020-07-06T15:55:04Z |
| dc.date.available.spa.fl_str_mv |
2020-07-06T15:55:04Z |
| dc.date.issued.spa.fl_str_mv |
2020-07-02 |
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Libro |
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info:eu-repo/semantics/book |
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info:eu-repo/semantics/publishedVersion |
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http://purl.org/coar/resource_type/c_2f33 |
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http://purl.org/coar/version/c_970fb48d4fbd8a85 |
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Atribución-SinDerivadas 4.0 InternacionalDerechos reservados - Universidad Nacional de ColombiaAcceso abiertohttp://creativecommons.org/licenses/by-nd/4.0/info:eu-repo/semantics/openAccesshttp://purl.org/coar/access_right/c_abf2Rodríguez Niño, Gerardo09d02f57-df4f-4dd5-84b3-3c831e908fb7-1Gil Chaves, Iván Darío02f16ab2-3973-47c5-bfd2-f8e8d3feafd5-1Sánchez Correa, César Augustofaa65425-ca11-438d-a88b-b0a419f254acGrupo de Investigación en Procesos Químicos y Bioquímicos2020-07-06T15:55:04Z2020-07-06T15:55:04Z2020-07-02https://repositorio.unal.edu.co/handle/unal/77741En este trabajo se investigan las trayectorias directas de procesos de destilación reactiva (DR) para la síntesis de acetatos a partir de la esterificación de ácido acético con aceite de fusel (AF). El problema se encuentra limitado a una descripción aproximada donde el AF se considera como una mezcla de alcohol isoamílico + agua + etanol. Esta versión simplificada del problema puede ocurrir aproximadamente en la práctica. En este contexto el objetivo principal del trabajo consistió en diseñar un proceso de DR para la producción de acetato de fusel. Los objetivos específicos son: a) desarrollar un modelo termodinámico adecuado para predecir los equilibrios de fases líquido – vapor y líquido – líquido – vapor del sistema multicomponente a partir de la información experimental (generada y recopilada en la literatura) de los subsistemas binarios y ternarios; b) desarrollar un modelo cinético apropiado para describir la esterificación directa del ácido acético con aceite de fusel en fase líquida; c) sintetizar a nivel conceptual alternativas de proceso para la tecnología de DR; y d) calcular los tamaños de los equipos y el costo total anualizado para alternativas de proceso técnicamente factibles. Desde el punto de vista experimental, se generó información nueva en dos casos: a) para el equilibrio líquido – vapor de las mezclas binarias de acetatos; y b) datos de velocidad de reacción para la esterificación de ácido acético con alcohol isoamílico (y con mezclas de alcohol isoamílico y etanol) utilizando la resina Amberlyst 70 como catalizador. La información experimental se utilizó para correlacionar y validar los modelos termodinámico y cinético. Desde el punto de vista teórico se desarrolló la caracterización termodinámica completa del sistema multicomponente reactivo, y se usaron los planos de fases reactivos para sintetizar estructuras de proceso que se caracterizaron utilizando los estados estacionarios de máxima conversión. Se encontró que es posible implementar un proceso de DR con alimentos en la proporción estequiométrica, altas conversiones (~99%) y alta recuperación de los acetatos (≥99%).This work is a research on the direct trajectories of a reactive distillation process to synthetize acetates by the acetic acid esterification with fusel oil. The problem is bounding into the approximated description where the fusel oil is modeled as a mixture of isoamyl alcohol + ethanol + water. This simplified version of the problem can occur in the real world. In this context, the main objective of this work was to design a reactive distillation process for the fusel acetate production. The specific objectives are: a) to develop a thermodynamic model suitable for the prediction of the multicomponent phase equilibria (vapor – liquid and vapor – liquid – liquid) from experimental information (generated and extracted from literature) related with the associated binary and ternary subsystems; b) to develop a kinetic model suitable to describe the acetic acid esterification with fusel oil in the liquid phase; c) to synthetize, in the conceptual level, process alternatives for the reactive distillation technology; and d) to calculate the dimensions for the process units and the total annualized cost for the technically feasible process alternatives. From the experimental view, new information was generated in two subjects: a) vapor – liquid equilibrium for binary mixtures of acetates; and b) kinetic data for the liquid phase acetic acid esterification with isoamyl alcohol (or with binary mixtures of isoamyl alcohol and ethanol) using the Amberlyst 70 resin as catalyst. The experimental information was used to correlate and validate the thermodynamic and kinetic models. From a theoretical view, a complete thermodynamic characterization for the multicomponent reactive system was calculated, and the reactive phase diagrams were used to synthesize process structures that were characterized using the stationary states with maximum conversion. It was found that is possible to implement a reactive distillation process with the feeds in the stoichiometric proportion, high conversions for the reactants (~ 99 %) and high recoveries for the acetates (≥ 99 %)Doctorado167application/pdfspa660 - Ingeniería química::664 - Tecnología de alimentos660 - Ingeniería químicafusel oilisoamyl acetateethyl acetatereactive distillationaceite de fuselacetato de isoamiloacetato de etilodestilación reactivaProducción de acetato de fusel por destilación reactivaFusel acetate production by reactive distillationLibroinfo:eu-repo/semantics/bookinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_2f33http://purl.org/coar/version/c_970fb48d4fbd8a85Texthttp://purl.org/redcol/resource_type/LIBBogotá - Ingeniería - Doctorado en Ingeniería - Ingeniería QuímicaUniversidad Nacional de Colombia - Sede BogotáAbbott, M.M., Smith, J.M.M., Van Ness, H.C., Ness, H. Van, Abbott, M.M., 2005. 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