Conceptual design of a palm oil hydrotreatment reactor for commercial diesel production

A reactor with an industrial production of renewable diesel via palm oil hydrotreatment was conceptually designed based on laboratory-scale continuous and semi-batch reactor experiments. The conversion of vegetable oil to biodiesel through transesterication is responsible for a reduction in the use...

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Autores:
Vélez Manco, Juan Felipe
Tipo de recurso:
Fecha de publicación:
2014
Institución:
Universidad Nacional de Colombia
Repositorio:
Universidad Nacional de Colombia
Idioma:
spa
OAI Identifier:
oai:repositorio.unal.edu.co:unal/55709
Acceso en línea:
https://repositorio.unal.edu.co/handle/unal/55709
http://bdigital.unal.edu.co/51154/
Palabra clave:
66 Ingeniería química y Tecnologías relacionadas/ Chemical engineering
Vegetable oil
Hydrotreating
Trickle bed reactor
Renewable diesel
Aceite Vegetal
Hidrotratamiento
Reactor tipo trickle bed
Diesel renovable
Rights
openAccess
License
Atribución-NoComercial 4.0 Internacional
id UNACIONAL2_d48ca7cb83e28eb9c94436c7d390a138
oai_identifier_str oai:repositorio.unal.edu.co:unal/55709
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network_name_str Universidad Nacional de Colombia
repository_id_str
spelling Atribución-NoComercial 4.0 InternacionalDerechos reservados - Universidad Nacional de Colombiahttp://creativecommons.org/licenses/by-nc/4.0/info:eu-repo/semantics/openAccesshttp://purl.org/coar/access_right/c_abf2Molina, AlejandroVélez Manco, Juan Felipea05b93b1-fe5d-49e9-abd7-a5d9e32e8b863002019-07-02T11:26:30Z2019-07-02T11:26:30Z2014https://repositorio.unal.edu.co/handle/unal/55709http://bdigital.unal.edu.co/51154/A reactor with an industrial production of renewable diesel via palm oil hydrotreatment was conceptually designed based on laboratory-scale continuous and semi-batch reactor experiments. The conversion of vegetable oil to biodiesel through transesterication is responsible for a reduction in the use of a signi cant fraction of fossil fuels. Unfortunately, the diesel produced by transesterication has limitations such as high density, high viscosity and low cetane number. An alternative to transesteri cation is the hydrotreatment (HDT) of vegetable oils to produce a fuel with properties more similar to petroleum diésel than those of diesel obtained by transesterication. This thesis presents hydrotreating as an alternative for the production of renewable diesel in Colombia. It proposes a reaction pathway for hydrotreatment based on experiments with Rened, Bleached and Deodorized Palm Oil (RBDPO) and using a comercial solid trilobite NiMo catalyst (NiMo/).Resumen: un reactor con una producción industrial de diesel renovable a través de hidrotratamiento de aceite de palma fue diseñado conceptualmente con base a experimentos en reactores continuos y semi-batch a escala laboratorio. La conversiíon a biodiesel mediante el proceso de transestericación es responsable de la sustitución de una fracción signicativa de los combustibles fósiles a los biocombustibles. Desafortunadamente, el diesel producido por transestericación tiene limitaciones, tales como la alta densidad, alta viscosidad y bajo número de cetano. Una alternativa a la transestericación es el hidrotratamiento (HDT) de aceites vegetales para producir un combustible con propiedades más similares a las del diesel del petróleo y a las del diesel obtenido por transestericación. Esta tesis presenta el hidrotratamiento como una alternativa para la producción de diesel renovable en Colombia. Inicialmente se propone una ruta de reacción de hidrotratamiento basado en experimentos con aceite de palma renado, blanqueado y desodorizado (RBDPO) y usando un catalizador NiMo sólido comercial en forma de trilobita (NiMo/).Maestríaapplication/pdfspaUniversidad Nacional de Colombia Sede Medellín Facultad de Minas Escuela de Química y PetróleosEscuela de Química y PetróleosVélez Manco, Juan Felipe (2014) Conceptual design of a palm oil hydrotreatment reactor for commercial diesel production. Maestría thesis, Universidad Nacional de Colombia - Sede Medellín.66 Ingeniería química y Tecnologías relacionadas/ Chemical engineeringVegetable oilHydrotreatingTrickle bed reactorRenewable dieselAceite VegetalHidrotratamientoReactor tipo trickle bedDiesel renovableConceptual design of a palm oil hydrotreatment reactor for commercial diesel productionTrabajo de grado - Maestríainfo:eu-repo/semantics/masterThesisinfo:eu-repo/semantics/acceptedVersionTexthttp://purl.org/redcol/resource_type/TMORIGINAL1017176429.2014.pdfTesis de Maestría en Ingeniería - Ingeniería Químicaapplication/pdf19339710https://repositorio.unal.edu.co/bitstream/unal/55709/1/1017176429.2014.pdf10e567f79680d88b17cf5433d86be9d7MD51THUMBNAIL1017176429.2014.pdf.jpg1017176429.2014.pdf.jpgGenerated Thumbnailimage/jpeg4065https://repositorio.unal.edu.co/bitstream/unal/55709/2/1017176429.2014.pdf.jpg07a32a92d0eee49cc3e6e170b03bd94fMD52unal/55709oai:repositorio.unal.edu.co:unal/557092024-03-19 23:09:09.593Repositorio Institucional Universidad Nacional de Colombiarepositorio_nal@unal.edu.co
dc.title.spa.fl_str_mv Conceptual design of a palm oil hydrotreatment reactor for commercial diesel production
title Conceptual design of a palm oil hydrotreatment reactor for commercial diesel production
spellingShingle Conceptual design of a palm oil hydrotreatment reactor for commercial diesel production
66 Ingeniería química y Tecnologías relacionadas/ Chemical engineering
Vegetable oil
Hydrotreating
Trickle bed reactor
Renewable diesel
Aceite Vegetal
Hidrotratamiento
Reactor tipo trickle bed
Diesel renovable
title_short Conceptual design of a palm oil hydrotreatment reactor for commercial diesel production
title_full Conceptual design of a palm oil hydrotreatment reactor for commercial diesel production
title_fullStr Conceptual design of a palm oil hydrotreatment reactor for commercial diesel production
title_full_unstemmed Conceptual design of a palm oil hydrotreatment reactor for commercial diesel production
title_sort Conceptual design of a palm oil hydrotreatment reactor for commercial diesel production
dc.creator.fl_str_mv Vélez Manco, Juan Felipe
dc.contributor.author.spa.fl_str_mv Vélez Manco, Juan Felipe
dc.contributor.spa.fl_str_mv Molina, Alejandro
dc.subject.ddc.spa.fl_str_mv 66 Ingeniería química y Tecnologías relacionadas/ Chemical engineering
topic 66 Ingeniería química y Tecnologías relacionadas/ Chemical engineering
Vegetable oil
Hydrotreating
Trickle bed reactor
Renewable diesel
Aceite Vegetal
Hidrotratamiento
Reactor tipo trickle bed
Diesel renovable
dc.subject.proposal.spa.fl_str_mv Vegetable oil
Hydrotreating
Trickle bed reactor
Renewable diesel
Aceite Vegetal
Hidrotratamiento
Reactor tipo trickle bed
Diesel renovable
description A reactor with an industrial production of renewable diesel via palm oil hydrotreatment was conceptually designed based on laboratory-scale continuous and semi-batch reactor experiments. The conversion of vegetable oil to biodiesel through transesterication is responsible for a reduction in the use of a signi cant fraction of fossil fuels. Unfortunately, the diesel produced by transesterication has limitations such as high density, high viscosity and low cetane number. An alternative to transesteri cation is the hydrotreatment (HDT) of vegetable oils to produce a fuel with properties more similar to petroleum diésel than those of diesel obtained by transesterication. This thesis presents hydrotreating as an alternative for the production of renewable diesel in Colombia. It proposes a reaction pathway for hydrotreatment based on experiments with Rened, Bleached and Deodorized Palm Oil (RBDPO) and using a comercial solid trilobite NiMo catalyst (NiMo/).
publishDate 2014
dc.date.issued.spa.fl_str_mv 2014
dc.date.accessioned.spa.fl_str_mv 2019-07-02T11:26:30Z
dc.date.available.spa.fl_str_mv 2019-07-02T11:26:30Z
dc.type.spa.fl_str_mv Trabajo de grado - Maestría
dc.type.driver.spa.fl_str_mv info:eu-repo/semantics/masterThesis
dc.type.version.spa.fl_str_mv info:eu-repo/semantics/acceptedVersion
dc.type.content.spa.fl_str_mv Text
dc.type.redcol.spa.fl_str_mv http://purl.org/redcol/resource_type/TM
status_str acceptedVersion
dc.identifier.uri.none.fl_str_mv https://repositorio.unal.edu.co/handle/unal/55709
dc.identifier.eprints.spa.fl_str_mv http://bdigital.unal.edu.co/51154/
url https://repositorio.unal.edu.co/handle/unal/55709
http://bdigital.unal.edu.co/51154/
dc.language.iso.spa.fl_str_mv spa
language spa
dc.relation.ispartof.spa.fl_str_mv Universidad Nacional de Colombia Sede Medellín Facultad de Minas Escuela de Química y Petróleos
Escuela de Química y Petróleos
dc.relation.references.spa.fl_str_mv Vélez Manco, Juan Felipe (2014) Conceptual design of a palm oil hydrotreatment reactor for commercial diesel production. Maestría thesis, Universidad Nacional de Colombia - Sede Medellín.
dc.rights.spa.fl_str_mv Derechos reservados - Universidad Nacional de Colombia
dc.rights.coar.fl_str_mv http://purl.org/coar/access_right/c_abf2
dc.rights.license.spa.fl_str_mv Atribución-NoComercial 4.0 Internacional
dc.rights.uri.spa.fl_str_mv http://creativecommons.org/licenses/by-nc/4.0/
dc.rights.accessrights.spa.fl_str_mv info:eu-repo/semantics/openAccess
rights_invalid_str_mv Atribución-NoComercial 4.0 Internacional
Derechos reservados - Universidad Nacional de Colombia
http://creativecommons.org/licenses/by-nc/4.0/
http://purl.org/coar/access_right/c_abf2
eu_rights_str_mv openAccess
dc.format.mimetype.spa.fl_str_mv application/pdf
institution Universidad Nacional de Colombia
bitstream.url.fl_str_mv https://repositorio.unal.edu.co/bitstream/unal/55709/1/1017176429.2014.pdf
https://repositorio.unal.edu.co/bitstream/unal/55709/2/1017176429.2014.pdf.jpg
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bitstream.checksumAlgorithm.fl_str_mv MD5
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repository.name.fl_str_mv Repositorio Institucional Universidad Nacional de Colombia
repository.mail.fl_str_mv repositorio_nal@unal.edu.co
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