Nanomaterial for the control of rheological properties of hydrolyzed polyacrylamide based polymeric solutions

Enhanced oil recovery (EOR) processes were developed as a strategy to extend the productivity of mature reservoirs. Polymer flooding-based HPAM is the EOR process more implemented due to its relatively low cost and operational flexibility; however, the degradation and retention in the reservoir are...

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Autores:
Santamaria Torres, Oveimar
Tipo de recurso:
Doctoral thesis
Fecha de publicación:
2020
Institución:
Universidad Nacional de Colombia
Repositorio:
Universidad Nacional de Colombia
Idioma:
eng
OAI Identifier:
oai:repositorio.unal.edu.co:unal/79687
Acceso en línea:
https://repositorio.unal.edu.co/handle/unal/79687
https://repositorio.unal.edu.co/
Palabra clave:
Polymeric nanofluid
SiO2 Nanoparticles
Polymer Flooding
Transport in porous medium
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License
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id UNACIONAL2_cf81bdc80fd4ec83dc244dd2c0394667
oai_identifier_str oai:repositorio.unal.edu.co:unal/79687
network_acronym_str UNACIONAL2
network_name_str Universidad Nacional de Colombia
repository_id_str
dc.title.eng.fl_str_mv Nanomaterial for the control of rheological properties of hydrolyzed polyacrylamide based polymeric solutions
dc.title.translated.spa.fl_str_mv Nanomaterial para el control de propiedades reológicas de soluciones poliméricas a base de poliacrilamida hidrolizada
title Nanomaterial for the control of rheological properties of hydrolyzed polyacrylamide based polymeric solutions
spellingShingle Nanomaterial for the control of rheological properties of hydrolyzed polyacrylamide based polymeric solutions
Polymeric nanofluid
SiO2 Nanoparticles
Polymer Flooding
Transport in porous medium
title_short Nanomaterial for the control of rheological properties of hydrolyzed polyacrylamide based polymeric solutions
title_full Nanomaterial for the control of rheological properties of hydrolyzed polyacrylamide based polymeric solutions
title_fullStr Nanomaterial for the control of rheological properties of hydrolyzed polyacrylamide based polymeric solutions
title_full_unstemmed Nanomaterial for the control of rheological properties of hydrolyzed polyacrylamide based polymeric solutions
title_sort Nanomaterial for the control of rheological properties of hydrolyzed polyacrylamide based polymeric solutions
dc.creator.fl_str_mv Santamaria Torres, Oveimar
dc.contributor.advisor.none.fl_str_mv Lopera Castro, Sergio Hernando
Cortés Correa, Farid Bernal
dc.contributor.author.none.fl_str_mv Santamaria Torres, Oveimar
dc.subject.proposal.eng.fl_str_mv Polymeric nanofluid
SiO2 Nanoparticles
Polymer Flooding
Transport in porous medium
topic Polymeric nanofluid
SiO2 Nanoparticles
Polymer Flooding
Transport in porous medium
description Enhanced oil recovery (EOR) processes were developed as a strategy to extend the productivity of mature reservoirs. Polymer flooding-based HPAM is the EOR process more implemented due to its relatively low cost and operational flexibility; however, the degradation and retention in the reservoir are the main challenges. Several copolymers of polyacrylamide have been proposed to mitigate polymer deficiencies in “hard” conditions; however, these technologies are limited to favorable pricing scenarios. Nanotechnology has attracted widespread interest for use in recovery processes. Nanoparticles (NPs) incorporate new properties into traditional technologies applied in EOR. Polymer-based nanofluids or polymeric nanofluids consist of a combination of nanoparticles with polymeric solutions. Polymeric nanofluids are of great interest because they combine the advantages of inorganic NPs and organic polymers, generating synergy between the best of each of the two materials. Although numerous studies have shown a high potential of polymeric nanofluids, little evidence is available about the stability of polymeric microstructure exposed at thermal degradation, adsorption, and deformations caused by converging-diverging flow in pores. Hence, the main objective of this study is to characterize the rheological behavior of polymeric nanofluids formed by solutions of HPAM and SiO2 nanoparticles under the instability of the microstructure due to thermal degradation and concentration losses. This study provides crucial evidence about the stability of polymeric nanofluids and offers an understanding of its performance in the porous medium. Finally, it opens the landscape about the use of nanofluids in IOR/EOR processes. (Tomado de la fuente)
publishDate 2020
dc.date.issued.none.fl_str_mv 2020-10-15
dc.date.accessioned.none.fl_str_mv 2021-06-23T16:39:43Z
dc.date.available.none.fl_str_mv 2021-06-23T16:39:43Z
dc.type.spa.fl_str_mv Trabajo de grado - Doctorado
dc.type.driver.spa.fl_str_mv info:eu-repo/semantics/doctoralThesis
dc.type.version.spa.fl_str_mv info:eu-repo/semantics/acceptedVersion
dc.type.coar.spa.fl_str_mv http://purl.org/coar/resource_type/c_db06
dc.type.content.spa.fl_str_mv Text
dc.type.redcol.spa.fl_str_mv http://purl.org/redcol/resource_type/TD
format http://purl.org/coar/resource_type/c_db06
status_str acceptedVersion
dc.identifier.uri.none.fl_str_mv https://repositorio.unal.edu.co/handle/unal/79687
dc.identifier.instname.spa.fl_str_mv Universidad Nacional de Colombia
dc.identifier.reponame.spa.fl_str_mv Repositorio Institucional Universidad Nacional de Colombia
dc.identifier.repourl.spa.fl_str_mv https://repositorio.unal.edu.co/
url https://repositorio.unal.edu.co/handle/unal/79687
https://repositorio.unal.edu.co/
identifier_str_mv Universidad Nacional de Colombia
Repositorio Institucional Universidad Nacional de Colombia
dc.language.iso.spa.fl_str_mv eng
language eng
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spelling Attribution-NonCommercial-NoDerivatives 4.0 InternacionalAttribution-NonCommercial-NoDerivatives 4.0 Internacionalhttp://creativecommons.org/licenses/by-nc-nd/4.0/http://purl.org/coar/access_right/c_abf2Lopera Castro, Sergio Hernandoc1d2db9f0161570ed15ed1b535ce8010Cortés Correa, Farid Bernal6f38276fc4b86e342a0d27ccc8379886Santamaria Torres, Oveimar39146c03050e68c361b2ecd750b639132021-06-23T16:39:43Z2021-06-23T16:39:43Z2020-10-15https://repositorio.unal.edu.co/handle/unal/79687Universidad Nacional de ColombiaRepositorio Institucional Universidad Nacional de Colombiahttps://repositorio.unal.edu.co/Enhanced oil recovery (EOR) processes were developed as a strategy to extend the productivity of mature reservoirs. Polymer flooding-based HPAM is the EOR process more implemented due to its relatively low cost and operational flexibility; however, the degradation and retention in the reservoir are the main challenges. Several copolymers of polyacrylamide have been proposed to mitigate polymer deficiencies in “hard” conditions; however, these technologies are limited to favorable pricing scenarios. Nanotechnology has attracted widespread interest for use in recovery processes. Nanoparticles (NPs) incorporate new properties into traditional technologies applied in EOR. Polymer-based nanofluids or polymeric nanofluids consist of a combination of nanoparticles with polymeric solutions. Polymeric nanofluids are of great interest because they combine the advantages of inorganic NPs and organic polymers, generating synergy between the best of each of the two materials. Although numerous studies have shown a high potential of polymeric nanofluids, little evidence is available about the stability of polymeric microstructure exposed at thermal degradation, adsorption, and deformations caused by converging-diverging flow in pores. Hence, the main objective of this study is to characterize the rheological behavior of polymeric nanofluids formed by solutions of HPAM and SiO2 nanoparticles under the instability of the microstructure due to thermal degradation and concentration losses. This study provides crucial evidence about the stability of polymeric nanofluids and offers an understanding of its performance in the porous medium. Finally, it opens the landscape about the use of nanofluids in IOR/EOR processes. (Tomado de la fuente)Los procesos de recuperación mejorada de petróleo (EOR) se desarrollaron como una estrategia para extender la productividad de los yacimientos maduros. La inyección de polímeros basada en HPAM, es el proceso EOR más implementado debido a su costo relativamente bajo y flexibilidad operativa; sin embargo, la degradación y retención en el yacimiento son los principales desafíos. Se han propuesto varios copolímeros de poliacrilamida para mitigar las deficiencias del polímero en condiciones "duras"; sin embargo, estas tecnologías se limitan a escenarios de precios favorables. La nanotecnología ha atraído un interés generalizado para su uso en procesos de recuperación. Las nanopartículas (NP) incorporan nuevas propiedades a las tecnologías tradicionales aplicadas en EOR. Los nanofluidos a base de polímeros o nanofluidos poliméricos consisten en una combinación de nanopartículas con soluciones poliméricas. Los nanofluidos poliméricos son de gran interés porque combinan las ventajas de los NP inorgánicos y los polímeros orgánicos, generando sinergia entre lo mejor de cada uno de los dos materiales. Aunque numerosos estudios han demostrado un alto potencial de los nanofluidos poliméricos, hay poca evidencia disponible sobre la estabilidad de la microestructura polimérica expuesta a la degradación térmica, adsorción y deformaciones causadas por el flujo convergente-divergente en los poros. Por tanto, el objetivo principal de este estudio es caracterizar el comportamiento reológico de los nanofluidos poliméricos formados por soluciones de HPAM y nanopartículas de SiO2, bajo inestabilidad de la microestructura por degradación térmica y pérdidas de concentración. Este estudio proporciona evidencia crucial sobre la estabilidad de los nanofluidos poliméricos y ofrece una comprensión de su desempeño en el medio poroso. Finalmente, abre el panorama sobre el uso de nanofluidos en procesos IOR / EOR. 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Energies, 7(6), 3858–3871. https://doi.org/10.3390/en7063858Polymeric nanofluidSiO2 NanoparticlesPolymer FloodingTransport in porous mediumUso de nanotecnología para el potenciamiento de la técnica de recobro mejorado de agua alternada con gas (eWAG)Colciencias - Agencia Nacional de HidrocarburosLICENSElicense.txtlicense.txttext/plain; charset=utf-83964https://repositorio.unal.edu.co/bitstream/unal/79687/4/license.txtcccfe52f796b7c63423298c2d3365fc6MD54ORIGINAL80883010-2021.pdf80883010-2021.pdfMedellín Doctorado en Ingeniería - Sistemas Energéticosapplication/pdf23844764https://repositorio.unal.edu.co/bitstream/unal/79687/5/80883010-2021.pdf3ff1da5d347ee3e718bcedf1d50f95b7MD55CC-LICENSElicense_rdflicense_rdfapplication/rdf+xml; charset=utf-8805https://repositorio.unal.edu.co/bitstream/unal/79687/6/license_rdf4460e5956bc1d1639be9ae6146a50347MD56THUMBNAIL80883010-2021.pdf.jpg80883010-2021.pdf.jpgGenerated 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