Relationship between the chemical composition and atomic volume in ag- x % at zn (x ≤ 20) solid solutions
In this work the relationship between the chemical composition and atomic volume in the Ag – x % Zn (x ≤ 20) system was studied. For this purpose, 10 solid solutions were obtained by means of casting and mechanical alloying. The microstructural characterization was carried out by means of X ray diff...
- Autores:
-
Guzmán, Danny
Aguilar, Claudio
Serafini, Daniel
Rojas, Paula
Ordoñez, Stella
Olivares-Pacheco, Juan F.
- Tipo de recurso:
- Article of journal
- Fecha de publicación:
- 2014
- Institución:
- Universidad Nacional de Colombia
- Repositorio:
- Universidad Nacional de Colombia
- Idioma:
- spa
- OAI Identifier:
- oai:repositorio.unal.edu.co:unal/44840
- Acceso en línea:
- https://repositorio.unal.edu.co/handle/unal/44840
http://bdigital.unal.edu.co/34939/
- Palabra clave:
- Solid solution
atomic volume
Ag-Zn alloys
X-ray diffraction
chemical composition
- Rights
- openAccess
- License
- Atribución-NoComercial 4.0 Internacional
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| dc.title.spa.fl_str_mv |
Relationship between the chemical composition and atomic volume in ag- x % at zn (x ≤ 20) solid solutions |
| title |
Relationship between the chemical composition and atomic volume in ag- x % at zn (x ≤ 20) solid solutions |
| spellingShingle |
Relationship between the chemical composition and atomic volume in ag- x % at zn (x ≤ 20) solid solutions Solid solution atomic volume Ag-Zn alloys X-ray diffraction chemical composition |
| title_short |
Relationship between the chemical composition and atomic volume in ag- x % at zn (x ≤ 20) solid solutions |
| title_full |
Relationship between the chemical composition and atomic volume in ag- x % at zn (x ≤ 20) solid solutions |
| title_fullStr |
Relationship between the chemical composition and atomic volume in ag- x % at zn (x ≤ 20) solid solutions |
| title_full_unstemmed |
Relationship between the chemical composition and atomic volume in ag- x % at zn (x ≤ 20) solid solutions |
| title_sort |
Relationship between the chemical composition and atomic volume in ag- x % at zn (x ≤ 20) solid solutions |
| dc.creator.fl_str_mv |
Guzmán, Danny Aguilar, Claudio Serafini, Daniel Rojas, Paula Ordoñez, Stella Olivares-Pacheco, Juan F. |
| dc.contributor.author.spa.fl_str_mv |
Guzmán, Danny Aguilar, Claudio Serafini, Daniel Rojas, Paula Ordoñez, Stella Olivares-Pacheco, Juan F. |
| dc.subject.proposal.spa.fl_str_mv |
Solid solution atomic volume Ag-Zn alloys X-ray diffraction chemical composition |
| topic |
Solid solution atomic volume Ag-Zn alloys X-ray diffraction chemical composition |
| description |
In this work the relationship between the chemical composition and atomic volume in the Ag – x % Zn (x ≤ 20) system was studied. For this purpose, 10 solid solutions were obtained by means of casting and mechanical alloying. The microstructural characterization was carried out by means of X ray diffraction. The lattice parameter was obtained using the Rietveld’s method, while the chemical composition was determined by dispersive energy X-ray spectroscopy. Based on the results obtained, it can be concluded that there is an inverse lineal relationship between the atomic volume of the solid solution and its Zn concentration, which shows a negative deviation from Vegard`s law (-2.96%). Additionally, it was proposed an equation which relates the Zn concentration with the atomic volume of the solid solution, which showed a prediction error less than 12%. |
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2014 |
| dc.date.issued.spa.fl_str_mv |
2014-04-24 |
| dc.date.accessioned.spa.fl_str_mv |
2019-06-28T14:20:28Z |
| dc.date.available.spa.fl_str_mv |
2019-06-28T14:20:28Z |
| dc.type.spa.fl_str_mv |
Artículo de revista |
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http://purl.org/coar/resource_type/c_2df8fbb1 |
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info:eu-repo/semantics/article |
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http://purl.org/coar/resource_type/c_6501 |
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http://purl.org/coar/version/c_970fb48d4fbd8a85 |
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Text |
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http://purl.org/redcol/resource_type/ART |
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http://purl.org/coar/resource_type/c_6501 |
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publishedVersion |
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https://repositorio.unal.edu.co/handle/unal/44840 |
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http://bdigital.unal.edu.co/34939/ |
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https://repositorio.unal.edu.co/handle/unal/44840 http://bdigital.unal.edu.co/34939/ |
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spa |
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spa |
| dc.relation.spa.fl_str_mv |
http://revistas.unal.edu.co/index.php/dyna/article/view/35170 |
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Universidad Nacional de Colombia Revistas electrónicas UN Dyna Dyna |
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DYNA; Vol. 81, núm. 184 (2014); 144-149 Dyna; Vol. 81, núm. 184 (2014); 144-149 2346-2183 0012-7353 |
| dc.relation.references.spa.fl_str_mv |
Guzmán, Danny and Aguilar, Claudio and Serafini, Daniel and Rojas, Paula and Ordoñez, Stella and Olivares-Pacheco, Juan F. (2014) Relationship between the chemical composition and atomic volume in ag- x % at zn (x ≤ 20) solid solutions. DYNA; Vol. 81, núm. 184 (2014); 144-149 Dyna; Vol. 81, núm. 184 (2014); 144-149 2346-2183 0012-7353 . |
| dc.rights.spa.fl_str_mv |
Derechos reservados - Universidad Nacional de Colombia |
| dc.rights.coar.fl_str_mv |
http://purl.org/coar/access_right/c_abf2 |
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Atribución-NoComercial 4.0 Internacional |
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http://creativecommons.org/licenses/by-nc/4.0/ |
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info:eu-repo/semantics/openAccess |
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Atribución-NoComercial 4.0 Internacional Derechos reservados - Universidad Nacional de Colombia http://creativecommons.org/licenses/by-nc/4.0/ http://purl.org/coar/access_right/c_abf2 |
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Universidad Nacional de Colombia Sede Medellín |
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Atribución-NoComercial 4.0 InternacionalDerechos reservados - Universidad Nacional de Colombiahttp://creativecommons.org/licenses/by-nc/4.0/info:eu-repo/semantics/openAccesshttp://purl.org/coar/access_right/c_abf2Guzmán, Dannya5557134-1831-4f83-823d-885fa33f5fec300Aguilar, Claudio4e0f1fdf-fd8f-4bbb-a68e-9b4ffb8ed523300Serafini, Daniel74af9d3d-8d95-4f8b-93b8-def38c723013300Rojas, Paula7f733799-42d2-4e81-b33f-18bf97740b2c300Ordoñez, Stella2b526e0b-3c54-4965-bc06-204583e830eb300Olivares-Pacheco, Juan F.ca77e1e6-4500-4b70-89c0-ed8472b5fa563002019-06-28T14:20:28Z2019-06-28T14:20:28Z2014-04-24https://repositorio.unal.edu.co/handle/unal/44840http://bdigital.unal.edu.co/34939/In this work the relationship between the chemical composition and atomic volume in the Ag – x % Zn (x ≤ 20) system was studied. For this purpose, 10 solid solutions were obtained by means of casting and mechanical alloying. The microstructural characterization was carried out by means of X ray diffraction. The lattice parameter was obtained using the Rietveld’s method, while the chemical composition was determined by dispersive energy X-ray spectroscopy. Based on the results obtained, it can be concluded that there is an inverse lineal relationship between the atomic volume of the solid solution and its Zn concentration, which shows a negative deviation from Vegard`s law (-2.96%). Additionally, it was proposed an equation which relates the Zn concentration with the atomic volume of the solid solution, which showed a prediction error less than 12%.application/pdfspaUniversidad Nacional de Colombia Sede Medellínhttp://revistas.unal.edu.co/index.php/dyna/article/view/35170Universidad Nacional de Colombia Revistas electrónicas UN DynaDynaDYNA; Vol. 81, núm. 184 (2014); 144-149 Dyna; Vol. 81, núm. 184 (2014); 144-149 2346-2183 0012-7353Guzmán, Danny and Aguilar, Claudio and Serafini, Daniel and Rojas, Paula and Ordoñez, Stella and Olivares-Pacheco, Juan F. (2014) Relationship between the chemical composition and atomic volume in ag- x % at zn (x ≤ 20) solid solutions. DYNA; Vol. 81, núm. 184 (2014); 144-149 Dyna; Vol. 81, núm. 184 (2014); 144-149 2346-2183 0012-7353 .Relationship between the chemical composition and atomic volume in ag- x % at zn (x ≤ 20) solid solutionsArtículo de revistainfo:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501http://purl.org/coar/resource_type/c_2df8fbb1http://purl.org/coar/version/c_970fb48d4fbd8a85Texthttp://purl.org/redcol/resource_type/ARTSolid solutionatomic volumeAg-Zn alloysX-ray diffractionchemical compositionORIGINAL35170-137639-1-SP.tifimage/tiff196702https://repositorio.unal.edu.co/bitstream/unal/44840/1/35170-137639-1-SP.tif4b27f29f85710d6b688f3bc1b8b6de7dMD5135170-137649-1-SP.pngimage/png172337https://repositorio.unal.edu.co/bitstream/unal/44840/2/35170-137649-1-SP.pngaa5e24f1c65d3877ea650d0d92bfc47aMD5235170-137652-1-SP.tifimage/tiff21753056https://repositorio.unal.edu.co/bitstream/unal/44840/3/35170-137652-1-SP.tif9203be2f0c713493e027d829dce8d098MD5335170-199965-1-PB.pdfapplication/pdf1540060https://repositorio.unal.edu.co/bitstream/unal/44840/4/35170-199965-1-PB.pdf8ad32f9352b39d9256eb7a3edad9edc8MD5435170-137638-1-SP.tifimage/tiff193312https://repositorio.unal.edu.co/bitstream/unal/44840/5/35170-137638-1-SP.tif262b35e10874a4857cfc09101174340aMD5535170-137651-1-SP.tifimage/tiff21753056https://repositorio.unal.edu.co/bitstream/unal/44840/6/35170-137651-1-SP.tif621d6e4cf1c18e0200ba6aa566261ce7MD5635170-137641-1-SP.tifimage/tiff263162https://repositorio.unal.edu.co/bitstream/unal/44840/7/35170-137641-1-SP.tif5124531777f366d37758df1854e805d0MD5735170-137640-1-SP.tifimage/tiff218786https://repositorio.unal.edu.co/bitstream/unal/44840/8/35170-137640-1-SP.tiff0925bf9bd075ae42c53b92ecd6a97c3MD5835170-137654-1-SP.docapplication/msword69120https://repositorio.unal.edu.co/bitstream/unal/44840/9/35170-137654-1-SP.docebb1cb8b4622caaf7f6cb262c7510968MD5935170-137648-1-SP.tifimage/tiff1826076https://repositorio.unal.edu.co/bitstream/unal/44840/10/35170-137648-1-SP.tif34575d8c246b063fcaacace3846e3af1MD51035170-137643-1-SP.tifimage/tiff178442https://repositorio.unal.edu.co/bitstream/unal/44840/11/35170-137643-1-SP.tif39446a35539435c046e99024b76b0fb5MD51135170-137653-1-SP.tifimage/tiff1563646https://repositorio.unal.edu.co/bitstream/unal/44840/12/35170-137653-1-SP.tifd70ff7790d4f77e3f589df97143802d6MD51235170-137642-1-SP.tifimage/tiff244166https://repositorio.unal.edu.co/bitstream/unal/44840/13/35170-137642-1-SP.tif608bf52701290a746afa72c0e5377e7eMD513THUMBNAIL35170-199965-1-PB.pdf.jpg35170-199965-1-PB.pdf.jpgGenerated Thumbnailimage/jpeg9623https://repositorio.unal.edu.co/bitstream/unal/44840/14/35170-199965-1-PB.pdf.jpg55d5ecd925b31ca147b77966fe7c5ccbMD514unal/44840oai:repositorio.unal.edu.co:unal/448402024-02-24 23:08:27.607Repositorio Institucional Universidad Nacional de Colombiarepositorio_nal@unal.edu.co |