Remoción de colorantes presentes en aguas reales provenientes de un laboratorio de microbiología mediante el proceso CWAO con un catalizador Mn, Cu, y/o Fe soportado en carbón activado a partir de caucho de llanta
ilustraciones, graficas, mapas
- Autores:
-
Meneses Madroñero, Paula Stefania
- Tipo de recurso:
- Fecha de publicación:
- 2022
- Institución:
- Universidad Nacional de Colombia
- Repositorio:
- Universidad Nacional de Colombia
- Idioma:
- spa
- OAI Identifier:
- oai:repositorio.unal.edu.co:unal/82198
- Palabra clave:
- 540 - Química y ciencias afines::542 - Técnicas, procedimientos, aparatos, equipos, materiales
PURIFICACION DEL AGUA-OXIDACION
Water - purification - oxidation
Tinción de Gram
Oxidación húmeda catalítica con aire
Remoción
Caucho de llanta
CWAO
Tire rubber
Gram stain
Removal
- Rights
- openAccess
- License
- Atribución-SinDerivadas 4.0 Internacional
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UNACIONAL2 |
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Universidad Nacional de Colombia |
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| dc.title.spa.fl_str_mv |
Remoción de colorantes presentes en aguas reales provenientes de un laboratorio de microbiología mediante el proceso CWAO con un catalizador Mn, Cu, y/o Fe soportado en carbón activado a partir de caucho de llanta |
| dc.title.translated.eng.fl_str_mv |
Removal of colorants present in real water from a microbiology laboratory through the CWAO process with a Mn, Cu, and/or Fe catalyst supported on activated carbon from tire rubber |
| title |
Remoción de colorantes presentes en aguas reales provenientes de un laboratorio de microbiología mediante el proceso CWAO con un catalizador Mn, Cu, y/o Fe soportado en carbón activado a partir de caucho de llanta |
| spellingShingle |
Remoción de colorantes presentes en aguas reales provenientes de un laboratorio de microbiología mediante el proceso CWAO con un catalizador Mn, Cu, y/o Fe soportado en carbón activado a partir de caucho de llanta 540 - Química y ciencias afines::542 - Técnicas, procedimientos, aparatos, equipos, materiales PURIFICACION DEL AGUA-OXIDACION Water - purification - oxidation Tinción de Gram Oxidación húmeda catalítica con aire Remoción Caucho de llanta CWAO Tire rubber Gram stain Removal |
| title_short |
Remoción de colorantes presentes en aguas reales provenientes de un laboratorio de microbiología mediante el proceso CWAO con un catalizador Mn, Cu, y/o Fe soportado en carbón activado a partir de caucho de llanta |
| title_full |
Remoción de colorantes presentes en aguas reales provenientes de un laboratorio de microbiología mediante el proceso CWAO con un catalizador Mn, Cu, y/o Fe soportado en carbón activado a partir de caucho de llanta |
| title_fullStr |
Remoción de colorantes presentes en aguas reales provenientes de un laboratorio de microbiología mediante el proceso CWAO con un catalizador Mn, Cu, y/o Fe soportado en carbón activado a partir de caucho de llanta |
| title_full_unstemmed |
Remoción de colorantes presentes en aguas reales provenientes de un laboratorio de microbiología mediante el proceso CWAO con un catalizador Mn, Cu, y/o Fe soportado en carbón activado a partir de caucho de llanta |
| title_sort |
Remoción de colorantes presentes en aguas reales provenientes de un laboratorio de microbiología mediante el proceso CWAO con un catalizador Mn, Cu, y/o Fe soportado en carbón activado a partir de caucho de llanta |
| dc.creator.fl_str_mv |
Meneses Madroñero, Paula Stefania |
| dc.contributor.advisor.none.fl_str_mv |
Pérez Flórez, Alejandro Ramírez Franco, José Herney |
| dc.contributor.author.none.fl_str_mv |
Meneses Madroñero, Paula Stefania |
| dc.contributor.researchgroup.spa.fl_str_mv |
Investigación en Tecnología Ambiental y de Materiales |
| dc.subject.ddc.spa.fl_str_mv |
540 - Química y ciencias afines::542 - Técnicas, procedimientos, aparatos, equipos, materiales |
| topic |
540 - Química y ciencias afines::542 - Técnicas, procedimientos, aparatos, equipos, materiales PURIFICACION DEL AGUA-OXIDACION Water - purification - oxidation Tinción de Gram Oxidación húmeda catalítica con aire Remoción Caucho de llanta CWAO Tire rubber Gram stain Removal |
| dc.subject.lemb.spa.fl_str_mv |
PURIFICACION DEL AGUA-OXIDACION |
| dc.subject.lemb.eng.fl_str_mv |
Water - purification - oxidation |
| dc.subject.proposal.spa.fl_str_mv |
Tinción de Gram Oxidación húmeda catalítica con aire Remoción Caucho de llanta |
| dc.subject.proposal.eng.fl_str_mv |
CWAO Tire rubber Gram stain Removal |
| description |
ilustraciones, graficas, mapas |
| publishDate |
2022 |
| dc.date.accessioned.none.fl_str_mv |
2022-08-30T16:51:49Z |
| dc.date.available.none.fl_str_mv |
2022-08-30T16:51:49Z |
| dc.date.issued.none.fl_str_mv |
2022 |
| dc.type.spa.fl_str_mv |
Trabajo de grado - Maestría |
| dc.type.driver.spa.fl_str_mv |
info:eu-repo/semantics/masterThesis |
| dc.type.version.spa.fl_str_mv |
info:eu-repo/semantics/acceptedVersion |
| dc.type.content.spa.fl_str_mv |
Text |
| dc.type.redcol.spa.fl_str_mv |
http://purl.org/redcol/resource_type/TM |
| status_str |
acceptedVersion |
| dc.identifier.uri.none.fl_str_mv |
https://repositorio.unal.edu.co/handle/unal/82198 |
| dc.identifier.instname.spa.fl_str_mv |
Universidad Nacional de Colombia |
| dc.identifier.reponame.spa.fl_str_mv |
Repositorio Institucional Universidad Nacional de Colombia |
| dc.identifier.repourl.spa.fl_str_mv |
https://repositorio.unal.edu.co/ |
| url |
https://repositorio.unal.edu.co/handle/unal/82198 https://repositorio.unal.edu.co/ |
| identifier_str_mv |
Universidad Nacional de Colombia Repositorio Institucional Universidad Nacional de Colombia |
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spa |
| language |
spa |
| dc.relation.indexed.spa.fl_str_mv |
RedCol LaReferencia |
| dc.relation.references.spa.fl_str_mv |
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Journal of Cleaner Production, 234, 124–131. https://doi.org/10.1016/j.jclepro.2019.06.164 Yang, X., Li, Y., Du, Q., Sun, J., Chen, L., Hu, S., Wang, Z., Xia, Y., & Xia, L. (2015). Highly effective removal of basic fuchsin from aqueous solutions by anionic polyacrylamide/graphene oxide aerogels. Journal of Colloid and Interface Science, 453, 107–114. https://doi.org/10.1016/J.JCIS.2015.04.042 Yang, Y., Ding, X., Chang, K., Zeng, Z., Hou, Y., & Huang, Z. (2022). In situ DRIFTS combined with GC–MS to identify the catalytic oxidation process of dibenzofuran over activated carbon-supported transition metals oxide catalysts. Fuel, 312, 122492. https://doi.org/10.1016/J.FUEL.2021.122492 Yin, J., Cai, J., Yin, C., Gao, L., & Zhou, J. (2016). Degradation performance of crystal violet over CuO@AC and CeO 2 -CuO@AC catalysts using microwave catalytic oxidation degradation method. 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xviii, 116 páginas |
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Universidad Nacional de Colombia |
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Bogotá - Ingeniería - Maestría en Ingeniería - Ingeniería Química |
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Departamento de Ingeniería Química y Ambiental |
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Atribución-SinDerivadas 4.0 Internacionalhttp://creativecommons.org/licenses/by-nd/4.0/info:eu-repo/semantics/openAccesshttp://purl.org/coar/access_right/c_abf2Pérez Flórez, Alejandro882e42a7e5df421016ee67b45b9affcdRamírez Franco, José Herney50c4f1e63d416e6c5aaa0e73a06bd6a3Meneses Madroñero, Paula Stefania438839c1b9c87552b47c860e36940877Investigación en Tecnología Ambiental y de Materiales2022-08-30T16:51:49Z2022-08-30T16:51:49Z2022https://repositorio.unal.edu.co/handle/unal/82198Universidad Nacional de ColombiaRepositorio Institucional Universidad Nacional de Colombiahttps://repositorio.unal.edu.co/ilustraciones, graficas, mapasEl desarrollo de nuevas tecnologías, permiten el control de sustancias químicas peligrosas presentes en los efluentes de diversas industrias o recintos educativos, cuya remoción no es factible por métodos convencionales. Asimismo, el aumento en el número de vehículos cada año es mayor y esto está generando residuos como el caucho de las llantas. En esta investigación se emplea el caucho de llanta como materia prima para producir carbón activado que se usa como soporte de óxidos metálicos de Fe, Cu, Mn y una mezcla de los dos mejores metales analizados (CuMn), estos catalizadores son preparados por medio del método de impregnación húmeda y caracterizados por XRD, SEM-EDX, TPR-H2, FTIR y propiedades texturales. Los sólidos se evaluaron mediante la oxidación húmeda catalítica con aire de un efluente contaminado con colorantes de tinción de Gram a condiciones ambientales de reacción: 25 °C, presión atmosférica. y flujo de aire de 2 mL/min. Los resultados experimentales indicaron porcentajes de remoción del 98%, eliminación de DQO del 33% en tan solo 3 horas de reacción y conversión del carbono orgánico total (COT) del 80% a las 24 horas de reacción. El catalizador de Cu con una relación másica del 5% demostró ser el catalizador con mayor actividad catalítica. (Texto tomado de la fuente)The development of new technologies allows the control of dangerous chemical substances present in the water currents of various industries or educational facilities, whose removal is not feasible by conventional methods. Similarly, the increase in the number of motor vehicles is greater each year and this is generating waste such as tire rubber. In this research, tire rubber is use as a raw material to produce activated carbon that is use as a support for metal oxides of Fe, Cu, Mn and a mixture of the two best metals analyzed (CuMn), these catalysts are prepared by means of the wet impregnation method and characterized by XRD, SEM-EDX, TPR-H2, FTIR and textural properties. Water contaminated with Gram stain dyes was treated with the synthesized solids by catalytic wet oxidation with air under ambient conditions: 25°C, atmospheric pressure and air flow of 2 mL/min. The experimental results indicated percentages of colorant removal of 98%, COD elimination of 33% in only 3 hours of reaction and conversion of total organic carbon (COT) of 80% at 24 hours of reaction. The Cu catalyst with a mass ratio of 5% proved to be the catalyst with the highest catalytic activity.MaestríaMagíster en Ingeniería - Ingeniería QuímicaCatálisis Ambientalxviii, 116 páginasapplication/pdfspaUniversidad Nacional de ColombiaBogotá - Ingeniería - Maestría en Ingeniería - Ingeniería QuímicaDepartamento de Ingeniería Química y AmbientalFacultad de IngenieríaBogotá, ColombiaUniversidad Nacional de Colombia - Sede Bogotá540 - Química y ciencias afines::542 - Técnicas, procedimientos, aparatos, equipos, materialesPURIFICACION DEL AGUA-OXIDACIONWater - purification - oxidationTinción de GramOxidación húmeda catalítica con aireRemociónCaucho de llantaCWAOTire rubberGram stainRemovalRemoción de colorantes presentes en aguas reales provenientes de un laboratorio de microbiología mediante el proceso CWAO con un catalizador Mn, Cu, y/o Fe soportado en carbón activado a partir de caucho de llantaRemoval of colorants present in real water from a microbiology laboratory through the CWAO process with a Mn, Cu, and/or Fe catalyst supported on activated carbon from tire rubberTrabajo de grado - Maestríainfo:eu-repo/semantics/masterThesisinfo:eu-repo/semantics/acceptedVersionTexthttp://purl.org/redcol/resource_type/TMRedColLaReferenciaAbu Sharib, A. S. A. A., Bonilla-Petriciolet, A., Selim, A. Q., Mohamed, E. A., & Seliem, M. K. (2021). Utilizing modified weathered basalt as a novel approach in the preparation of Fe3O4 nanoparticles: Experimental and theoretical studies for crystal violet adsorption. Journal of Environmental Chemical Engineering, 9(6), 106220. https://doi.org/10.1016/J.JECE.2021.106220Ahmad, A., Jini, D., Aravind, M., Parvathiraja, C., Ali, R., Kiyani, M. Z., & Alothman, A. (2020). A novel study on synthesis of egg shell based activated carbon for degradation of methylene blue via photocatalysis. Arabian Journal of Chemistry, 13(12), 8717– 8722. https://doi.org/10.1016/j.arabjc.2020.10.002Ahmed, S., Ahmad, Z., Kumar, A., Rafiq, M., Vashistha, V. K., Ashiq, M. N., & Kumar, A. (2021). Effective removal of methylene blue using nanoscale manganese oxide rods and spheres derived from different precursors of manganese. Journal of Physics and Chemistry of Solids, 155, 110121. https://doi.org/10.1016/J.JPCS.2021.110121Al-Rahbi, A. S., & Williams, P. T. (2016). Production of activated carbons from waste tyres for low temperature NOx control. Waste Management, 49, 188–195. https://doi.org/10.1016/J.WASMAN.2016.01.030Benhamed, I., Barthe, L., Kessas, R., Julcour, C., & Delmas, H. (2016). Effect of transition metal impregnation on oxidative regeneration of activated carbon by catalytic wet air oxidation. Applied Catalysis B: Environmental, 187, 228–237. https://doi.org/10.1016/j.apcatb.2016.01.016Berkün Olgun, Ö., Palas, B., Atalay, S., & Ersöz, G. (2021). Photocatalytic oxidation and catalytic wet air oxidation of real pharmaceutical wastewater in the presence of Fe and LaFeO3 doped activated carbon catalysts. Chemical Engineering Research and Design, 171, 421–432. https://doi.org/10.1016/J.CHERD.2021.05.017Bes Monge, Sra. S., Silva, Dr. A. M. T., & Bengoa, Dr. C. (2016). Manual técnico sobre procesos de oxidación avanzada aplicados al tratamiento de aguas residuales industriales. In (Tritón-316Rt0506) (Issues 978-84-09-08637–5). http://www.cyted.org/sites/default/files/manual_sobre_oxidaciones_avanzadas_0.pdfBessashia, W., Berredjem, Y., Hattab, Z., & Bououdina, M. (2020). Removal of Basic Fuchsin from water by using mussel powdered eggshell membrane as novel bioadsorbent: Equilibrium, kinetics, and thermodynamic studies. Environmental Research, 186, 109484. https://doi.org/10.1016/J.ENVRES.2020.109484Cao, D. J., Wang, J. J., Zhang, Q., Wen, Y. Z., Dong, B., Liu, R. J., Yang, X., & Geng, G. (2019). Biodegradation of triphenylmethane dye crystal violet by Cedecea davisae. Spectrochimica Acta - Part A: Molecular and Biomolecular Spectroscopy, 210, 9–13. https://doi.org/10.1016/j.saa.2018.11.004Castro Carreño, N., & Rojas Chitiva, W. J. (2018). Síntesis de óxidos mixtos de mn-fe mediante el método de autocombustión para la degradación de cristal violeta en aguas residuales [Fundación Universidad de América]. https://repository.uamerica.edu.co/handle/20.500.11839/6703Celis-Salazar, P., Zea, H., Luhrs, C., Phillips, J., & Ramirez, J. (2015). Iron on carbon catalaysts for the photocatalytic degradation orange II. Journal of Advanced Oxidation Technologies, 18(2), 295–302. https://doi.org/10.1515/JAOTS-2015- 0216/MACHINEREADABLECITATION/RISChang, R., & Goldsby, K. (2017). Química (McGraw-Hill/Interamericana Editores, Ed.; 12th ed., Vol. 12). McGraw-Hill. http://www.ebooks7- 24.com.ezproxy.unal.edu.co/stage.aspx?il=&pg=&ed=Chatwal, G. R. (2009). Synthetic Dyes (M. Arora, Ed.; 1st ed.). Himalaya Publishing House. https://ebookcentral.proquest.com/lib/unal/reader.action?docID=3011371&query=dy esCherono, F., Mburu, N., & Kakoi, B. (2021). 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