Fabricación de películas delgadas conductoras y transparentes a partir de nanohilos de cobre
ilustración, fotografías, diagramas
- Autores:
-
Perez Ayala, Yineth Melissa
- Tipo de recurso:
- Fecha de publicación:
- 2023
- Institución:
- Universidad Nacional de Colombia
- Repositorio:
- Universidad Nacional de Colombia
- Idioma:
- spa
- OAI Identifier:
- oai:repositorio.unal.edu.co:unal/85519
- Palabra clave:
- 530 - Física::535 - Luz y radiación relacionada
530 - Física::539 - Física moderna
540 - Química y ciencias afines::541 - Química física
Nanohilos de cobre
Electrodo transparente
Síntesis hidrotérmica
Conductividad
Película delgada
Copper nanowires
Transparent electrodes
Hydrothermal synthesis
Conductivity
Thin films
nanowire
reducing agent
nanostructure
nanohilo
agente reductor
nanoestructura
- Rights
- openAccess
- License
- Reconocimiento 4.0 Internacional
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| dc.title.spa.fl_str_mv |
Fabricación de películas delgadas conductoras y transparentes a partir de nanohilos de cobre |
| dc.title.translated.eng.fl_str_mv |
Fabrication of copper nanowires based transparent and conductive thin films |
| title |
Fabricación de películas delgadas conductoras y transparentes a partir de nanohilos de cobre |
| spellingShingle |
Fabricación de películas delgadas conductoras y transparentes a partir de nanohilos de cobre 530 - Física::535 - Luz y radiación relacionada 530 - Física::539 - Física moderna 540 - Química y ciencias afines::541 - Química física Nanohilos de cobre Electrodo transparente Síntesis hidrotérmica Conductividad Película delgada Copper nanowires Transparent electrodes Hydrothermal synthesis Conductivity Thin films nanowire reducing agent nanostructure nanohilo agente reductor nanoestructura |
| title_short |
Fabricación de películas delgadas conductoras y transparentes a partir de nanohilos de cobre |
| title_full |
Fabricación de películas delgadas conductoras y transparentes a partir de nanohilos de cobre |
| title_fullStr |
Fabricación de películas delgadas conductoras y transparentes a partir de nanohilos de cobre |
| title_full_unstemmed |
Fabricación de películas delgadas conductoras y transparentes a partir de nanohilos de cobre |
| title_sort |
Fabricación de películas delgadas conductoras y transparentes a partir de nanohilos de cobre |
| dc.creator.fl_str_mv |
Perez Ayala, Yineth Melissa |
| dc.contributor.advisor.none.fl_str_mv |
Ardila Vargas, Angel Miguel |
| dc.contributor.author.none.fl_str_mv |
Perez Ayala, Yineth Melissa |
| dc.contributor.educationalvalidator.none.fl_str_mv |
Carriazo Baños, Jose Gregorio |
| dc.contributor.researchgroup.spa.fl_str_mv |
Grupo de física aplicada |
| dc.subject.ddc.spa.fl_str_mv |
530 - Física::535 - Luz y radiación relacionada 530 - Física::539 - Física moderna 540 - Química y ciencias afines::541 - Química física |
| topic |
530 - Física::535 - Luz y radiación relacionada 530 - Física::539 - Física moderna 540 - Química y ciencias afines::541 - Química física Nanohilos de cobre Electrodo transparente Síntesis hidrotérmica Conductividad Película delgada Copper nanowires Transparent electrodes Hydrothermal synthesis Conductivity Thin films nanowire reducing agent nanostructure nanohilo agente reductor nanoestructura |
| dc.subject.proposal.spa.fl_str_mv |
Nanohilos de cobre Electrodo transparente Síntesis hidrotérmica Conductividad Película delgada |
| dc.subject.proposal.eng.fl_str_mv |
Copper nanowires Transparent electrodes Hydrothermal synthesis Conductivity Thin films |
| dc.subject.wikidata.eng.fl_str_mv |
nanowire reducing agent nanostructure |
| dc.subject.wikidata.spa.fl_str_mv |
nanohilo agente reductor nanoestructura |
| description |
ilustración, fotografías, diagramas |
| publishDate |
2023 |
| dc.date.issued.none.fl_str_mv |
2023 |
| dc.date.accessioned.none.fl_str_mv |
2024-01-30T15:59:26Z |
| dc.date.available.none.fl_str_mv |
2024-01-30T15:59:26Z |
| dc.type.spa.fl_str_mv |
Trabajo de grado - Maestría |
| dc.type.driver.spa.fl_str_mv |
info:eu-repo/semantics/masterThesis |
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info:eu-repo/semantics/acceptedVersion |
| dc.type.content.spa.fl_str_mv |
Text |
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http://purl.org/redcol/resource_type/TM |
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acceptedVersion |
| dc.identifier.uri.none.fl_str_mv |
https://repositorio.unal.edu.co/handle/unal/85519 |
| dc.identifier.instname.spa.fl_str_mv |
Universidad Nacional de Colombia |
| dc.identifier.reponame.spa.fl_str_mv |
Repositorio Institucional Universidad Nacional de Colombia |
| dc.identifier.repourl.spa.fl_str_mv |
https://repositorio.unal.edu.co/ |
| url |
https://repositorio.unal.edu.co/handle/unal/85519 https://repositorio.unal.edu.co/ |
| identifier_str_mv |
Universidad Nacional de Colombia Repositorio Institucional Universidad Nacional de Colombia |
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spa |
| language |
spa |
| dc.relation.references.spa.fl_str_mv |
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Caltun, eds., Woodhead Publishing, 2023, págs. 309-334, isbn: 978-0-12-823717-5. doi: https:// doi . org / 10 . 1016 / B978 - 0 - 12 - 823717 - 5 . 00021 - 8. dirección: https : / / www . sciencedirect.com/science/article/pii/B9780128237175000218. W. Commons, File:Cu-pourbaix-diagram.svg, https : / / commons . wikimedia . org / wiki/File:Cu-pourbaix-diagram.svg, [Accessed: 14-08-2023], 2007. S. HwanáKo et al., “A dual-scale metal nanowire network transparent conductor for highly efficient and flexible organic light emitting diodes,” Nanoscale, vol. 9, n.o 5, págs. 1978-1985, 2017. D. Lee, H. Lee, Y. Ahn e Y. Lee, “High-performance flexible transparent conductive film based on graphene/AgNW/graphene sandwich structure,” Carbon, vol. 81, págs. 439-446, 2015. S. Sharma, S. Shriwastava, S. Kumar, K. Bhatt y C. C. Tripathi, “Alternative transparent conducting electrode materials for flexible optoelectronic devices,” Opto-Electronics Review, vol. 26, n.o 3, págs. 223-235, 2018. S. H. Kim, W. I. Choi, K. H. Kim, D. J. Yang, S. Heo y D.-J. Yun, “Nanoscale chemical and electrical stabilities of graphene-covered silver nanowire networks for transparent conducting electrodes,” Scientific reports, vol. 6, n.o 1, págs. 1-12, 2016. M. Zhang, S. Fang, A. A. Zakhidov et al., “Strong, transparent, multifunctional, carbon nanotube sheets,” science, vol. 309, n.o 5738, págs. 1215-1219, 2005. R. V. Salvatierra, C. E. Cava, L. S. Roman y A. J. Zarbin, “ITO-free and flexible organic photovoltaic device based on high transparent and conductive polyaniline/carbon nanotube thin films,” Advanced Functional Materials, vol. 23, n.o 12, págs. 1490-1499, 2013. S. Bae, H. Kim, Y. Lee et al., “Roll-to-roll production of 30-inch graphene films for transparent electrodes,” Nature nanotechnology, vol. 5, n.o 8, págs. 574-578, 2010. P. Blake, P. D. Brimicombe, R. R. Nair et al., “Graphene-based liquid crystal device,” Nano letters, vol. 8, n.o 6, págs. 1704-1708, 2008. R. Das y H. S. 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Bol, “Chemical doping of large-area stacked graphene films for use as transparent, conducting electrodes,” ACS nano, vol. 4, n.o 7, págs. 3839-3844, 2010. S. L. Hellstrom, M. Vosgueritchian, R. M. Stoltenberg et al., “Strong and stable doping of carbon nanotubes and graphene by MoO x for transparent electrodes,” Nano letters, vol. 12, n.o 7, págs. 3574-3580, 2012. T. M. Higgins y J. N. Coleman, “Avoiding resistance limitations in high-performance transparent supercapacitor electrodes based on large-area, high-conductivity PEDOT: PSS films,” ACS applied materials & interfaces, vol. 7, n.o 30, págs. 16 495-16 506, 2015. I.-K. Suh, H. Ohta e Y. Waseda, “High-temperature thermal expansion of six metallic elements measured by dilatation method and X-ray diffraction,” Journal of Materials Science, vol. 23, págs. 757-760, 1988. N. Calos, J. Forrester y G. Schaffer, “A crystallographic contribution to the mechanism of a mechanically induced solid state reaction,” Journal of Solid State Chemistry, vol. 122, n.o 2, págs. 273-280, 199 A. Kirfel y K. Eichhorn, “Accurate structure analysis with synchrotron radiation. The electron density in Al2O3 and Cu2O,” Acta Crystallographica Section A: Foundations of Crystallography, vol. 46, n.o 4, págs. 271-284, 1990 S. Matsuyama, Y. Takizawa, S. Kinugasa, K. Tanabe y T. Tamura, Spectral Database for Organic Compounds SDBS, https://sdbs.db.aist.go.jp/sdbs/cgi-bin/cre_ index.cgi, Accessed: 2023-07-3. THE FINGERPRINT REGION OF AN INFRA-RED SPECTRUM, https://www. chemguide.co.uk/analysis/ir/fingerprint.html, Accessed: 2023-07-20. Q.-m. LIU, D.-b. ZHOU, Y. YAMAMOTO, R. ICHINO y M. OKIDO, “Preparation of Cu nanoparticles with NaBH4 by aqueous reduction method,” Transactions of Nonferrous Metals Society of China, vol. 22, n.o 1, págs. 117-123, 2012. R. Betancourt-Galindo, P. Reyes-Rodriguez, B. Puente-Urbina et al., “Synthesis of copper nanoparticles by thermal decomposition and their antimicrobial properties,” Journal of Nanomaterials, vol. 2014, págs. 10-10, 2014. M. Salavati-Niasari, F. Davar y N. Mir, “Synthesis and characterization of metallic copper nanoparticles via thermal decomposition,” Polyhedron, vol. 27, n.o 17, págs. 3514-3518, 2008. K. Mikami, Y. Kido, Y. Akaishi, A. Quitain y T. Kida, “Synthesis of Cu2O/CuO nanocrystals and their application to H2S sensing,” Sensors, vol. 19, n.o 1, pág. 211, 2019. |
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Reconocimiento 4.0 Internacionalhttp://creativecommons.org/licenses/by/4.0/info:eu-repo/semantics/openAccesshttp://purl.org/coar/access_right/c_abf2Ardila Vargas, Angel Miguel62d8f9feaac799d1feffd0d7485e263aPerez Ayala, Yineth Melissa9fa7bac5ff2aa68ccc4536935f72560dCarriazo Baños, Jose GregorioGrupo de física aplicada2024-01-30T15:59:26Z2024-01-30T15:59:26Z2023https://repositorio.unal.edu.co/handle/unal/85519Universidad Nacional de ColombiaRepositorio Institucional Universidad Nacional de Colombiahttps://repositorio.unal.edu.co/ilustración, fotografías, diagramasThe main objective of this project was to fabricate copper nanowires (CuNWs) thin films with good optical and electrical properties, i.e., conductive, and transparent electrodes. For this purpose, different procedures were assessed to obtain Cu nanowires by a hydrothermal method, where tests of optimum reducing agents’ concentrations were done. The synthesis was carried out using copper (II) chloride dihydrate (CuCl2· 2H2O) as copper precursor and Octadecylamine (ODA) as surfactant. In this first phase of the project, the results obtained by using ascorbic acid as a reducing agent were compared with those obtained with glucose, where the latter produced the best nanowires. After the hydrothermal procedure CuNWs were obtained together with other unwanted nanostructures. Therefore, a suitable purification method was researched. The nanowires were kept in hexane and thin films were fabricated by the spin coating method. Thin films were characterized using the following techniques: scanning electron microscopy (SEM), UV-VIS spectrophotometry studies, IR, and sheet resistance measurement. The above with the intention of studying the optoelectrical and morphological properties of the Cu nanowire thin films as a function of the synthesis conditions. The results included transmittance spectrum between 28 and 80 % at λ = 550 nm. Also, Rs values were found to be 4.61, 8.76 and 1183 Ω/□. Moreover, reduction methods were investigated and PEDOT:PSS films were used to improve thin films properties. This work was conducted with the aim of fabricating conductive and transparent electrodes that can be used as substitutes of indium tin oxide (ITO) electrodes.El objetivo principal en este proyecto fue fabricar películas delgadas de nanohilos de cobre (Cu) que presentaran buenas propiedades ópticas y eléctricas, es decir, películas conductivas y transparentes. Para ello se probaron diferentes procedimientos para la obtención de los nanohilos de Cu mediante síntesis hidrotérmica, procurando establecer la óptima concentración de agentes de reducción usando ácido ascórbido y glucosa. Además, la síntesis se realizó usando cloruro de cobre (II) dihidratado (CuCl2・ 2H2O) como precursor del cobre y Octadecilamina (ODA) como surfactante. En primer lugar se determinó que el uso de glucosa permitía obtener mejores nanohilos. Así mismo, el método hidrotérmico fue usado en la síntesis y se obtuvieron tanto nanohilos como nanopartículas, por lo que un método de purificación se usó para la separación de los nanohilos. Las películas delgadas fabricadas por Spin Coating se caracterizaron usando las siguientes técnicas: microscopía electrónica de barrido (MEB), espectrofotometría UV-VIS, IR, medición de la resistencia y de la resistencia de hoja. Con esto se determinaron las propiedades optoeléctricas y morfológicas de las películas delgadas de nanohilos de Cu. Se encontraron espectros de transmitancia de entre 28 y 80% y resistencia de hoja de 4.61, 8.76 y 1183 Ω/□. Métodos de reducción fueron estudiados para mejorar la conductividad de las películas así como uso de PEDOT:PSS para mejorar sus propiedades. Todo lo anterior se hizo con el ánimo de fabricar electrodos conductivos y transparentes que puedan ser usados como sustituto de los electrodos de ITO (óxido de indio y estaño). (Texto tomado de la fuente)MaestríaMagíster en Ciencias - FísicaFísica aplicadaxvi, 78 páginasapplication/pdfspaUniversidad Nacional de ColombiaBogotá - Ciencias - Maestría en Ciencias - FísicaFacultad de CienciasBogotá, ColombiaUniversidad Nacional de Colombia - Sede Bogotá530 - Física::535 - Luz y radiación relacionada530 - Física::539 - Física moderna540 - Química y ciencias afines::541 - Química físicaNanohilos de cobreElectrodo transparenteSíntesis hidrotérmicaConductividadPelícula delgadaCopper nanowiresTransparent electrodesHydrothermal synthesisConductivityThin filmsnanowirereducing agentnanostructurenanohiloagente reductornanoestructuraFabricación de películas delgadas conductoras y transparentes a partir de nanohilos de cobreFabrication of copper nanowires based transparent and conductive thin filmsTrabajo de grado - Maestríainfo:eu-repo/semantics/masterThesisinfo:eu-repo/semantics/acceptedVersionTexthttp://purl.org/redcol/resource_type/TMJ.-Y. Lee, S. T. Connor, Y. Cui y P. 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