The influence of the glycerin concentration on the porous structure of ferritic stainless steel obtained by anodization

Anodizing of ferritic stainless steel has been used for decoration purposes to obtain a barrier effect. The most commonly used electrolyte for this process is INCO (5M H2SO4 + 2,5M CrO3). INCO electrolyte with glycerin addition induces the formation of ordered porous structures, because glycerin red...

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Autores:
Bervian, Alexander
Ludwig, Gustavo Alberto
Kunst, Sandra Raquel
Rossa Beltrami, Lílian Vanessa
Dewes Moura, Angela Beatrice
Malfatti, Célia Fraga
Oliveira, Cláudia Trindade
Tipo de recurso:
Article of journal
Fecha de publicación:
2015
Institución:
Universidad Nacional de Colombia
Repositorio:
Universidad Nacional de Colombia
Idioma:
spa
OAI Identifier:
oai:repositorio.unal.edu.co:unal/60732
Acceso en línea:
https://repositorio.unal.edu.co/handle/unal/60732
http://bdigital.unal.edu.co/59064/
Palabra clave:
62 Ingeniería y operaciones afines / Engineering
Anodizing
ferritic stainless steel
glycerin
porous structure.
Rights
openAccess
License
Atribución-NoComercial 4.0 Internacional
Description
Summary:Anodizing of ferritic stainless steel has been used for decoration purposes to obtain a barrier effect. The most commonly used electrolyte for this process is INCO (5M H2SO4 + 2,5M CrO3). INCO electrolyte with glycerin addition induces the formation of ordered porous structures, because glycerin reduces the electrolyte conductivity. Ferritic stainless steel was anodized in electrolyte composed by 2M H2SO4 with glycerin addition in different concentrations, without chromium oxide addition. It was observed that the addition of 90 v/v% glycerin promoted a reduction in the electrolyte conductivity, which caused an increase in the anodizing potential. The glycerin addition to the electrolyte diminished the oxide dissolution in the electrolytic solution, promoting the formation of an oxide with an ordered porous structure.