Desarrollo de un modelo fenomenológico y simulación numérica de la remediación química del daño de formación por precipitación de asfaltenos

En esta tesis se presenta el desarrollo de un modelo fenomenológico para la remediación química del daño de formación por precipitación de asfaltenos. Se estableció el modelo matemático de la fenomenología que se presenta al inyectar tratamientos químicos a un yacimiento con el fin de revertir las p...

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Autores:
Olaya Marín, Guiber
Tipo de recurso:
Work document
Fecha de publicación:
2020
Institución:
Universidad Nacional de Colombia
Repositorio:
Universidad Nacional de Colombia
Idioma:
spa
OAI Identifier:
oai:repositorio.unal.edu.co:unal/78730
Acceso en línea:
https://repositorio.unal.edu.co/handle/unal/78730
Palabra clave:
660 - Ingeniería química
620 - Ingeniería y operaciones afines
550 - Ciencias de la tierra
Asfaltenos
Disolución
Modelo fenomenológico
Remediación química
Daño de formación
Asphaltenes
Dissolution
Phenomenological model
Chemical remediation
Formation damage
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Atribución-NoComercial-SinDerivadas 4.0 Internacional
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oai_identifier_str oai:repositorio.unal.edu.co:unal/78730
network_acronym_str UNACIONAL2
network_name_str Universidad Nacional de Colombia
repository_id_str
dc.title.spa.fl_str_mv Desarrollo de un modelo fenomenológico y simulación numérica de la remediación química del daño de formación por precipitación de asfaltenos
dc.title.alternative.spa.fl_str_mv Development of a phenomenological model and numerical simulation of the chemical remediation of formation damage by asphaltene precipitation
title Desarrollo de un modelo fenomenológico y simulación numérica de la remediación química del daño de formación por precipitación de asfaltenos
spellingShingle Desarrollo de un modelo fenomenológico y simulación numérica de la remediación química del daño de formación por precipitación de asfaltenos
660 - Ingeniería química
620 - Ingeniería y operaciones afines
550 - Ciencias de la tierra
Asfaltenos
Disolución
Modelo fenomenológico
Remediación química
Daño de formación
Asphaltenes
Dissolution
Phenomenological model
Chemical remediation
Formation damage
title_short Desarrollo de un modelo fenomenológico y simulación numérica de la remediación química del daño de formación por precipitación de asfaltenos
title_full Desarrollo de un modelo fenomenológico y simulación numérica de la remediación química del daño de formación por precipitación de asfaltenos
title_fullStr Desarrollo de un modelo fenomenológico y simulación numérica de la remediación química del daño de formación por precipitación de asfaltenos
title_full_unstemmed Desarrollo de un modelo fenomenológico y simulación numérica de la remediación química del daño de formación por precipitación de asfaltenos
title_sort Desarrollo de un modelo fenomenológico y simulación numérica de la remediación química del daño de formación por precipitación de asfaltenos
dc.creator.fl_str_mv Olaya Marín, Guiber
dc.contributor.advisor.spa.fl_str_mv Benjumea Hernández, Pedro Nel
Mejía Cárdenas, Juan Manuel
dc.contributor.author.spa.fl_str_mv Olaya Marín, Guiber
dc.contributor.corporatename.spa.fl_str_mv Universidad Nacional de Colombia - Sede Medellín
dc.subject.ddc.spa.fl_str_mv 660 - Ingeniería química
620 - Ingeniería y operaciones afines
550 - Ciencias de la tierra
topic 660 - Ingeniería química
620 - Ingeniería y operaciones afines
550 - Ciencias de la tierra
Asfaltenos
Disolución
Modelo fenomenológico
Remediación química
Daño de formación
Asphaltenes
Dissolution
Phenomenological model
Chemical remediation
Formation damage
dc.subject.proposal.spa.fl_str_mv Asfaltenos
Disolución
Modelo fenomenológico
Remediación química
Daño de formación
dc.subject.proposal.eng.fl_str_mv Asphaltenes
Dissolution
Phenomenological model
Chemical remediation
Formation damage
description En esta tesis se presenta el desarrollo de un modelo fenomenológico para la remediación química del daño de formación por precipitación de asfaltenos. Se estableció el modelo matemático de la fenomenología que se presenta al inyectar tratamientos químicos a un yacimiento con el fin de revertir las pérdidas de porosidad y permeabilidad. Se realizaron pruebas de disolución de asfaltenos en solventes puros y en mezclas en tolueno, xileno y quinolina; obteniendo hasta el 85% de disolución en tolueno en concentraciones de 100 ppm. Se encontró que no hay sinergia entre solventes, dispersantes y surfactantes en la disolución. Con tratamientos comerciales se encontró sinergias entre el xileno y el solvente mutual. Además, se validó el modelo con datos de laboratorio con pruebas cinéticas de disolución de asfaltenos en tratamientos químicos y pruebas de desplazamiento de fluidos tratados con la remediación en núcleos.
publishDate 2020
dc.date.accessioned.spa.fl_str_mv 2020-12-18T22:26:18Z
dc.date.available.spa.fl_str_mv 2020-12-18T22:26:18Z
dc.date.issued.spa.fl_str_mv 2020-08-30
dc.type.spa.fl_str_mv Documento de trabajo
dc.type.driver.spa.fl_str_mv info:eu-repo/semantics/workingPaper
dc.type.version.spa.fl_str_mv info:eu-repo/semantics/acceptedVersion
dc.type.coar.spa.fl_str_mv http://purl.org/coar/resource_type/c_8042
dc.type.content.spa.fl_str_mv Text
dc.type.redcol.spa.fl_str_mv http://purl.org/redcol/resource_type/WP
format http://purl.org/coar/resource_type/c_8042
status_str acceptedVersion
dc.identifier.citation.spa.fl_str_mv Olaya-Marín, G. Desarrollo de un modelo fenomenológico y simulación numérica de la remediación química del daño de formación por precipitación de asfaltenos. 2020.
dc.identifier.uri.none.fl_str_mv https://repositorio.unal.edu.co/handle/unal/78730
identifier_str_mv Olaya-Marín, G. Desarrollo de un modelo fenomenológico y simulación numérica de la remediación química del daño de formación por precipitación de asfaltenos. 2020.
url https://repositorio.unal.edu.co/handle/unal/78730
dc.language.iso.spa.fl_str_mv spa
language spa
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spelling Atribución-NoComercial-SinDerivadas 4.0 InternacionalAtribución-NoComercial-SinDerivadas 4.0 InternacionalDerechos reservados - Universidad Nacional de ColombiaAcceso abiertohttp://creativecommons.org/licenses/by-nc-nd/4.0/info:eu-repo/semantics/openAccesshttp://purl.org/coar/access_right/c_abf2Benjumea Hernández, Pedro Nel41199880-ae6a-4335-b958-ee823ebe5509-1Mejía Cárdenas, Juan Manuelb4e18ab6-066b-4890-a2fd-7c244d070797-1Olaya Marín, Guiberd049848a-14fa-4edb-9365-61f6c080e554600Universidad Nacional de Colombia - Sede Medellín2020-12-18T22:26:18Z2020-12-18T22:26:18Z2020-08-30Olaya-Marín, G. Desarrollo de un modelo fenomenológico y simulación numérica de la remediación química del daño de formación por precipitación de asfaltenos. 2020.https://repositorio.unal.edu.co/handle/unal/78730En esta tesis se presenta el desarrollo de un modelo fenomenológico para la remediación química del daño de formación por precipitación de asfaltenos. Se estableció el modelo matemático de la fenomenología que se presenta al inyectar tratamientos químicos a un yacimiento con el fin de revertir las pérdidas de porosidad y permeabilidad. Se realizaron pruebas de disolución de asfaltenos en solventes puros y en mezclas en tolueno, xileno y quinolina; obteniendo hasta el 85% de disolución en tolueno en concentraciones de 100 ppm. Se encontró que no hay sinergia entre solventes, dispersantes y surfactantes en la disolución. Con tratamientos comerciales se encontró sinergias entre el xileno y el solvente mutual. Además, se validó el modelo con datos de laboratorio con pruebas cinéticas de disolución de asfaltenos en tratamientos químicos y pruebas de desplazamiento de fluidos tratados con la remediación en núcleos.This thesis presents the development of a phenomenological model for chemical remediation of formation damage due to asphaltene precipitation. The mathematical model of the phenomenology that occurs when injecting chemical treatments into a reservoir was established to reverse the losses of porosity and permeability. Asphaltenes dissolution tests were carried out in pure solvents and in mixtures in toluene, xylene and quinoline, obtaining up to 85% of dissolution in toluene in concentrations of 100 ppm. It was found that there is no synergy between solvents, dispersants, and surfactants in the solution. Synergies between xylene and mutual solvent were found with commercial treatments. In addition, the model was validated with laboratory data with kinetic tests for dissolving asphaltenes in chemical treatments and fluid displacement tests treated with remediation in cores.Doctorado138application/pdfspa660 - Ingeniería química620 - Ingeniería y operaciones afines550 - Ciencias de la tierraAsfaltenosDisoluciónModelo fenomenológicoRemediación químicaDaño de formaciónAsphaltenesDissolutionPhenomenological modelChemical remediationFormation damageDesarrollo de un modelo fenomenológico y simulación numérica de la remediación química del daño de formación por precipitación de asfaltenosDevelopment of a phenomenological model and numerical simulation of the chemical remediation of formation damage by asphaltene precipitationDocumento de trabajoinfo:eu-repo/semantics/workingPaperinfo:eu-repo/semantics/acceptedVersionhttp://purl.org/coar/resource_type/c_8042Texthttp://purl.org/redcol/resource_type/WPMedellín - Minas - Doctorado en Ingeniería - Sistemas EnergéticosDepartamento de Procesos y EnergíaUniversidad Nacional de Colombia - Sede Medellín1. 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Energy and Fuels. 2015;29(3):1397-1406. doi:10.1021/ef502494dORIGINAL93370604.2020.pdf93370604.2020.pdfTesis de Doctorado en Ingeniería - Sistemas Energéticosapplication/pdf3318380https://repositorio.unal.edu.co/bitstream/unal/78730/5/93370604.2020.pdf9224ded43bfa80b1d766540fda1fb659MD55LICENSElicense.txtlicense.txttext/plain; charset=utf-83895https://repositorio.unal.edu.co/bitstream/unal/78730/7/license.txte2f63a891b6ceb28c3078128251851bfMD57CC-LICENSElicense_rdflicense_rdfapplication/rdf+xml; charset=utf-8811https://repositorio.unal.edu.co/bitstream/unal/78730/8/license_rdf217700a34da79ed616c2feb68d4c5e06MD58THUMBNAIL93370604.2020.pdf.jpg93370604.2020.pdf.jpgGenerated Thumbnailimage/jpeg5265https://repositorio.unal.edu.co/bitstream/unal/78730/9/93370604.2020.pdf.jpgbf10b0943b3cbde92bd96057754b181eMD59unal/78730oai:repositorio.unal.edu.co:unal/787302024-08-01 23:10:37.549Repositorio Institucional Universidad Nacional de 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GVyZWNob3MgZGUgYXV0b3IgcXVlIGNvbmxsZXZlIGxhIGRpc3RyaWJ1Y2nDs24gZGUgZXN0b3MgYXJjaGl2b3MgeSBtZXRhZGF0b3MuCkFsIGhhY2VyIGNsaWMgZW4gZWwgc2lndWllbnRlIGJvdMOzbiwgdXN0ZWQgaW5kaWNhIHF1ZSBlc3TDoSBkZSBhY3VlcmRvIGNvbiBlc3RvcyB0w6lybWlub3MuCg==

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