Barrier property determination and lifetime prediction by electrochemical impedance spectroscopy of a high performance organic coating

The anticorrosion performance of an Epoxy-Mastic organic coating was evaluated during continuous immersion in saline solution using electrochemical impedance spectroscopy (EIS). The typical parameters of pore resistance and charge transfer resistance were determined employing an equivalent electric...

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Autores:
Calderón Gutierrez, Jorge Andres
Bedoya Lora, Franky Esteban
Tipo de recurso:
Article of journal
Fecha de publicación:
2014
Institución:
Universidad Nacional de Colombia
Repositorio:
Universidad Nacional de Colombia
Idioma:
spa
OAI Identifier:
oai:repositorio.unal.edu.co:unal/72208
Acceso en línea:
https://repositorio.unal.edu.co/handle/unal/72208
http://bdigital.unal.edu.co/36681/
Palabra clave:
organic coatings
electrochemical impedance spectroscopy
water diffusion
delaminated area
failure time prediction
Rights
openAccess
License
Atribución-NoComercial 4.0 Internacional
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spelling Atribución-NoComercial 4.0 InternacionalDerechos reservados - Universidad Nacional de Colombiahttp://creativecommons.org/licenses/by-nc/4.0/info:eu-repo/semantics/openAccesshttp://purl.org/coar/access_right/c_abf2Calderón Gutierrez, Jorge Andresba457e7c-2b26-41dc-bc38-78f33013aab9300Bedoya Lora, Franky Estebane948e9d2-3ab0-4f38-bda4-e710eb1116973002019-07-03T14:59:33Z2019-07-03T14:59:33Z2014-01-22https://repositorio.unal.edu.co/handle/unal/72208http://bdigital.unal.edu.co/36681/The anticorrosion performance of an Epoxy-Mastic organic coating was evaluated during continuous immersion in saline solution using electrochemical impedance spectroscopy (EIS). The typical parameters of pore resistance and charge transfer resistance were determined employing an equivalent electric circuit. Constant phase elements (CPE) were used in order to determine fraction of water absorbed, mass diffusion, solubility and the swelling coefficients, as well as to predict the failure times of the coating. The results found by EIS measurements match very well with the high resistance to deterioration exhibited by the coating. It was also found that the excellent protection performance of the coating was mainly due to low water solubility and low permeability.application/pdfspaUniversidad Nacional de Colombia Sede Medellínhttp://revistas.unal.edu.co/index.php/dyna/article/view/37609Universidad Nacional de Colombia Revistas electrónicas UN DynaDynaDYNA; Vol. 81, núm. 183 (2014); 97-106 Dyna; Vol. 81, núm. 183 (2014); 97-106 2346-2183 0012-7353Calderón Gutierrez, Jorge Andres and Bedoya Lora, Franky Esteban (2014) Barrier property determination and lifetime prediction by electrochemical impedance spectroscopy of a high performance organic coating. DYNA; Vol. 81, núm. 183 (2014); 97-106 Dyna; Vol. 81, núm. 183 (2014); 97-106 2346-2183 0012-7353 .Barrier property determination and lifetime prediction by electrochemical impedance spectroscopy of a high performance organic coatingArtículo de revistainfo:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501http://purl.org/coar/resource_type/c_2df8fbb1http://purl.org/coar/version/c_970fb48d4fbd8a85Texthttp://purl.org/redcol/resource_type/ARTorganic coatingselectrochemical impedance spectroscopywater diffusiondelaminated areafailure time predictionORIGINAL37609-166625-1-SP.pdfapplication/pdf66862https://repositorio.unal.edu.co/bitstream/unal/72208/1/37609-166625-1-SP.pdf353fa9bda5148551353e722efb6ee170MD5137609-194754-1-PB.pdfapplication/pdf1023296https://repositorio.unal.edu.co/bitstream/unal/72208/2/37609-194754-1-PB.pdf571bed7991d1a72beeacc3a58f520078MD52THUMBNAIL37609-166625-1-SP.pdf.jpg37609-166625-1-SP.pdf.jpgGenerated Thumbnailimage/jpeg8237https://repositorio.unal.edu.co/bitstream/unal/72208/3/37609-166625-1-SP.pdf.jpg99a2851032d31f3cd8f34db246916aa0MD5337609-194754-1-PB.pdf.jpg37609-194754-1-PB.pdf.jpgGenerated Thumbnailimage/jpeg9610https://repositorio.unal.edu.co/bitstream/unal/72208/4/37609-194754-1-PB.pdf.jpg97cc48a7da2edcc31531eef8586397ffMD54unal/72208oai:repositorio.unal.edu.co:unal/722082023-06-22 23:03:51.619Repositorio Institucional Universidad Nacional de Colombiarepositorio_nal@unal.edu.co
dc.title.spa.fl_str_mv Barrier property determination and lifetime prediction by electrochemical impedance spectroscopy of a high performance organic coating
title Barrier property determination and lifetime prediction by electrochemical impedance spectroscopy of a high performance organic coating
spellingShingle Barrier property determination and lifetime prediction by electrochemical impedance spectroscopy of a high performance organic coating
organic coatings
electrochemical impedance spectroscopy
water diffusion
delaminated area
failure time prediction
title_short Barrier property determination and lifetime prediction by electrochemical impedance spectroscopy of a high performance organic coating
title_full Barrier property determination and lifetime prediction by electrochemical impedance spectroscopy of a high performance organic coating
title_fullStr Barrier property determination and lifetime prediction by electrochemical impedance spectroscopy of a high performance organic coating
title_full_unstemmed Barrier property determination and lifetime prediction by electrochemical impedance spectroscopy of a high performance organic coating
title_sort Barrier property determination and lifetime prediction by electrochemical impedance spectroscopy of a high performance organic coating
dc.creator.fl_str_mv Calderón Gutierrez, Jorge Andres
Bedoya Lora, Franky Esteban
dc.contributor.author.spa.fl_str_mv Calderón Gutierrez, Jorge Andres
Bedoya Lora, Franky Esteban
dc.subject.proposal.spa.fl_str_mv organic coatings
electrochemical impedance spectroscopy
water diffusion
delaminated area
failure time prediction
topic organic coatings
electrochemical impedance spectroscopy
water diffusion
delaminated area
failure time prediction
description The anticorrosion performance of an Epoxy-Mastic organic coating was evaluated during continuous immersion in saline solution using electrochemical impedance spectroscopy (EIS). The typical parameters of pore resistance and charge transfer resistance were determined employing an equivalent electric circuit. Constant phase elements (CPE) were used in order to determine fraction of water absorbed, mass diffusion, solubility and the swelling coefficients, as well as to predict the failure times of the coating. The results found by EIS measurements match very well with the high resistance to deterioration exhibited by the coating. It was also found that the excellent protection performance of the coating was mainly due to low water solubility and low permeability.
publishDate 2014
dc.date.issued.spa.fl_str_mv 2014-01-22
dc.date.accessioned.spa.fl_str_mv 2019-07-03T14:59:33Z
dc.date.available.spa.fl_str_mv 2019-07-03T14:59:33Z
dc.type.spa.fl_str_mv Artículo de revista
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url https://repositorio.unal.edu.co/handle/unal/72208
http://bdigital.unal.edu.co/36681/
dc.language.iso.spa.fl_str_mv spa
language spa
dc.relation.spa.fl_str_mv http://revistas.unal.edu.co/index.php/dyna/article/view/37609
dc.relation.ispartof.spa.fl_str_mv Universidad Nacional de Colombia Revistas electrónicas UN Dyna
Dyna
dc.relation.ispartofseries.none.fl_str_mv DYNA; Vol. 81, núm. 183 (2014); 97-106 Dyna; Vol. 81, núm. 183 (2014); 97-106 2346-2183 0012-7353
dc.relation.references.spa.fl_str_mv Calderón Gutierrez, Jorge Andres and Bedoya Lora, Franky Esteban (2014) Barrier property determination and lifetime prediction by electrochemical impedance spectroscopy of a high performance organic coating. DYNA; Vol. 81, núm. 183 (2014); 97-106 Dyna; Vol. 81, núm. 183 (2014); 97-106 2346-2183 0012-7353 .
dc.rights.spa.fl_str_mv Derechos reservados - Universidad Nacional de Colombia
dc.rights.coar.fl_str_mv http://purl.org/coar/access_right/c_abf2
dc.rights.license.spa.fl_str_mv Atribución-NoComercial 4.0 Internacional
dc.rights.uri.spa.fl_str_mv http://creativecommons.org/licenses/by-nc/4.0/
dc.rights.accessrights.spa.fl_str_mv info:eu-repo/semantics/openAccess
rights_invalid_str_mv Atribución-NoComercial 4.0 Internacional
Derechos reservados - Universidad Nacional de Colombia
http://creativecommons.org/licenses/by-nc/4.0/
http://purl.org/coar/access_right/c_abf2
eu_rights_str_mv openAccess
dc.format.mimetype.spa.fl_str_mv application/pdf
dc.publisher.spa.fl_str_mv Universidad Nacional de Colombia Sede Medellín
institution Universidad Nacional de Colombia
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