Estudio de los mecanismos de bombeo en sistemas de moléculas orgánicas fuertemente acopladas a campos de luz confinada

ilustraciones a color, diagramas, fotografías

Autores:
Rodríguez Martínez, Gina Tatiana
Tipo de recurso:
Fecha de publicación:
2023
Institución:
Universidad Nacional de Colombia
Repositorio:
Universidad Nacional de Colombia
Idioma:
spa
OAI Identifier:
oai:repositorio.unal.edu.co:unal/85550
Acceso en línea:
https://repositorio.unal.edu.co/handle/unal/85550
https://repositorio.unal.edu.co/
Palabra clave:
530 - Física::535 - Luz y radiación relacionada
530 - Física::539 - Física moderna
Compuestos orgánicos
Análisis espectral
Bombeo óptico
Espectros vibracionales
Espectroscopía molecular
Óptica cuántica
Organic compounds
Spectrum analysis
Optical pumping
Vibrational spectra
Molecular spectroscopy
Quantum optics
Molécula orgánica
Espectro de emisión
Microcavidades
EIT
Asistencia vibracional
Antiagrupamiento
Polarización
Acoplamiento fuerte
Organic molecule
Emission spectrum
Microcavities
EIT
Vibrational assistance
Anti-bunching
Polarization
Strong coupling
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Atribución-NoComercial-SinDerivadas 4.0 Internacional
id UNACIONAL2_b786352f45dcb31151c2937ad3803b95
oai_identifier_str oai:repositorio.unal.edu.co:unal/85550
network_acronym_str UNACIONAL2
network_name_str Universidad Nacional de Colombia
repository_id_str
dc.title.spa.fl_str_mv Estudio de los mecanismos de bombeo en sistemas de moléculas orgánicas fuertemente acopladas a campos de luz confinada
dc.title.translated.eng.fl_str_mv Study of the pumping mechanisms in organic molecules strongly coupled to confined light fields
title Estudio de los mecanismos de bombeo en sistemas de moléculas orgánicas fuertemente acopladas a campos de luz confinada
spellingShingle Estudio de los mecanismos de bombeo en sistemas de moléculas orgánicas fuertemente acopladas a campos de luz confinada
530 - Física::535 - Luz y radiación relacionada
530 - Física::539 - Física moderna
Compuestos orgánicos
Análisis espectral
Bombeo óptico
Espectros vibracionales
Espectroscopía molecular
Óptica cuántica
Organic compounds
Spectrum analysis
Optical pumping
Vibrational spectra
Molecular spectroscopy
Quantum optics
Molécula orgánica
Espectro de emisión
Microcavidades
EIT
Asistencia vibracional
Antiagrupamiento
Polarización
Acoplamiento fuerte
Organic molecule
Emission spectrum
Microcavities
EIT
Vibrational assistance
Anti-bunching
Polarization
Strong coupling
title_short Estudio de los mecanismos de bombeo en sistemas de moléculas orgánicas fuertemente acopladas a campos de luz confinada
title_full Estudio de los mecanismos de bombeo en sistemas de moléculas orgánicas fuertemente acopladas a campos de luz confinada
title_fullStr Estudio de los mecanismos de bombeo en sistemas de moléculas orgánicas fuertemente acopladas a campos de luz confinada
title_full_unstemmed Estudio de los mecanismos de bombeo en sistemas de moléculas orgánicas fuertemente acopladas a campos de luz confinada
title_sort Estudio de los mecanismos de bombeo en sistemas de moléculas orgánicas fuertemente acopladas a campos de luz confinada
dc.creator.fl_str_mv Rodríguez Martínez, Gina Tatiana
dc.contributor.advisor.spa.fl_str_mv Vinck Posada, Herbert
dc.contributor.author.spa.fl_str_mv Rodríguez Martínez, Gina Tatiana
dc.contributor.researchgroup.spa.fl_str_mv Superconductividad y Nanotecnología
Grupo de Óptica E Información Cuántica
dc.contributor.orcid.spa.fl_str_mv 0009-0001-4470-1381
dc.subject.ddc.spa.fl_str_mv 530 - Física::535 - Luz y radiación relacionada
530 - Física::539 - Física moderna
topic 530 - Física::535 - Luz y radiación relacionada
530 - Física::539 - Física moderna
Compuestos orgánicos
Análisis espectral
Bombeo óptico
Espectros vibracionales
Espectroscopía molecular
Óptica cuántica
Organic compounds
Spectrum analysis
Optical pumping
Vibrational spectra
Molecular spectroscopy
Quantum optics
Molécula orgánica
Espectro de emisión
Microcavidades
EIT
Asistencia vibracional
Antiagrupamiento
Polarización
Acoplamiento fuerte
Organic molecule
Emission spectrum
Microcavities
EIT
Vibrational assistance
Anti-bunching
Polarization
Strong coupling
dc.subject.lemb.spa.fl_str_mv Compuestos orgánicos
Análisis espectral
Bombeo óptico
Espectros vibracionales
Espectroscopía molecular
Óptica cuántica
dc.subject.lemb.eng.fl_str_mv Organic compounds
Spectrum analysis
Optical pumping
Vibrational spectra
Molecular spectroscopy
Quantum optics
dc.subject.proposal.spa.fl_str_mv Molécula orgánica
Espectro de emisión
Microcavidades
EIT
Asistencia vibracional
Antiagrupamiento
Polarización
Acoplamiento fuerte
dc.subject.proposal.eng.fl_str_mv Organic molecule
Emission spectrum
Microcavities
EIT
Vibrational assistance
Anti-bunching
Polarization
Strong coupling
description ilustraciones a color, diagramas, fotografías
publishDate 2023
dc.date.issued.none.fl_str_mv 2023
dc.date.accessioned.none.fl_str_mv 2024-01-31T14:02:53Z
dc.date.available.none.fl_str_mv 2024-01-31T14:02:53Z
dc.type.spa.fl_str_mv Trabajo de grado - Maestría
dc.type.driver.spa.fl_str_mv info:eu-repo/semantics/masterThesis
dc.type.version.spa.fl_str_mv info:eu-repo/semantics/acceptedVersion
dc.type.content.spa.fl_str_mv Text
dc.type.redcol.spa.fl_str_mv http://purl.org/redcol/resource_type/TM
status_str acceptedVersion
dc.identifier.uri.none.fl_str_mv https://repositorio.unal.edu.co/handle/unal/85550
dc.identifier.instname.spa.fl_str_mv Universidad Nacional de Colombia
dc.identifier.reponame.spa.fl_str_mv Repositorio Institucional Universidad Nacional de Colombia
dc.identifier.repourl.spa.fl_str_mv https://repositorio.unal.edu.co/
url https://repositorio.unal.edu.co/handle/unal/85550
https://repositorio.unal.edu.co/
identifier_str_mv Universidad Nacional de Colombia
Repositorio Institucional Universidad Nacional de Colombia
dc.language.iso.spa.fl_str_mv spa
language spa
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spelling Atribución-NoComercial-SinDerivadas 4.0 Internacionalhttp://creativecommons.org/licenses/by-nc-nd/4.0/info:eu-repo/semantics/openAccesshttp://purl.org/coar/access_right/c_abf2Vinck Posada, Herbertcb451c328e333b7d420c1effb3732257Rodríguez Martínez, Gina Tatiana82f2f5bab537b912340637362c092309Superconductividad y NanotecnologíaGrupo de Óptica E Información Cuántica0009-0001-4470-13812024-01-31T14:02:53Z2024-01-31T14:02:53Z2023https://repositorio.unal.edu.co/handle/unal/85550Universidad Nacional de ColombiaRepositorio Institucional Universidad Nacional de Colombiahttps://repositorio.unal.edu.co/ilustraciones a color, diagramas, fotografíasLas moléculas orgánicas presentan algunas ventajas en comparación con otros emisores ópticos debido a sus características particulares. Entre estas, se destaca la formación de grandes momentos dipolares, induciendo un acoplamiento fuerte con la luz de manera prácticamente inherente y generando notables energías de Rabí. Además, exhiben un amplio rango de emisión, son fácilmente escalables y se distinguen por su bajo costo de producción mediante métodos de síntesis utilizados. Estas propiedades hacen que las moléculas orgánicas sean especialmente atractivas para aplicaciones en tecnologías ópticas, contribuyendo tanto en el avance de la investigación científica como el desarrollo de dispositivos cuánticos. El objetivo de esta tesis consistió en estudiar la respuesta óptica de estos sistemas orgánicos cuando han sido sometidos a diferentes mecanismos de bombeo. Para ello, se modeló la molécula como un sistema de dos niveles, la cual estuvo inmersa en una microcavidad. Adicionalmente, se consideraron las vibraciones moleculares como un mecanismo disipativo que facilita la interacción entre la radiación y el sistema orgánico. Para describir el estado del sistema, se empleó la matriz densidad y se incorporaron los efectos de los mecanismos disipativos mediante la aplicación de la ecuación maestra en las aproximaciones de Born y Markov. Los cálculos numéricos se llevaron a cabo mediante el uso de la librería de Python: Qtip. Inicialmente, se llevó a cabo un análisis hamiltoniano para investigar la influencia de las constantes de acoplamiento, definiendo ası́ los parámetros necesarios para obtener diversos comportamientos de los estados vestidos del sistema. Posteriormente, mediante la aplicación de la teoría espectral en el sistema abierto, se determinó que los términos de asistencia vibracional redistribuyen las poblaciones del sistema, generando modificaciones en la emisión que resultan en la coalescencia o supresión de algunos picos. Además, se observó que el sistema puede funcionar como una fuente de fotones individuales y exhibe la propiedad adicional de generar fotones con polarización contraria al láser utilizado para su bombeo. Asimismo, se realizaron caracterizaciones de los espectros de emisión bajo diferentes mecanismos de bombeo, identificando las transiciones más relevantes. Por último, se propuso un modelo en el que la interacción tipo Förster induce transparencia electromagnética. (Texto tomado de la fuente)Organic molecules offer distinct advantages over other optical emitters due to their particular characteristics. One notable feature is the formation of large dipole moments, leading to strong coupling with light almost inherently and generating remarkable Rabi energies. Additionally, they exhibit a broad emission range, are easily scalable, and stand out for their cost-effectiveness through commonly used synthesis methods. These properties make organic molecules particularly appealing for applications in optical technologies, contributing to both the advancement of scientific research and the development of quantum devices. This thesis aimed to investigate the optical response of these organic systems when subjected to different pumping mechanisms. To achieve this, the molecule was modeled as a two-level system immersed in a microcavity. Additionally, molecular vibrations were considered as a dissipative mechanism facilitating the interaction between radiation and the organic system. To describe the system’s state, density matrix formalism was employed, and the effects of dissipative mechanisms were incorporated using the master equation in Born and Markov approximations. Numerical calculations were performed using the Python library Qutip. Initially, a Hamiltonian analysis was conducted to explore the influence of coupling constants, defining the necessary parameters to obtain various behaviors of the dressed states of the system. Subsequently, applying spectral theory in the open system determined that vibrational assistance terms redistributed the system’s populations, resulting in modifications to the emission that led to the coalescence or suppression of certain peaks. Moreover, it was observed that the system could operate as a source of individual photons and exhibited the additional property of generating photons with polarization opposite to the laser used for pumping. Characterizations of emission spectra under different pumping mechanisms were also performed, identifying the most relevant transitions. Finally, a model was proposed in which Förster-type interaction induces electromagnetic transparency.MaestríaMagíster en Ciencias - FísicaOptica cuánticaxvii, 109 páginasapplication/pdfspaUniversidad Nacional de ColombiaBogotá - Ciencias - Maestría en Ciencias - FísicaFacultad de CienciasBogotá, ColombiaUniversidad Nacional de Colombia - Sede Bogotá530 - Física::535 - Luz y radiación relacionada530 - Física::539 - Física modernaCompuestos orgánicosAnálisis espectralBombeo ópticoEspectros vibracionalesEspectroscopía molecularÓptica cuánticaOrganic compoundsSpectrum analysisOptical pumpingVibrational spectraMolecular spectroscopyQuantum opticsMolécula orgánicaEspectro de emisiónMicrocavidadesEITAsistencia vibracionalAntiagrupamientoPolarizaciónAcoplamiento fuerteOrganic moleculeEmission spectrumMicrocavitiesEITVibrational assistanceAnti-bunchingPolarizationStrong couplingEstudio de los mecanismos de bombeo en sistemas de moléculas orgánicas fuertemente acopladas a campos de luz confinadaStudy of the pumping mechanisms in organic molecules strongly coupled to confined light fieldsTrabajo de grado - Maestríainfo:eu-repo/semantics/masterThesisinfo:eu-repo/semantics/acceptedVersionTexthttp://purl.org/redcol/resource_type/TMP. 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Echeverry, “Interacción radiación-materia mediada por fonones en la electrodinámi- ca cuántica de cavidades.” Tesis doctoral, Universidad Nacional de Colombia, 2019.EstudiantesInvestigadoresMaestrosLICENSElicense.txtlicense.txttext/plain; charset=utf-85879https://repositorio.unal.edu.co/bitstream/unal/85550/3/license.txteb34b1cf90b7e1103fc9dfd26be24b4aMD53ORIGINAL1032458462.2023.pdf1032458462.2023.pdfTesis de Maestría en Ciencias - Físicaapplication/pdf9516075https://repositorio.unal.edu.co/bitstream/unal/85550/4/1032458462.2023.pdfa26e9bc248ee35fd27719d642b06f1b7MD54unal/85550oai:repositorio.unal.edu.co:unal/855502024-01-31 09:05:47.641Repositorio Institucional Universidad Nacional de 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