Estudio de la formación de nanoestructuras de carbono a partir de alquitrán de gasificación de biomasa

ilustraciones, diagramas

Autores:: Martínez Smit, Carlos David

Tipo de recurso:: Doctoral thesis

Fecha de publicación:: 2023

Institución:: Universidad Nacional de Colombia

Repositorio:: Universidad Nacional de Colombia

Idioma:: eng

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dc.title.spa.fl_str_mv	Estudio de la formación de nanoestructuras de carbono a partir de alquitrán de gasificación de biomasa
dc.title.translated.eng.fl_str_mv	Study of the formation of carbon nanostructures from biomass gasification tar
title	Estudio de la formación de nanoestructuras de carbono a partir de alquitrán de gasificación de biomasa
spellingShingle	Estudio de la formación de nanoestructuras de carbono a partir de alquitrán de gasificación de biomasa 660 - Ingeniería química 540 - Química y ciencias afines::547 - Química orgánica Carbón - Gasificación Coal gasification Biomasa Alquitranes Gasificación Pirólisis Nanoestructuras Carbonizado Biomass Tar Gasification Pyrolysis Carbon nanostructures Biochar
title_short	Estudio de la formación de nanoestructuras de carbono a partir de alquitrán de gasificación de biomasa
title_full	Estudio de la formación de nanoestructuras de carbono a partir de alquitrán de gasificación de biomasa
title_fullStr	Estudio de la formación de nanoestructuras de carbono a partir de alquitrán de gasificación de biomasa
title_full_unstemmed	Estudio de la formación de nanoestructuras de carbono a partir de alquitrán de gasificación de biomasa
title_sort	Estudio de la formación de nanoestructuras de carbono a partir de alquitrán de gasificación de biomasa
dc.creator.fl_str_mv	Martínez Smit, Carlos David
dc.contributor.advisor.none.fl_str_mv	Chejne Janna, Farid Bastidas Barranco, Marlon José
dc.contributor.author.none.fl_str_mv	Martínez Smit, Carlos David
dc.contributor.researchgroup.spa.fl_str_mv	Termodinámica Aplicada y Energías Alternativas
dc.contributor.orcid.spa.fl_str_mv	Martinez-Smit, Carlos
dc.contributor.cvlac.spa.fl_str_mv	Martínez Smit, Carlos David
dc.contributor.researchgate.spa.fl_str_mv	Martinez-Smit, Carlos
dc.contributor.googlescholar.spa.fl_str_mv	Martinez-Smit, Carlos
dc.subject.ddc.spa.fl_str_mv	660 - Ingeniería química 540 - Química y ciencias afines::547 - Química orgánica
topic	660 - Ingeniería química 540 - Química y ciencias afines::547 - Química orgánica Carbón - Gasificación Coal gasification Biomasa Alquitranes Gasificación Pirólisis Nanoestructuras Carbonizado Biomass Tar Gasification Pyrolysis Carbon nanostructures Biochar
dc.subject.lemb.none.fl_str_mv	Carbón - Gasificación Coal gasification
dc.subject.proposal.spa.fl_str_mv	Biomasa Alquitranes Gasificación Pirólisis Nanoestructuras Carbonizado
dc.subject.proposal.eng.fl_str_mv	Biomass Tar Gasification Pyrolysis Carbon nanostructures Biochar
description	ilustraciones, diagramas
publishDate	2023
dc.date.accessioned.none.fl_str_mv	2023-04-19T17:11:09Z
dc.date.available.none.fl_str_mv	2023-04-19T17:11:09Z
dc.date.issued.none.fl_str_mv	2023
dc.type.spa.fl_str_mv	Trabajo de grado - Doctorado
dc.type.driver.spa.fl_str_mv	info:eu-repo/semantics/doctoralThesis
dc.type.version.spa.fl_str_mv	info:eu-repo/semantics/acceptedVersion
dc.type.coar.spa.fl_str_mv	http://purl.org/coar/resource_type/c_db06
dc.type.content.spa.fl_str_mv	Text
dc.type.redcol.spa.fl_str_mv	http://purl.org/redcol/resource_type/TD
format	http://purl.org/coar/resource_type/c_db06
status_str	acceptedVersion
dc.identifier.uri.none.fl_str_mv	https://repositorio.unal.edu.co/handle/unal/83740
dc.identifier.instname.spa.fl_str_mv	Universidad Nacional de Colombia
dc.identifier.reponame.spa.fl_str_mv	Repositorio Institucional Universidad Nacional de Colombia
dc.identifier.repourl.spa.fl_str_mv	https://repositorio.unal.edu.co/
url	https://repositorio.unal.edu.co/handle/unal/83740 https://repositorio.unal.edu.co/
identifier_str_mv	Universidad Nacional de Colombia Repositorio Institucional Universidad Nacional de Colombia
dc.language.iso.spa.fl_str_mv	eng
language	eng
dc.relation.indexed.spa.fl_str_mv	RedCol LaReferencia
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dc.format.extent.spa.fl_str_mv	xiv, 108 páginas
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dc.publisher.spa.fl_str_mv	Universidad Nacional de Colombia
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dc.publisher.faculty.spa.fl_str_mv	Facultad de Minas
dc.publisher.place.spa.fl_str_mv	Medellín, Colombia
dc.publisher.branch.spa.fl_str_mv	Universidad Nacional de Colombia - Sede Medellín
institution	Universidad Nacional de Colombia
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spelling	Atribución-NoComercial 4.0 Internacionalhttp://creativecommons.org/licenses/by-nc/4.0/info:eu-repo/semantics/openAccesshttp://purl.org/coar/access_right/c_abf2Chejne Janna, Farid401f8232cbbed073cf4612ce7bc3b54bBastidas Barranco, Marlon José27a9fbf428fbf4b0e703dbbb5a210de9Martínez Smit, Carlos David9e17307197d1ad0667d53b3d107b16baTermodinámica Aplicada y Energías AlternativasMartinez-Smit, CarlosMartínez Smit, Carlos DavidMartinez-Smit, CarlosMartinez-Smit, Carlos2023-04-19T17:11:09Z2023-04-19T17:11:09Z2023https://repositorio.unal.edu.co/handle/unal/83740Universidad Nacional de ColombiaRepositorio Institucional Universidad Nacional de Colombiahttps://repositorio.unal.edu.co/ilustraciones, diagramasDurante la gasificación de la biomasa, se producen alquitranes junto con los gases. Estos compuestos pueden causar problemas operativos cuando se condensan, disminuyendo la eficiencia global del proceso. Se han estudiado muchos métodos para reducir o eliminar estos compuestos, siendo los más comunes las modificaciones del gasificador, los métodos de limpieza en húmedo y en seco, y el craqueo térmico o catalítico. El craqueo de estas moléculas produce más gases, pero pocos estudios se interesan por los depósitos de carbono formados, que en algunos casos pueden dar lugar a nanoestructuras de carbono. El presente trabajo propone una metodología que permite el aprovechamiento de estos compuestos para la formación de productos de valor agregado en sistemas de gasificación o pirólisis de biomasa. Se partió de un fraccionamiento para determinar el tamaño y tipo de moléculas presentes en las fracciones de los alquitranes. Asimismo, se plantea el uso de un catalizador soportado en el carbonizado que es subproducto de estos procesos termoquímicos de biomasa, para que al contacto con los volátiles o alquitranes se formen depósitos de carbono en él. Estas nuevas estructuras de carbono pueden aportar nuevas posibilidades para las tecnologías de gasificación y pirolisis de biomasa, lo que se puede traducir en un equilibrio técnico-económico y medioambiental de los procesos. (Textos tomado de la fuente)During biomass gasification, tars are produced along with the gases. These compounds can cause operational problems when they condense, decreasing the overall efficiency of the process. Many methods have been studied to reduce or eliminate these compounds, the most common being gasifier modifications, wet and dry-cleaning methods, and thermal or catalytic cracking. Cracking of these molecules produces more gases, but few studies are interested in the carbon deposits formed, which in some cases can give rise to carbon nanostructures. The present work proposes a methodology that allows the utilization of these compounds for the formation of value-added products in biomass gasification or pyrolysis systems. The starting point was a fractionation to determine the size and type of molecules present in the tar fractions. Also, the use of a catalyst supported on the carbonized by-product of these biomass thermochemical processes is proposed, so that upon contact with the volatiles or tars, carbon deposits are formed on it. These new carbon structures can provide new possibilities for biomass gasification and pyrolysis technologies, which can be translated into a techno-economic and environmental balance of the processes.DoctoradoDoctor en IngenieríaProcesos termoquímicos de biomasaÁrea curricular de Ingeniería Química e Ingeniería de Petróleosxiv, 108 páginasapplication/pdfengUniversidad Nacional de ColombiaMedellín - Minas - Doctorado en Ingeniería - Sistemas EnergéticosFacultad de MinasMedellín, ColombiaUniversidad Nacional de Colombia - Sede Medellín660 - Ingeniería química540 - Química y ciencias afines::547 - Química orgánicaCarbón - GasificaciónCoal gasificationBiomasaAlquitranesGasificaciónPirólisisNanoestructurasCarbonizadoBiomassTarGasificationPyrolysisCarbon nanostructuresBiocharEstudio de la formación de nanoestructuras de carbono a partir de alquitrán de gasificación de biomasaStudy of the formation of carbon nanostructures from biomass gasification tarTrabajo de grado - Doctoradoinfo:eu-repo/semantics/doctoralThesisinfo:eu-repo/semantics/acceptedVersionhttp://purl.org/coar/resource_type/c_db06Texthttp://purl.org/redcol/resource_type/TDRedColLaReferenciaMartinez-Smit, C.; Bastidas-Barranco, M.; Chejne, F.; García-Pérez, M. 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Y. 2019, 148, 258–266. https://doi.org/10.1016/j.carbon.2019.03.077Poligeneración: La Biomasa, precursor para nuevos productos de valor agregado y oportunidad para garantizar un sistema eléctrico confiable y sustentableMincienciasUniversidad Nacional de ColombiaUniversidad de La GuajiraEstudiantesInvestigadoresPúblico generalTHUMBNAIL8358492.2023.pdf.jpg8358492.2023.pdf.jpgGenerated Thumbnailimage/jpeg5067https://repositorio.unal.edu.co/bitstream/unal/83740/4/8358492.2023.pdf.jpg23e3b03de96320844fa4304acf0a0a39MD54ORIGINAL8358492.2023.pdf8358492.2023.pdfTesis de Doctorado en Ingeniería - Sistemas Energéticosapplication/pdf3499456https://repositorio.unal.edu.co/bitstream/unal/83740/2/8358492.2023.pdf040e87bdfcfc7680bfdba567fd59a06fMD52LICENSElicense.txtlicense.txttext/plain; charset=utf-85879https://repositorio.unal.edu.co/bitstream/unal/83740/3/license.txteb34b1cf90b7e1103fc9dfd26be24b4aMD53unal/83740oai:repositorio.unal.edu.co:unal/837402023-08-02 23:03:56.833Repositorio Institucional 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Colombiarepositorio_nal@unal.edu.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Estudio de la formación de nanoestructuras de carbono a partir de alquitrán de gasificación de biomasa

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